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By Paul F. Richardson

Liquids containing suspended solids are encountered in most mineral processing applications. Solids levels cover a very wide range, from ppm levels in cooling water systems to slurries containing greater than 70% solids. When the aqueous phase is recycled or further processed, a solid/liquid separation process is used. Chemical additives used to carry out this process are called coagulants and flocculants. In other cases, one seeks to control or modify the properties of the suspension. Dispersants are chemicals used to aid in suspending solids in a liquid as well as to control the properties of the resulting suspension. Dispersants find a range of uses in mining and mineral processing such as scale control, filter aids, flotation aids, and slurry viscosity modification. Materials used as dispersants include inorganic salts, alkalies, organic surfactants, and polyelectrolytes. This paper discusses the use of dispersants in mineral processing, with an emphasis on control of slurry viscosity. The mechanism of dispersion and factors that affect the choice of dispersant will be discussed.

Jan 1, 1986

By R. V. Ramani, K. Bode

"IntroductionThe theory of particle dispersion and deposition in turbulent flow is important to many fields of science and engineering. Dispersion has been studied in some detail since the early fifties (Taylor, 1954; Fischer, 1967; Osipov and Grekov, 1968; Skobunov, 1970 and 1973; Klebanov and Martynyuk, 1974). A broad research effort has also been underway in studying the mechanics of dry particle deposition. Friedlander and Johnstone (1957) proposed a theory, according to which particle deposition from vertical pipe flow could be described by an eddy diffusion transport followed by a final flight to the surface. There have been numerous revisions and additions to this original theory (Owen, 1960; Liu and Agarwal, 1974; Liu and llori, 1974; El-Shobokshy and Ismael, 1980) The mining process essentially consists of breaking in situ materials and transporting them out of the mine. An inherent characteristic of this process is the generation of fine particles. Fine airborne particulates are associated with a number of threats to the health of the miners; fine coal dust can also result in mine-wide catastrophic incidents such as dust explosions. For these and other reasons, it is important to understand the behaviour of airborne dust particulates, particularly their generation, entrainment, transport, dispersion, and deposition in the mine environment for their control.Mine related studies on dispersion and deposition have been few. Yet, several studies of gas and dust dispersion, diesel exhaust contamination, and methane ingress into mine workings have recognized the need for developing reliable parameter values for fundamental understanding of the phenomena (Da""Yes and Slack, 1954; Hodkinson, 1957; Hodkinson and leach, 1958; Mass and Wildschut, 1966; Airey, 1969; Courtney et al., 1986; Stefanko, Ramani, and Thakur, 1974; Stefanko, Ramani and Kenzy, 1977; Bhaskar, 1987, Bhaskar and Ramani 1990; Qin and Ramani, 1989; Shankar and Ramani, 1990)."

Dec 1, 1995

By R. V. Ramani, K. Bode

"IntroductionIn part 1 of this paper, the results of the experimental work in a wind tunnel under controlled conditions were presented. To understand the spatial and temporal behaviour of airborne dust under mine conditions, experiments were performed in the Lake Lynn Experimental Mine of the US Bureau of Mines. The mine airway experiments were designed to study the variations of ambient concentrations along the length of an airway, and the deposition rates and deposition velocities in an airway cross section. Other objectives of the study were to investigate the spatial and temporal behaviour of airborne dust with regard to air velocity and particle density, the size distribution of the airborne dust cloud as it travels in the airway, and the size distribution of the dust particles deposited along the airway. Other objectives of the study were to compare wind tunnel results with In-Mine results, whenever appropriate.Experimental ProcedureLocationA complete description of the Lake Lynn Laboratory Mine of the US Bureau of Mines (USBM) can be found in the US Bureau of Mines Information Circular 8911 (Mattes et al., 1983). This mine provides excellent facilities for dust experiments. The airway dimensions are similar to those of a coal mine airway. The mine has a drift (D Drift, see Figure 1) that extends almost 500 meters without interconnecting airways, stoppings, or bends. The D drift measures approximately 6m in width and 2,25m in height.The Lake Lynn Laboratory Mine· is ventilated by a variable speed, 75 kW (100 hp), 28,3 m3/s (60 000 cfm) blower fan installed on the top of the ventilation shaft. Air velocities of 1, 1,3 and 1,8 m/s, respectively, could be obtained in the D Drift. However, the temperature changes at the surface can cause small variations in air quantities and velocities underground. The low background dust level in the mine reduces the problem of sample contamination from other sources of dust. Extended periods of uninterrupted data collection can also be scheduled. Mine airway parameters which are important for the analysis include the dimensions of the airway and the ventilation data such as the air velocity, and the pressure loss in the drift. All these data were acquired during altimeter surveys which were conducted prior to each of the experiments."

Dec 1, 1995

By Ramiro Escudero G.

Since the introduction of column flotation almost forty years ago the column technology has grown into several non-mineral applications such as among others the effluent treatment, soils recovery and de-inking of recycled paper. Recent studies have demonstrated that particular characteristics of the dispersion (bubble size, gas holdup, bubble surface area flux) are needed for a given flotation column duty. In this work, two kind of spargers were tested (i.e., internal and external) using a 4 inch column lab in a two phase system. Results show that the external sparger provides a dispersion with characteristics that include those produced by the two internal spargers.

Jan 1, 2003

By Allen Garrison

IT is the purpose of this article to present. the results of an investiga-tion of certain clay and shale suspensions having viscosities that are materially influenced by fluid motion, and to discuss the bearing of these results, upon the choice of policy in the control of drilling fluids. A previous article described the design and the characteristics of an instru-ment adapted to measure the viscosity of plastic suspensions during continuous uniform motion and at a variety of speeds.1 It has long been recognized that the viscosity of a clay suspension depends on the past history of the fluid motion. Since an abundance of literature is available on this phenomenon,2 it is not necessary to describe it in more than general terms. It is usually observed that rapid motion reduces the viscosity of a clay suspension, and that some time is required for the viscosity to fall to its equilibrium value after the steady motion is started. On reducing the speed of motion to some lower value, the viscosity again rises, but it also requires some time to attain a steady viscosity value at the slower rate of motion. Thus clay suspensions are usually observed to be increasing in viscosity as time passes when the measurement has been immediately preceded by fluid motion that was more rapid than that employed in the measurement. And it is usually observed that the viscosity falls as time passes when the measurement has been preceded by more quiescent conditions. Reed,3 and Broughton and Hand4 have reported a condition of observa-tion of clay suspensions in which the viscosity was observed to fall during the first few moments of steady motion, and rise thereafter. The characteristics of the new instrument are particularly well adapted to studies of this kind. With it we have been able to observe all of the phenomena described above, and it is important to understand their nature because they all occur at some time during normal drill-

Jan 1, 1939

By Robert F. Conley

In the mining, manufacturing and application of inorganic pigments, dispersion contributes significantly. This is especially true with mineral pigments because of the variety, in slurry operations required for their processing. Such operations include any of the following: (1) mine-transport (2) wet grinding (3) flotation/beneficiation (4) wet magnetic separation (5) selective floculation (6) size classification (7) chemical processing (8) spray drying Dosage levels and general economics of dispersant use are broadly variant, being dependant upon the agents employed, from the simplist, i.e., sodium silicate or sodium carbonate, to the more complex, as polyacrylates and organo-phosphates. In certain unit processes the dispersant must exhibit unusual chemical stability and persistence, e.g., in protracted pigment slurry shipments. In others, the agent should be fugitive to prevent secondary reactions from occurring, e.g., with high temperature calcination where alkali salts can act as aggregation fluxing agents.

Jan 1, 1985

By Jhon Silva-Castro, Russell Lamont

Understanding the behavior of materials subjected to high strain rate conditions is of fundamental importance to the mining industry. Several stages of the mining process involve high speed loading rates including blasting, scraping, comminution, etc. Technical comprehension of how rocks deform, fracture, and fail under these loads is a fundamental first step required prior to any serious attempts at optimization of the energy utilized for pertinent activities in the mining process. A Split-Hopkinson Pressure Bar (SHPB) was designed and constructed at the University of Kentucky to study the dynamic properties of various types of rocks.

Jan 1, 2017

[The following notations will be used: O an ore body. z a point in O. z' another point in O. w0 (z) a point support of infinitely small dimensions w0 centred in z. w (z) a sample (or block) of finite dimensions kv centred in z. W (z) a block of size W greater than or equal to w. W'(z) a block of size W' greater than or equal to W. W" (z) a block of size W" greater than or equal to W'. x (z) value of the regionalized variable x with support wO at point z. p (z) average value of x in w (z). pw WZ) = E[x(z')l zt in w(z) pw (z) average value of x in W (z). pwl (z) average value of x in W' (z). pwU (z) average value of x in W" (z). Note that pW (z), pw (z), pwf (z) and pw,, (z) are (regular- ized) regionalized variables with support w, W, W' and W" respectively. The relative sizes of wO, w, W', W" and O are represented schematically in Fig. 7.1. The variance of pw (z) when w (z) takes all possible positions in O is known as the dispersion variance of w in O and is denoted by a? (w in O) or a\: 0; = a2(w in a = Ew,z, inn {[p~ (z) - p121. (7.1) For convenience, the following simpler notation will be used: a> Ew in n [(p w - pl21. Consider now a large block W (z) in O with average value p~(z), and all the possible smaller blocks (or samples) w (z') of size w in W (z). We can calculate the variance of the blocks w (z') in the block W(z), which is the dispersion vaciance of w in W (z), from the relationship a2 [w in W(z)l = Ewcz,, in W(Z) {[PW (z') -pw (z)l21. (7.2) Provided the intrinsic hypothesis is satisfied (§3.4.4), this variance is a function only of the dimensions of the supports w and W, and is independent of the position z of the block W (z). We can therefore define the dispersion variance of w in W, as follows: u2 (win W) = Ew in w [(ptti - PW)~]. (7.3) In cases where the intrinsic hypothesis is not satisfied, the variance of samples w in blocks W may vary only slightly from block to block, so that the average dispersion variance of w in W (z) for all possible W (z) in O can be used: ayw in W) = Ew(,, ~n n {a2 [W in W (z)]}. (7.4) The following example will help to illustrate the importance of the variance of dispersion. Assume that we plan to develop a bedded coal deposit Q. We consider mining the ore body with only one giant dragline, which will extract each day a block of coal of size W'. The total area mined in a year will have a size W". We want to know whether this scheme is acceptable, given that the daily variation in ash content must not exceed a given percentage specified in the sales contract, which is renewable on a yearly basis. On a given day, if we mine the block W' (z), the ash content will average pwT (z). In a period of one year, the expected daily variation in ash content is measured by the expected variance of pwf (z) in W", i.e. by a2 (W'in W"). An alternative mining method might be to use two smaller draglines, each one mining W'/2 of ore per day, and Wn/2 per year. If the draglines are used to mine two distinct sections of the deposit, the expected daily variation in ash content will be u2 (W'/2 in Wj1/2)/2 Other situations, where economic decisions cannot be made without knowledge of the dispersion variance, are illustrated in § 7.4 and 7.5 below. Remark: The notation a2 (w in W) is used in this publication because of its clarity. An alternative notation, which is increasingly accepted in the literature, is s2w/W. ]

Jan 1, 1978

By M. C. Fuerstenau, J. J. Fitzgerald

Aluminum silicate hydrosol synthesis and characterization are discussed. Plausible polymeric aluminosilicate species are presented together with their effect on electrokinetics of selected minerals and flotation response of various ores. The addition of aluminosilicate hydrosol to porphyry and oxide copper ores and to a tungsten ore resulted in enhanced flotation recoveries ranging from about 1.5 to 5 percent. A significant portion of the nation's mineral resources are presently lost in the form of particles with very fine grain size. In the case of copper, for example, approximately 225 million tons of ore are concentrated by flotation per year in the United States. Total losses from porphyry ores are generally 15 to 20 percent with half of these losses being finely-divided copper sulfide minerals which do not respond to flotation. The additional 5 to 10 percent loss is the result of copper oxide minerals which are not floated. The losses of copper sulfide minerals are thought to be due in part to the lack of appropriate dispersion of the finely-divided solids less than 20 microns in size. To effect dispersion in flotation systems, sodium silicate is commonly added. Enhanced dispersion effectiveness is achieved when polyvalent metal salts are combined with sodium silicate. Since originally described by Patek (1), numerous workers have explored the utility of metal silicates. Makrousov (2), Belash et al. (3), and Eigeles (1950) (4) showed the applicability of these reagents to calcite/apatite and fluorite/calcite ores. Mercade (5, 6) reported depression of calcite in the presence of 3.33/1 mole ratio Al/Si hydrosols prepared from Type N sodium silicate (Si02/Na20 ratio 3.22/1) and 1% A12(SO4) 3•18H20 solutions. He importantly observed that the colloidal precipitates did not play a significant role in dispersion and depression but that the soluble species were responsible for this action. Patented work by this author described metal silicates used to depress calcite in scheelite flotation using 1% metal salt (FeSO4•7H2O, CoSO4•7H2O, etc.) and 5% Type N sodium silicate solutions to produce hydrosols with Si/Fe or Si/Co ratios of 8.79/1. Aluminum (III) ion systems were less effective as depressants than the iron and cobalt systems. Yang (8, 9) has studied metal silicate sols for use in the flotation of lithium and ultra-fine hematite ores. Using 10/1 Si/Fe mole ratio hydrosols prepared from 2% ferric nitrate, Fe(NO3)3.9H20, and 5% Type N sodium silicate solutions, solutions, he showed that the hydrosols either modify the slime particle surfaces or are adsorbed on the slime particles preventing anionic collector adsorption. In a subsequent patent, Yang also reported the use of these hydrosols as dispersants for beneficiation of lithium ores. Recent studies of aluminum silicate hydrosols in the flotation of chalcocite, chalcopyrite and scheelite have been reported using Si/Al dispersants prepared from 5% Type N sodium silicate and 0.1 M aluminum chloride (A1C13.6H20) solutions. Dispersant properties were shown to be dependent upon the method of synthesis, supernatant pH, and the hydrosol Si/Al mole ratio. Polymeric soluble species in these hydrosolsupernatants have been proposed as the active dispersant species. Aluminosilicate hydrosols are synthesized by the general reaction scheme presented in Figure 1. Commercial sodium silicates are available with ratios of SiO2 to Na20 of 1.60-3.25. The sample which is most frequently employed is Type N whose ratio of Si02/Na20 is 3.22/1.00. Gel filtration chromatography and NMR studies have shown that these sodium silicates contain numerous species of molecular weight from 325-2,000 gm/mole. Monomeric, oligomeric and higher molecular weight linear polymeric arrangements of these structures are found in these solutions.

Jan 1, 1989

By Hector O. Romero, Paulo C. Fernández A, Christian Rees Prado, Claudio C. Gajardo

In open-pit mining operations, the presence of remnants from past underground labors represents a significant operational challenge, especially if they are in the surroundings of high-grade zones. The existence of uncrushable elements, such as metallic support fragments of abandoned equipment, can trigger critical operational issues if they reach conveyor belts systems or primary crushers, jeopardizing the mine to plant operational continuity. These kinds of incidents lead to expensive unplanned shutdowns, the increasing of corrective maintenance events costs, and risk to meeting expected production results. This work demonstrates the application of a three-dimensional numerical modeling tool for simulating rock displacement post-blasting (by integrating key design parameters, such as blast pattern design, detonating times, charge distribution and pre and post blast surveying). The study was conducted at Andina Mine, operated by Codelco, Chile, and enabled the identification and zoning of areas with potential presence of underground hazards in displaced rock mass, using historical data from previous workings and geotechnical mapping. The displacement results were compared to the actual post-blast surveying, ensuring an acceptability level above 80%, considering both fully confined (bank opening) and free-face blasts. Additionally, this approach allows the determination of an optimal safety offset, initially set at 10 meters and currently under validation for potential reduction. The results supported the determination of safe extraction zones and the design of excavation, loading, and haulage strategies from mine to plant or stockpile, ensuring 100% reliability in the segregation of high risk materials. Implementing displacement simulations underscores their relevance in operational risk prevention and mitigation, adding value to short-term mine planning and strengthening the safety, efficiency and profitability of the open-pit mining production process.

Jan 26, 2026

By André Luiz Monteiro Martins

O objetivo do projeto foi otimizar a disponibilidade e o tempo de utilização do equipamento responsável pelo refino secundário de aço líquido da CSN, o Desgaseificador a vácuo RH. Esta otimização ocorreu através da monitoração de eventos gerados por sensores instalados no equipamento para verificar quando o mesmo iniciou a operação e qual foi o tempo necessário para completar o processo. O Disponibilidade do Desgaseificador a Vácuo RH se trata de uma ferramenta gerencial que realiza o mapeamento completo da produção no Desgaseificador durante vinte e quatro horas por dia, capaz de mapear o tempo do processo com base no tempo padrão do grau de aço e tempo de parada do equipamento, apontando todos os problemas que afetam a produção.

Aug 16, 2017

By Richard W. Patton

With the advent of the Clean Air Act and the installation of flue gas desulfurization (FGD) equipment (scrubbers) on coal fired power plants, the management of solid wastes has taken on added importance. Aside from the large amounts of fly ash and bottom ash usually generated, large quantities of liquids in the form of scrubber sludge are also produced. These wastes must be disposed of within the constraints of land and water quality regulations. This paper describes the practices adopted by the electric utility industry in denting with this problem, including methods of generation and treatment, quantities and characteristics of the materials, and transportation and disposal practices. The paper also briefly describes final product characteristics and several applications for commercial utilization and land reclamation.

Jan 1, 1983

By Martti Hagfors, Mervi Hokkanen

The Finnish Defence Forces has destroyed obsolete and spoiled ammunition in open surface mass detonations at Hukkakero fell, in municipality of Kittilä, in Lapland since 1988. The de-struction method was learned from Sweden in 1987. The disposal camp is organized every au-tumn and it lasts four to six weeks. A gross weight of an average charge varies from 150 to 250 tons and the net weight of explosives from 15 to 25 tons. As a booster there have been used 2 to 3 tons of emulsion explosives. The explosives mainly consist of trinitrotoluene (TNT) containing smaller a mounts of amatol and hexotol. The Finnish Defence Forces Tech-nical Research Centre (PVTT) has studied the environmental effects of these mass detona-tions since they began in 1988.

Jan 1, 2011

By D. A. Shock

Utilizing the technology developed for oil well stimulation by hydrofracing, a disposal system which permanently fixes the waste has been proven. Large quantities of radioactive waste can be processed by a single well system making this method an attractive method for permanent radioactive waste disposal. The system depends on locating a relatively thick formation of impermeable, but easily fracturable rock such as a shale, creating a horizontal fracture, pumping the waste into the fracture in a form which will subsequently solidify and seal the fracture from the well system. The paper presents the theoretical considerations from creating and extending horizontal fractures and how these considerations were used in designing a waste disposal system which is now operating.

Jan 1, 1964

By Devraj Sharma

This paper presents technical issues in the design and management of a retorted oil shale disposal site. Major physical and geochemical mechanisms which affect the disposal are: heat transport, moisture migration, chemical species transport, auto-ignition, and mechanical behavior alterations of the retorted oil shale pile. The interaction of these mechanisms and their relative magnitude will affect the environmental behavior of the pile. The paper discusses the coupling between the mechanisms, presents a framework to quantify the processes by laboratory and field measurements, and in addition discusses the use of mathematical models to provide quantitative predictions.

Jan 1, 1981

By Watters R

Modem open cut and underground mining in the tropics inevitably expose partially weathered and unweathered rocks to oxygen and water, leading to weathering and the release of solutes and often acidity as well. Historical monitoring data can demonstrate these phenomena. Three case studies from open cut mines in the north of the Northern Territory illustrate the deterioration in quality of pond water receiving drainage from waste rock dumps. The potential for deterioration of water quality was not recognised in many mine Environmental Impact Statements prepared and accepted in the 1980s. The examples documented indicate the importance of adequately planning for this near inevitable process. Retrofitting a mine water management system to 'no' or minimal release can be very difficult and expensive, and may not be feasible, leading to downstream pollution. The characterisation of acid and solute production potential of ore and waste rock, and improved dumping strategies and water management are very important to minimise the environmental impact of mining in the tropics.

Jan 1, 1994

By W. C. Muehlhof, L. D. Lamont

THROUGHOUT the anthracite industry's history, the problem of handling and dis¬posing of refuse material has been one of major importance. In the early days of the industry's activities, only the large sizes of anthracite were satisfactory for market requirements and the smaller sizes were deposited as refuse. As time went by, more efficient coal-burning equipment was developed and a market demand was created for the finer sizes of coal. This demand made it possible to recover market¬able coal from banks deposited as refuse in the earlier days of mining. The same condition holds good today and we can see a definite trend toward the objective of utilizing the No. 4 and No. 5 buckwheat sizes. Under present conditions, we know that a limited market exists for No. 4 and 5 buckwheat; we know that the finer sizes of anthracite can be burned as pulverized fuel; we know that these fine sizes can be processed and sold as bri¬quettes, and we also know that the heat content of these fine sizes of coal is compar¬able with that of the sizes now merchan¬dized. Therefore, it should be the objective of the industry to conserve these fine sizes of coal in such manner that if and when processing facilities are developed, and market demands exist, the material can be salvaged and made available to meet these demands. From the standpoint of economical future reclamation, the ideal method of disposing of refuse containing the finer sizes of coal is to deposit it in banks separate and apart from other breaker refuse. By this procedure, the minimum amount of material will be processed in future salvage operations to recover the No. 4 and No. 5 buckwheat sizes. Many collieries in the anthracite region are operated under leases that have a specific term. These lease agreements provide that, upon expiration of the lease by term, exhaustion or otherwise, the ownership of the refuse material reverts to the lessor. Therefore, a question was raised in the minds of these operators: Why should I assume the expense of such pro¬cedure when I have no assurance that I will benefit by the future processing and sale of these fine sizes? Under present conditions, the answer to this question is not one of choice but of necessity, as restrictions imposed by legislation make it mandatory on operators of preparation plants to take necessary steps to properly treat silt-laden waters before permitting them to enter the streams. By reason of these restrictions, the disposal of fine sizes becomes a secondary_ rather than a primary operating con sideration, and the procedure for disposing of this refuse becomes a matter of choice governed principally by topographical and geographical conditions. METHODS OF HANDLING REFUSE There are three principal methods of handling and disposing of fine-size refuse; namely :

Jan 1, 1946

By Paul D. Bybee

The Freeport Sulphur Company operates four sulphur mines in the coastal marsh area-03 South Louisiana. Employing the Frasch process of mining, approximately 13-million gallons of water per day is heated to a mining temperature of 325°F and is injected into the sulphur bearing formations of the four mines. A volume of cold waste water, roughly equal to the Input, is removed from the formations and presents a disposal problem. Two additional mines are currently being developed and will increase the disposal volume by an additional 5-million gallons per day. Although these properties are in a relatively small area, geographically speaking, as shown in Figure 1, they each represent a separate disposal problem with the treatment methods designed for the individual mine.

Jan 1, 1959

By Hideki Yamamoto, Junji Shibata

"The chemical reactions of fluoride and chloride gases with metal chloride or metal oxide are utilized as an effective treatment for harmless disposal. These chemical reactions can be adopted in the temperature range of 80°C~400°C, which is lower than that in the combustion treatment (800°C). Reaction products are metal fluoride or metal chloride which are a harmless and a valuable chemical material as one of new resources. This paper, concerns with a new harmless disposal treatment of toxic global warming gases.IntroductionNew technology to make fluoride and chloride gases such as NF3, CF4, SF6 BF3, Cl2 and BCl3 harmless has been developed and a new concept on the removing toxic gas to be used in the advanced process of materials has been established. The fluoride gases ~re toxic and special type of gases to be used in the process of manufacturing semiconductors and their specific applications include the dry etching of semiconductors, cleaning of CVD systems, an oxidation agent for rocket fuel etc. Especially, NF3 is also attracting an attention as a high-energy source for chemical laser systems. As a fluoride gas like NF3 is, however; toxic and highly stable chemically, if discharged into the atmosphere, it is liable to cause far-reaching adverse influences on global warming in the same manner as carbon dioxide gas and feron gas.Up till now, the combustion treatment method has been adopted for the disposal of the gas, and when treating the gas by high-temperature combustion (800""C), the generation of nitrogen oxides (NOx), sulfur oxides (SOx) and hydrogen fluoride (HF) have been confirmed: These chemical substances are not only linked with an intense c0rrosion of the combustion systems but also create the generation of atmospheric pollution and acid rains, and therefore, constitute a serious social issue."

Jan 1, 2000

By Hideki Yamamoto

A new technology to convert fluoride gas (C2H2F4 : R-134a) contained in the exhaust gases from semiconductor manufacturing plants and refrigerators directly into a harmless substance have been established, thus, presenting a new concept for the disposal of fluoride gases such as CFCs that are associated with the global warming. Experimental results verify that chemical reactions with metal compounds can take place at substantially lower temperatures of 700- 800K as compared with combustion treatment temperatures of 1200-1500K. The reaction product is mainly metal fluoride, which chemically is a harmless material. Furthermore, this process is compact, easily controlled, safe and has low running costs. This paper deals with a new chemical reaction method for the harmless disposal of gases effecting the global warming.

Jan 1, 2003