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By G. M. Zhao

The gasification of lump coke with CO2 was studied in a fixed-bed reactor. The effective diffusivity of the gas was evaluated from measurements of the reactivity of the lump coke, produced by BHP Steel in New South Wales, and from kinetic parameters that were determined from the reactivity of fine grains. The grain model of effective diffusion in porous media was adopted to express the gasification rate of the lump coke and was found to fit the experimental data well. The relationship between reactivity and textural characteristics of the coke was examined

Jun 18, 1905

By Gheorghe Marin, Franco Chiesa, David Levasseur, Bernard Duchesne

Over the past 20 years, pressure die casting has evolved to a point where structural parts can now be produced by this process. This has been made possible by the development of vacuum die casting and by the development of die-castable, low iron content alloys. This resulted in the production of low porosity, weldable die-cast parts on which heat treatment may be applied. In the present paper, the influence porosities on the tensile properties of as-cast A360 tensile test bars was evaluated. This was done by casting 24 clusters, comprising three 6mm diameter test bars each, in a 280T cold chamber pressure die casting machine after a steady dynamic equilibrium had been reached. Modeling of filling allowed to explain the differences in porosity observed in the 3 samples of a same cluster while the results of solidification modeling were related to the microstructure. Tensile samples were radiographed on a real time X-cube apparatus and separated into 2 lots: samples where no porosity defect were visible and samples with visible defects. By measuring the tensile properties of the 2 lots it was possible to quantify the drop in tensile properties brought about by porosity, which is the most common defect observed in pressure die-cast parts.

Jan 1, 2015

By J T. Woodcock, G J. Sparrow

A sample of pyrrhotite flotation concentrate pulp assaying 15.3 g/t Au, which had been prepared from an old tailing dump, was treated to extract the gold. Examination of the concentrate with an SEM showed that exposed or free native gold, 5- 40 ¦m in diameter, was present but no locked gold was observed. Direct cyanidation of the concentrate to extract the gold showed that the flotation reagents present inhibited gold extraction. A range of pre-treatments was used to overcome these effects. Direct cyanidation for 48 h extracted only 26 per cent of the gold, indicating possible contamination of the gold in the concentrate with flotation reagents. Pre-treatment of the concentrate pulp by aeration for 24 h, or by 72 h aeration with an addition of 3.65 kg/t of sodium sulphite, gave little improvement in gold extraction by subsequent cyanidation. Pre-treatment by filtration, or by aeration with 12.5 L/t 100 volume hydrogen peroxide, followed by cyanidation for 48 h gave gold extractions in the range 67-77 per cent. Combining filtration and an aeration period with hydrogen peroxide addition raised the subsequent cyanidation extraction of gold to 88 per cent, giving a tailing assaying 1.5 g/t Au. Re-cyanidation of some of the dried tailings from the initial tests extracted most of the remaining gold giving a tailing assaying 0.5 g/t Au. This indicated that most of the gold was available for dissolution by cyanide. The poor dissolution of gold by cyanidation of the untreated concentrate was attributed to the presence of flotation reagents. It was shown by UV spectrometry that xanthate-containing compounds were present in the solids fraction of the original pulp and that they were partly removed by pre-treatment. MIBC was also present, and dithiophosphate, which was used in the flotation step, was also probably present. The results indicated that the improvement in gold extraction after filtration and oxidation of the original pulp was due to partial removal of the flotation reagents, and illustrates the detrimental effects that residual flotation reagents can have on the extraction of gold by cyanidation of a flotation concentration.

Jan 1, 1990

By Sheng-li Wu, Guo-liang Zhang, Bo Su

One of the major challenges for the Canadian Gen IV Super-Critical Water-cooled Reactor (SCWR) concept is the selection of fuel cladding materials. The Canadian SCWR concept will operate at a core outlet temperature of 625 oC and 25 MPa of pressure with peak cladding temperature reaching as high as 800 oC. Corrosion resistance is an important factor for material selection. Austenitic stainless steels that contain Cr contents greater than 18 wt.% are generally considered to provide adequate corrosion resistance. In this work, the pressure dependence of the corrosion of austenitic stainless steel 310 containing 24 wt% Cr is assessed at 625 C for exposures of 1000 hours to evaluate the suitability of superheated steam as a surrogate for supercritical water at 25 MPa. Transmission Electron Microscopy (TEM) revealed that 310 exposed to different pressure conditions at 625 oC. (i.e., 0.1, 8 and 29 MPa) had generally the same type of the oxide structure, i.e., a Cr-rich oxide with the spinel structure on outer surface adjacent to the water phase. The material exposed at 8 and 29 MPa had a double layer oxide structure, with the outer oxide layer having a much larger grain size, while the samples exposed at 0.1 MPa showed only a single spinel-phase oxide layer. Cr-depleted recrystallized austenite grains were found underneath the spinel phase oxide. The adjacent large-grained austenite substrate had M23C6 carbides in the grain interior. The implications of these results are discussed.

Jan 1, 2015

By G. Bartolacci

In a COREM-McGill collaborative research and development project, gas dispersion parameters and froth properties were manipulated in a copper flotation plant to study interactions between the collection and the cleaning zones. In this paper, specific work on developing some relationships between operating conditions and froth stability in several different types of flotation cells is reported. Froth stability, measured by image analysis, was related to the following process conditions for specific flotation machines in an industrial case study: Gas flow rate, collector dosage, pH, frother type and dosage. Across the range examined, froth stability was improved through an increase in gas flow rate and/or frother dosage. Metallurgical results (grade and recovery) showed that both gold and copper were dependent on froth stability. Results indicated that flotation conditions could be optimized by monitoring froth stability.

Jan 1, 2007

By C. Machio

This paper reports the results of a study to determine the effect of process control agent (PCA) on the characteristics of Ti-Mg powders during milling. It has been shown that a 2% increase in PCA content leads to up to a 40% increase in yield of the milled powder but reduces the kinetics of the mechanical alloying process. The introduction of 4% PCA decreases the mean powder particle size by up to 30%, whereas 6% PCA increases the mean particle size by up to 230%. The characteristics of the milled powders will be discussed in relation to the role of PCA in the milling process. Keywords Titanium?magnesium, mechanical alloying, PCA.

Jan 1, 2011

By J. J. Jonas

The categories of interpass time encountered in hot rolling are characterized. These are shown to fall into three broad categories: short (in rod rolling); intermediate (in strip processing); and long (in plate schedules). The effects of interpass time on recrystallization and carbonitride precipitation are described, and particularly on the interaction between these two mechanisms. The interactions, in turn, determine the final microstructure produced as well as the mechanical properties.

Jan 1, 2005

By Hidenori Hatta, Takero Watanabe, Hideo Yoshida

"The effect of the quenching rate on age hardening in an Al-6.0mass%Zn-0.75mass%Mg alloy sheet was investigated. The quenching rates and aging conditions were as follows: water quenching (WQ) or furnace cooling (FC) followed by pre-aging at 20°C,then artificial aging at 120, 160 or 200°Cwere performed. The peak strength of the FC and the WQ are very similarat120°C aging. It is important high strength was obtained even at the extremely slow quenching rate. On the other hand, the strength of the WQ significantly decreased compared to the FCat200°C aging. GP(I) zones were formed during the pre-aging at 20°C even if the cooling rate was very slow like the FC, and were transformed into the GP(II) ones at 70°C or higher and then into the ?’ phase. However, these zones were dissolved by reversion during heating to 200°C. Thus the strength of the WQ decreased. On the other hand, it is considered that an unknown cluster or GP zone with a thermal stability formed during the FC was not dissolved up to 200°C and was transformed into the ?’ phase. Therefore, a higher strength was obtained in the FC for the200°Caging.INTRODUCTIONAl-Zn-Mg alloys are widely available in commercial production because these alloy have lower quench sensitivity and can be produced by air cooling (AC). Heat treatable aluminum alloys are usually produced by water quenching (WQ) to increase their strength because a high cooling rate inhibits the precipitation of the stable phase during cooling and increases supersaturated solute atoms. However, Baba(1967)reported the strength of an Al-6%Zn-1.8%Mg(mass%) alloy without additional elements quenched by very slow cooling (15°C/min) was 96% of that quenched by WQ. Furthermore,the age hardening at room temperature (RT) occurs after annealing at 410°C followed by furnace cooling (FC, 0.5ºC/min or less)in these alloys. Therefore, the process of annealing at 410 to 430°C for 120 min followed by AC, and reheating at 230°C for 240 min, then cooling is recommended in the specifications (Japan Aluminum Association, 2011). Matsuda and Yoshida(1996)also recommended annealing at 300°C for Al-Zn-Mg alloy extruded products to inhibit age hardening at RT by precipitating the solute atoms and decreasing them in the matrix. It has been considered that the higher the content of excess quenched-in vacancy becomes by WQ, the higher aging rate at RT is obtained. Therefore,it is theoretically and commercially important to clarify the reason why the age hardening occurs relatively quickly in almost no excess quenched-in vacancies such as the FC, and why the same strength as the WQ can be obtained in the FC"

Jan 1, 2018

By E. Matinde, S. L. Msibi

"The robust nature of alumina refractory materials presents opportunities for their in-process reclaiming and re-use in non-critical applications. Virgin refractories can be substituted with different quantities of reclaimed materials without compromising the quality of the refractory products. In this study, the effect of reclaimed bauxite on andalusite-containing refractory castables for tundish applications was investigated. The recycled bauxite was formulated in different proportions to replace virgin andalusite in the castables. Standard tests were conducted to evaluate the physical, physicochemical, and thermochemical properties of the formulated products. Static corrosion tests were conducted using tundish slag in order to simulate the actual operating conditions. The results show that the standard flow behaviour, open porosity, and bulk density of samples containing up to 22 mass% reclaimed bauxite were comparable to those of the reference castable. However, high-temperature properties such as static corrosion at 1400°C and hot modulus of rupture at 1500°C indicated that there is an upper constraint to the amount of substitution. The study demonstrated direct potential savings of up to 10% when the reclaimed alumina replacement ratio was increased to 22 mass%. IntroductionAlumina-based refractories can be classified into low-alumina, containing less than 50% Al2O3, and high-alumina or bauxite, containing between 50 and 90% Al2O3. High-alumina refractories have widespread applications in high-temperature metal extraction processes due to their outstanding thermochemical and thermomechanical properties and stability (Rebouillat and Rigaud, 2002; Frulli, 2016). The typical chemical composition of refractory-grade bauxite consists of 85–90 wt.% Al2O3, 5–10 wt.% SiO2, 1–2wt.% Fe2O3, 3–4 wt.% TiO2, 0.4–0.8 wt.% CaO + MgO, and 0.20–0.8 wt.% K2O + Na2O (Nyoka et al., 2013). The thermochemical and thermomechanical properties of bauxite-based refractories rely principally on the conversion of the contained silica and alumina to the highly stable corundum (?-Al2O3) and mullite (3Al2O3· 2SiO2) phases (Rebouillat and Rigaud, 2002; Hill and Sehnke, 2006; Garbers-Craig, 2008; Frulli, 2016)."

Jun 1, 2019

By Rajagopala Reddy Kallu

After the Sago and Darby No. 1 mine incidents, the new regulatory standards for the design of mine seals in underground coal mines of the United States require the mine seals to withstand higher explosion standards. This necessitated for the development of new design approaches and standards. For development of any new design standards or approaches a detailed understanding of effect of key influencing parameters on the stability of mine seal is a must. This paper attempts to address one of the factors, i.e. roof convergence, that play an important role in the stability of mine seal under explosion loading. Initially a couple of three dimensional numerical models were built and tested for different levels of roof convergence. These models confirmed that roof convergence has great influence on seal stability. A detailed study is undertaken, with some simple assumptions, to establish typical influence of roof convergence on the stability of mine seal under different levels of static explosion pressures. Three dimensional distinct element code 3DEC is used for this purpose.

Jan 1, 2007

By J. J. Quinn

Several mineral flotation plants utilize process water with high soluble salt content. The processing of semi-soluble minerals, the use of recycle streams, sea or well water give rise to this situation. It is unclear as to the overall effect on flotation response though there does seem to be evidence of bubble size reduction, increased froth stability and reduced reagent dosage. The present work aims to quantify the effects of salts present in process water on gas dispersion (bubble size and gas holdup) and froth properties. The salts examined were NaCI, CaCl2, Na2SO4, Na2S2O3 and Al2(SO4)3. Tests were conducted to determine the effects of salt type and concentration on gas holdup and bubble size distribution. The salts containing multivalent ions had a greater impact than the monovalent ions, in keeping with the literature. A relationship between gas holdup and ionic strength was established. The concentration of frother (methyl isobutyl carbinol, MIBC) giving equivalent gas holdup was determined. The effect of salt and frother combinations was also explored.Proposed mechanisms for coalescence inhibition in salt solutions are briefly reviewed in light of the current findings.

Jan 1, 2006

By Liu Xinghua

Yuanjiacun iron ore located in Shanxi province of China has finely disseminated grain size and contains refractory iron-bearing silicate gangue minerals such as chlorite. Therefore, a large amount of secondary slime (the content of -10µm fraction was up to 32.92%) was produced inevitably in fine grinding process, and chlorite was also enriched in concentrate from the content of 4.3% to 14.8% after high intensity magnetic separation. These two characteristics result in the difficulty to deal with Yuanjiacun iron ore by flotation. In this test work, contrast tests between single reverse flotation and selective flocculation desliming-reverse flotation were conducted on Yuanjiacun iron ore. The test results show that after selective flocculation desliming, the iron grade of cationic reverse flotation concentrate increases by 6.15% and the recovery increases by 7.25%; the iron grade of anionic reverse flotation concentrate also increases by 2.15%. Furthermore, analyses of grain size composition and mineral composition were carried out on separation products, the results indicate that selective flocculation desliming plays a dual role of optimizing grain size composition of flotation feed and removing iron-bearing silicate gangue minerals (chlorite) effectively.

Sep 1, 2012

By Luiz Henrique Accorsi Gans

First, this works carries an experimental evaluation for austempered ductile iron (ADI) as a gear material. And second, in order to provide a better understanding of the microstructural effect on the stress state of subsurface regions, a finite element method approach was considered using the submodeling tool in ANSYS 11.0. For this, ADI gears were produced from continuous cast iron bars, heat and thermochemical treated and tested in FZG test rig. The results were compared to those of carburized steel AISI 8620 and induction hardened steel AISI 4140 gears. The wear experiments were performed at the temperature of 90ºC with two torque stages: 135 N.m (running-in) and 302 N.m (steady-state). The time for pitting and spalling on the gears surfaces were measured using image analysis. The results showed a very good potential of using ADI for manufacturing gears, replacing induction hardened steels. Also, the ADI gear with smaller nodules showed higher life for pitting. In contact fatigue tests with severe load, the carburized AISI 8620 steel proved more adequate than the austempered ductile iron, showing that the mechanical properties are critical in the resistance to damage in gear contact. The austempered ductile iron with smaller nodule size showed to be very competitive with wear resistance similar to AISI 4140 steel induction hardened. With ANSYS, it was verified that the nodule size affects the gears life independently of the mechanical properties of the matrix. The results showed that the nodules indicate the presence of a concentration stress, but their size doesn’t affect the contact fatigue life as much as the total amount of nodules, regardless of the ductile iron microstructure. The size and number of nodules affects both the nucleation and the propagation stage of cracks. ADIs with higher amount of nodules have a greater wear resistance. Also, compared to the Hertz contact theory (isotropic material), the presence of graphite nodules indicates a non-isotropic material and made the maximum shear stress point moves toward the surface.

Jul 31, 2018

By R. H. Eric, A. Chaendera

Gas jet was blown through bottom nozzles of a 1/5th scale CLU model in the presence and absence of slag. Kerosene and water were used to simulate the slag and metal phases respectively. Mixing time increased with increasing bath height and with a decrease in the gas flow rate. It was related to bath weight, bath height and gas flow rate. Slag increased mixing time by about 16% and the mass transfer values by about 32%. Mass transfer rates were higher near the bath surface and in the gas-liquid plume region. They increased with increasing gas flow rate and with a decrease in bath height. A relationship showing the dependence of derived mass transfer coef ficient on the gas injection rate was established. Turbulence characteristics inside the bath liquid were established to vary with location, vessel geometry and gas injection rate.

Mar 1, 2017

By B. Kahraman

About 70% of the world?s total boron reserves are located in Turkey. Boron minerals are typically concentrated by attrition scrubbing followed by screening and classification to remove clay minerals and other impurities. These wet concentration methods, however, result in a considerable amount of accumulated tailings in large tailings dams. The tailings are approximately 28% solids and contain 14% B2O3. Problems caused by these tailings can be minimized by employing dry beneficiation techniques involving heat treatment. This method has been successfully tested on laboratory and pilot scales. During heat treatment, borax undergoes expansion in volume. The amount of expansion is dependent on the particle size, temperature and duration of heat treatment. Because the optimum temperature and the duration of the heat treatment are not well defined, the boron ore acts as a calcined clay mineral and is discarded along with the gangue. It is important to predict such parameters using mathematical formulations. Thus, a mathematical model is used to predict the required temperature and duration period prior to heat treatment. In the experimental study presented here, a series of systematic thermal tests was carried out in a muffle furnace. Two variables, temperature and time, were studied in a response surface design. A quadratic regression model was chosen and regression coefficients were calculated. Using a regression equation, the volume expansion of the particles in various circumstances can be predicted. The mathematical test results are then correlated with the experimental results to relate the optimum expansion of borax with heating time and temperature and with borax grades and recoveries.

Jan 1, 2008

By H. A. Bilgin, G. G. U. Aldas

"Ground vibration is the natural result of the blasting process. Many empirical formulae and methodologies including analysis of travel path effects have been developed. The scaled distance, which is the most popular approach for the calculation of the attenuation of particle velocity in the ground, has led to significant advances in the prediction of particle velocity when both explosive charge and distance vary. However, this approach does not consider the effect of ground anisotropy and existence of structural geological features on ground vibration. Therefore, in this study, the effects of these rock mass properties on types, amplitudes, and frequencies of ground vibration waves at four surface mines are examined. The results, which were implemented at Kangal coal mine, Bastas quarry and Kíbrís quarry, provided guidance for the extensive study at Orhaneli surface coal mine.As a result of the study, the authors came to the conclusion that vibration amplitudes change depending on the ground on which sensors were deployed and the conditions depending on whether measurements were done near major structural geological features. It was determined that the vibration amplitudes, measured at equal distances from the source but in different directions, change because of the propagation velocity anisotropy. Besides the change of wave type due to the kind of ground at the measurement location, it was determined that vibration anomolies were due to structural features."

Jan 1, 2004

By A. W. Khair

Laboratory studies indicate that the specimen size influences the compressive strength of coal significantly. In the past, the diameter/height ratio of coal and rock specimens with different geometry and its influence on failure characteristics was discussed (Khair, 1993; Khair, 1994; Khair and Xu, 1994). In the current attempt, tests are designed and carried out under uniaxial condition in the laboratory to investigate the influence of specimen size. Cubical specimens of coal with edge dimension ranging from 5 cm (2 in.) through 20 cm (8 in.) were prepared according to the standards and tested uniaxially. Results show that compressive strength of coal is dependent on specimen size until certain level and later the change in specimen size would not yield significant change in compressive strength. Cubical specimens were chosen for testing because they are not only in close resemblance to underground pillars, but they are also the most stable shape under loading. The failure characteristics of these specimens were analyzed and their applicability to pillar design aspects in coal mines is studied. A detailed analysis of the physical and mechanical properties of the tested coal seam is also presented.

Jan 1, 1996

By P. D. Lee

The effect of strontium on porosity formation in aluminum-silicon alloys is not well understood and there is no consensus upon the cause of the effects observed. This paper describes a series of experiments where the effect of adding strontium on pore formation was observed directly with combination of a traditional temperature gradient stage and real time micro-focus radiography. These in situ observations provide a new insight into the effect of strontium on the nucleation and growth kinetics of porosity. The addition of strontium was found to have a minor effect on the growth of the pores in the mushy zone. However, strontium appeared to alter the nucleation and stability of hydrogen bubbles within the melt. The interaction of strontium with titanium-boride grain refiners produced an even stronger change in the nucleation and stability of the bubbles formed.

Jan 1, 2002

By Darrell Wilder

When designing excavation support systems in urban environments, it is often necessary to consider the effect of vertical surcharge loads from adjacent structures. Several methods are used in practice to establish the horizontal surcharge-induce pressure on the excavation support. According to the experience of the authors, these methods often seem to overestimate the effect of the surcharge and may have significant impact on the construction costs. This paper explores several of these procedures and provides a discussion as to the reasons for the differences in surcharge effect predictions between different procedures. It also provides practical recommendations for designers dealing with excavation support design.

Jan 1, 2006

By X. Zhang, E. Li, Y. Xiao, Z. Yu, H. Han, J. Xie, J. Tian, W. Sun, K. Hong

In a pulp environment, the surface properties of magnesite and dolomite tend to be similar, due to the re-adsorption of dissolved calcium species, which makes the flotation separation difficult. In this paper, the chelating reagent EDTA is introduced to eliminate the adverse influence of the calcium species and to restore the selectivity of magnesite-dolomite separation using sodium hexametaphosphate (SHMP) as a depressant. Flotation experiments confirm that the recovery of magnesite improves significantly in the presence of EDTA. Zeta potential experiments confirm that the negatively charged EDTA4+ and HEDTA3+ species can form soluble and stable chelates with positively charged Ca2+ and Ca(OH)+ species preventing their adsorption on the magnesite surface. Adsorption measurements prove the addition of EDTA can decrease the adsorption of depressant SHMP on the magnesite surface. X-ray photoelectron spectroscopy (XPS) measurements further confirm the transformation from the surface of magnesite to dolomite in the presence of calcium ions, and the possible adsorption mechanism of EDTA and SHMP on the magnesite and dolomite surface. Key words: Magnesite; Dolomite; Surface dissolution; Flotation separation

Jan 1, 2020