Search Documents

By R. C. Head

The investigation describe the history of copper in the seventties, as well as indicates the forecast the probable trend of the Copper Industry over the coming decade, and second, to stimulate some discussion on what is a somewhat controversial subject. At the same point, the period of surplus production from about 1972 to 1976-1977, during part of which some voluntary restriction on output maybe necessary. In consecuence, its a necessity for forward planning so that, by 1973-1974, new mines maybe developing to preserve the continuity of supply .

Nov 20, 1969

By O. E. Kiessling

THE present system of competitive exploitation of oil pools results in losses, both of petroleum and of profits. Under a competitive system the owner produces or withholds his product according to the price, which reflects the demand, but in the pe-troleum industry the producer does not have complete control over the expansion and contraction of his out-put. Under a series of court decisions, reviewed in detail in the paper, petroleum is not covered by- the general theory of English common law that the owner of land owns everything from the center of the earth to the sky within the areal limits of his property, but is considered to be his only when he has reduced it. to possession, which he can only do by taking it out of the ground. If A can obtain possession of the petro-leum which is beneath the property of B without tres-passing on B's property he commits no legal wrong and B has no defense except to get it into his (surface) possession before A takes it. No one would expect an. owner under such a system to forego the possibility of securing some oil from his property in order to in-crease the ultimate production of the pool. The pe-troleum industry. should offer a constructive program, that will eliminate losses and protect the interests of individuals as far as possible. If improved methods of oil recovery can be applied the quantity of petroleum recovered might be double or even treble the amount recovered by ordinary procedure. But increased recovery is not the only benefit from pool development. In brief, the following advantages can be claimed for unit operation: 1. Saving in development and operating costs. 2. Less danger of damage to the fields by defective wells. 3. Development is better gaged to fit market demand and to effect the most efficient recovery of oil. 4. More oil, gas, and gasoline can be marketed. 5. By regulating pressures, recovery .of oil and gas will be greater and the wells will flow longer. Reagan County (Big Lake), Rainbow Bend and Cabin Creek are examples of longer life of pools thus obtained.

Jan 11, 1927

By W. A. Vine

Next year, in 1964, Butte will celebrate its Centennial. It was in May, 1864, that the first recorded mining activity took place. During that summer, several rich placers were found on Silver Bow Creek and its tributaries, and a gold rush followed. As placer mining proceeded in the creek beds, the quartz lodes on the hillsides were located and the veins were prospected. Mining in Butte entered its second phase when the rich silver mines, the Alice, Moulton, and Lexington, were opened. The silver boom lasted until the decline in the price of silver in the early 1890's forced the closure of many of the mines. An indication of the beginning of the copper mining era in Butte was in 1866 when it was noticed that green copper carbonate discolored some of the, lode material. It was not until ten years later, however, that the Anaconda and St. Lawrence claims were located by Michael and Ed Hickey. The claims were sold in 1880 to Marcus Daly and in 1881, Daly obtained financing and organized the Anaconda Silver Mining Company to exploit the vein The silver venture was a failure because of the predominance of copper which diluted the bullion to only 400 fine.

Jan 1, 1963

By Herbert F. ?Buck? Darling

A bridge replacement project in Rochester, NY, encountered difficulties when it was determined that rock below one pier was sloping downward toward the river at an angle of 42 degrees versus anticipated 12 degrees. Cofferdam design and construction became very difficult. The unanticipated subsurface conditions delayed the project by eighteen months and increased the cofferdam cost by almost $3.0 million ($US) when direct costs and associated delays were taken into account. The initial approach after discovery of the problem was to use the same type pier design and modify the cofferdam accordingly. This resulted in a cofferdam 12 meters (39.4 feet) deep on the shore side and 18 meters (59.0 feet) deep on the water side. The design used a master pile system to attain required wall strength and used rock anchors to prevent the cofferdam from moving toward the river. The pier foundation was then redesigned by the owner using revised seismic parameters. The original stepped footing carved into rock was replaced by caissons socketed into the rock beneath a large tremie concrete placement. The revised pier and cofferdam designs caused a shift from a mostly land based cofferdam, excavation, and rock removal project into an almost entirely water based cofferdam, caisson drilling, and tremie construction project. These design changes resulted in a reliable, safe, and unusual cofferdam and construction method. All of this was accomplished within a very narrow worksite with a railroad on one side, and the river with its public and commercial freighter traffic on the other. In addition, the existing two-leaf drawbridge was to be maintained in place which put further limitations on the water borne equipment. The engineering and construction considerations, problems, and solutions related to these cofferdams and pier foundations are presented.

Jan 1, 2013

By W. C. MENDENHALL

THE problem of maintaining the mining industry is two-fold; finding new supplies in the face of increasing difficulties, and making such advances in the arts of extraction and preparation as to use supplies of lower grade. Progress in mining and reduction methods and in transportation makes ore today of that which was waste yesterday. These are the fields of the metallurgists and the transportation engineers. The geologists and mining engineers must work together on the problem of ore finding. As the old prospector fades from the scene, men with equal hardihood and patience and equal power to meet the physical obstacles which confront the seeker after ore, must take his place, armed with all that has been learned from human experience about the causes, the controlling conditions, the indications, and hiding places of the metals. Such a seeker is dealing with some of the most complex and obscure of natural phenomena. In nature's laboratory, tremendous forces are at work. Tempera-

Jan 1, 1926

By Donald M. Keagy

How many times have you said or heard someone say, 'What are you doing right now?" And how many times have you heard the reply, "Breathing air!" Probably never, or at most only a few times in a facetious vein. Breathing air is absolutely necessary to sustain human life, and yet most of us take it completely for granted. Beginning ten to fifteen years ago there was growing concern on the part of the general public that pollution of the air is a threat to man's health and welfare. Concurrently much thought and effort was devoted to the task of defining and resolving the problem of air pollution. In the course of this effort it has become quite clear that our National policy in this regard should be founded upon three basic axioms: (1) Action should not be postponed until emergency conditions make it compulsory; (2) The air cannot be purified after it is polluted, and (3) Air pollution control cannot be accomplished without close cooperation among all levels of government, industry, and the public.

Jan 1, 1967

By Jan G. H. du Preez, C. Viviers, B. J. A. M. van Brecht, H. E. Rohwer, Nicole M. Sumter

"At the basis of metal ion separation lies some particularly metal ion specific chemical property which lends itself towards exploitation. This could be in the form of an anionic complex or a neutral chelate complex. In the former a cationic centre with a particularly high affinity for the complex will have to be designed. In the latter case a stereospecific chelate ligand containing the correct symmetry and type of donor atoms will have to be designed. In both above cases the ""active centre"" can be entered in a from that it can function in different media of hydrophobicity, eg a precipitant, a resin or a solvent extractant. Recent results obtained in this laboratory will be used to illustrate how the above variables can be exploited to develop improved processes for the separation of base metal and platinum group metals.IntroductionThe separation of metal ions in hydrometallurgy can be performed broadly speaking with two major aims. Firstly the separation/removal of a certain group of metal ions, either as a means of preconcentration or as a removal from effluent as part of a purification process and, secondly the removal of a specific metal ion from an industrial stream in order to produce a specific metal in a pure form. This latter operation is by far the most difficult of the two and is becoming more so in the light of the fact that the world is moving in the direction of lower grade ores and increasing pollution. Such a process can be divided into three essential parts, firstly the molecular one in which an active centre is required to obtain specificity, secondly a matrix within which this active centre must function, i.e. as part of a resin or solvent extractant and thirdly the design of the total system to optimize the realization of the operation."

Jan 1, 1996

By Anoop Sattineni

Over the past decade the use of BIM in the AEC industry has grown several fold and with it the number of standards available for implementing BIM. The ?National BIM Standard? by buildSmart Alliance, the ?Contractor Guide to BIM? by the Associated General Contractors of America, the ?BIM Project Execution Planning Guide and Templates? from Penn State University, the ?BIM Roadmap? by the US Army Corps of Engineers are some of the several BIM guidelines that are currently available to the AEC industry practitioners. Some of these guidelines are as comprehensive as defining BIM and the associated taxonomy while others are meant to be used on an individual project basis. From a contractor?s perspective one of the key benefits of using BIM is for the purpose of collision detection and coordination. This research has found that currently available guidelines do not address these issues adequately. For instance, the currently available guidelines do not allow the subcontractor to quickly communicate issues such as naming conventions and color schemes within the model, to the general contractor. Consequently general contractors and sub-contractors find themselves making changes to their BIM deliverables based on each other?s abilities and levels of adoption, apart from reason?s stemming from use of different software platforms. This paper describes how a group of contractors and subcontractors from Atlanta and Birmingham in the United States came together to create and adopt a ?Coordination Guidelines for Virtual Design and Construction?. These guidelines were specifically created with the purpose of streamlining the construction coordination process using BIM. This paper describes how the guidelines created differ from other guidelines currently available in the industry.

Aug 1, 2013

By V. F. Hollister, M. Bernstein

The Copaquire porphyry copper deposit lies in an island of pre-Upper Tertiary rocks surrounded by Quaternary and Upper Tertiary formations. The pre-Upper Tertiary appears to be a horst block in a typical basin-range setting. Major right lateral faults have been mapped within the range from Chuquicamata north to Copaquire. All of the major porphyry copper deposits known in the block (e.g., Quebrada Blanca, El Abra, Chuquicamata, and Copaquire) are on or are very close to one of these major right lateral shears. In the Copaquire district, an epizonal igneous complex with diorite, quartz diorite, quartz monzonite, and intrusive dacite (in that intrusive order) invade folded Jurassic shale. Mineralization appears spatially and temporally associated with the quartz monzonite porphyry and dacite. Alteration zoning shows two separate core phyllic (quartz-sericite-pyrite) zones within one large argillic (clay-pyrite) zone. A propylitic (chlorite) zone is peripheral to the argillic zone. No potassic zone has been recognized yet at the surface. The intrusive petrology together with the phyllic, argilic, and propylitic alteration zoning as well as the chalcopyrite-molybdenite ore mineralogy characterize this deposit as being typical of the Lowell and Guilbert model. Copper and molybdenum minerals appear to be most strongly developed in the phyllic zone, in either a breccia or a zone of veinlets and stockwork which trend dominantly northeast, conjugate to the district's largest fault, the Sulfato fault. The setting is basically similar to that found in some other porphyry copper deposits in this block, in that the ore body is a zone of veinlets which appear to be genetically related to movement on a major north-south trending right lateral fault. The presence of the major fault in each deposit, and the speculative hypothesis that paleo-subduction zone operated at the time of mineralization, suggest the possibility that mineralization took place when a major fault permitted escape to the surface of cal-calkalic magma generated in a subduction zone as proposed by Ericksen. A hypothesis such as that proposed by Ericksen explains the near linearity of porphyry copper deposits in Chile, since the source of calc-alkalic magma would exist at about the same distance from a paleo-trench throughout the length of the paleo-subduction zone.

Jan 1, 1976

By Valerio Violo, Antonio Raschillà, Livia Cicinelli

"The Cityringen project foresees the construction of a new circular metro line in and around the city center of Copenhagen. Both drives, the north and the south one, required the TBMs to be equipped in order to cope with contaminated water table and soil. The north drive mined in water contaminated with chlorinated compounds, including chloroform and vinyl chloride, while the south TBMs excavated in a highly benzene contaminated area, becoming the first TBMs to complete such a challenge. Despite the pollution and the stricter operative procedures, the production has been extremely successful with record up to 520 m in one month and 32 m in one day. 1 INTRODUCTION The Cityringen is an extension of the existing metro line. The 15 km long twin tunnels will form a new circular line with 21 new stations (17 + 4 crossovers). When finished it will interchange with the existing metro, rail and bus infrastructure at key locations around town, taking 90% of Copenhagen citizen at less the 600m from a metro station (Figure 1). The Contract has been awarded in April 2011 to the Copenhagen Metro Team (CMT), a joint venture between the Italian companies Salini Impregilo, Tecnimont and Seli SpA. Tunnels are being excavated with 4 Seli-Kawasaki EPB TBMs, two of which manufactured in Denmark by Seli Tunneling Denmark ApS, which is also operating them. At the moment this article is written 50% of the tunnels have been completed and over 40% handed over for the electromechanical works. Seli Tunnelling Denmark is a Danish company constituted in 2012 as a subsidiary of Seli SpA for this project and subsequently acquired by the Salini Impregilo Group in 2015."

Jan 1, 2016

By C. Tom Blevins

LADIES AND GENTLEMEN : This presentation is to discuss production and roof control problems associated with directional lateral stresses in an in situ stress field and the approach that Inland Steel Coal Company made in trying to cope with them. Before proceeding, a brief description of the mine location, product, geology, restraints, and mine history is in order.

Jan 1, 1982

By C. Tom Blevins

The purpose of this paper is to discuss production and roof control problems associated with directional lateral stresses in an in situ stress field and the approach that Inland Steel Coal Company made in trying to cope with them. Before proceeding, a description of the mine location, product, geology, restraints, and mine history is in order. The mine is located in Hamilton County in Southeastern Illinois. It produces a high volatile metalurgical coal and is slated to produce 2.1 MTY. Product ion is in the Illinois No. 5 seam at a depth of 930 feet, approximately 490 feet below sea level. The scam height averages from 5.5 to 6.0 feet throughout the reserves with height increasing in the eastern reserve area to approximately feet and a 5 Foot average in the West. The scam tends to dip to the North, North East, but is locally very undulating. The Galatia channel washout outlines the eastern boundary of the reserves and there is a split coal area toward the central part of the property than runs south-southeast. The top above the #5 seam is laminated medium gray shale called Dykersburg. Individual shale bedding planes vary locally From ½ to 1" in thickness to a more normal thickness of 1 to 1 ½ with some areas being interlayed by thin carboncous material. The top normally must be considered as materially competent. Even though the mine is still relatively small in area with only 1.3 million tons of total production to (late, we have encountered dense zones of slicker sides and premining, stress cracks (joints). There are also areas of siltstone, that vary from a few inches to several feet thick, and areas of rider coal, clay instrusions, and rolls. We have crossed lineament concentrations that show strong evidence of corelation to localise top problems. These are being monitored closely to see their predictability on our present and future mining conditions. The face cleat runs N 55° E and butt cleat runs S. 25° E. On a regional basis, there are several anticlinal belts that trend in a northerly direction. The one major restraint is that Inland does not own surface subsidence rights. Therefore, a partial extraction mining plan is being followed. The Holland-Gaddy formula for pillar strength design is used to calculate theortical pillar sides. When production began in March of 1979, it was noted that ground control problems occurred as we drove north entries. East-west cross cuts tended to have better working conditions. This phenomia occurred from a couple hundred feet, but seemed to dispate as we got away from the men and material shafts. Once the production shaft was connected and enough entries extended for installation of belts, ground control problems were again experienced in north-south headings. It was also observed that when mining north-south headings with east-west crosscuts, if the crosscut was driven through ahead and supported, the intersection was stable upon entry connection. This held true even where fairly extreme ground control, problems were encountered. The reverse held true. when driving east-west headings with north-south crosscuts. At this time, we started searching in earnest for a working theory to explain this roof phenomia. It also became the first step of what eventually was a four step sequence to derive a workable solu¬tion to the problem. The combination of the many geological changes and the fact that north-south condition was at times intermitent, helped to disguise the stress field. The mine also being in a fairly virgin area with no mines in approximately 25 milt, radius, meant we didn't have a reliable case history to examine. Various theories were researched before it was concluded that our primary ground control problem was a directional lateral stress Field, with the major stress axis in an east-west direction. The second stop of the procedure was then to test. mining methods and determine if these stresses could be modified to a

Jan 1, 1982

By F. J. Munn

"Since 1976, Cardinal River Coal s Ltd. has completed mining in eight pits. In each of these pits, at least one wall has failed, none by design, although not totally unexpected, yet there was no loss of production nor risk to personnel or equipment. Cardinal River Coals Ltd. has been successful in implementing a program to cope with failures and now feels justified in adopting more optimistic design parameters.The wall control program at Cardinal River Coals Ltd. is based on the premise that the walls are going to fail, monitoring is to confirm when. The program consists of monitoring slope movements and piezometric levels as well as structural mapping and visual inspections. In case of excessive movement, the frequency and intensity of the monitoring is increased. If a failure is impending, suitable remedial action is undertaken such as cutting down the crest, building up the toe, depressurization of the wall, artificial support, or a combination of the above. If remedial action is not possible, monitoring permits operations to continue up to near the time of failure.At the design stage, the emphasis is on identifying the potential failure mechanisms and the con sequences of failure. Once the potential failure mechanisms are identified, a monitoring system can usually be employed to give sufficient response time, and providing the consequence of failure is not severe and/ or remedial action can be taken to arrest the movements, then it is practical to mine pit slope s which have a higher probability of failure."

Jan 1, 1985

By Julian W. Feiss

Before undertaking to present to you a current analysis of copper, I would like to preface my remarks with a few observations that in themselves have a bearing upon commodity reviews in general. Having sat through a large number of such reviews since first joining the A. I. M. E. nearly forty years ago, I have no illusions about the hazards of the undertaking. If a speaker presents a statistical summary of commodity economics for the last year, most of his audience, having already read at least four commodity summaries on the identical subject, either get up and walk out or fall asleep. Should the latter happen, and were the listener to tumble from his chair and break his neck, obviously the speaker is liable. The subject matter seldom lends itself to histrionics on the part of the speaker so dangers of heart attack in the audience are not too great. Therefore the speaker, in order to retain listener interest, resorts to prophecy. Such venture was undertaken long ago by weather soothsayers, the "harouspex" of Ancient Rome, who generally cut up a sacrificial sheep and after staring at the entrails made their predictions which I understand had a batting average somewhat better than those undertaken on Wall Street based upon Dow Jones averages. Not being a licensed harouspex I cannot undertake predictions. I shall, however, fall back upon the experts.

Jan 1, 1965

By R. A. Wagstaff

Since the time of the early Egyptians, the use of copper: has been a boon to the life of most of the civilized world. Its use has been varied; in many connections, the art by which it attained its greatest usefulness has been lost. In this paper an endeavor will be made to take into consideration some of the many changes that have occurred during the last 40 years of copper-smelting operations. During that period the copper blast furnace has been almost forced out of existence by new methods of ore concen-tration—first, gravity concentration, and then flotation. These new methods of concentration introduced many new factors into the metallurgy of copper. The product was wet, it was fine and it was high grade. To overcome all these factors many changes have been necessary throughout the smelting agenda. New equipment has been necessary for transportation, unloading, sampling, bedding and moisturing in all smelting plants, especially the custom smelter' During the early days of "flotation," little was known about filtering or the use of an alkaline circuit; often the concentrate going to the smelter contained 2' to '5 Per cent moisture. It is easy to imagine the difficulty arising with a product of this nature when it had to be shoveled by hand labor. To meet these conditions, mechanical unload- ing and sampling devices were soon developed. In many instances such good progress was made that actual costs for handling this unfavorable product were lower than those formerly incurred on the old product. Today most sampling of copper ores and concentrates is being done by mechanical sampling, pipe or augur sampling, or shovel sampling. Where concentrates are uniform in metal content, a great many of the plants now use pipe or augur sampling. For spotty ores, the old shovel sample with cone and quartering during the final stages is still in' use. Where big tonnages are handled, mechanical sampling of concentrates is being done, with satisfactory results. To curtail slow and tedious cutting and mixing procedure, mechanical mixing boxes, splitters and cutters are used to cut down labor costs. Milling As crude ores become scarcer, the use of milling operations increases. The few crude ores that are still smelted are used as fluxing types. To use these ores finer grinding has been found advantageous. This has made for better bedding and fluxillg conditions, which in turn makes for faster smelting, lower fuel consumption and better metal recovery. The degree of fineness is more or less determined by the nature of the product. Most plants have set a standard of through 3/8-in. mesh screen for roaster -reverberatory smelting and through 3/4-in. mesh screen for converter fluxes. For some refractory Ores, even finer grinding has been found to be advantageous for good reverberatory smelting-

Jan 1, 1944

By C. R. Kuzell

Although furnaces constructed of refractory brick have been operated for many decades, there has always been an unfulfilled desire by the operators for a less arduous and more satisfactory method of patching weak spots and burned-out zones in order to postpone and to effectively extend the termination of a furnace campaign. Not only has this desire frequently arisen when small spots have approached incipient failure while the furnace structure as a whole was still in good condition, but also when larger areas showed signs of needing replacement. The available methods have been arduous, sometimes dangerous, inefficient with respect to the life of new refractory material used, and nearly always have necessitated interruption of the continuity of the furnace operations and therefore reduction in furnace production during the period of time required for the repair work. Most of these older methods have involved the replacement of masonry by refractory shapes in the weakened areas. Many attempts have been made to develop a method of patching the burned-out areas by spraying granular refractory material upon old surfaces. While some success has been attained in attempts to renew the grooved, corroded side walls and fettling, and the edges of hearths, there have been no known successful applications of the spraying method in patching the underside of arches of operating furnaces. The method developed recently at the Clarkdale smelter of the United Verde Branch of Phelps Dodge Corporation, at Clarkdale, Aria., and described in this paper, has been found to be not only convenient and successful with respect to patching vertical or inclined surfaces, but has met with a marked degree of success in patching the parts of furnace arches that are exposed to flame, the successful result being obtained without interruption or interference with the continuity of furnace operations. It may be described as a method of renewing the interior refractory surfaces of operating furnaces by pneumatic spraying of an aqueous suspension of finely divided. particles of refractory material. It has been used

Jan 1, 1944

By Leonard Larson

Before direct or wet smelting of copper concentrate was adopted at the McGill smelter, in November 1932, actual furnace smelting tests had indicated the possibility of smelting between 400 and 500 dry tons of wet concentrate per furnace day. Under calcine smelting practice, solid charge up to 116; tons per furnace day had been smelted. It was realized that in order to smelt wet tonnage in equivalent amount per furnace day, a higher combustion rate and higher temperatures would be necessary within the furnace. The reverberatory furnace considered in the following history of wet-smelting developments is a unit rz7 ft. long and 28 ft. 8 in. wide, inside dimensions (Fig. I). This furnace was in operation through all the years from 1934 to date. During 1933, the first complete year of direct or wet smelting, the plant was on a curtailed copper-production basis and the available concentrate tonnage to be smelted was limited. The average coal-firing rate in the reverberatory for that year was 124 tons per furnace day. This rate was lower than the average for years immediately preceding under calcine smelting practice. With this coal-firing rate, an average of 391 tons of new metal-bearing material (N.M.B.M.) was smelted per furnace day. The following year, 1934, the coal-firing rate was increased to 139 tons and the smelting rate increased to 448 tons N.M.B.M. per fur- nace day. In succeeding years production required that either more tonnage be smelted in the one furnace or an additional furnace be placed in operation. With this situation confronting the smelting department, it was determined to continue the program of increasing the coal-firing rate and also to intensify the temperature in the smelting zone of the furnace. In order to accoinplish this, various improvements were made to aid combustion within the furnace. The burners were enlarged, increased primary air was supplied to the burners, and changes were made in the furnace to enlarge and streamline the outlet, thus increasing the furnace draft. The coal-firing rate was increased yearly until 1937 when the firing rate averaged 210 tons per furnace day. Thereafter the firing rate fluctuated according to character of charge and production requirements. In general, however, with the same character of charge the smelting rate increased in almost direct proportion to the increases in firing rate. Table I shows the average coal-firing rate, smelting rate, and other pertinent data for the direct-smelting years of 1933 to 1939 inclusive, the first fivc months of 1940 and May 1940. These figures show that the water evaporated in the waste-heat boilers was in almost direct proportion to the coal-firing rate. In making comparisons in the table, it should be borne in mind that the figures, except for May 1940, are yearly averages. Because of changes in character of charge or operating conditions, records for individual days or even months

Jan 1, 1944

By M. G., Corson

1. In addition to the alloys of copper with iron previously found by Hanson and Ford to show an increase in the concentration of the alpha range with increase in temperature the following binary and ternary systems have been found by the author to exhibit: the same feature: (a) Copper-chromium. (b) Copper-cobalt. (c) Copper-silicon. (d) Copper-nickel-silicon and its pseudo-binary section Cu-Ni2Si (formula of compound definitely established). (e) Copper-cobalt-silicon and its pseudo-binary section Cu-Co2Si (formula of compound established with some probability but not as definitely as for Ni2Si). (f) Copper-chromium-silicon; formation of a compound definitely established (compare Figs. 1 and 2). The formula of this compound may be either Cr2Si or Cr3Si. (g) Copper-iron-silicon; presence of a phase containing both iron and silicon established in an indirect way only. No definite microconstituents observed. 2. RANGES OF SOLID SOLUBILITY (percentage at various tempera¬tures). (a) For copper-chromium: 0.8 at 1000° C.; 0.5 at 900° C.; 0.25 at 800° C.; 0.05 to 0.1 at 500° C. (b) For copper-cobalt: 3.4 at 1000'C.; 2.4 at 900'C.; 1.7 at 800'C.; 0.9 at 600°C.; 0.35 at room temperature. (c) For copper-silicon (Fig. 3) : 6.8 ± 0.1. per cent. at 800° C.; 3 per cent. at 400° C. and probably below 2 per cent. at room temperature if sufficiently long annealed. (d) For copper-cobalt silicide: 3.3 at 1000° C.; 2.4 at 900° C.; 1.6 at 800° C.; 0.7 at 600° C.; 0.3 at 300° C. (e) For copper-nickel silicide (Fig. 4): 8.2 at 1000° C.; 5.5 at 900° C.; 3.6 at 800° C.; 1.6 at 600° C.; 0.7 at 300° C.

Jan 1, 1927

By R. G. Helberg, S. M. Rebelo

"Copper and cadmium are removed from the zinc sulphate solution in primary purification by cementation reaction followed by filtration. The solids are sent to the cake leach section where zinc and cadmium are recovered from the copper rich slurry. The copper solids from cake leach are filtered, bagged and sold. In order to achieve a lower cadmium copper cake, an altered process flow is suggested. It is proposed the primary purification be split into two steps for individual removal of copper and cadmium. INTRODUCTIONCopper cake is a product of primary purification, also known as copper and cadmium removal. Copper and cadmium are removed by cementation reaction in four stirred reaction tanks. The slurry is then filtered through Shriver manual plate and frame presses with the solution advancing to the next stage of purification, hot zinc purification (HZP). The solids from primary purification are further processed at the cake leach section where zinc and cadmium are separated from the copper rich slurry. Cadmium and zinc are dissolved in the cold cake leach tanks using spent electrolyte. Cadmium is recovered from this cadmium rich solution by cadmium sponging, leaching and electro-winning circuits. The residue from this cold leach step is further leached using spent electrolyte at a temperature of 85°C. The copper rich solids from hot cake leach are filtered on a drum filter and bagged in 1 ton bulk bags for shipping to buyers.Current assays of copper cake are shown in Table 1. The goal is to produce a copper cake product that is below 0.5% cadmium."

Jan 1, 2012

By W. H. Bassett

THE modern smelting and refining of copper is distinctly an American development. The present demand for sound and perfect castings for rolling is due to the development of American industry. Prac-tically every article made from sheet metal or, for that matter, from any form of metal is made by mass produc-tion methods. Faulty material disturbs the orderly sequence of operations and in addition requires expen-sive inspection and unbearable rejection of finished product. This demand, therefore, is positive and will have to be met. Some mines produce ore that can be smelted and re-fined without the electrolytic process into satisfactory copper for the wrought metal industry, and some of these ores carry small amounts of impurities that are of use in hardening and toughening the copper. Most of the copper ore mined contains impurities that must be removed and, fortunately, precious metals which are separated at the same time make this re-moval profitable. The modern electrolytic refineries have their methods so well under control that the product meets all re-quirements without question if properly fire refined and cast. The "if" in this case is important, because there is evidence of carelessness or want of control at times in the material from some of the producers. It is nec-essary that the melted cathodes should be saturated with oxide to dispose of sulfur and that the copper should then be poled to the proper pitch or set. Sometimes statements leak out to the effect that it is unnecessary to oxidize completely the molten cathodes and a little less rabbling saves poles, which are expensive. The re-sult is that the rolling mill gets porous castings and produces seamy or slivered sheets or strips. The condition of the molds, their temperature, and the temperature of the metal are all important to good copper cakes, wedges, or wire bars. Cracked, and burned molds leave rough places and porous spots. Molds which are out of shape, or cracked, make shrink-age cracks which gap open when the castings are hot-rolled. Dampness means porosity. Drops of oil mean porous or honey-combed areas. Poor or irregular dress-ing means mold wash in the castings. Cold copper or slow pouring means cold sets.

Jan 4, 1928