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By Bin Zhu, Mingmei Zhu, Hong Zhou, Xiaofei Dou, Bin Xie, Yu Wang, Tiancheng Lin

In this study, the formation of 2CaO·SiO2 and 3CaO·P2O5 solid solution (nC2S-C3P) in hot metal dephosphorization process is discussed. The variations of CaO and SiO2 mass, both in nC2S-C3P solid solution phase and liquid slag phase with increasing P2O5 mass in CaO-SiO2-FetO-P2O5 slags were calculated using Factsage software. CaO-SiO2-FeOt-P2O5 slag containing up to 18 % P2O5 was melted at 1823 K then cooled to 1673 K. The contents of CaO and SiO2 both in the solid solution phase and liquid slag phase of quenched samples were observed and analyzed by SEM/EDS. Both the calculated and experimental results show that the contents of CaO and SiO2 in the solid solution phase decreased, just opposite in the liquid slag phase, with increasing P2O5 content in the slags. Formation mechanism of nC2S-C3P solid solution in the slags was derived based on the ionic structure theory of molten slag. The SiO4 4- in the nC2S-C3P solid solution can be replaced by PO4 3- in the liquid phase resulting in the increasing of free Ca2+ and SiO4 4- in liquid phase.

Jan 1, 2015

By Zan Yao, Sha Lv, Geoff Wang, Baojun Zhao, Zongze Huang, Jin Zou, Xiaodong Ma, Zhouhua Jiang

55SiCr steel is one of the important spring steels widely used in automobile manufacturing. The presence of micro inclusions in the steel can significantly influence a number of spring properties such as fatigue strength. It is important to understand the mechanism of the inclusion formation so that size and proportion of the inclusions can be controlled. Inclusions in Si-killed 55SiCr spring steel have been analysed by scanning electronic microscopy and electron probe X-ray microanalysis. The chemistry of the inclusions observed in 55SiCr steels can be represented by the SiO2–Al2O3–CaO–MgO system. It was found that the compositions of the inclusions cover a wide composition range, which indicates that these inclusions were formed from different reactions. The possible mechanisms of the inclusion formation are discussed. It would be possible to characterize and manage the inclusions in the spring steels deoxidized by Si.

Mar 1, 2017

By K. Hanumantha Rao, A. Javadi Nooshabadi

"Formation of hydrogen peroxide (H2O2), an oxidizing agent stronger than oxygen, by chalcopyrite (CuFeS2), which is a copper iron sulfide mineral, during grinding, was investigated. It was observed that chalcopyrite generated H2O2 in pulp liquid during wet grinding and also in the solids when placed in water immediately after dry grinding. The generation of H2O2 during either wet or dry grinding was thought to be due to a reaction between chalcopyrite and water where the mineral surface is catalytically active in producing •OH free radicals by breaking down the water molecule. The effect of pH in the grinding medium or in the water in which solids are added immediately after dry grinding showed that the lower the pH value, the higher the H2O2 generation. When chalcopyrite and pyrite are mixed in different proportions, the formation of H2O2 was seen to increase with increasing pyrite fraction in the mixed composition. The results of H2O2 formation in pulp liquid of chalcopyrite and together with pyrite at different experimental conditions have been explained by Eh-pH diagrams of these minerals. This study highlights the necessity of revisiting the electrochemical and/or galvanic interaction mechanisms between the chalcopyrite and pyrite in terms of their flotation behavior.IntroductionHydrogen peroxide causes nonselective oxidation of sulfide minerals if present in pulp liquid. Oxidation of sulfide minerals takes place when they are exposed to atmosphere and during the grinding process when the particle size is reduced for flotation. The oxidation of chalcopyrite leads to iron dissolution from the particle surface and from a metal-deficient, sulfur-rich surface (Fairthorne et al., 1997). Other studies report the formation of iron hydroxide on the surface with the metal ion dislodged on the surface (Buckley and Woods, 1984; Chander, 1991). The chemical reactions for the oxidation of chalcopyrite in alkaline and in acidic solutions with the addition of oxidants, such as oxygen or hydrogen peroxide, are shown in Eqs. (1) and (2), respectively (Shi and Fornasiero, 2010)."

Jan 1, 2015

By N. Hiroyoshi, R. D. Corpuz, M. Ito, Hokkaido University, C. B. Tabelin, S. Veerawattananun

"Acid mine drainage (AMD), the very acidic and heavy metal-contaminated leachate generated when pyrite-bearing rocks are exposed to surface oxidizing conditions, is a serious environmental problem encountered after the closure of mines and mineral processing operations. In this study, we investigated the effects of soluble phases and metallic oxides, which are commonly found in strongly weathered pyritic wastes, on pyrite oxidation. Strongly weathered pyrite containing melanterite (FeSO4·7H2O) as the main soluble phase was obtained from Furikusa mine, Japan. The sample was washed using two methods to vary the relative amounts of melanterite in the sample. The effect of metallic oxides on pyrite oxidation was evaluated using ultrapure hematite suspensions. Our results showed that under acidic conditions, the effect of soluble salts on the oxidation of pyrite was stronger than hematite. More thorough washing of the sample resulted in the formation of an arsenic-bearing iron-oxyhydroxysulfate coating that minimized pyrite dissolution. This oxidized layer became relatively thicker and mechanically stronger when hematite was introduced after the more thorough removal of soluble salts. Characterization of this “coating” coupled with geochemical modeling suggest that it is most probably composed of two materials: schwertmannite and scorodite. Based on these results, a new approach to suppress pyrite oxidation by directly using iron-oxyhydroxysulfate as coating material is introduced.INTRODUCTION Acid mine drainage (AMD), the very acidic and heavy metals-contaminated leachate produced in closed/abandoned mine sites (Evangelou, 1995), mineral processing and coal cleaning tailings (Evangelou, 1995), and tunnel construction waste rocks (Tabelin and Igarashi, 2009, Tabelin et al., 2012), is one of the oldest and probably the most serious environmental problem of anthropogenic origin. When released to the environment, it rapidly pollutes river, soil and groundwater systems leading to the destruction of affected ecosystems. AMD is produced when pyrite (FeS2), one of the primary gangue minerals in sulfide ores and coals, is exposed to oxidizing conditions as illustrated by the following reactions:"

Jan 1, 2016

Electrochemical measurements are presented on electro-deoxidation of silica in molten calcium chloride at 900°C, with porous silica pellets as starting material. Measurements during pre-electrolysis (to remove water from the melt) showed electrochemical noise, which is consistent with the evolution of hydrogen. Throughout, the dominant anodic reaction appears to be CO2formation, based on the observed potential at the anode, and measured anode wear. Because of the presence of dissolved CaO in the melt, some of the CO2 candissolve in the melt; the resulting calcium carbonate formation was confirmed by electrolyte analysis after reduction runs. Reduction of dissolved CO2 at the cathode is likely to contribute to the background current during the reduction process. For the electrode and cell configuration used here, most of the over potential arises from polarization of the anode, and ohmic potential drop in the electrolyte.

Jan 1, 2006

By H. Krogerus, P. Niemelä, P. Oikarinen

High carbon ferrochromium is produced by carbon reduction. No replacement for carbon as reductant has yet been developed. The reduction creates a considerable amount of CO-gas. In open and semi-closed furnaces the gas is burned when leaving the burden. In closed furnaces the formed gas is sucked out by a fan, washed and utilised as fuel. The formation of carbon monoxide is presented briefly starting from thermodynamic considerations up to solid and liquid state reduction. The volume, composition and energy content of the furnace gas are discussed, focusing on the raw materials and pre-treatment processes of the furnace feed as well as on the process equipment and control. Outokumpu has been using closed and sealed furnaces and utilising the CO-gas in its Tornio Ferrochrome Works since 1968. Today in Tornio with an annual ferrochromium production of 260 000 t CO-gas production is 186 million m3, representing 68 MWh an hour. At the same time the furnace power input is 95MW. About 98 % of the CO-gas is utilised, whereof 30% in the ferrochrome production itself. This paper focuses on the characteristics and utilisation of CO-gas. CO-gas is secondary energy, which on one hand saves primary electric and fossil fuel energy in ferrochromium production and, on the other, replaces other fossil fuels at the adjacent steel works. The characteristics of the fuel, requirements for utilisation as well as health and safety aspects are discussed. Utilisation of the gas has a high impact on the total dust and gaseous emissions and on the energy optimisation at the ferrochromium and steel works.

Jan 1, 2004

By A M. Sardo, D E. Sinnett

This study uses the Q Method to examine how those living in former metal mining landscapes value this heritage and their preferences for the long-term management of mine waste. Such sites are often perceived as derelict or degraded, and of very little value. It is therefore assumed that their reuse, for example for development or recovery of metals, is likely to be beneficial. There are around 5,000 former metal mines in England and Wales, many of which are protected for their ecological, geological or cultural value. The Q Method is particularly suitable for issues where there is no consensus of opinion. We asked 38 residents of six mining areas in England and Wales to ‘sort’ a series of statements based on their resonance with the resident’s perspective; this is the Q sort. The statements covered a range of opinions of the mining legacy, its value and options for its management with a particular focus on the potential for metal recovery from the wastes. Analysis of the Q sorts revealed five perspectives on the mining heritage. All placed a high value on the cultural and ecological value of this heritage, however, they differed in their priorities for long-term management. For example, emphasis was placed on either nature conservation, cultural heritage, water quality or the opportunity for job creation through reworking the mines. Cutting across these themes there were also differing perspectives on the role of experts and local people in shaping the future management of the wastes. This research suggests that the views of local people are nuanced; they value their mining heritage but opinion is split on the most effective way to manage these sites especially where there is an impact on water quality.CITATION:Sinnett, D E and Sardo, A M, 2018. Former metal mining areas in England and Wales – local residents’ preferences for the management of wastes, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 126–134 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

To predict the spontaneous combustion potential of bituminous coals using a simple expression based on an easily acquired coal property. Background Approximately 20% of underground coal mine fires in the United States since 1978 have been attributed to spontaneous combustion. Spontaneous combustion fires in underground mines are most likely to occur in gob area; and are difficult to detect and to extinguish by direct fire fighting methods. Often, sections of the mine or the entire mine must be sealed for long periods, at a great economic loss to the mine operator, mine employees, and the surrounding community. It is conservatively estimated that the cost of scaling a large mine is about $50 million.

Jan 1, 1989

By Norman O. Lotter, Dominic Fragomeni, Jorge Oliveira, Dee J. Bradshaw, Rebecca Monnapula

"The role of mixed collectors in enhancing the metallurgical performance of sulphide flotation processes was reviewed in 2008, and later published as an integrated theory by Lotter and Bradshaw, 2009. The theory proposed that xanthates, dithiophosphates and dithiocarbamates could be synergistically combined in an optimal formula to deliver improved grade and recovery. The approach uses a five-step structure, viz.1. A mineralogical study of the ore to be treated, identifying and quantifying the economic minerals (with hosting and association) and gangue species present.2. Selection of candidate collectors from this mineralogical information and from the known pulp conditions of that operation (e.g. Eh, pH).3. Design and execution of a factorial experiment to estimate and test the main effects and interactions, and to model the response surface for an optimum formulation [Box et al., 1978].4. Use of a High-Confidence Flotation Test platform in the factorial to reduce overall errors and allow for clearer observations [Lotter, 1995; Lotter and Fragomeni, 2010].5. Statistical design of a plant scale trial to measure and validate the gains [Napier-Munn, 1995; Lotter et al., 2009]. Eland Platinum, which was commissioned in November 2007, appointed a team to apply this theory to formulate an optimized mixed collector suite for use in the operation. The West Pit ore (UG2 - Normal ore) was sampled at site and brought to Xstrata Process Support, Sudbury, Canada, for mineralogical and metallurgical testing in 2008. Microprobe and QEMSCAN measurement characterized the type, grain size and textural association of the discrete Platinum Group Minerals (PGM) present. From the mineralogical data, it was clear that a mixture of dithiocarbamate and two xanthates would be a likely reagent suite selection. A factorially designed set of High-Confidence Flotation Tests studying these was performed, concluding that an optimal suite using certain amounts of these collectors was a viable formulation that would advance the grade and recovery performance at Eland above the standard PIBX by approximately 2.13% 4E PGE. The plant trial, which used a form of the replicated block design after Napier-Munn, 1995, and Lotter et al., 2009, exceeded this estimate with an overall PGE recovery gain of 2.48% (absolute basis) and a concentrate grade gain of 26.4 g/t PGE (absolute basis), as well as reducing chrome in concentrate from 2.04 to 1.62% (absolute basis). These gains proved to be statistically significant using the analysis of variance method, and have validated the theory."

Jan 1, 2011

By Ray Brandon

The recent introduction of polymer geogrids for ground control purposes in underground mines allows mine operators more flexibility in choosing improved products for several applications. This is evidenced most clearly in longwall recovery operations. Since November, 1994, many mine operators have chosen Fortrac geogrid assemblies for the purpose of securing longwall recovery areas prior to shield removal. Fortrac is a lightweight, strong, and flexible polyester geogrid available in many strengths. Utilizing the "diamond" seaming method, different strengths of Fortrac geogrids are easily fastened together so stronger geogrids may be placed in the most critical areas and lighter geogrids in less critical areas.

Jan 1, 1996

By J. M. Hemstock, H. L. Ames

THESE forums have been held annually since they were introduced by Mr. L. E. Djingheuzian in 1957. The response of millmen to questionnaires such as the one this year is ample evidence of the interest these create. This year's topic is unlike those of past years since it is an attempt to understand a new concept of grinding rather than to improve the old. Before, we were thinking in terms of 2-5 cents improvement in grinding costs, now we will be discussing savings of 15-2 5 cents. As a background for this forum we will begin by summarizing the major controversial issues relating to grinding with steel, many of which will undoubtedly apply to pebble milling. Our •task to-day is to learn what has already been done in pebble milling and obtain a fair overall view of this method of grinding.

Jan 1, 1961

By W. H. Zieman

"THIS IS THE THIRD of the consecutive Annual Forums on Grinding that were instituted by Mr. L. E. Djingheuzian in 1957. The first was on the subject of Ball Milling (Transactions, Volume LX, 1957) and the second on The N on-Cataracting Ball Mill (Trans-actions, Volume LXI, 1958). From the discussions at these forums it was evident that one of the most important factors affecting the efficiency of grinding is the shape of the liners. In order to make a study of liners in use, it was •decided to seek the co-operation of operators across the country by sending out questionnaires requesting basic information. Additionally, these operators were urged to set down briefly any pertinent information on the subject acquired through experience and experiments at their own particular plants. A compilation and analysis of these data were to form a basis for discussion at the Forum on Liners at the Annual Meeting in Montreal, April, 1959. The response of the milling fraternity to this solicitation was most gratifying, and clearly indicated the importance attached by the operators to the effect of liner design upon overall grinding performance."

Jan 1, 1959

By Patrick J. Hannigan, Geir Veslegard, Frank Rausche, Rozbeh B. Moghaddam

A common type of deep foundation used in Norway to support bridge structures is the drilled pipe piles (piles) filled with concrete reinforcement after installation. The standard installation practice is the use of down-hole hammers. Complex geology and difficult subsoil conditions in Norway causes a high variability of soil and rock layers which in turn make for differences between actual subsurface conditions and those expected from geotechnical exploratory borings. This situation is strongly noted when the foundations are not fully socketed, and the rock layer is sloped. In this particular case, special testing procedures are required to assess the drilled pile base material and evaluate the rock-socket to ensure full contact between the foundation base and the rock surface. The local standard practice to verify the latter condition, consists of coring and visually evaluating the material recovered at the bottom of the drilled pile. This paper presents a case where the coring and visual inspection were not possible and alternatively the geological material encountered at the base of the deep foundations was evaluated using force-displacement measurements. Two 1016-mm (40in) diameter open-end drilled piles identified as P02-04 and P02-05 were tested and evaluated using in-situ force-displacement data prior to filling the piles with concrete. Test results showed an average displacement of 7mm (0.28in) corresponding to 35MPa (5.1ksi) stress level for P02-04, and 7.2mm (0.28in) corresponding to a stress level of 38MPa (5.5ksi). Based on testing results, both drilled piles were within the established material assessment criterion presented by the local authorities. INTRODUCTION This paper presents a case study in Norway where the material encountered at the base of an open- end drilled pipe pile (pile) was evaluated using force-displacement data. In the deep foundation industry in Norway, it is a common practice to install piles to support transportation structures. Once the piles reach the embedment elevation, and the pile base is assessed, these are filled with concrete. In projects where sloping rock is the supporting layer, and all nominal loads are supported by the pile base resistance, assessing the material encountered at the pile base to ensure full contact with the rock becomes critical. The local practice to make this assessment consists of the use of weighted tape, coring, or inspection cameras. However, similar to any other testing and evaluation methods, these come with their own limitations. The variability associated with the use of the weighted tape, accessibility for the coring equipment to complete a coring process, or the conditions at the foundation base such as murky water or thick drilling fluids could significantly impact the photo or video quality taken at the pile base. In such conditions, it is important to consider alternate testing methods to evaluate the material at the foundation base.

Jan 1, 2018

By Mohammad Nasim

Vertical expansion of existing structures frequently requires foundation retrofitting to enhance the capacity of existing foundations for supporting additional loads. Owing to their small diameter, a variety of suitable drilling methods available for installation, and smaller installation equipment capable of operating under limited headroom conditions, micropiles are often preferred for foundation retrofitting. This paper presents a case history demonstrating application of micropiles to underpin the existing foundation of the Washington D.C. Children?s National Medical Center (CNMC) for its future expansion. Located at 111 Michigan Avenue in northwest Washington, DC, portions of the hospital currently extend five stories above grade and three levels below-grade as parking garages. The hospital intends to expand the surgical wing up to the current build out (five stories) above the remaining portion of the existing parking garage. The original foundations consist of 80-ton Raymond Step-Tapered piles. New loading on the foundations required each Raymond pile to be capable of supporting 150 tons. Results from quick load tests on existing piles indicated that two entire column lines (Column Line A and B) would experience loads beyond their capacity, requiring enhancement of the existing foundation at these locations. The design and construction of the foundation upgrading work was particularly challenging due to various project constraints related to a high groundwater table, micropile installation under limited head room, and ensuring that the parking garage remained fully operational for the entire duration of construction. The paper presents the challenges faced during testing of existing foundations amid a high groundwater table, design developments of underpinning options to support the additional column loads, difficulties and challenges encountered during installation of the micropiles and construction of the micropile pilecaps, and value engineering options developed during various phases of the project. Understanding that micropiles are often a preferred option for foundation retrofitting, the case history is expected to provide a baseline design approach and innovative solutions to typical challenges faced during construction, thereby reducing potential cost overruns during design development and construction of similar future projects.

Jan 1, 2008

By Sara Anderson, Rachel Nicholls, Tim Chapman, Janice Windle

"In city center sites around the world, and in particular in London, foundation reuse is becoming increasingly widespread as the ground is filled with detritus from previous developments. This paper sets out a systematic framework to consider the need for and benefits of foundation reuse and key issues to be resolved for foundation reuse to be successfully adopted on redevelopment projects. Once foundation reuse has been identified as a potential foundation solution there are several key stages in the design and construction process where the decision to reuse foundations needs to be assessed. The paper concludes by emphasising the importance of ensuring that the foundations being installed now can more easily be reused in the future.INTRODUCTIONThe concept of re-using foundations is not new, and has been adopted on an isolated project-byproject basis for many years. However, over the past decade, interest in the potential of reusing existing piles and caissons within Europe has increased significantly, with a growing interest in the United States of America and Japan. The need has been driven by necessity: on many urban sites the space available for new foundations diminishes with each new set of piles, and these problems can only grow in the future.Initiatives such as the European Union's RuFUS (Re-use of Foundations for Urban Sites) research project have resulted in identification of the key issues for technical viability and risk that have previously hampered potential foundation reuse projects.There is a need to define a systematic approach to the reuse of foundations so that the risks associated with reuse can be identified, managed and mitigated. This requires improvements in knowledge to provide confidence in the long term behaviour of the foundation support and address the risks involved in reusing existing foundations to overcome perceived obstacles in making foundation reuse a realistic option for many sites."

Jan 1, 2005

By K. Viking

This article deals with some of the civil engineering related problems to be encountered when offshore wind energy projects transform from prototype offshore wind energy converter farms, developed and installed during the 1990?s, to commercial farms that?s currently planned to be built. The offshore wind energy converter (OWEC) installations encounter a wide range of problems, only partial of these are geotechnical. In Europe both onshore and offshore wind farms have, from a historical point of view, usually been founded by using the monopole technique, installed with traditional impact hammers, or by using gravitational foundations. However, the rapid development of bigger turbines and larger wind farms, together with increasing considerations of fatigue aspects, has lead to financial benefits of developing and exploring other foundation techniques. This paper reviews some Scandinavian experiences regarding critical components of the design phase in relation to connecting the superstructure to the ground, and some of the main considerations of how the loads applied to the structure are transferred to the surrounding soil.

Jan 1, 2013

By John F. Spence

Ever since opening, the M25 motorway to the west of London has carried a rapidly increasing volume of traffic. The section of M25 between the junctions with the M3 and M4 motorways, which is in the near vicinity of Heathrow airport, is the most heavily trafficked section. Piling and ground treatment was required for motorway widening works over this route, which is 7 miles long. The foundation works were undertaken next to the live motorway and beneath the flightpath for aircraft landing and taking off at the airport. The paper describes the foundation construction techniques used, and the how the methods were affected by the live motorway and the height restrictions imposed by the airport. A unique method of piled retaining wall construction is also described.

Jan 1, 2007

By Clyde N. Baker

Foundations for the Sohio Corporate Headquarters in downtown Cleveland have column loads of 11,400 kips, which increase to 15,000 kips with wind loading. An extensive exploratory program was conducted and comprehensive studies made to select the economically dependable support for the 46-story structure. A test on bond or socket friction for the caissons has usable values.

Jan 1, 1984

By J. M. Mitchell

Kuala Lumpur, Malaysia is underlain by karstic limestone. Firm clays, mudstones and siltstoncs of the Kenny Hill Formation overlie the limestone for about two thirds of the city. The remaining third has deep deposits of very soft alluvium, or tin mining slimes, overlying the limestone. It is only recently that large buildings have been constructed in the area. Arup Jururunding have been concerned with several projects located on the limestone, although space here only permits the description of four sites in detail. The experience has allowed the development of a design approach for the foundations. The aim is to make the architectural scheme compatible with the geology. This is not always possible, and examples are given of both situations. The case histories give examples of compensated foundations, and piled foundations include steel H-piles, precast concrete piles, micropiles, bored piles with rock sockets, and barrettes up to 90m deep.

Jan 1, 2010

By K. J. Stanaway

Major world ilmenite and rutile accumulations reveal similar regional geology and Proterozoic age deeper crustal source rocks. During crustal collision titanium crystallizes as ilmenite and rutile at buried sites of high pressure and temperature rock metamorphism. Hydrothermal activity can convert titanium minerals to rutile, but titanium migration and enrichment seem only local. Many melts crystallize rocks with iron-titanium oxides in solid solution, but titanium enrichment at economic scale takes place in basic intrusive melts often associated with anorthosites and charnokite. Sedimentary placer enrichments have formed since the Proterozoic with water-resistant ilmenite, and rutile segregating by gravity from quartz sands deposited from flowing water. Placers have residual, alluvial, strand and shallow marine variants. Time, organic acids, and sand permeability play lead roles in the leaching of iron from ilmenite during weathering and diagenesis.

Jan 1, 2005