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By Arthur Notman

IN VIEW of the wide publicity given to the charges by the Couzens Committee of the United States Senate of discrimination by the Bureau of Internal Revenue in favor of the copper companies, it becomes a matter of interest to consider the basis for these charges. The point to be determined is whether they rest on a foundation of fact or are purely and simply matters of opinion. The whole question boils down to the purpose of the Tax Law as applied to mines, which is to afford the same protection to them as provided for all other taxpayers, namely: that they were to be allowed to pay back as depletion to their owners the values of their properties as they existed or were estimated to exist on May 1, 1913, free from tax. To determine these valuations it was? necessary to select from a wide range of possibilities a set of values for a number of essential factors.

Jan 1, 1925

By W. A. Yuill

A process has been developed for increasing the grade of chalcopyrite concentrates from about 25 percent copper to about 60 percent copper. The concentrates are treated with two steps of autoclaving and then by flotation. Because of the lower associated weight, copper in the concentrates could be shipped and smelted at less cost than untreated concentrates. Use of the process can also increase overall yield from an orebody if a lower grade concentrate is sent to enrichment than would be sent to a smelter. Potential applications of the process would be for treating concentrates that must be transported a long distance for smelting or for treating concentrates so as to increase the capacity of a smelter.

Jan 1, 1984

By G. Zárate, G. Tapia

Anglo American Chile has been doing copper concentrate leaching studies at the laboratory and small pilot plant scale since 1992. Among the processes evaluated are bacterial leaching and pressure leaching using Mantos Blancos, Salobo Project and Quellaveco Project concentrates. Late in the nineties, it was decided to focus the research on pressure leaching, either medium or total pressure oxidation. Preliminary scouting tests were run with Mantos Blancos concentrate samples during 2000, which were repeated during 2003 together with samples of Los Bronces and El Soldado concentrates, in order to define the most suitable concentrate for running a pilot plant campaign at AARL, which was carried out in two campaigns, a first one from November 2003 through January 2004 and a second one during April 2004. Mantos Blancos was the selected concentrate and the laboratory and pilot plant results are discussed in this paper together with some preliminary economic estimates.

Jan 1, 2004

By E. N. Mounsey

Ausmelt Technology was selected by Bindura Nickel Corporation (BNC) as the basis for a new copper circuit to process nickel plant copper leach residue to blister, anode and finally cathode copper and recover PGM values at the Bindura Smelter Refinery (BSR). The process selected, based on Ausmelt Technology to smelt and convert the residue to matte and blister copper and produce a discard slag, is novel incorporating smelting, converting and slag reduction process steps in a single Ausmelt vessel. The process demands a high quality blister copper product with low levels of arsenic and nickel. This paper reviews the project and the initial operational results to the end of 1997 of the Ausmelt Top Submerged Lancing (TSL) smelter and discusses the implications for the wider TSL converter market.

Jan 1, 1998

By Kim Fagerlund

Boliden Harjavalta Oy operates a copper smelter in Finland, which is based on flash smelting together with Peirce-Smith converting of copper matte. This paper reviews a case study when a high arsenic feed mixture was successfully eliminated in order to guarantee the anode quality. Based on theoretical and practical knowledge in slag chemistry at Outokumpu Research, the CaO-fluxing practice was introduced. Description of a thermodynamic simulation using MTDATA and implementation of the results into converting practice is given. Results showed that the impurity fluctuations in raw materials could be effectively controlled by efficient utilization of different slag chemistry.

Jan 1, 2005

By Lauri Holappa

Copper converting is mostly performed in Peirce-Smith converters. The process is still very similar to the original one developed in the early 20th century. It is a batch process in a horizontal cylindrical reactor with air blowing via tuyeres along the length of the reactor side. The Peirce-Smith converter has its roots in Bessemer's inventions in the 1850's as he tested both horizontal and vertical vessels for steel converting. However, for steel making a vertical pear-shaped converter with air bottom-blowing was established. In the course of time, there was a distinct necessity for oxygen usage instead of air due to harmful effects of nitrogen to steel properties and its cooling effect. In-bath blowing of oxygen did not succeed, however, and top-blown oxygen converter with oxygen lance (LD or BOF) was first developed in he 1950's and emerged rapidly to a dominating position. Somewhat later oxygen bottom-blowing via special shrouded tuyeres was developed (OBM or Q-BOP) but has attained only fractional share. Bottom-blowing technique had, however, impact on the current combined blown converters which adopted the benefits of both top and bottom blowing. In copper converting Peirce-Smith type converters have kept their position until today although new processes have been introduced and at least few of them seem to be emerging. In one respect copper converting has a clear leading position i.e. in the progress of continuous converting processes (Mitsubishi, Ausmelt). These processes utilise top-blowing lances instead of in-bath blowing tuyeres. A different principle for continuous converting is flash converting by Kennecott Outokumpu, which makes smelting and converting independent of each others. Solid ground matte is used as a feed for flash converting in a reactor shaft similar to Outokumpu matte flash smelting. A comparable process has been presented by Inco too. The paper discusses principal physico-chemical and process technical similarities and differences in copper and steel converting. Although these processes are metallurgically quite different it seems that during the modem history of ferrous and non-ferrous metallurgy, starting from the 1850's, the exchange of knowledge between these disciplines has been quite intensive. In long-term perspective, many similarities in the development can be found but also divergences due to different ambient circumstances.

Jan 1, 2003

By R. B. Nourse, R. Hundermark, B. Masters, H. Joubert

The new 30 MVA slag cleaning furnace at Waterval Smelter, Rustenburg Platinum, South Africa, has been in operation since 10 March 2003. The furnace design and operation face a number of challenges including a wide variety of feed materials and resulting bath conditions. Furnace feed varies in combinations of granulated Waterval Ausmelt Converter Slag (WACS), hot fed Peirce-Smith converter slag, concentrate and reverts. Coke is added as reductant. The resulting slag composition varies considerably and regularly. For the case feeding WACS an almost pure fayalitic slag (60%+ FeO, 30%+ SiO2) with a very low viscosity results. Due to the widely varying slag conditions, including a superheated fayalitic slag with high fluidity, a robust sidewall design is required adjacent to the slag bath. For this reason the furnace sidewall is equipped with Pyromet's MAXICOOL® high intensity copper cooling system. The design and installation of the copper coolers as well as tap holes are discussed. To cope with the variation in bath conditions and high slag superheat (350°C when tapped at 1650°C), the copper coolers are capable of removing peak sidewall heat fluxes above 500 kW/m2. Feedback is included on the performance of the Pyromet MAXICOO® copper cooling system for the first two years of operation. The paper further includes an overview on the design and performance of the tap holes, furnace shell, furnace roof and copper slag spouts.

Jan 1, 2005

By R. J. Sandberg

The Copper Creek area, part of the Bunker Hill District, Pinal County, Arizona, lies within the southwest porphyry copper province of North America at the intersection of a northwest trend and an east-northeast trend of Laramide porphyry copper deposits. The Copper Creek area has been mined and explored for copper and molybdenum since the early 1900?s. The majority of this work focused on the more than 400 surface exposed breccia bodies. In the 1960 to 1970?s deeper drilling discovered a deep porphyry copper-like setting. Redhawk Copper currently has NI 43-101 compliant resources of about 0.652 billion pounds of measured and indicated and 2.745 billion pounds of inferred copper equivalent in breccia hosted and porphyry style deposits. See Figure 1.

Jan 1, 2010

By Claudio Parra De Lazzari

The determination of the governing step of the deoxidation rate and the effects of the hydrogen content of the mixtures (C), the diameter of the delivery orifice (4) and the Reynolds number of the orifice (Re.) on the product Av kjg were investigated. A,, is the total surface area of the interface between the bubbles and the melt and kjg is the mass transfer coefficient in the gas phase. The design of the experiments was based on a two level statistically fractionated, factorial planning. Oxygen in the melt was measured as a function of time. It was found that the governing step of the deoxidation rate was the transport of hydrogen in the gaseous phase and that {Ay kjg} increases with C, {o} and Reo.

Jan 1, 1997

By R. H. W. Chadwick

We in Kennecott are well aware that Alaskans are interested in the progress of our project at Ruby Creek. We would very much like to be able to present you with a final report at this time and tell you about a new mine. I'm afraid, however, that it will be several years at best before such a report can be made. This, then, is an interim report to describe briefly some of our findings to date, and to acquaint you with some of the problems, both geologic and economic, which must 5e resolved favorably before we can talk about a mine. There are several things about this project which make it unusual and interesting to those of us who have been connected with it. Firstly, there is the fundamental importance to Alaska, in the present stage of its economic history, of any undertaking which offers promise of turning a natural resource into a competitive export product. I am sure all of us would get a lot more satisfaction out of having a part in bringing in a new mine in Alaska than we would out of adding another one to the long list in, say, Arizona.

Jan 1, 1960

Uranium, discovered in 1949 at Rum Jungle, 40 miles south of Darwin, N. T., was mined and processed to U3O8 from 1954 to 1963 by the Territory Enterprises Pty. Ltd. TEP is a Government company managed by Conzinc RioTinto of Australia Ltd. During this period, the uranium oxide was sold under contract to the Combined Development Agency, a joint Anglo-American uranium procurement agency. When the contract terminated in 1963, more than 31/4 million pounds of uranium oxide had been delivered which had been mined from three open pits. Copper ores, found with the uranium, necessitated the addition of a copper circuit to the concentrator. Copper concentrates containing 12,981 pounds of copper were also produced. Rum Jungle was the largest single industrial enterprise in the Northern Territories and, as such, was an important economic and social factor in this sparsely settled tropical region. To stretch out the life of this enterprise for the above reasons, and with the added possibility that the uranium market might improve, the Commonwealth mined out and stockpiled 650,000 tons of ore containing 9.6 lb of U,O, per ton, which is sufficient to sustain the treatment plant at 200 tpd until about 1971. In the plant, uranium is recovered from solution by solvent ex- traction. Current output is being stockpiled pending suitable market conditions.

Jan 10, 1964

By Judson G. Brown

In the May, 1969 issue of Mining Engineering the Editorial Director, John V. Beall, described the Japanese Onahama Copper Smelter and Refinery as follows: "On the shore of the Pacific, 120 miles north of Tokyo, is the world's most modern copper smelter and refinery.? One of the improvements that has been made at the Onahama Refinery is the quality of the electrolyte in the copper refinery electrolytic cells. This has been accomplished by reducing the concentration of slimes in the cells between the electrodes. In a December 19, 1966 review in Chemical Engineering magazine reference was made to some tests in Sweden as follows: ?However, at 1,000 amps/sq.M., satisfactory cathodes could be prepared, provided electrolyte flow past the anode and cathode was at least 3 to 4 meters per minute, and the slime content was not allowed to exceed 20 to 30 mg. per liter. By dropping the current to 500 amps with the same electrolyte velocity, the slime content could grow to 50 mg. per liter (50 ppm) without causing occlusion at the cathode." From this data it appears that the production capacity of copper refining electrolytic cells can be significantly increased. In order to do this the concentration of suspended contaminating slimes in the electrolyte solution is reduced by filtration. The electrolyte in-between the active electrodes must be purged with higher velocities to maintain a high concentration of the desirable copper ion in the liquid film adjacent to the cathode and the sulfate ion in the liquid film at the anode. This higher velocity also carries away from the cathode the undesirable impurities released from the anode as they are released into the electrolyte as filterable solids.

Jan 1, 1970

By H. Kudelka

Copper electrowinning at Duisburger Kupferhuette was introduced in March 1975. The electrowinning plant has a capacity of 10,000 mT of copper cathodes a year. The cuprous oxide feed material is an intermediate product of the treatment of the leach solutions, originating from chloridizing roasting of pyrite cinders. This material is characterized not only by a wide spectrum of accompanying impurities, but also by an unusually high level of precious metals. As the priority set was the production of high-purity cathodes. there was a need for developing a process which would be suited to treat complex leach liquors . The process adopted consist s of an oxidizing leach in spent electrolyte, followed by two- stage purification, By this means. a low- acid pregnant copper electrolyte is obtained free of elements detrimental to copper quality. Electrowinning is carried out at a current density of 200 A / m2 in the presence of 10 g/l zinc. The electrowon copper has a conductivity of at least 101.4% lACS and a softening temperature not exceeding 200°C, which makes it a suitable product for continuous casting and dip ?forming.

Jan 1, 1977

By P. M. Tyroler

Inco operates a hydrometallurgical plant to treat the residue from the pressure carbonylation process. The main constituent in the residue is cop¬per. The residue is leached under pressure in an acid sulphate solution in two stages and the copper is recovered via electrowinning. The electrowinning tankhouse is fully integrated into the overall plant flowsheet as spent elect¬rolyte is required in upstream leaching steps. In recent years, the amount of residue had increased and copper removal capacity became the rate limiting factor for the entire plant. Consequently, a major program was undertaken to upgrade the tankhouse with regards to capacity, efficiency, cathode quality, working environment and structual integrity and appearance. This paper will describe current facilities and operation, and detail progress in our up¬grading efforts.

Jan 1, 1987

Solvent extraction-electro- winning appears to be one of the most important processes for the future in the North American copper industry and for this reason both the SX and EW steps are furtive areas for development. This paper has the objective of reviewing the present state of the electrowinning technology. It discusses some recent equipment developments and concludes by discussing the direction the technology will likely go fn the next decade.

Jan 1, 1985

By E. Rosseland

Glencore Nikkelverk is operating its Chlorine Leach Process in Kristiansand, Norway, producing nickel, copper and cobalt metals by electrowinning. The copper tankhouse, with an annual capacity of 40 000 tons, is based on traditional technology with copper starting sheets and cast lead anodes. Due to the integration of this copper sulphate process in a nickel chloride refinery, operating conditions are unique. In recent years, operating costs have escalated, and health, safety and environment are top priorities. Test work on a new copper process involving permanent cathodes was therefore initiated in 2007, and a pilot plant was started up in 2012. The objective was to introduce innovative technologies and tailor these to be robust in the Nikkelverk process, to form a basis for a new sustainable copper tankhouse with a high degree of automation. Key learnings from more than 10 years of R&D work is presented, focusing on cathode materials and copper metal deposition including product quality, robotic stripping, coated titanium anodes, electrode contacts and alignment, electrode current monitoring with Hatch HELM tracker technology and acid mist capture using cell hoods with off-gas scrubbing. The new copper tankhouse project was approved in December 2018, and commissioning is planned in 2022. INTRODUCTION The Kristiansand nickel refinery was started up in 1910, processing nickel-copper matte originating from Norwegian mines. It was the first industrial plant in the world to produce nickel by electrolysis using the Hybinette electrorefining process. After roasting to burn off sulphur in the matte, copper was leached and recovered as cathodes by electrowinning with lead anodes. In the first years, the copper cathodes were fire- refined and cast into ingots for sale (Thonstad Sandvik, 2004). The Nikkelverk refinery was acquired by Falconbridge Ltd. in 1929, and since then matte from Sudbury, Canada has been the main feed source. The Hybinette process was in operation until 1975 when conversion to the newly developed Chlorine Leach Process was started (Stensholt, Zachariasen, & Lund, 1986). In this process still used today, nickel and part of the copper in the matte is leached using chlorine gas generated on dimensionally stable anodes in the nickel and cobalt electrowinning tankhouses, as illustrated in Figure 1. The presence of dissolved copper ions in the strong chloride leach solution is essential for effective chlorine absorption and nickel dissolution. To improve copper-nickel separation, slurry from the atmospheric leach is pumped to autoclaves and then to cementation tanks for precipitation of copper as copper sulphide, which is collected in filter presses. The leach residue, also containing the precious metals, goes through a 3-stage wash to remove chlorides before being introduced as a slurry to fluid-bed roasters for sulphur removal. The resulting calcine is then leached in spent electrolyte from the copper electrowinning tankhouse, to dissolve most of the copper and also some nickel, cobalt and other elements. After separation of the leach residue, elements like Bi, Te, As and Ag are removed from the strong copper sulphate solution by reaction with metallic copper in three columns in series filled with cut copper cathodes. The purified solution then passes polishing filters before being mixed with spent electrolyte and returned to the electrowinning cells.

Jan 1, 2019

By W. J. Dolinar

The U.S. Bureau of Mines implemented the Fe2+ /Fe3+-SO2 anode reaction in a Cu electrowinning cell with full-size electrodes. Electrowinning was conducted using industrial electrolyte at 258 A/m2 (24 A/ft2) and 40 'C. Manifold injection of electrolyte provided circulation between the electrodes. Five-day operation using an optimized manifold gave an average cell voltage of 0.94 V at 89% current efficiency, which amounted to an energy savings of 2.82 MJ/kg (0.355 kW-hr/lb) compared to conventional electrowinning. Acid misting was completely eliminated, and SO2 concentration 23 cm (9 in.) above the cell averaged 0.06 ppm.

Jan 1, 1995

By K. Asokan, K. Subramanian

"Electrowinning of copper by monopolar cells require common anode and cathode busbar and crossbars to connect each electrode to the respective common busbar. On the other hand, the bipolar configuration warrants the end electrodes only to be connected to busbars; there is substantial reduction in copper requirement. In the present work, an electrowinning cell with bipolar electrodes and end electrodes, each having an area of 1000 cm2 was designed and operated. The bipolar electrode is made of mixed metal oxide coated titanium mesh welded to plain titanium sheet. Coated titanium mesh acts as anode and the plain titanium sheet acts as cathode. Environmentally unacceptable lead anode and the recurring loss of lead are done away with. Closer spacing of the electrodes, paves way for the application of higher current density leading to mass transfer enhancement. Performance of bipolar copper electrowinning cell is reported.1. IntroductionThe normally adopted practice in electrowinning of copper is the conventional monopolar configuration. In this practice, the individual electrodes act either as anode or cathode. Hence there is a need to connect every one of the electrodes to the common anode or cathode busbar and crossbars running across the top of the cell are necessary. The common busbar carries very high current which is divided among the individual crossbars and hence has to be thicker in relation to the current load of the cell. The drawback of the need to use common busbars of thicker cross section and the need to have crossbars are obviated in the bipolar configuration."

Jan 1, 2009

By K. C. Sole, G. Robinson, M. S. Moats, W. G. Davenport, S. Sandoval

Global practice in hydrometallurgical production of copper cathode by electrowinning is reviewed, based on individual plant operating data for 2018. Data from 29 plants were collected, representing 38% of world cathode copper production. Similar surveys were carried out in 1997, 1999, 2003, 2007, and 2013. This survey includes analysis of historical and current data. Evolving trends in operating conditions and performance, as well as equipment design and process technology choices, are analysed and differences in operating practices with location are assessed. Examples of recent technology and operational choices to increase productivity, improve copper quality, and decrease electrical energy consumption are discussed. Significant project expansions, particularly in Africa, and the consolidation of numerous small Chinese operations are also presented. INTRODUCTION Global trends and operating practices in copper electrowinning (EW) in 2018 are reviewed and evaluated. Similar world and African surveys were carried out in 1997, 1999, 2001, 2002, 2003, 2007, and 2013 (Robinson, Davenport, & Jenkins, 1997; Jenkins, Davenport, Kennedy, & Robinson, 1999; Davenport, Jenkins, Robinson, & Karcas, 2001; Robinson, Garbutt, & Davenport, 2002; Robinson, Davenport, Jenkins, King, & Rasmussen, 2003; Robinson, Davenport, Moats, Karcas, & Demetrio, 2007; Robinson, Sole, Sandoval, Moats, Siegmund, & Davenport, 2013). Contributing operations included sites from the USA and Mexico (9), Chile and Peru (6), Laos (1), Kazakhstan (1), and Africa (9). Despite fewer contributions compared with past experience, this survey nevertheless represents 2018 copper EW cathode production of 1.76 Mt, or about 38% of world production of 4.64 Mt (International Copper Study Group, 2017). This drop in permission to contribute is attributed to the more competitive nature of the industry and unprecedented production pressures; furthermore, several operations in Australia have shut down, while large operations that are currently commissioning or ramping up to full production in Africa and Asia declined to participate. Of the Chinese operations, which represent an increasingly important proportion of global electrowon cathode copper, particularly in Africa, only Tenke Fungurume (Democratic Republic of Congo; DRC) participated in this survey.

Jan 1, 2019

By F. Nava-Alonso, O. Alonso-González, A. Uribe-Salas, R. Pérez-Garibay

"Cyanidation is the most used method to recover gold and silver from their ores. In this process, other metals besides gold and silver may sometimes dissolve and interfere with the efficiency of extraction. Copper is one of those metals, reaching concentrations as high as 1000 mg/L in some cyanidation plants, making difficult the extraction and purification processes, and increasing the operating costs.This preliminary work was intended to study the feasibility of using amines to form a precipitate and to eliminate copper from a synthetic solution containing high copper and cyanide concentrations, as is the case of some cyanidation effluents. The solid formed is removed from the solution using conventional filtration techniques. Seven amines were evaluated at different pH values and amine additions. Up to 90% of copper present may be removed at the natural pH of the effluent (alkaline). The remaining copper would permit to recycle the solution back to the cyanidation process. IntroductionCopper is generally considered the most problematic metal in gold leaching due to the rapid formation of copper cyanide complexes when some readily-soluble minerals are processed (e.g., azurite, malaquite, cuprite, chalcocite and bornite). The copper solubilization as cuprous cyanide complexes leads to a significant economic penalty in terms of excessive cyanide consumption and high cost for cyanide elimination. When activated carbon is used to recover gold and silver, the copper-cyanide complexes decrease the efficiency of the process because of the competition of the cuprocyanides with the aurocyanide for the adsorptive sites on the activated carbon (Rees and Deventer, 1999).Several techniques have been developed to attempt to overcome the problems caused by the copper presence in cyanidation solutions, notably: acidification-volatilization-regeneration (AVR), ion exchange-electrolysis or solvent extraction-electrowinning (Lu et al., 2002). In this work the use of some amines is proposed to remove the copper-cyanide complexes by precipitation of a copper-cyanide-amine solid. The process was evaluated for different amine additions and pH values, using copper-cyanide synthetic solutions of composition similar to that presented by some cyanidation plants with high copper."

Jan 1, 2008