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By Harry Schnabel, Mitchell L. Fong, Douglas R. Jenevein, Thomas S. Lee

"The Warm Springs Extension (WSX) is one of a series of projects that will eventually extend the Bay Area Rapid Transit System (BART) from Fremont to San Jose, California. A cut and cover tunnel was used for a portion of the extension that runs through Fremont Central Park to minimize the impacts that an at-grade railway would have on the Park. A cement deep soil mix (CDSM) wall was selected by the engineer as the preferred method of providing structural support and groundwater cut-off for a portion of the tunnel where it passes through an important aquifer and near Lake Elizabeth. In addition to the CDSM wall, a jet grout plug was constructed at the base of the tunnel to provide a complete groundwater cut-off.This paper will discuss the unique quality assurance and quality control measures taken for the soil mix wall and jet grout plug as well as the methods used to repair leaks and mitigate water seepage through the exposed wall and grout plug.PROJECT DESCRIPTIONThe Bay Area Rapid Transit (BART) Warm Springs Extension (WSX) project is located south of the existing Fremont BART station extending 8.9-km (5.4 miles) to Warm Springs District in Fremont, California. The WSX project has been divided into two contracts with different delivery methods. In order to minimize impacts to Fremont Central Park, a subway was selected at this portion of the alignment under a conventional design/bid/build contract.The Fremont Central Park Subway (FCPS) which begins on the south side of Walnut Ave and ends just north of Paseo Padre Parkway and is about 2.3-km (1.4 miles) long. Fig. 1 shows the entire WSX and the FCPS project. The FCPS contract consists of a cut-and-cover subway box, subway transition structures, ventilation structures and a section of which transverses Lake Elizabeth (a man-made lake). The geologic conditions consist of fill (sand, silt, clay and construction debris), Young Alluvium (clay and silt), Basin Deposits (clay, silt, and sand), and Older Alluvium (sand and gravel) as shown in Fig. 2.HYDROGEOLOGY OF THE PROJECT SITEThe FCPS is dominated by two geologic features - the Hayward Fault and the Above Hayward Fault (AHF) aquifer. The AHF aquifer provides a significant source and storage of water for the local water district. The underground subway will penetrate this aquifer and is up to 11m (36 ft) below the groundwater table. No groundwater was allowed to be pumped during construction of the subway box by Alameda County Water District (ACWD). To facilitate excavation for the subway box, temporary cut-off walls and a grout plug were designed to retain and resist high differential hydraulic pressure. The following section describes the selection of a deep soil mixing method for water cutoff. Design of the grout plug has been described in Lee, et al., 2011 and Fong and Lee, 2009, and is not the focus of this paper."

Jan 1, 2015

By Michael Forrest, John Roadifer, Glen Gorski

"The Calaveras Dam Replacement Project (CDRP) requires large disposal sites to store excess excavated materials that could not be utilized for dam construction. Because of access restrictions during design, the disposal site rockfill toe dike area at the edge of the reservoir could not be explored to evaluate soil conditions. As such, the site had to be explored as part of the construction contract. Exploration revealed very soft clay and loose silty sand up to 40 feet thick that would not be able to support the rockfill dike at the toe of a large disposal site fill. Several alternatives were evaluated to stabilize these soils. Based on constructability, cost and risk considerations, cement deep soil mixing (CDSM) was selected as the preferred method of soil stabilization. The challenge was to design and construct the CDSM stabilization to minimize construction delays. A joint effort by the design engineer, construction manager and contractor achieved CDSM stabilization in about three months, from design through completion of construction. A rigorous quality control program included compression testing of both wet grab and cored soil cement samples to demonstrate that specified strength requirements were being achieved.INTRODUCTIONDisposal Site 3 (Figure 1) is one of the primary CDRP disposal sites having a height of 240 feet and a storage capacity of about 2,500,000 cubic yards. An approximately 40-foot-high rockfill dike at the base of the disposal site provides an erosion resistant toe for the disposal site. The rectangular foundation area shown in red was not able to be investigated during design because of access restrictions."

Jan 1, 2015

By D. H. Stonehouse

Of the f ive Canadian cement producing regions- Atlantic, Quebec, Ontario, Prairie and Pacific-Ontario has the greatest capacity and normally produces the most cement. However, during the last 5 years the greatest activity within the industry in Canada has been in the Prairie and Pacific regions where major capacity increases have taken place. Most Canadian cement companies produce normal Portland, high-earlystrength Portland and sulphate resisting Portland cements. Some companies also manufacture moderate Portland cement, and low-heat-of-hydration Portland cement. Escalating energy costs highlight the need for technology research into more energy-efficient equipment for the energy-intensive cement industry. The industry is well integrated and plants are well situated to support construction in Canada. Expansion into the United States has become common during the past decade.

Jan 1, 1984

By I. Spector

A SHORTAGE of cement in the Prairie Provinces, together with an aggressive policy on the part of the Saskatchewan Government in bringing new industries to the province, combined to create a favourable set of conditions for the establishment of Saskatchewan's first cement plant on the outskirts of Regina. Built by Saskatchewan Cement Corporation Limited, this single-kiln plant, tl1e latest addition to cement producers on the Prairies, began operations in the Fall of 1956. Location of the plant followed the trend of building cement manufacturing facilities in market areas rather than at raw material sources. In 1957, all assets of the Corporation were taken over by Inland Cement Company Limited and the plant and quarry now operate as Saskatchewan Cement Company, an Inland division. The Regina plant's production makes up approximately eleven per cent of the productive capacity of all plants in the Prairie Provinces. At present, two types of cement are manufactured -normal portland and sulphate resisting.

Jan 1, 1960

By C. F. Clausen

"Cement" means binding agent or glue. It is derived from the Latin word "Caementum," the name of a limestone, chips of which were used in mortar more than 2,000 years ago in Italy. During the middle ages "cement" or "cement" generally denoted mortar. Today it means any binding material. The Thomas Register lists nearly 200 classifications for "cement" including automobile cement, household cement, rubber cement, etc. The material most commonly associated with this word, however, is portland cement which, when mixed with water and allowed to hydrate, is a ceramic binding material used to cement aggregates (crushed stone, gravel and sand) together in "concrete," the most universally used building material of today. It is estimated that more tons of concrete are used annually than all other building materials put together including steel, lumber, gypsum, bricks, tiles, aluminum and glass. Its use in foundations, building construction, sanitary work, dams, railroads, and highways, makes it difficult to conceive of modem civilization without concrete. A survey made in October 1955 showed the following uses of portland cement: [Percent Highways20 Nonresidential buildings20 Residential buildings15 Military construction10 Sewer and water works8 Public utilities10 Other (conservation, farm, and maintenance and repair)17 100] As of today, the percentage for highways is probably even higher. Ceramic binding materials have unquestionably been used in construction work for thousands of years. The mortar between the blocks of the great pyramids was calcined gypsum (plaster of paris). The use of calcined and slaked limestone goes back earlier than the Roman Empire. Gypsum, however, is relatively soft, and common lime mortar is not "hydraulic," i.e., it does not harden under water. The Greeks and Romans discovered later that an addition of a finely divided active siliceous material (Santorin earth or Pozzolana) would react with slaked lime to form a stronger, and hydraulic, cement. The Appian Way in Italy, Colosseum, and the great Aqueducts built by the Romans were made with this type cement, and some of these structures are still in existence today. However, not until 1756 did some serious research result in the development of better cements. In that year the English engineer, John Smeaton produced a stronger cement by burning a limestone containing considerable proportions of clayey impurities. Other investigations and improvements were made by Bryan Higgins, Bergmann, Joseph Parker, L. J. Vicat, J. F. John, James Frost, and I. C. Johnson.2 Traditionally, but perhaps unfairly to others, the invention of the prototype of today's portland cement is credited to the English mason Joseph Aspdin who in 1824 obtained a patent and gave the product its name, because in color the mortar produced from it resembled a natural building stone obtained from the British Isle of Portland. The contributions of Johnson and Aspdin were primarily the important step of preparing a synthetic mixture of lime and clay without depending on raw materials found in nature which might contain such elements in desirable proportions. However, even these early

Jan 1, 1960

By W. M. Myers

THE hydraulic properties exhibited by the calcination products of certain limestones were recognized at an early datemore than 2000 years ago. It was known that calcined limestone with the addition of other minerals would react with water and produce an insoluble and stable product. This material could be cast in desired forms or could be used as a cement for the unification of other materials in large masses or for bonding brick or masonry structures. Cements are essentially mineral glues and it is their ability to unify other materials plus their fluidity when first mixed with water, enabling the mass to assume any desired shape, that has made them so extraordinarily useful to modern industry. Like other glues, cements do not exhibit their maximum strength when used alone and only when mixed with proper aggregates do their optimum properties appear. The resulting concrete, a mixture of cement, mineral aggregates and frequently of reinforcing steel, exhibits the most desirable properties of the individual constituents with regard to tensile strength, stability and permanence. The speed with which such mixtures can be -prepared and installed in place with mechanical equipment has facilitated their adoption by the engineering profession concerned with the construction industries. The development and application of improved methods of manufacture have resulted in such economies that the finished product can be sold at a remarkably low price. In addition, the necessary raw materials are of such common occurrence and wide geographic distribution that the manufacture of cement was established in 34 of the 48 states by 1946. Plants under construction will add to this number. In recent years the industry has been characterized by the development of a number of new cements designed to possess special properties essential for use in unusual environments. These have introduced the use of some new raw materials and also have complicated the processes of manufacture. In the following pages, the major varieties of cement of commercial importance are treated in the chronological order of their appearance on the market.

Jan 1, 1949

By W. H. Andrews

THE constantly increasing consumption of Portland cement in the State makes the above subject of partlcular interest at this time. The increasing demand is due to the rapid settling of the country and the fact that new uses are being found frequently for the above named commercial article. The industry is one that is bound to grow as the population increases, and this being the case, it may be well ,it this time to consider briefly- the matter of the chemical and physical com-position of proper raw materials. A cement mixture is one that contains approximately 75 per cent. carbonate of lime, 15 per cent. Silica, and 5 to 7 per cent. alumina, and iron oxides; the other elements being magnesium carbonate and small quantities of the rarer elements general associated with limestone deposits. It call be readily seen from the above composition that it is possible to build up this mixture from a number of different materials. First.-A rock high in carbonate of lime can be mixed with clay or shale in such proportions as to bring about the desired composition ; the chief difficulty in the building up of such a mixture is that it is hard to find a clay or shale in which the silica-alumina, ratio lies .between 4 to 1 and 3 to 1 and at the same time shows physical characteristics which will make certain its adaptability to the practical manufacture of Portland cement. Very often clays or shales are found which are right chemically but contain large quantities of grit or free silica. Such clays or shale must be ground to extreme fineness in the mixture in order to make the silica and alumina combine with the lime when the mixture is burned. On the other hand, clays or shales are often found that have the proper physical characteristics but in which the amount of alumina, is too great.

Jan 9, 1913

By H. R. Shidel

THIS paper summarizes the results obtained from the preliminary cementing of wells in an effort to cut off the bottom water. The object of this work was two-fold: (1) To prevent the oil sand from becoming flooded. (2) To plug off bottom water, thereby preserving the individual well and reclaiming production. Valuable suggestions and help have been given by the following named: Messrs. Kyle and La Velle, of the U. S. Bureau of Mines; Magnolia Petroleum Co.; Freed Oil and Gas Co. The cementing work was carried out under the personal supervision of L. J. Snyder. In an unpublished paper on the "Water Problem in the Augusta Field," S. K. Clark reaches the following conclusions: (1) That the great amount of water present is bottom water, occurring in the Varner sand, the main producing or the 2500-ft. horizon. (2) That the only striking connection between structure and water is in the area of the marked fault on the Ralston, E. C. Varner, and F. Varner leases in sections 8, 9, 16 and 17. (3) That the oil occurs in porous streaks, generally separated by fine-grained, well cemented sand, which is barren. Possibly two, or three such pay streaks may be found. That under a pay, fine-grained sand occurs, which is presumably barren at the time of drilling, but soon reveals water. The writer takes partial exception to the last point, because well defined shale, slate, lime, or hard sand breaks have been encountered in a great many cases, separating the pay streaks under which water is often found. This is not an invariable occurrence, as cases have been noted when the oil has been followed immediately by water in the same stratum. In an effort to overcome the water menace, the following methods of plugging were tried: (1) Plugging with wood, lead, and limit plugs. (2) Plugging with sand pumpings.

Jan 10, 1918

By Malcolm J. Robinson

Over 80% of Australia's population lives within 200 km of the coast, 70% in 10 major coastal cities. Potential cement raw materials are widely distributed but deposit size, quality, transport, market and environmental considerations are important in determining economic value. Major production locations are in a variety of geological environments ranging from Lower Paleozoic crystalline limestones to Tertiary and Recent polyzoal limestones and limesands, both onshore and offshore. Raw material transportation is by road, rail, sea, aerial ropeway and pipeline; road/rail transportation of the finished product is traditional but movement by sea of clinker and cement is increasingly a feature of the industry.

Jan 1, 1982

By Pollard D. M

The effects of pH, temperature and the form of zinc used on the kinetics of cementation of cadmium from process liquors were investigated. Batch tests were conducted in stirred beakers, and the cementation reaction was found to be first order controlled. The rate controlling step was thought to be the diffusion of zinc ions from the zinc surface to the bulk solution. The pH was found to have a significant effect when using Prime Western zinc or zinc dust. High reaction rates were favoured at low pH levels and a minimum rate was observed at a pH level of approximately 5 to 5.5. The pH was found to have little effect when using high grade and cathode zinc. The reaction rates increased significantly with increasing temperature; a reaction temperature of 55¦C resulted in almost complete removal of zinc from solution. Effective cementation rates were only acheived with cathode zinc after pickling in acid. The nature and specification of zinc used determined the cementation rate of cadmium, resulting in the following order: 1. Zinc dust 2. Prime Western zinc at pH 3 3. High Grade zinc at pH 3 4. Pickled cathode zinc 5. Prime Western zinc at pH 3 6. High Grade zinc at pH 3 7. Cathode zinc "as received".

Jan 1, 1989

By A. A. Zatout, G. H. Sedahmed, T. M. Zewail, M. H. Abdel-Aziz, B. S. Ibrahim, E-S. Z. El-Ashtoukhy

In this work, the possibility of intensifying the cementation process in stirred vessels was studied by using the perforated baffles as turbulence promoters; the cementation reaction of Cu+2 on Zn was selected as a model. Zn was used in the form of a sheet lining the inner wall of an agitated vessel. Parameters considered are initial concentration of Cu+2, solution temperature, impeller rotation speed, and impeller geometry. Within the present range of parameters studied, the rate of cementation was found to increase with increasing initial concentration of Cu+2, solution temperature, and impeller rotation speed. At the same rotational speed, a flat turbine gave a higher rate of cementation than a 45° pitched turbine. The present suggested that baffles’ geometry gave superior performance in terms of mass transfer of copper cementation compared to the conventional baffle geometry. All parameters that affect the rate of cementation were correlated in the form of dimensionless equations suitable for the design and performance prediction of the agitated vessel. Potential applications of the obtained results in the field of hydrometallurgical processes and wastewater treatment were discussed.

Jan 12, 2021

A rotating disc geometry was used to provide a uniformly accessible surface for a kinetic study of copper cementation with zinc in sulphate solution. For copper concentrations of the order of 10 p.p.m., a porous, adherent deposit is formed on the zinc surface and this has a significant influence on the reaction rate. When the specific mass of deposit is less than about O· 35 mg/cm2 the surface may be considered as smooth and the rate is described by simple convective counter diffusion of zinc and copper ions through a laminar diffusion boundary layer to the deposit-solution interface. In the presence of additional deposit, the diffusional mass transfer rate is increased by increased surface roughness.The rate under these conditions is first order, with the degree of enhancement independent of further increases in the specific deposit mass. The enhancement in rateis, however, directly related to the initial mass flux and the species involved in the reaction.Preliminary work showed the same mechanism to apply to cementation from chloride solution, solutions of high zinc concentration, and cementation of copper with iron..

Jan 1, 1970

By Henrique Gobbi Soares

Peças fabricadas em aos inoxidáveis austeníticos permanecem íntegras em ambientes corrosivos severos, ambientes industriais, marítimos, na presença de ácidos e gases oxidantes. Entretanto, quando o sua a aplicação além de requerer resistência à corrosão relativamente alta, necessite de boas propriedades em termos de resistência ao desgaste sua utilização se torna restringida. Este trabalho teve como objetivo o estudo da melhoria dessas propriedades restritivas e o aprimoramento da técnica, através do aumento da dureza superficial dos aços inoxidáveis austeníticos AISI 316, utilizando cementação a plasma frio. Para tanto foram propostos tratamentos na temperatura de 350°C, 5hrs, 340 Pa, variando a composição do gás de tratamento. As análises dos produtos de cementação foram feitas utilizando técnicas de caracterização estrutural, difração de raios-X, medidas de perfis de dureza e ensaios microabrasivos. Todas as condições apresentaram melhorias na resistência ao desgaste e na dureza, entretanto o aumento da concentração de metano na atmosfera de trabalho promoveu a formação de fuligem, promovendo regressão das propriedades conforme se elevava a concentração de metano nos processos.

Oct 30, 2017

By Baogui Yang, Jie Yang, Anthony Iannacchione

"The cemented coal gangue-fly ash backfill technique (CGFB) has commonly been used to control subsidence damage caused by underground coal mining. This paper discusses the CGFB backfilling process used at the Xin-Yang coal mine, Shanxi Province, China. A general description of the components of the CGFB are provided. The reaction of the strata to the backfilling process is simulated with a scaled physical model based on the Xin-Yang conditions and verified with subsidence points on the surface. With the help of the cemented filling materials, the CGFB produces only a slight bend to the overburden roof strata over the longwall panel. Physical models were constructed at the China University of Mining and Technology, Beijing, to simulate actual conditions. The modeling results show minor fracture distribution in the overlying strata and lower abutment pressure development within the backfilling area. The effectiveness of the CGFB technique is verified by a reduction in the vertical surface subsidence measured above the backfilled area.INTRODUCTIONUnderground longwall mining is the most efficient underground means to recover coal resources and is used widely in China, the US, Australia, and Europe. However, this type of mining has introduced some serious environmental impacts. Perhaps the most significant environmental issues are the surface and groundwater impacts associated with the formation of the subsidence basin (Bell and Donnelly, 2006). Backfill technology has been used for years to mitigate subsidence impact. Simply speaking, the backfilling technique places filling materials into the void left from the extraction of coal. When this material is placed within the gob, it is capable of partially supporting the overburden until a new equilibrium is reached. Essentially, the backfill material inhibits crack development and expansion caused by the strata movement and mitigates damaging ground deformations.The cemented gangue-fly ash backfill (CGFB) is one type of novel backfill technology, consisting of cement, coal gangue, fly ash, water, and additives in varying concentrations. The CGFB is mixed on the surface, pumped underground through a pipeline as a slurry, and placed in the void behind the longwall shield under the protection of specially designed hydraulic supports."

Jan 1, 2018

By M Dorricott

This paper describes the design, construction and performance of sill pillars using cemented development mullock at the Crusader Gold Mine. The orebody is some 35 m - 60 m in length, 5 m - 8 m wide, dipping at 60¦ - 85¦ and plunging at about 40¦ to the north. It is accessed via a footwall decline. The ore occurs at the contact between basalt and ultramafic. This contact is characterised by shearing and alteration; and is prone to unraveling failure. The cut and fill mining method at Crusader extracts 25 m high ore blocks in four flat back lifts and one 8 m thick crown pillar. To enable full recovery of these high-grade crown pillars with minimal dilution, a 5 m thick sill pillar is constructed using cemented rock fill (CRF), after mining of the bottom two lifts in each block. Uncemented development mullock is used as rock fill (RF) for subsequent lifts. Development mullock and cement/water slurry is mixed underground to produce CRF. The fill is transported to the stope in LHDs and dumped on the floor. The sill pillar is advanced progressively, with compaction provided by the loader driving over the previously placed fill. Old jumbo rods are installed as shear pins along the flat dipping hangingwall to reduce the risk of rotational failure of the pillar. A fan of cable bolts is installed into the hangingwall to prevent unraveling failure in the sheared ground. Buffer blasting is used to minimise damage to the CRF sill pillar when the crown pillar below is extracted. At the time of writing, extraction of the crown pillar underneath the CRF has taken place at the 930 stope. The crown pillar was extracted successfully with dilution from the backfill and hangingwall minimised and 98 per cent of the gold recovered. This compares with pillars that were mined beneath uncemented backfill where only 70 per cent of the gold was recovered and where there was significant dilution from the backfill and from hangingwall failures. Where no CRF was placed, there were also numerous production delays caused by large rocks from the hangingwall blocking the stope brow.

Jan 1, 2002

By J Szymanski, S Planeta

In pursuit of optimising the cemented rockfill system fragmentation of the aggregate, while travelling through the surface-to-underground aggregate transport raise, was investigated and a æfines estimationÆ equation was determined. When used with the rockfill strength estimation equation, the fines estimation equation enables an accurate estimation of the compressive strength to be derived theoretically. Optimum fill raise orientation was examined and recommendations are given depending on the varying stope dimensions. If the maximum dimension of the stope is less than 30.5 m (100 ft), a single, centrally located fill raise will suffice. However, as the stope dimensions increase, the number and orientation of the fill raises becomes more complicated and each stope must be examined on an individual basis.

Jan 1, 1998

By T. Emery, D. Sweet, J. Bourgeois, B. Seymour, D. Porter

Cemented rockfill (CRF) is being used to backfill primary and secondary stopes at the Eagle Mine, an underground nickel and copper mine operated by Lundin Mining. National Institute for Occupational Safety and Health (NIOSH) researchers from the Spokane Mining Research Division (SMRD) are conducting cooperative research with the mine staff to determine if the size of a CRF sample affects its measured strength properties. Based on previous research by NIOSH, cylindrical samples of CRF ranging in size from six to eighteen inches in diameter were cast at the mine and cured underground. The samples were later transported to the SMRD laboratory and the Michigan Technological University where tests were conducted to determine the strength and elastic properties of the CRF. To further analyze the relationship between backfill density and compressive strength, different ASTM International compaction techniques were used to cast the samples. For comparison, tests were also conducted on in-situ core samples that were drilled from a stope which had been backfilled with the same CRF mix. The data collected from this study not only improves our understanding of CRF in-situ properties but also helps optimize Quality Assurance/Quality Control (QA/QC) methods for backfill preparation and testing.

Feb 1, 2023

By J. McCreedy

"The addition of Portland cement to hydraulic sand fill has resulted in the production of stable and self-supporting cemented sand fill. The use of cemented fill in the mines of The International Nickel Company has resulted in substantial economies in timber requirements, de-creased dilution of ore and greater flexibility in mining methods.Coupled with special mining techniques, it has permit-ted mining by both cut-and-fill and shrinkage stoping methods to much greater depths than heretofore. The use of cemented sand fill has permitted revisions to undercut-and-fill mining which have significantly improved the efficiency of this method.Automated mixing systems have been developed for preparing cemented sand fill in surface sand plants on a continuous throughput basis. Control of cement-sand mixtures is obtained by the use of a mass flow measuring system and weighing cement feeders."

Jan 1, 1966

By P. Moran

A promising and increasingly popular tailings management strategy is to place cemented tailings underground as backfill. The placement of cemented tailings results in enhanced geotechnical stability and a purportedly more geochemically stable tailings form with lower leaching potential. Conventional subaerial tailings management can negatively affect water quality if weathering causes acid rock drainage and metal leaching (ARD/ML) to occur, whereas cemented tailings can limit leaching via porosity and permeability reductions and contribute alkalinity to limit the potential for ARD/ML. Cemented tailings backfill appears to be better, but how can this advantage be proven? Currently, cemented tailings backfill is utilized at mining operations internationally, but there is limited guidance on performing geochemical characterization and associated evaluation of the potential impacts to water quality. As a result, various approaches to simulating the leaching behavior of cemented backfill have been utilized, including some methods that are unlikely to represent weathering under site-relevant conditions. American Society for Testing and Materials (ASTM) Standard Test Method C1308-08 is a diffusion testing method initially developed to assess constituent release rates from solid nuclear waste forms. ASTM C1308-08 uses intact cylinders that more closely represent actual backfill than methods that require crushing or size reduction. It is widely believed that leaching from actual cemented tailings is controlled by diffusion through small pores that exhibit limited exposed surface area, making diffusion testing particularly applicable to cemented tailings placement.

Feb 27, 2013

By L. L. Wyman

IN order to clarify and amplify the existing data concerning the action of the cementing material in cemented tungsten carbide alloys, the authors have initiated this investigation of the entire range of cobalt-tungsten carbide alloys. Inasmuch as the ultimate objective is relative to what actually goes on during the sintering of cemented tungsten carbide materials, this work was necessarily restricted to heat treatments similar to those used in actual production of these materials. In the course of numerous experiments, the authors have noted several conditions that indicated that there was a solubility to be considered. Among these factors are the following: 1. Many of the alloys showed a much larger amount of binding constituent to be present than could possibly be accounted for by the cobalt content. 2. In many areas, grains of the carbide constituent are much larger than the particles of carbide originally added. In addition, these grains are of very regular contour. 2a. In samples of cemented tungsten carbide which had been fused in the atomic hydrogen torch in the presence of excess hinder constituent, immense grains are formed, and their shapes are very regular. This is also true when the cemented tungsten carbide of 13 per cent. Co content is fused alone in the atomic hydrogen torch. Contrary to general expectation, chemical analysis of this material, after fusion in the atomic hydrogen torch, checks the analysis of unfused material. 3. In making the cemented tungsten carbide materials by the process of exerting the pressure at the time of heating a certain portion of the contents squeezed out of the mold. Chemical analysis has shown that this material contains approximately 12 to 20 per cent. of tungsten. The microstructure shows a cored dendritic structure interlaced with eutectic network, and some graphite, as shown in Fig. 1. 4. Thermal analysis of these materials has consistently indicated an arrest point close to 1350° C.

Jan 1, 1930