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By S. Steinlechner

"Today the common recycling technologies of automotive catalysts are either energy intensive pyrometallurgical processes generating huge amounts of residues or hydrometallurgical ones which have to cope with effluent problems. Next to that, other valuable metals beside PGMs such as rare earths from the wash coat are not recovered.Therefore, the present paper introduces a hydrometallurgical concept developed in cooperation with the company Railly & Hill for the recovery of the PGMs as well as cerium from the wash coat of the catalysts in a closed loop. Next to the process concept, the required parameters for the different steps are discussed, including the chemical reactions, leaching efficiencies and mass flows, which form the basis for an economic estimation of the concept.Contrary to the pyrometallurgical recycling where the monolith is completely melted down to slag which is typically dumped, in this process the remaining monolith forms an utilizable product for the ceramics/refractory industry. As a result of the closed loop of the leaching media an environmentally friendly process was developed from which nearly no new residues or effluents are generated, with a sustainable usage of chemicals."

Jan 1, 2014

By N. Loganathan, Tan Boon Tee, Joe O’Carroll, Richard Flanagan

In recent years, tunnelling activities in Singapore have increased considerably with the construction of extensions to the existing sub-surface transport system, a deep tunnel sewerage disposal system, and tunnels for the laying power cables and other utilities. These tunnels are excavated through urban areas, adjacent to high-rise buildings, depressed road structures, beneath other tunnels, and buried services. Earth pressure balance (EPB) tunnel boring machines (TBM) have been used extensively in Singapore with great success. The risk associated with soft ground tunnelling, including tunnelling through Old Alluvium, can be minimized with an understanding of the geology, geotechnical parameters, and the tunnelling-induced behaviour of Old Alluvium (OA The purpose of this paper is to present some design and construction aspects of EPB TBM tunnelling through Old Alluvium.

Jan 1, 2005

By Craig Bournes, David Chapman, Michael DiPonio

Historically, boulders are a frequent source of problems in soft ground tunneling. During tunnel construction, the need to manually break and remove boulders as obstructions causes delays to the project. Repairs to a tunnel boring machine (TBM) can also be a source of delays. Managing these problems is difficult since normal soil investigation techniques do not accurately predict the presence or frequency of boulders. This has lead to considerable number of claims for extra costs and delays during the construction of soft ground tunneling projects. These issues are exacerbated in pressurized face tunneling systems where there is limited access to the TBM cutterhead for obstruction removal and/or cutterhead maintenance. The project team that built the Big Walnut Augmentation/Rickenbacker Interceptor (BWARI) Project for the City of Columbus successfully managed the design and construction of a 4,267 mm (14 ft) diameter soft ground tunnel with high boulder concentrations in a complex geologic setting. The management of the boulder issue tookplace during several phases of the project.

Jan 1, 2007

By Laura McNally

In 2006 McNally International Inc. in a Joint Venture partnership with Aecon Constructors was the successful bidder on two York Region Tunnel Projects: Bathurst Collector/Langstaff Trunk Sewers; and YDSS Interceptor Sewer 19th Avenue Project. These projects comprise a total of 13 kilometres of 2.74 meter finished diameter tunnels and are both part of the York Durham Sewer System (YDSS). Both contracts require the use of EPB tunnel boring machines with a precast concrete segmental liner. The following provides an overview the two projects.

Jan 1, 2008

By KOKOWSKI J., RUDZIŃSKI Ł.

The LUMINEOS network was established in 2013 to monitor mining-induced seismicity in Legnica-Głogów Copper District (LGCD), located in south-western Poland. Since the starting time, the network was improved and today consists of 17 seismometers and 10 accelerometers. Up to now, the strongest recorded earthquake in the region had Mw4.0. Both raw seismic data and earthquakes catalog for events recorded by the LUMINEOS network are fully open and available on the EPISODES platform (https://tcs.ah-epos.eu/#episode:LGCD). During the last 7 years, the network improvements gave us a possibility to increase location accuracy for shallow mining events. This accuracy is influenced by factors such as the configuration of seismic stations, noise level at seismic stations, and the influence of the velocity model. Here we encountered two main issues which are worth to discuss. The first one is the low detection threshold of two seismic stations and their significant impact on the location errors. The second one is the large uncertainty in the S-wave picking. Even though S-waves are not so clearly visible on seismograms, they are very helpful in the estimation of source location and strength of seismic events in the region. In our work, we present the history of LUMINEOS network and corresponding improvement on location accuracy as well as the influence of noisy stations on the error distribution and how it is connected with location results. We also investigate the effect of the S-wave phases and how they are related to the accuracy of the earthquakes locations in the network.

Apr 26, 2022

By O. T. Rämö, E. Suikkanen

Episyenites are sub-solidus, quartz-depleted alkali-feldspar-rich rocks. They form veins and lenticular bodies in granitoid rocks and migmatites in a late- to post-orogenic or anorogenic setting. Leaching of quartz is usually a response to a flux of weakly saline hydrothermal solution in circulation cells above cooling intrusions, where sufficient fluid-rock ratios and thermal gradients are achieved. Fluid Si-undersaturation is achieved by rapid cooling within the field of retrograde Si solubility or by temperature and pressure increase outside retrograde conditions. Some quartz may also be consumed in metasomatic reactions and in response to pressure fluctuation in sealed episyenite bodies. The small size and overall rarity of episyenites imply that conditions for episyenite formation are not commonly encountered in the crust. In addition to quartz depletion, episyenites record complex histories of metasomatic alteration and hydrothermal mineral growth. Nearly all episyenites have undergone Na-metasomatism, which may have led to the formation of nearly monomineralic albitite, and which is occasionally followed by late K-metasomatism, phyllic alteration, and argillization. Depending on the effectiveness of later compaction, recrystallization and vug-filling episyenites may preserve the macroscopic porosity formed by quartz dissolution and brittle deformation. Vuggy episyenites can act as significant sinks for metals carried by crustal fluids and host many significant U, Sn, and Au deposits worldwide. Rare earth-critical syenitic fenites around alkaline intrusions share mineralogical and genetic traits with episyenites.

By O. T. Rämö, E. Suikkanen

Episyenites are sub-solidus, quartz-depleted alkali-feldspar-rich rocks. They form veins and lenticular bodies in granitoid rocks and migmatites in a late- to post-orogenic or anorogenic setting. Leaching of quartz is usually a response to a flux of weakly saline hydrothermal solution in circulation cells above cooling intrusions, where sufficient fluid-rock ratios and thermal gradients are achieved. Fluid Si-undersaturation is achieved by rapid cooling within the field of retrograde Si solubility or by temperature and pressure increase outside retrograde conditions. Some quartz may also be consumed in metasomatic reactions and in response to pressure fluctuation in sealed episyenite bodies. The small size and overall rarity of episyenites imply that conditions for episyenite formation are not commonly encountered in the crust. In addition to quartz depletion, episyenites record complex histories of metasomatic alteration and hydrothermal mineral growth. Nearly all episyenites have undergone Na-metasomatism, which may have led to the formation of nearly monomineralic albitite, and which is occasionally followed by late K-metasomatism, phyllic alteration, and argillization. Depending on the effectiveness of later compaction, recrystallization and vug-filling episyenites may preserve the macroscopic porosity formed by quartz dissolution and brittle deformation. Vuggy episyenites can act as significant sinks for metals carried by crustal fluids and host many significant U, Sn, and Au deposits worldwide. Rare earth-critical syenitic fenites around alkaline intrusions share mineralogical and genetic traits with episyenites.

By R M. Briggs

Kapowai Caldera Complex (KCC), located 10 km west of Tairua (eastern Coromandel Peninsula), is a late Miocene composite collapse caldera, formed during eruption of several small and large volume andesitic rhyolitic ignimbrites. Numerous epithermal Au-Ag mineral deposits and associated alteration zones at the KCC are related to caldera (rhyolite lava domes, intracaldera faults) or regional structures (faults). The main epithermal deposit exposed in the central KCC is associated with an E-W striking structural boundary fault that cuts the Welcome Jack rhyolite dome. Propylitic (calcite - chlorite) and sericitic (quartz - sericite) alteration haloes surround this deposit. Sporadic zones of sericitic alteration are also exposed within and on the margins of the Bulls Run rhyolite dome complex. Epithermal systems post-dated emplacement of these rhyolite domes, but were controlled by them. Propylitic alteration of ignimbrite in the floor of the Kapowai and Kauaeranga valleys is related to the major NE-trending Kapowai Fault which extends SW to south of Thames. Alteration along this fault pre-dates alteration associated with the rhyolite lava domes. Numerous sericitic and propylitic altered welded ignimbrite, rhyolite and andesite lava lithic fragments have been sampled from intracaldera ignimbrites, and although no direct source is known, they infer the presence of buried epithermal systems. Repeated epithermal activity at the KCC is inferred by the exposed epithermal deposits/alteration zones and the older buried geothermal systems. Silicic caldera volcanoes are considered to be critical volcanic environments for epithermal Au-Ag mineralisation in Coromandel, but are highly variable and need detailed stratigraphic, structural, petrologic, and geophysical studies to characterise them.

Jan 1, 1999

By J L. Mauk

Low sulfidation epithermal deposits are important sources of gold and silver, and are considered the extinct analogues of modern geothermal systems. The aerial extents of alteration halos that surround twenty-two epithermal deposits range from 4 to 315 km2, with many less than 60 km2. Deposits with alteration halos <30 km2 typically have well defined limits, whereas deposits with alteration exceeding 30 km2 are commonly complicated by overlapping alteration centres related to adjacent epithermal deposits or other deposit types (i.e. high sulfidation, porphyry). Irrespective of the physical coverage of vein or alteration halos, both large (>60 km2) and small (<20 km2) deposits can contain large amounts of gold and silver. The size ranges for twenty-one analogous liquid-dominated geothermal fields from around the world have a restricted size range of 5 to 60 km2 and irrespective of physical size, commonly have multiple zones of focused fluid upflow. From an exploration perspective the comparison between epithermal deposits and geothermal fields provide the following four important points. 1) Alteration halos surrounding epithermal deposits as well as those for analogous geothermal systems show a range of sizes, although most are less than 60 km2. Therefore, where alteration exceeds 60 km2 multiple vein systems related to several paleogeothermal systems are predicted. 2) Multiple upflow zones are common in geothermal fields of all sizes (5 to 60 km2) and although difficult to demonstrate in epithermal deposits there is a strong possibility of discovering several discrete adjacent mineralised centres. 3) The orientation of veins parallels the principle orientation of the surrounding alteration and where alteration is wider than the vein strike length, this could suggest the occurrence of adjacent veins. 4) The physical size of both veins and alteration zones is not important in relation to amount of contained gold, as both large and small can contain large amounts of gold. These conclusions provide insight into the physical size limits and hydrologic structure of these paleogeothermal systems and highlight the potential for multiple mineralisation centres within a single alteration halo.

Jan 1, 2004

A subsurface study of the Maria Lode and associated hydrothermal alteration of andesites within the Karangahake epithermal gold-silver deposit defined the local evolutionary sequence in the once active geothermal system.   Some implications for mining of epithermal deposits arise as a result.

Jan 1, 1984

By D S. Clarke, K B. Sporli

The Thames Goldfi.eld has been a major gold resource in the west of the Coromandel Peninsula, New Zealand, with the Waiotahi quartz vein system forming a large part of the field. Mineralisation is hosted by hydrothermally altered Miocene andesitic volcanic rocks. Both massive columnar-jointed and fragmental volcanic rocks are present. The vein system is dominated by the steeply dipping NE striking Waiotahi-Cambria vein, and associated splays. Hydrothermal alteration increases in intensity from isolated blocks of propylitic altered andesitic material, into the intensely clay altered equivalent. Low rank propylitic alteration is typified by chlorite, calcite and pyrite, with local illite or epidote. Clay alteration is characterised by illite, quartz, kaolinite and pyrite. While broadly forming halos around veining, intense clay alteration also occurs in strongly jointed portions of the hostrock.   Vein textures and the intense illitic clay alteration at Thames are similar to those in some of the other epithermal gold deposits of the Coromandel Volcanic zone, and in deposits of the Philippines, all related to andesitic terranes. Possible causes for textures and alteration being different in these deposits from the more classic Quartz-Adularia-Illite type epithermal systems may be that cooling/mixing rather than boiling dominates fluid evolution. Kaolinite may be also be a product of either of these different fluid types, or has resulted from overprinting of an illitic assemblage by downward percolation of acidic fluid.

Jan 1, 1991

In the Ngakuru area, zeolite deposits occur in late Quaternary lake sediments and ignimbrites. The deposits are associated with sinters, hydrothermal eruption breccias, and quartz-adularia altered fault breccias: all indicators of a shallow epithermal environment. Several of the deposits are adjacent to epithermal gold prospects. Zeolites are most abundant in lacustrine tuffs of the Ngakuru Formation, a 100-300 m thick sequence of siltstone, tuff, diatomite, sandstone and conglomerate. The formation overlies the Ohakuri Ignimbrite dated at c. 270 Ka, and is unconformably overlain by alluvial sands and gravels which are younger than 20 Ka. Individual zeolite deposits contain 30-80 per cent zeolite over a thickness of up to 45 m in thinly stratified tuff beds. The tuff beds are locally overlain by diatomite. The tuffs are composed mainly of glass shards and pumice clasts, with minor volcanic plagioclase, quartz and biotite crystals. Glass shards in the tuffs are replaced by the silica-rich zeolites mordenite and clinoptilolite. Amorphous silica (opal A), opal-CT, K-feldspar and smectite are also present. The distribution of the Ngakuru Formation is controlled by northeast trending normal faults, which separate it into the Ngakuru and Guthrie grabens. A silicified (quartz-adularia altered) hydrothermal breccia along one of the fault zones suggests that the faults acted as feeders for heated water that caused the deposition of the zeolite minerals. Some of the zeolite deposits are adjacent to sinters and hydrothermal eruption breccias. The location of the sinter about 20 m above one deposit indicates that the zeolites were formed at a depth of 20 to 70 m below the paleosurface. The hydrothermal eruption breccias contain clasts of altered ignimbrite, which contain geochemically anomalous gold and silver values. By analogy with their occurrence in active geothermal systems in the Taupo Volcanic Zone, mordenite and clinoptilolite in the Ngakuru deposits probably formed at temperatures of 60-150oC from near-neutral pH waters as a result of interaction with glass-rich tuff beds. The Ngakuru zeolite deposits are therefore interpreted as shallow hydrothermal alteration zones within larger epithermal gold-bearing systems.

Jan 1, 2002

The Illawarra District, from 50 to 100 miles south of Sydney, is one of the State's important coalfields. It extends from Clifton on the north, to the Shoalhaven river on the south, and from the coast westward beyond the coastal scarp.For descriptive purposes, this area falls naturally into two zones:(a) the coastal belt backed-by the eastern edge of the plateau;(b) the plateau, westerly from the coastal scarp.(a) The Coastal Belt.A triangular shaped area extending from Clifton to the Shoalhaven river, composed for the most part of soft coal measures strata of Permian age, which, on weathering, undermines the massive overlying Mesozoic sandstones and causes the gradual recession of thecliffs.South of Wollongong, upper marine sediments and contemporaneous igneous rocks make their appearance beneath the coal measure beds and occupy the greater portion of the coastal belt.(b) Plateau Area.Extending westerly from the coastal escarpment is a plateau known as the Robertson Tableland, composed of Triassic sandstone and shales dipping gently in a northerly direction, and capped in places by Wianamatta. shales and r.rertiary basalts. This tableland is approximately 2400 feet above sea level in the vicinity of Robertson, and gradually falls to about 750 feet at Waterfall.The plateau area for the most part is highly dissected, rough, steep gorges alternate with sharp ridges.A large part of the northern watershed of the Robertson tableland is a reserve for Sydney water supply, and large dams have been constructed at Cataract, Avon, Burke, and Cordeaux.

Jan 1, 1938

In parallel work, the cyanide/silver impregnated activated carbon system was studied for the purpose of developing an alternate cyanide removal system. It was found that free cyanide can be reduced from 20 ppm to below 10 ppb with a fixed bed of silver impregnated activated carbon, since such cyanide removal might be applicable to gold mill effluents, the investigation was extended to the cyanide/gold impregnated activated carbon (GIAC) system. Batch tests were conducted varying the gold content of activated carbon, carbon/CN ratio, stirring speed, pH of the initial solution, and the reaction temperature. The adsorption isotherm of cyanide/gold impregnated activated carbon system was also studied. The results of these batch tests show that the behaviour of the cyanide/GIAC system is very similar to the cyanide/silver impregnated activated carbon system variation of the gold content of the impregnated activated carbon has some influence on the cyanide adsorption rate. The latter is mainly increased, however, by increasing the GIAC/CN ratio. The activation energy was determined to be 3.12 kca1/mole (13.08 kj/mole) and the Au(CN)2 saturation at 194 µ M/g NORIT ROX O.B. The experimental results of reaction temperature and stirring speed show that the adsorption of free cyanide on such activated carbon is controlled by pore diffusion inside the activated carbon particle or by surface reaction. The adsorption isotherm follows the linear model and it is favourable for the cyanide/gold impregnated activated carbon system.

Jan 1, 1994

By E. H. Jr. Dix

THE use of magnesium as an alloying element in aluminum alloys has been limited, in general, to comparatively small quantities. In duralumin-type, strong-aluminum alloys, magnesium is present to the extent of ½ to ¾ per cent. and various grades of Magnalite and the "Y" alloy of the National Physical Laboratory of England contain up to 1 1/2 per cent. In this country small quantities of aluminum alloy sheet containing 4 per cent. magnesium are produced commercially. All commercial aluminum contains sufficient silicon to convert a portion of the magnesium added to the compound Mg2Si. It is well known that the solubility of both magnesium and magnesium-silicide decrease with decrease in temperature. It is, therefore, impossible to separate the age-hardening effect of the magnesium-silicide from that of magnesium, except by the use of aluminum of such high purity that the silicon content is negligible. The present paper is the fifth1, 2,3,4 of a series from the laboratories of the Aluminum Co. of America reporting the results of investigations of the equilibrium relations in aluminum-rich alloys made from the high purity aluminum manufactured by this company .5

Jan 1, 1929

From a vast army of workers to gargantuan machines to immense volumes of material being moved, almost everything about the Port of Miami Tunnel (POMT) project points to tunneling on a massive scale. Almost.The star of this underground and underwater show is a Herrenknecht tunnel boring machine (TBM,) nicknamed ?Harriet? by a local Girl Scout troop. With her 12.9-m- (42.3-ft-) diameter cutting head and a total length of 139 m (457 ft), Harriet is boring through thousands of cubic meters of clay, dirt and sand, which is often mixed with coral and other materials, to create two 1,280-m (4,200-ft) traf?c tunnels connecting Watson Island and the Port of Miami (Dodge Island) beneath Biscayne Bay, FL. But in the midst of all of the oversized equipment and machines, a strong contender for the best supporting nod goes to a relatively tiny machine: the Brokk 400. Bouygues Civil Works Florida crews are using the compact, remote-controlled and electric-powered machine to excavate five cross passages between the twin traffic tunnels. The pas-sages will be essential to the safety of people who drive their vehicles under the bay every day.

Sep 1, 2013

Mining companies in order to compete and succeed in being viable business propositions must look to the future and select mining methods which guarantee improved efficiency and productivity as well as lower costs. A mining company in adopting a method of mining must now select the equipment most compatible. To some mines compatible equipment may mean the use of drilling jumbos to replace hand held rock drills or the use of load haul dump units to replace scrapers. To other more mechanised mines compatible equipment may mean the use of raise borers and road heading machines. The right decision will be where equipment compliments method in such a way that the working environment is improved, productivity is maximised, cost if reduced and all profit opportunities are optimised. An example of such is where the use of improved mining techniques in underground operations may see cut off grades reduced. By selectively mining these lower grade orebodies, smaller operation's ore reserves improve and the capacity for continued growth is enhanced.

Jan 1, 1990

By A. Paviani

The subject of this session is "Equipment Installa­tion, Recent Developments". This is a subject which is not usually addressed at conferences of Foundation Engineering. It is rare to find sessions dealing with the technological side of deep foundations, a subject which only recently seems to have aroused sufficient interest at national and international conferences. It is therefore natural for the subject of "Equipment", or the tools used to implement the various "technologies", to be over­looked or mentioned only occasionally during the discussion of other issues. At conferences, most of the attention is attached to research and to the theoretical interpretation of the performance and behaviour of deep foundations, as well as to establishing the most suitable calculation algorithms and approaches for the study, design and control of foundation structures. It is almost as if the subject of equipment is felt to be less important or, perhaps, that it is considered to belong more strictly to mechanical engineering than to civil engineering.

Jan 1, 1994

By Paul D. Tomlingson

During the next several months, SME’s E-Newsletter will feature 15 articles on maintenance management. The articles may be read online or downloaded and distributed within your organization. They will address maintenance management topics, offer guidelines to mining managers and provide techniques that the maintenance manager can use. The articles will stress equipment management, a strategy that the mining industry has accepted as a modern replacement for outdated maintenance practices. Equipment management is the mutually supportive interaction of all mine departments as they establish equipment needs, procure equipment, test, commission, operate, maintain, modify and eventually replace equipment. The successful application of equipment management principles can quickly and reliably produce cost reduction and performance improvement results while providing a dependable way of sustaining them. Equipment management embraces modern management techniques. These include reliability-centered maintenance, life-cycle costing, capital performance, the effective use of information and productive organizational models.

Jan 1, 2003

The selection of the mining fleet can have as much of an effect on the efficiency and effectiveness of an operation as the mining method. This is not to say that inefficiencies are only attributable to inappropriate equipment selections, these aspects have many factors but are not the subject of this paper.This paper will give an overview of equipment selection processes that have been utilised to date. It will also look at the increase in application of study programs/simulations from an aspect of accuracy, as well as the importance of enabling the analysis of multiple sensitivity scenario planning. An aspect that is increasingly important in project planning with commodity market movements.Another aspect that is increasing in popularity is that of automation, what effect does this have on equipment selection? What additional aspects need to be taken into consideration when assessing Automation of equipment from the beginning of a project as well as introduction into an operating mine?Once the selection process has been finalised and equipment implemented, how do we, as an industry, 'close the loop' through analysis of estimated versus actual equipment application?

Dec 6, 2010