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By J. Rostami, J. Brune, S. Slouka

Respirable dust poses long-term health issues to personnel working in mining and civil projects where mechanized mining and tunneling machines are used for hard rock excavation. Machines, such as longwall shearers, roadheaders, or continuous miners, use consumable picks to cut rock. However, rock dust is generated in the work environment each time the pick tip contacts the rock surface. Additionally, the generated dust can be reintroduced into the air further down in production, such as at transfer points. The purpose of this study is to characterize respirable dust particles generated at the pick tip at two stages of pick wear: new and moderately worn. Understanding dust characteristics in terms of concentration, size distribution, and particle shape throughout the life-cycle of the pick will provide a basis to mine and tunnel operators for changing out picks to mitigate dust generation at the source. This paper discusses the dust characteristics generated from preliminary full-scale cutting tests in a laboratory of an igneous rock block cut with conical picks at new and moderately worn levels of wear. The moderately worn pick generated a size distribution that favored smaller particle sizes compared to the new pick. The moderately worn pick also generated more overall dust, as the concentration level in mg/m3 was over double the amount of the new pick. Lastly, both picks generated particles that had similar aspect ratios and roundness measures.

May 18, 2022

By R. Sellaro, E. Sarver

It has long been understood that extended occupational exposures to respirable mine dusts can lead to chronic lung disease. In underground coal mines, coal workers pneumoconiosis (CWP) and silicosis are major concerns. While many efforts have been made with the aim of understanding the mass-based concentrations and silica contents of respirable dusts under a variety of mining conditions, little research has been completed in characterizing dust at the individual particle level (by composition, size and shape). This study employed scanning electron microscopy with energy dispersive x-ray (SEM-EDX) to analyze dust samples collected from an underground coal mine in Central Appalachia. The results indicated that particle characteristics can vary widely between locations, though many trends might be explained based on knowledge of mining conditions. A continuous personal dust monitor (CPDM) was also used during the collection of some samples to determine respirable dust concentrations, which were compared against estimated concentrations based on the particle-level analysis.

Jan 1, 2014

By R. L. Grayson, S. S. Peng

"Abstract. Sampling of respirable dust and analyses of samples have been partially completed for a longwall panel. Physical and compositional properties which have been characterized include:l. Respirable mass concentration, 2. Mineral composition,3. Particle size distribution by mineral,4. Particle shape distribution by mineral,5. Particle angularity distribution by mineral, and6. Respirable size distribution.Analytical techniques used in the characterization of samples are described, and results are reported with emphasis placed on relationships between the various characteristics and worker locations. Details of existing mining conditions, equipment arrangements, dust control methods and operating system parameters are presented.INTRODUCTIONThrough the work of many researchers worldwide, the health of coal miners in modern societies is now protected from dangerous exposure to respirable coal mine dust. A vast amount of research culminated in the exposure-response model of Jacobsen, et al. (1971) whi3h has been used to establish the 2mg/m exposure limit in the United States. According to the model, exposure to respirable dust for 35 years at this level or less would prevent the occurrence of a clinically significant case of coal workers' pneumoconiosis (CWP). The exposure limit, of course, must be adjusted whenever greater than five percent free silica exists in the respirable dust.The Jacobsen model was built around a mass concentration exposure, which showed the highest correlation with incidence and progression of CWP. As Morgan; et al. (1973) noted, howev.er, the quantity of respirable dust inhaled is not the only significant factor. It is noted that although mass of respirable dust correlates highest with the incidence of CWP, it is not a causal factor. Indeed, the insidious processes causing the disease occur on the cell-particle scale, requiring microscopic investigation."

Mar 1, 1989

By T. I. Urbancic, C-I. Trifu

"ABSTRACTSeveral case studies are presented on the use of seismic techniques to map active structures, evaluate changes in stress levels, and identify the conditions leading to large magnitude seismic events and the generation of rock-bursts in Canadian mines. The results suggest that microseismicity can be used to identify the orientation of active fractures; define regions of relatively high and low stress, and those most likely to host a rockburst; determine the role of local stress on observed shear failures; and identify the path of stress transfer associated with the remote triggering of rockbursts. Additionally, the conditions leading to rock-bursts can be characterized by a significant increase in the clustering of microseismic events along the fault plane orientation of an impending event, and an increase in the effective stress levels. It is concluded that the analysis of microseismicity provides the means for remotely monitoring rock mass behaviour as a result of mining."

Jan 1, 1997

By Shengli Wu, Fengjie Zhang, Feng Chang, Hua Lu, Kaiping Du

In order to make a complete understanding of steel plant metallurgical dusts and to realize the goal of zero-waste, a study of their properties was undertaken. For these purposes, samples of two sintering dusts (SD), two blast furnace dusts (BFD), and one electric arc furnace dust (EAFD) taken from the regular production process were subjected to a series of tests. The tests were carried out by using granulometry analysis, chemical analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy via SEM (EDS), and Fourier transform infrared spectroscopy (FTIR). The dominant elements having an advantage of reuse are Fe, K, Cl, Zn, C. The dominant mineralogical phases identified in sintering dust are KCl, Fe2O3, CaCO3, CaMg(CO3)2, NaCl, SiO2. Mineralogical phases exist in blast furnace dust are Fe2O3, Fe3O4, with small amount of KCl and kaolinite coexist. While in electric arc furnace dust, Fe3O4, ZnFe2O4, CaCO3, CaO, Ca(OH)2 are detected.

Jan 1, 2015

By Rodrigo Sanchotene Silva

Currently the industries of paint have directed their efforts on cleaner production of products that provide effective performance in corrosion protection of metallic materials. This work search introduce a new alternative of organic coating, without the presence of hazardous metals and replace equipments commercials used method of anodic protection for protection of oxidized metals. From this it, was produced Smart Paint (SP), consisting of Paint Acrylic Commercial (PAC) mixed the 1 % of binder, compound by the conducting polymer, Polyaniline Emeraldine Base (PAni EB) and plasticizer 4-chloro-3-methylphenol. The SP and PAC were applied to plates of carbon steel AISI 1010, with the aid of dip coat technique and then were subjected to drying for 48 h. The SP was characterized by thermals and physicochemical analyzes in order to verify possible changes in chemical properties of the ink produced, beyond perform electrochemical tests of Open Circuit Potential and Electrochemical Impedance Spectroscopy, employing equipment Potentiostat/Galvanostat Autolab PGSTAT302 Ecochemie, and aqueous 2 mol.L-1 of H2SO4. The results obtained allow us to state that the plasticizer does not alter the electrochemical properties of PAni and application of binder PAni EB to PAC does not alter the physicochemical properties of commercial coating. The binder PAni EB adds to PAC the capacity to induce the formation or maintenance of protective oxides in oxidizable metals submitted to harsh environments, method known as anodic corrosion protection.

Aug 8, 2018

By M. Nusheh, C. Bumby, A-H. Puichaud

"Vanadium-bearing titanomagnetite ironsand deposits occur along a 480 km stretch of the west coast of New Zealand. In the present study, the leaching behaviour of NZ ironsand was investigated in hydrochloric acid (2–10 M) solution at 50–80°C for 2 h. The resulting leaching liquors exhibited Fe/V ratios in the range 150–180. The distribution of trace element contaminants between solution and solid residue was investigated, and processing conditions have been determined for rapid and efficient dissolution of Fe, Ti and V into the leaching solution. In addition, mineralogical analysis of raw ironsand and leached residues was performed in order to study the leaching mechanism. Samples were characterized by scanning electron microscopy, energy dispersive X-ray spectroscopy (EDX), X-ray fluorescence spectroscopy, qualitative and quantitative X-ray diffraction and inductively coupled plasma mass spectrometry (ICP). Results indicate that the dominant dissolution process follows shrinking particle mechanism. However, ironsand particles containing ex-solution lamellae exhibited a different leaching behaviour compared to homogenous titanomagnetite particles.INTRODUCTION Titanomagnetite ironsand (blacksand) forms Quaternary onshore beach and dune deposits and offshore marine deposits (Figure 1) along 480 km of coastline from Kaipara Harbour south to Wanganui on the west coast of the North Island (Christie, 2016). It attracted the attention of scientists from the earliest times (Galbreath, 1998). The principal minerals in ironsand are titanomagnetite (TTM), ilmenite, quartz and ferromagnesian minerals such as augite, hornblende, diopside, and olivine with smaller amounts of rutile and apatite (Mauk, 2016).Several large ironsand deposits have been discovered and exploited since the late 1960’s. The Waikato North Head and Taharoa mines are currently operating and they have a 2015 measured resource of 400 million tonnes in total and provide over 2 million tonnes of concentrate per year by simple cost effective magnetic separation process (Christie, 2016; Christie & Brathwaite, 1997). The concentrate contains not only 7–8% TiO2 and 56–60% SFe, but also 0.3–0.6% V2O5, is both a valuable titanium mineral and a source of vanadium. All the production is used for steelmaking industries. The other potential for utilizing more of this resource without requirement of integration into an iron and steel producing plant is to develop a hydrometallurgical route with advantages of higher efficiency along with lower emissions. Currently, there is no existing commercial process capable of extracting all three of these elements as industrial-grade commodity products. Acid leaching of TTM concentrate with higher degrees of recovery and selectivity is a key step in any possible hydrometallurgical route."

Jan 1, 2017

By Xiaolong Lin, Yuanbo Zhang, Jiann-Yang Hwang, Guanghui Li, Hongjin Zhang, Jiaxing Yan, Zhiwei Peng, Tao Jiang

The pollution caused by the spent printed circuit boards (PCBs) is currently a concern of researchers and environmental managers due to its large quantity and exceptionally complex properties. This study characterized printed circuit boards (PCBs) from discarded computers using a number of characterization techniques, including chemical analysis, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), granulometric analysis and scanning electron microscopy (SEM).The PCBs contain approximately 50 wt% metals, 25 wt% glass fibers and 25 wt% polymers. The principal metals include copper, calcium, tin, aluminum, zinc and lead. They are still wrapped by brominated epoxy resin after the PCBs are preliminarily crushed. As precious metals, such as gold and silver, are barely found in the PCBs, copper and tin are the main metallic elements of recycling value which warrants extra attention.

Mar 1, 2017

By M. G. Silva-Valenzuela, A. T. Machado, F. M. S. Carvalho, J. R. Matos, A. A. S. Araujo

Electric arc furnace steel dust is a by-product of the steelmaking process and contains high amounts of iron and zinc and significant amounts of lead, chromium, and cadmium and others chemical compounds in minor proportion. However, the material recycling is very complex, mainly due to their mineralogical composition. In this study the characterization and application of this material is presented. Ceramics were produced with clay and variable amounts of steel dust. Th bulk material was fired between 800 and 1000 °C. The influence to insertion of this material on the ceramic composition on the mechanical strength, linear shrinkage, water absorption, apparent density and bending strength of the ceramic samples was investigated. A blend of clay with 5% dus presents potential for use in structural ceramics production.

Mar 1, 2017

By Stephen R. Hunt

This paper summarizes some preliminary results of the Illinois State Geological Surveys current investigation into surface subsidence resulting from coal mining in Illinois. The purpose of the study is to characterize-the vertical movements that may result from various types of underground coal mining. In general there is relatively little published information about subsidence from room-and-pillar mining as compared with longwall mining. The findings of this study, based on mining operations in a variety of geologic settings, delineate the magnitude, shape, and position of the subsidence profile. Comparisons of case histories of subsidence are based primarily on the extraction ratio and the general geometry of the mine (depth, panel width, and mining height).

Jan 1, 1979

By Yuanbo Zhang, Zhixiong You, Li Qin, Guanghui Li, Tao Jiang

Low-grade manganese oxide ore is generally characterized by high iron content. In this work, sulfidation roasting of an iron-rich manganese oxide ore with elemental sulfur was characterized. The experimental results indicated that manganese dioxide can be selectively reduced over iron oxide by using elemental sulfur. The manganese phases in roasted product included low-valence manganese oxide, manganese sulfide and manganese sulfate, while those of iron mainly depended on the sulfur addition. Iron oxide would only be reduced or sulfidized at larger sulfur additions. The effect of roasting temperature and S/Mn mole ratio on the phase transformations was also investigated; extractions of Mn/Fe by sulfuric acid were evaluated. An extraction of Mn greater than 95% was obtained while that of Fe was controlled less than 10% under the optimal conditions.

Jan 1, 2016

By S. L. Huang, J. D. Rockaway, N. B. Aughenbaugh

Shale has long been recognized for its tendency to swell when exposed to the atmosphere. Interaction of moisture with exposed shale strata can cause serious ground stabi1ity problems, since the initial strength of a shale is reduced if the material is sensitive to moisture variations. In this paper, the authors present a classification system to estimate the response of swelling generated within shales. This characterization of the swelling potential is based upon plasticity, susceptibility to moisture, mineralogical constituents of clay size particles, and fabric. Use of this classification system in conjunction with other existing rock properties tests will provide data for more rational engineering design.

Jan 1, 1986

By Steven Derycke, Stephen C. Tadolini, Anand Bhagwat

"The tensile and shear strength of intrinsic bolting support systems has always been a major concern of designers. A comprehensive laboratory testing program was designed to evaluate the tensile and shear strength of individual wires and completely wound PC-strand cables. PC-strand cables with smooth wires and the recent anchorage enhancement innovation of indentation were evaluated and compared. The testing protocol detailed in ISO Standard 15630 utilizes a mandrel system that was investigated at 3 different diameters which alters the wire to mandrel ratio from 2:1 to 9:1. The results demonstrate that the difference between smooth and indented wires is statistically insignificant when larger diameter mandrels are used, and that indentation does not adversely affect strand properties and performance. Insight into the shearing mechanism and evaluation techniques are discussed with the introduction of triaxial loading to describe the PC-strand tensile and shearing mechanisms. Another important result indicates that the shear strength of PCstrand cable bolting systems has a greater shear strength value than traditional steel bar bolting systems.INTRODUCTIONPC-strand cable bolts have proven to be a global cost effective ground control solution in metal/non-metal and coal mines. The inherent strength to weight ratio of cable supports, combined with flexibility has been used in underground entries that range from 20 to less than 1.2 m in height (65 to 4 ft). In coal mining, the systems are used as primary and secondary support installed both passively or actively with installation tensions that range from 38 to over 178 kN (8,500 to 40,000 lbs) . While cable can be specified in several diameters, the most predominant sizes in the US remain 15.2mm (0.6 in) and 18mm (0.7 in). The capacity of the systems defined in the ASTM 432-13 is 90% of the minimum strand strengths of 260 kN (58,600 lbs) and 320 kN (72,000 lbs), respectively.Cables are not only suitable to support vertical loads, but are also often used to effectively support fractured and jointed materials and can be exposed to shear forces across the wound PC-strand structure. In fact, Goris et al. reported that cable bolts placed across jointed surfaces could more than double the shear resistance. These results were duplicated for both smooth and rough jointed surfaces (Goris et al., 1996). An example of tensioned cable bolts used to support a fractured and sliding roof in a longwall tailgate entry is shown in Figure 1."

Jan 1, 2015

By Djalma Souza, Felipe Perissé Duarte Lopes, Frederico Muylaert Margem, Sergio Neves Monteiro

The development of composite materials is a combination of distinct materials, with applications in various areas, such as: aerospace, automobile, etc. Regardingmechanicalresistance,composites reinforced with a dispersion phase in a fiber form is more relevant. The green idea is use composites with natural fibers instead offiberglass, especially in non-structural applications. The Fique fiber has occupying an important place at Colombian agricultural and agribusiness sectors. Epoxy matrix composites reinforced with 1–6 Fique fabric layers were tested and the results indicated that thetensile properties improve with increasing theamount of Fique fabric layers. The fiber/matrix interaction was analyzed by scanning electron microscopy.

Mar 1, 2018

By L. B. Kilius

The composite cathode system based on Ce0.9Gdo.1O2_,5 electrolyte with a painted cathode was used for an intermediate temperature (500-700°C) solid oxide fuel cell. This cathode system was chosen due to its excellent thermal expansion match to the electrolyte, its relatively high conductivity (115 S cm-1 at 700°C), and its low activation energy for oxygen reduction (99 kJ/mol). It was found that the decrease of sintering temperature of the composite cathode system produces a significant decrease in charge transfer resistances to a level of 0.25 SI cm2. The conductivity measurements of porous samples produced values between 40 and 88 S/cm for porosities of 30-40%.

Jan 1, 2005

By T. Inoue, K. Okaya

"Movement of mill charge in the centrifugal mill is essentially different from that in the vibration mill with circular path despite the apparently similar mode in the motion of mill body. As proved e.g. in [11], this results in substantial advantage regarding the comminution intensity of the centrifugal mill over the conventional vibration mill accounting approximately to one order of magnitude.Back in 1983, Bradley et al. presented a model of the centrifugal mill based on the kinetics of the mill charge by regarding it as a lumped mass. On the other hand, numerical modeling by ‘discrete element method (DEM)’ enabled us to observe the movement of each ball in the centrifugal mill with an extremely minute time intervals (Inoue et al., XX IMPC in 1997). The former approach rendered simple, even though approximate, expression of the mill behavior, while the latter method was advantageous in describing the behavior of the mill in terms of individual events taking place in the mill body, even though the result did not reduce to a simple expression. The characteristics of the centrifugal mill described by both these approaches proved to be in a degree of agreement. Thus, the kinetic approach was capable of presenting the overall view of the mill, while the DEM model was informative of the details that could not be depicted well enough by the simple math expressions."

Jan 1, 2003

By C. L. Schneider

The problem of predicting the liberation spectra produced by a closed continuous grinding circuit is of fundamental importance for the design, optimization and control of most operations in an ore dressing plant. The only known approach through which such a calculation can be performed is the population balance model equation. The latest and certainly most significant progress made in this area is the solution proposed by King (1990), which requires one textural parameter that can be measured directly from the ore being studied. The main advantage of King's solution is that it does not require the estimation of hundreds of arbitrary parameters that cannot be independently measured, as required by the existing conventional solutions. However, King's solution relies heavily on a knowledge of the detailed internal structure of the Andrews-Milm diagram (Andrews and Mika, 1975). This has never been measured for any ore. The characterization of the internal structure of the Andrews-Mika diagram requires the measurement of the liberation spectra at several progeny sizes produced by the breakage of monosize, monograde particles at several different grades. In this paper, a procedure based on magnetic fluid fractionation for generating seven narrow-size, narrow-grade samples is presented. Each of these samples was then broken into six progeny size classes in an ultrasonic mill. The one-dimensional liberation spectra of each of the 42 progeny and seven parent particle samples were then measured by image analysis. The measured linear-grade distributions are presented in this paper. The calculation of the correspondent volumetric-grade distributions is discussed.

Jan 1, 1994

By T. T. Chen

The iron- and elemental sulphur-rich residues generated during batch and continuous pressure oxidative leaching of Inco Limited's Voisey's Bay nickel sulphide concentrate at 150°C in sulphate-chloride media have been characterized by X-ray diffraction analysis and scanning electron microscopy. The residues produced during the continuous leaching of the pentlandite- and pyrrhotite-rich concentrate consisted predominantly of hematite and elemental sulphur, with minor amounts of goethite. Although the iron species generated in the batch leaching tests were similar to those formed during continuous leaching, the morphologies of the hematite and goethite particles were significantly different. In addition to the tiny spheroids and bubble-like particles, the hematite and goethite generated during batch leaching occurred as larger "hollow" shell-like particles that contained residual pentlandite or sulphur cores. Although the leach solution from which the iron oxides had precipitated contained 5-15 g/L sodium, sodium jarosite was detected only in trace amounts in a few of the leach residues.

Jan 1, 2006

By T. T. Chen, J. E. Dutrizac

"Grooved cast Pb-Ag anodes are used by some zinc refineries to improve current efficiency. It was found that the manganese oxide scale formed on a grooved Pb-0.75% Ag anode consists mainly of MnO2, which occurs characteristically in rhythmically banded colloform structures and adheres to a layer of ""Pb02+PbS04"" that oxidized from the anode. The relatively homogeneous and nearly fracture-free morphology of the ""Pb02+PbS04"" layer suggests the relatively uniform corrosion of the anode. Deposition of the Mn oxide initially follows the contours of the anode surface, but the grooves eventually become filled with Mn oxide and gypsum. Hydrous Mn oxides and amorphous Mn oxides are believed to be also present in the manganese oxide scale. Tiny particles of PbS04 and SrS04, together with gypsum, other impurities and micro-pores, tend to concentrate in the grooves.IntroductionManganese is a common impurity in hydrometallurgical zinc processing circuits. The manganese originates from sphalerite (Zn,Fe,Mn)S and from the Mn02 added to the leaching circuit to oxidize ferrous ions [1]. Manganese in the sphalerite follows Zn through the roasting, leaching and purification processes, and is present as Mn(II) in the purified ZnS04 solution. The Mn in the added Mn02 is reduced to Mn(II) during the oxidation of the ferrous ions present in the leach solutions. In both cases, MnS04 is generated, and the MnS04 accumulates in the purified solution. In the cellhouse, Zn is plated at the cathodes to produce high quality metal. The Mn(II) is partly oxidized at the anode surface to Mn(IV), and the Mn(IV) precipitates as a scale on the surface of the anode and as a sludge on the bottom of the electrolysis cells. The presence of a thin layer of manganese oxide scale on the surface of the Pb-Ag anode can minimize the corrosion of lead and, accordingly, reduce the contamination of the electrodeposited zinc. However, a heavy manganese scale build-up can cause ""staining"" of the zinc deposits and reduced current efficiencies. Consequently, periodic anode cleaning to remove excess manganese oxide scale is carried out routinely in commercial operations."

Jan 1, 2011

By T. T. Chen

The manganese oxide scales, consisting mainly of MnO2, characteristically occur in banded colloform structures which adhere to porous layers of PbSO4 and PbO2 that oxidized from the rolled Pb-0.7% Ag anodes. Hydrous Mn oxides, Mn3O4 and amorphous Mn oxides are believed to be also present. Tiny particles of gypsum, PbSO4, SrSO4 and AgCl are entrapped in the colloform masses. The gypsum originated from the Zn electrolyte; strontium carbonate was added to the ZnSO4 solution to control Pb, and silver originated from the anodes. Some of the colloform bands contain minor amounts of Pb, implying a limited degree of dissolution of the Pb during electrolysis. Other colloform bands incorporate trace amounts of Zn. Colloform structures permeated with silica gel are presumably caused by the high silica content of the electrolyte.

Jan 1, 2009