Search Documents

By D R Van Eck

Western Deep Levels, a seismically active deep level told mine. stalled placing backfill in their narrow tabular workings as part of the regional support strategy in 1986. Over the years the percentage of working places being backfilled has been gradually increasing. At the end of 1995 the support efficiency and the labour productiveness relating to support installation were scrutinised to determine if resources were being optimised. Owing to financial, safety and productivity constraints it was decided to redesign stope support to be less labour intensive, safer and provide an integrated stope support system. This new integrated system will thus combine the previously used temporary, permanent and back area support consisting of mechanical props, hydraulic props and backfill respectively. Backfill previously formed an integral part of the regional support in conjunction with strike stabilising pillars. To design the integrated support system the backfill placement quality has to be exceptionally good and placement must be done as close as possible to the working face. The backfill to face distance was reduced by 30 per cent and in some areas by more than 50 per cent with an increase of square metres filled to increase the effect of the backfill even more. This paper addresses the design and successful implementation of an integrated stope support system based on the optimisation of backfill to he extent where installation of mechanical and hydraulic jacks could he Eliminated

Jan 1, 1998

By A. Vaillant

Classifiers that are used to separate granular materials into a coarse and a fine stream, are considered. Fundamental Equations are presented which apply to all, such Classifiers and all feed size distributions. The practical, real Classifier is compared quantitatively with the perfect. Classifier. A Formula is introduced for the Real Classifier Selectivity, that defines what portion of each particle size is sent to the coarse outlet duct. This selectivity function is characterized by three Parameters, one of which (b) is a numerical measure of the sharpness of classification. A new dimensionless variable (J) appears in Equations and Graphs for recirculating load, product size distribution and specific surface in the classified product. This variable combines the effects of sharpness of separation, Classifier setting and fineness of a Rosin-Rammler Type feed to the Classifier. Classifier efficiency is defined, based on Specific Surface.

Jan 1, 1967

By P. T. Luckie

Analysis of classifier performance independently of a closed grinding circuit configuration may result in a poor match-up between the grinding device and the classifying device. This paper examines the relationship between classifier and grinding device in dry grinding circuits by employing a semi-empirical methodology.

Jan 1, 1980

By N. A. Beier, R. Amos, Smith. L., C. Atherton, D. R. Barsi, D. Blowes, D. C. Sego

"Waste rock is one of the most abundant materials at mine sites and must be properly characterized and managed to limit acid rock drainage and other harmful byproducts. An experimental waste rock pile—part of the test piles research program—located at the Diavik diamond mine (Northwest Territories, Canada) was deconstructed and sampled to study the spatial variability of material properties. Bulk samples were classified based on the amount of material finer than 4.75 mm. Hydraulic properties of each sample were estimated and particle size distribution analysis was completed. These datasets and classification methods might be used to improve the understanding of hydraulic and geochemical behaviour of the material and to study waste rock at other sites. ¦ KEYWORDS Acid rock drainage (ARD), Material classification, Particle size distribution (PSD), Waste rock RÉSUMÉ Les stériles font partie des matériaux les plus abondants sur les sites miniers et, en tant que tels, doivent être correctement caractérisés et gérés afin de limiter le drainage rocheux acide (DRA) et la pré¬sence d’autres sous-produits nocifs. Dans le cadre du programme Test Piles Research Program, un amas de roches stériles expérimental situé à la mine de diamant Diavik (Territoires du Nord-Ouest, Canada) a été décomposé et mis à l’essai afin d’étudier la variabilité spatiale des propriétés des matériaux. Les échan¬tillons en vrac ont été classés en fonction de la quantité de matériaux plus fins que 4,75 mm. Les propriétés hydrauliques de chaque échantillon ont été estimées et l’analyse de la composition granulométrique effectuée. Ces ensembles de données et méthodes de classement serviront à mieux comprendre le com¬portement hydraulique et géochimique du matériau et à étudier les stériles sur d’autres sites. ¦ MOTS CLÉS classement des matériaux, composition granulométrique, drainage rocheux acide (DRA), stérilesINTRODUCTION Statement of problem The characterization of mine waste rock remains a challenge in active mining sites. The large volume of material and the large size of particles make it difficult to collect representative samples. Sampling techniques are often dis-ruptive to mining operations because they alter the structure of the waste rock pile or interfere with mine traffic. The convention at most mine sites to collect little to no information on waste rock material means that models and predictions of how waste material will behave and interact with the surrounding environment are based on general information that might not be site specific. This could lead to environmental damage or higher costs if environmental effects are underestimated during the construction of waste rock structures."

Jan 1, 2019

By E. Dendy Sloan

An overview of hydrate properties is given, with emphasis on unusual deviations from ice, the most common solid water form. Reliable sample preparation and reproduction of in situ hydrates provide the foundation for all hydrate science and engineering. Relations are given to connect the three domains in the title: (1) micro-scopic properties measured with Raman, NMR, and diffraction spectroscopy, (2) meso-scopic properties measured with single crystals, and (3) macro-scopic properties measured with pressures, temperatures, volumes, etc. A principal illustration relates micro-scopic and macro-scopic domains. Experiments provides the basis for improving statistical thermodynamics model for these compounds. To date, this model is one of the most commonly used industrial statistical thermodynamics applications, based upon the classical model of van der Waals and Platteeuw (1959). Microscopic measurements and simulations indicate model assumption improvements, resulting in the next generation of the statistical thermodynamics for improved macroscopic property prediction.

Jan 1, 2002

By Haydn H. Murray

The term clay is somewhat ambiguous unless specifically defined because it is used both as a rock term and as a particle size term. Actually most persons using the term clay realize that it has a double meaning and in most instances define it. As a rock term, clay is difficult to define because of the wide variety of materials that compose it so that the definition has to be general. Clay is a natural, earthy, fine-grained material composed largely of a limited group of crystalline minerals known as the clay minerals. Many definitions state that a clay has the property of plasticity when wet, but some clays are not plastic, i.e., halloysite and flint clay; however, most clay materials are plastic when wet. As a particle size term, clay is used for the category that includes the smallest particles. The maximum size particles in the clay size grade are defined differently on some grade scales. Soil investigators and mineralogists generally use 2 microns as the maximum size. The Wentworth scale' defines clay as material finer than approximately 4 microns. Grim' has found it convenient to use the term clay material for any fine-grained, natural, earthy, argillaceous material and in this way can include clays, shales, or argillites, and some soils if they are argillaceous. Even though no standard definition of the term clay is accepted by geologists, agronomists, engineers, and others, still the term is generally understood by all who use it. Clay is an abundant natural raw material and has an amazing variety of uses and properties which will be discussed in this chapter. In order to understand better the relationships between the clays and their uses, a brief discussion of the structure, chemical composition, and identification of the clay minerals is given. Mineralogical Composition of Clays Clays are composed of certain groups of hydrous aluminum, magnesium, and iron silicates that may contain calcium, potassium, and other ions, which are called the clay minerals, and other minerals of variable composition, which are nonclay minerals. Both clay minerals and nonclay minerals influence the properties of a clay material. In order to understand the relationship between clay minerals and the properties of a clay material, a short summary of the structure and composition of clay minerals is necessary. Any scheme of classification tends to impose a certain rigidity and as new and additional data become available it is necessary to revise classifications. Brindley3 has discussed the classification and structural mineralogy of clays in very lucid fashion and chose a classification based on structural features and chemical composition. Grim2 proposed a tentative classification which is based on the structural attributes of the various clay minerals. This classification is relatively simple and workable, and is shown as follows: I. Amorphous Allophane group II. Crystalline A. Two-layer types (sheet structures composed of units of one layer of silica tetrahedrons and one layer of alumina octahedrons). 1. Equidimensional Kaolin group kaolinite, dickite, nacrite 2. Elongate Halloysite group

Jan 1, 1960

By H. Ries

THE term "clay" is applied usually to certain earthy rocks whose most prominent property is that of plasticity when wet. This permits them to be molded into almost any shape, which they retain when dry. Furthermore, they harden under fire. Clays contain hydrous aluminum silicates-the clay minerals-in appreciable amounts, but aside from this a number of other mineral grains, particularly quartz, may be present. Texturally clays are fine grained, and the so-called true clay particles are usually under 2µ in diameter. MINERALS IN CLAY Certain hydrous aluminum silicates that predominate in many clays are known as the clay minerals"." and are grouped by Kerr41 as follows: [ ] The kaolin group has been found to consist of a number of minerals with the same chemical composition but different crystalline structures .83 Kaolinite is commonly formed by the weathering of other mineral particles, particularly feldspar, but some deposits, like those in Cornwall, England,36 and others in the Washington-Idaho district, are thought by some to be of hydrothermal origin. Dickite and nacrite are thought to be due usually to waters of

Jan 1, 1949

By H. H. Murray

Industrial usage of clays for current and new applications will continue to grow into the next century. The rate of growth will be highest in the less developed areas of the world. Transportation costs are a significant part of the delivered price, so the location of reserves and processing facilities for kaolin, bentonite, and palygorskite (attapulgite) are reviewed relative to serving these emerging markets. New value added applications will increase in the more developed areas which will require high quality raw materials, more sophisticated processing, and rigorous quality control.

Jan 1, 1998

By I. E. Odom

A study was made of the physical and chemical nature of silica minerals found as natural impurities in bentonites and montmorillonitic Fuller&apos;s earth clay products as well as in <10 micron dust from eight processing plants. The results show that the silica minerals present in these clay materials are totally encapsulated or encased in clay. No "free" silica minerals could be observed in SEM images of either granular or powder products or in dust samples collected for MSHA crystalline silica analysis. Silica minerals, such as quartz, are identifiable by SEM and EDS analysis only after removing the clay coatings by vigorous washing. After washing it can be observed that all crystalline quartz grains also have diagenetic overgrowths of what is probably opaline silica. The clay and opaline silica encapsulation of quartz plus the strongly hydro scopic nature of montmorillonite are believed to be responsible for there not being a single confirmed case of silicosis among workers in the subject plants after more than 65 years of production.

Jan 1, 1996

By H. H. Murray

New and improved benefication techniques are available to allow the production of clay minerals of exceptionally high purity. This is particularly true for kaolins and smectites. Wet processing techniques including particle size separation, high intensity magnetic separation, chemical leaching, flotation, and selective flocculation are described and results and applications are discussed. The blending of clay minerals with other minerals provide opportunites to make special ceramic materials such as cordierite and other minerals which have very special ceramic properties including low heat expansion, high fired strength, low absorption, and other desired qualities.

Jan 1, 1989

By Robert Linton

SPECIFICATIONS for clays serving raw materials in the ceramic industry usually contain the following items: (1) Chemical analysis, sometimes with mineralogical structure determined by microscopic investigation. (2) Maturing temperature and firing range, usually expressed in terms of pyrometric cone equivalent. (3) Shrinkage (drying and firing shrinkage separately). (4) Degree of plasticity. (5) Color after firing. Clays may be classified, according to the purpose of the classification, in several different ways, based on (1) Geological occurrence-transported, altered An place, indurated (shales). (2) Physical properties-plastic (bonding clays, ball clays) and nonplastic (flint clays, kaolins or china clays, bone clays). (3) Color. (4) Use. A common classification of clays for commercial designation, and one fol-

Jan 1, 1936

By S. J. Page, W. E. Wallace, P. Bolsaitis, D. Eppelsheimer, M. J. Keane, J. Poston, J. Harrison

"Respirable-sized dust particles from a clay mine and mill were examined for aluminium and silicon content by scanning electron microscopy-energy dispersive X-ray analysis at incident electron energies of 5--20 keV. Most of the high silica content particles, those which had a silicon to silicon plus aluminium signal fraction, measured at 20 ke V, of0.9 or greater, showed a decrease in the silicon fraction of signal with decreasing incident electron energy, down to values of between 0.6 and 0,8 at 5 keV: this decrease was a function of particle size and composition. Simple models for silicon fractiol) of signal vs incident electron voltage suggest this behavour is due to a heterogeneous particle structure in which an aluminosilicate coating occludes the surface of a silica particle core. The coating survives incubation in a major component of pulmonary surfactant.INTRODUCTIONMINING and some other dusty workplace atmospheres are monitored for respirable dust and quartz dust for purposes of occupational health protection, respirable quartz dust being a known cause of pulmonary disease. Respirable quartz exposure data are acquired also for epidemiological research on the correlation of pulmonary disease prevalence with respirable dust composition and concentration. For these purposes quartz content often is measured on collected dust samples by X-ray diffraction or in spectroscopy. Scanning electron microscopy-energy dispersive X-ray analysis spectrometry (SEM-EDX) is also used. The first two methods measure the bulk composition of a multi-particle dust sample; SEM-EDX measures the elemental composition of single ·particles. These methods as typically applied, including SEM-EDX with a 20-30 kilo-electron volt (keV) electron beam accelerating potential, do not distinguish homogeneous distribution of impurities in a particle from possible heterogeneous surface distribution. These measurements of quartz content are not always accurate predictors of the prevalence of dust-induced disease (ROBOCK and BAUER, 1990), which implies that the biologically available quartz surface may not be equivalent to conventionally measured quartz content of respirable dust in some exposure settings. Using a minor modification of conventional scanning electron microscopy-energy dispersive X-ray analysis (SEM-EDX) protocols on samples of settled and airborne dust from a clay mine and mill we have detected heterogeneity with depth for aluminium impurity in high silica content particles, indicating that some of the quartz or 'free silica' respirable particles of the dust are aluminosilicate occluded. Coatings were not removed by incubation of the dust in a surrogate pulmonary hypophase surfactant fluid."

Jan 1, 1990

By W. F., Dietrich

THIS paper deals with the- methods of mining the high-grade clays of California. Although the majority of the clay pits in the state are operated on a scale that is small by comparison with most metal mines, this very fact results in a diversity of methods and gives rise to problems of selection of the method best suited to given conditions. Two or three operators in California produce approximately 500 tons per day of a single kind of clay from a single pit. About five varieties of clay are mined on a scale of 200 to 400 tons per day; not over fifteen varieties are mined on a? scale of 50 to 200 tons per day; and more than 50 varieties are mined at a rate of less than 50 tons per day. It is the aim of this paper to delimit, insofar as the data at hand permit, the conditions and scale of operations that favor the selection of each dominant method of mining that is actually being applied at California properties. Details of the occurrence and utilization of the clays of California have been given in a recent bulletin and are not considered here.

Sep 1, 1928

By Haydn H. Murray

The area from Ohio on the east, Tennessee on the south, and Minnesota on the west: contains some very unique and useful clay deposits. Included are fireclays and plastic clays in Ohio, Kentucky, Indiana, Illinois, and Missouri; flint clays in Kentucky and Missouri; ball clays in Kentuckv and Tennessee; adsorbent clays (fuller&apos;s earth) in Missouri, southern Illinois, and Tennessee; and alluvial clays and shales for structural clay products from every state. Unique kaolin clays are known in Minnesota, Missouri, and southern Illinois and halloy-site localities are known in southern Indiana. The geology, physical properties, and uses or potential uses of these midwestern clays are described.

Jan 1, 1980

By D. Steele, B. Ndlovu

"Adequate characterisation of clays is becoming increasingly important as operating mines move into areas of more complex ores. The processing therefore needs better mineralogical characterisation to identify problematic ores for better planning before issues arise. While a number of instrumental mineral characterisation methods are available, X-ray Diffraction (XRD) is widely recognised as perhaps the best technique for the identification and quantification of minerals, particularly clays. When an appropriate sequential and systematic sample preparation and treatment protocol is employed with instrumental XRD analysis individual clays can be uniquely identified, and the proportions of interstratified clays can also be quantified. The effect of sample preparation on the XRD analysis and identification of clays was investigated in this study. The results showed that sample preparation protocol is indeed critical to accurately analysis and characterisation of clays. For example, both dry grinding and micronizing affected the degree of crystallinity of kaolinite leading to the formation of reactive surfaces or changes in the physicochemical behavior. It was also found that the apparent degree of preferred orientation in platy minerals correlates directly with the amount of force/pressure applied during the preparation of backfilled powder samples. This work showed that manual preparation can produce highly variable peak intensities especially with minerals that show any preferred orientation. KEYWORDS Clay; XRD; kaolinite INTRODUCTION Clays are important in our life and they have numerous applications in modern world from cosmetics to environmental remediation. Therefore, clays have been extensively investigated for many years. Adequate characterisation of clays is becoming increasingly important as the mineral processing industry faces more complex mineralogy with the need for better mineralogical characterisation to identify problematic ores and plan accordingly. In most studies, X-ray diffraction (XRD) method has shown the unique capability to characterise mineralogy, especially for the fine grained size materials. The XRD technique is particularly diagnostic for clays. It is known that under ideal conditions, the peak intensities of an XRD diffractogram are proportional to the concentrations of individual minerals present in the sample. Hence, the qualitative mineralogical data obtained from XRD can be quantified, using either the internal or external standard methods. However, it is also known that clays are particularly sensitive to the influences of sample preparation method due to their physical characteristics (e.g. fine grain size, morphology, relative physical softness, crystallinity, thermal sensitivity) that could be destroyed by inappropriate preparation prior to the analysis. Thermal and mechanical treatment and grinding of clays can change their crystalline structure, and consequently, their characterisation results by XRD analysis. The behaviour of clays in grinding has been widely studied, especially for kaolinite (Miller and Oulton, 1970, Milocevic et al., 1992, Tomasevic-Canovic et al., 1992). With prolonged grinding time, the crystallinity of the clays can decrease (Filipovic-Petrovic et al., 2002). It has been shown that grinding may gradually cause the loss of hydroxyl ions of kaolinite (Gonzalez Garcia et al., 1991)."

Jan 1, 2018

By M. A. Kessick

Current treatment and disposal procedures are compared for clay slimes resulting from the extraction of Alberta oil sands, the extraction of Florida phosphate matrix, the recovery of diamonds from kimberlite deposits in South Africa, the recovery of kaolin from clay deposits in southwest England and the upgrading of bauxite ore. Published research in the area is reviewed, and common trends which are emerging in the disposal of clay slimes are discussed.

Jan 1, 1978

By Thamyres C. Carvalho, Edemarino A. Hildebrando, Roberto F. Neves, Francisco R. Valenzuela-Diaz

Synthetic clays are an option of materials that can be modified to obtain better and specific properties when compared with natural clays. Although clays are found in nature, they have many disadvantages that limit the use of them, such as existence of impurities, and variations in composition. Therefore, the objective of this work was to obtain synthetic clay/polyester resin nanocomposites. To characterize the clay, we used X-ray Diffraction (XRD), Total Attenuated Reflection Spectroscopy in the Fourier Transform Infrared Region (ATR-FTIR) and Scanning Electron Microscope with Field Emission (FEG-SEM) methods and the nanocomposites were characterized by XRD and mechanical resistance to compression. The results show the purity of the clay and the time of synthesis is an important parameter for its crystallization process. The clay/polyester nanocomposites were obtained and showed an increase in the ductility.

Mar 1, 2018

By T. McCallum, C. Cooper, B. Hutzler

"In copper solvent extraction, managing the quality of the organic phase is a key parameter to ensure optimal physical and metallurgical performance in the plant. Increased throughput as a result of declining ore grades coupled with advances in plant design and practice, resulting in reduced organic losses, has pushed the limits of the status quo with respect to organic quality. Clay treatment of plant and recovered organic at the optimal dosage is critical in maintaining quality, however, achieving the optimal dosage through existing filtration capacity and practice can be difficult. Cytec has developed a process aid that increases efficiency of existing filtration equipment that has been successfully implemented at two commercial SX operations. ACORGA® CB1000 enables higher dosages of clay while allowing for more efficient use of existing filtration capacity. This study analyzes results from commercial trials and demonstrates that improved organic quality and clarity is achievable through optimization of current treatment practices. INTRODUCTION Decreasing ore grades have prompted copper solvent extraction operations to raise PLS flow rates, increasing plant throughput to maintain production1. The ability to process higher flow rates through existing mixer-settlers historically came at the expense of increased entrainments2. However, advances in mixer-settler design, practices and improvements in organic recovery processes have enabled operations to maintain, and in some cases reduce organic losses while achieving higher flow rates through existing equipment. Based on the increased demand on the SX equipment and reduced losses (or more efficient recovery) maintenance of the circuit organic quality through efficient clay treatment is now more important than ever. This paper discusses common industry practices and related issues in organic clay treatment, and presents benefits achieved in commercial operations through the use of ACORGA® CB1000 Clay Binder. IMPROVEMENTS IN DESIGN AND PLANT PRACTICE Mixer-settler design has improved since the first commercial copper SX operation in the late 1960s. Advanced designs in mixer, settler, and settler internals have contributed to reductions in entrainments. For example, improved impeller designs have been reported to decrease organic in aqueous entrainment from the ‘old designs’ of 50-200 ppm3 to as low as 4 – 10 ppm confirmed via diluent and reagent consumptions . Similarly, operations are reporting a 20-50% decrease in reagent consumption when compared to the original design criteria3. Operations have optimized settler internals to increase coalescence and have improved settler operating practices which have been shown to reduce entrainments7. Comparison of the SX world operating data from 1999 and 2007 shows reductions in organic entrainment losses with increases in flow rates."

Jan 1, 2015

By Frank E. Chase

Clay veins, also referred to as clay elastic dikes, have been responsible for numerous underground injuries and fatalities. These hazardous structures are also responsible for increased production costs during all phases of mining. For these reasons, the Bureau of Nines has investigated the physical characteristics of and roof instability problems associated with clay veins in order to make support and other mining recommendations. In addition the occurrence and origins of clay veins were examined to determine whether or not the structures could be projected into unmined portions of the coalbed. This investigation included portions of the Arkoma, Illinois, Northern Appalachian, Southern Appalachian, and Uarrior Coal Basins. Virtually a11 clay veins observed or documented occurred in the Illinois and Northern Appalachian Basins. Observed clay veins ranged in sire from 1 inch to 16 feet In cross-section and were found under shale, siltstone, sandstone, and limestone roof rock. Individual clay veins were predominantly composed of claystone; however, limestone. siltstone. and sandstone infilled clay veins do occur. Clay vein formation has been associated with the infilling of fissures which result from compressive, tensile, or shear ground failures. These gaping fissures were propagated by compactional processes and/or tectonic stresses active during and subsequent to coal iff cation. Associated fault, fracture, and slickenside planes commonly parallel clay veins and disrupt the lateral continuity of the immediate and, sometimes, main roof. When clay veins parallel or subparallel the direction of face advance the roof is segmented into cantilever beams causing unstable conditions. Therefore, the strata on either side of the clay vein must be bolted and strapped together to form a beam.

Jan 1, 1984

By J. Darlington, A. K. SenGupta

Water-swellable layered silicates, namely, the smectite clays can remove suspended materials (called herein as debris) and metal ions from aqueous streams. The present study shows that the flocculating and metal extracting abilities of smectite clay-based flocculants can be enhanced when these clays are used in conjunction with a specific anionic polymer. Such performance enhancement is attributed to the following: i) the clay-dispersing ability of the polymeric additive, that would translate into an increase in the clay-surface area available for the attachment of the debris particles onto the clay particles; ii) the possibility of dispersant-to-coagulant transition of the polymer during the later instants of the treatment process, as a result of reduction in solvency of the wastewater for the polymer due to the release of cationic species from the clay-based flocculant solids; iii) metal-complexing ability and adsorption properties of the polymer.

Jan 1, 2002