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The development of reliable and accurate solution sampling systems plus on-line atomic absorption spectrophotometers and voltammetric analysers at Pasminco Metals - EZ's (PMEZ) zinc refinery at Hobart, Tasmania, has led to extensive implementation of On-Stream Analysis (OSA) throughout the hydrometallurgical circuit. These systems complement industrial autotitrator and colorimetric analysers and with the comprehensive use of a powerful integrated Distributed Control System (DCS), provide extensive monitoring and control of all the important in solution' parameters for the plant. Samples can be left unaltered, or filtered or settled, to remove solids. They are then precision diluted and pneumatically transported to analyser shelters, where they are analysed for zinc, acid, copper, cadmium, lead, antimony, cobalt, nickel, mercury and ferrous, ferric and/or total iron. The range of analyses depends on the sample itself. The results are used for feed forward and/or feedback control of reagents where possible, or simple trend monitoring and out-of-specification alarming when closed loop control is not practical. The overall system reliability and accuracy is such that many daily composite plant samples are no longer analysed off-line. Operator sampling has also been reduced, and in two places, autotitrators with automatic sample pre-treatment have been installed for preparing and analysing samples collected by operators.

Jan 1, 1993

By J. L. SCHUELER

THE writer has reread Mr. Ingalls' interesting article in the July, 1923, issue of MINING AND METAL- LURGY on "The Use of Spelter in Galvanizing." It seems that most writers, in commenting upon coatings of spelter on sheets and wire, dwell upon the thin coatings which these materials carry, and rightly so. However, they seem to forget that until very recently, in the case of wire, the manufacturer did not know how to apply a heavy coating of spelter to the wire, especially if the wire was to be woven into fence or fabricated in some other manner, because heavy coatings of spelter are exceedingly brittle. This is even true in the case of high-grade spelter, but to a lesser degree than with Prime Western. Because of this brittleness, it has been necessary for wire manufacturers to smooth the coating by passing the wire through tightly compressed wiping means of some kind, usually asbestos. This removes all of the excess spelter and allows only a thin coating to remain. The latter, as a rule, is malleable and the wire can be fabricated without material injury to the coating.

Jan 1, 1924

By Ángel Ruiz-Sánchez

Ethylene glycol additions to aqueous acid solutions for leaching copper sulfides increase both copper and iron extractions compared to a conventional sulfuric acid leach with hydrogen peroxide (H2O2). The role of ethylene glycol is to prevent peroxide destruction, which normally occurs in solutions that contain both cupric and ferric ions. However, despite this improvement, ethylene glycol and sulfuric acid concentrations must be high (3.5 M and 0.7 M, respectively) to obtain satisfactory conversion levels at room temperature. In the present investigation, EDTA was used as an additive to complex the cupric and ferrous ions, lowering the requirements of ethylene glycol and H2SO4 to 0.11 M and 0.007 M, respectively, while minimizing oxidant decomposition. The experimental results for a mainly chalcopyrite, copper concentrate showed complete copper extraction in 24 h at room temperature, with the stoichiometric quantity of EDTA for the copper and iron dissolved. Tests using seawater were equally as successful.

By G. Henry, S. J. Domvile

Arsenic management practices at the Con Mine in Yellowknife, Northwest Territories have evolved over the last fifty years of operations under changing regulatory, economic and technological conditions and incentives. As a result of a processing upset in the mine' s arsenic trioxide reclamation plant circuit in August 1988, arsenic levels in the mine' s tailings pond rose from 30 to over 100 mg V. At these arsenic levels, water treatment operations were unable to meet water licence discharge criteria and the mine itself was under risk of closure due to limited water storage capacity. Under these internal pressures, the mine initiated its own research initiatives designed to restore water treatment operations. The new process developed from the mine's research, utilized the mine's existing water treatment plant hardware but introduced a pretreatment step involving a discrete sludge recycle and removal system. In February 1989, water treatment operations resumed under the new process.

Jan 1, 1992

By E. Haug, Quamrul Ahsan, R. Norcross

Cyanide leaching is the most common process employed in the majority of the gold extraction plants. These gold extraction plants naturally generate tailings and/or effluents that contain highly toxic cyanides, In geographic locations with excess precipitation and therefore net positive water balance, a portion of these tailings must be discharged. Before these highly toxic cyanide-containing effluents can be discharged to the waterways, cyanide and any other toxic substance must be destroyed. Geographic locations with high evaporation and low precipitation, as in the western USA, result in net negative water balance and therefore these plants can operate with a zero discharge option. However, with the current stringent environ­mental regulations and concerns for bird and wildlife mortality, even these operations may be required to partially treat their tailings to preclude potential harm to wildlife. Furthermore, heap leach opera­tions are now generally required to detoxify the heaps before abandonment. It is, there­fore, apparent that all gold extraction plants may be required to install some form of effluent treatment in order to achieve the above objectives,.

Jan 1, 1990

By E. L. Frueh

AMAX Base Metals Research & Development, Inc. has developed a process for treating copper-nickel mattes to produce copper cathodes and a pure nickel sulfate solution. In this process, the input matte is preleached in a copper sulfate electrolyte bleed solution so as to dissolve nickel from the matte and cement copper from solution. The preleach leaves a substantially pure nickel sulfate solution. The residue from the preleach is roasted to less than about one percent sulfur. A portion of the calcine is leached with sulfuric acid to make a copper sulfate solution for input to the tank house. The residue from this leach and the remaining calcine are smelted to form a bimetallic (copper/nickel.) anode. The anodes are electrolytically refined and copper is preferentially deposited on the cathode while the nickel reports to the electrolyte, A bleed stream is taken from the electrolyte and used in the preleaching of the input matte. This process produces high purity metal streams while consuming less energy and smaller amounts of reagents as compared with other matte processes.

Jan 1, 1983

By Albert R. Rule

Beneficiation studies were made by the Bureau of Mines to develop a process for concentrating phosphate minerals from the altered rock of the Phosphoria Formation. This report describes research on intermediate - and marginal-grade ores from southeast Idaho, The process developed consists of attrition scrubbing and sizing to produce a coarse concentrate; desliming at about 800 mesh (18.5 microns); flotation of the fine sands; roasting of the combined concentrates for removal of organic carbon and combined water; and leaching with SO2 for removal of magnesium and nonapatitic calcite. Results of continuous tests on three different ore types showed that approximately 80 percent of the available phosphate can be recovered at a grade suitable for phosphoric acid production. While leaching with SO2 is not necessary for all ore types, it is an important step in purifying concentrates containing excessive magnesium.

Jan 1, 1966

By J. A. Eisele, G. E. McClelland, M. D. Wroblewski

The Bureau of Mines is conducting research at its Reno Research Center to develop a staged agglomeration-heap leaching system and to electrowin the dissolved precious metals from the pregnant leaching solution. For direct electro- winning to be successful, the pregnant solutions generated during the Initial stages of leaching must be higher grade than obtained by conventional heap leaching. The precious metal concentration of the pregnant solution can be Increased by agglomeration pretreatment with cyanide solution which starts the leaching process during the curing period, by leaching with small volumes of solution and by cycling the leaching solution through more than one heap in a staged manner. The resulting pregnant solution is passed directly through an electrowinning circuit. The barren solution from electrowinning is recycled to the leaching circuit. Bench-scale research on the development of the staged leaching system and on the development of an efficient electrowinning cell are described. The Bureau of Mines developed agglomeration- heap leaching technology. This technology was readily adopted by the mining Industry for heap leaching crushed ores and mine wastes. Current research involves the application of this technology to finely ground feed materials such as precious metal-bearing milled tailings. Tailings agglomeration-heap leaching has also been used commercially.

Jan 1, 1984

By Dave Bulled, Jim Thompson, Tim Leriche, Mark Blake, Troy Wilkie

"A commitment to a core testing, plant modeling and reconciling technique has shown substantial economic benefits to IOC in terms of accurate production forecasting, smoother operation of the mill, improved expectations of throughput and co-operation across production departments from geology, planning, mining, and processing, to shipping of concentrate to market.This paper describes a successful seven year program of forecasting throughput of the autogenous milling circuit at the Carol Lake concentrator of IOC. Work started with audits of the grinding circuit in 2001 and benchmarking of the data collected from samples of mill feed and plant operation to the CEET mill design and throughput forecasting model.Initially 390 drill core samples were tested for SAG Power Index (SPI) to measure the energy required in milling, and the data distributed using a geostatistical technique across the two operating pits, so that hardness was estimated in each of the 40,000 blocks (or 1500 million tons) of potential ore. In 2004 a forecast of energy requirement, i.e. forecast of throughput for a given power availability at the mill, was produced for each ore block using the CEET model and used for mine planning to smooth plant throughput. The forecast for blocks mined on a monthly basis was reconciled with plant results over the next 2 years and minor changes made to the CEET model. The forecasting exercise was repeated in 2006 and in 2008 with the latest model based on the testing of almost 1300 samples of drill core at closer spacing.INTRODUCTIONThe contracting of sales to clients and the timely supply of products to meet those contracts is a cornerstone of good business practice. Ensuring the correct scheduling of production is a major concern of mining companies where the supply and qualities of the raw material is uncertain and production facilities are not flexible. This is particularly challenging when the product is of high volume and produced far from the customer, such as iron ore.Apart from the metal content of the ore being mined, the greatest impact on production scheduling is the throughput of the comminution section of the extraction plant; most notably when size reduction is achieved by autogenous grinding. The response of the mills to variability in the hardness of the ore can change throughput by as much as 50% from day to day at some plants."

Jan 1, 2009

By Luis Giraldo

Rock bolt installation characteristics near roof falls have been identified as contributing to failure. One documented and regularly occurring failure mechanism is loss of anchorage between the grout and the rock wall of the bolt hole. Key contributors to the integrity of the grout interlocking with the rock mass are the diameter of the hole relative to the diameter of the bolt, resin versus cement type grouts, rock type, and condition of the hole. Smooth bolt holes consistently exhibit less rock bolt load bearing capacity than rough walled holes. The goal of this study was to quantify the benefits of borehole conditioning and develop a systematic approach that would allow improvement of roof bolt performance. A new rock drilling technology, the Helical Drag Bit (HDB), was used in the early stages of this project to condition the borehole. The HDB cuts a prescribed helical groove in the borehole wall. When a bolt is grouted into a hole that has been conditioned using the HDB, the grout fills the helical groove and provides a stronger, more reliable mechanical lock between the rock and the grout. This paper presents results of a series of tests conducted in the laboratory and in the field. Short encapsulation pull out tests have demonstrated considerable increase in pull out strength and more consistent bolt performance when hole geometry is modified using the HDB. The results have also shown that greater load bearing capacity improvements are obtained in mines with weak roof rock, where it is most needed. Additionally, bolts recovered for examination suggest that hole conditioning during roof bolting reduces the effects of finger gloving. Therefore, mines with stronger roof rock could also benefit from hole conditioning. A new roof bolt that uses the HDB principle has been designed and tested. The new system works with existing bolting equipment requiring minimal modifications to the traditional procedure used for installation of fully grouted rebar bolts. The use of these higher anchorage capacity bolts will allow mines to reduce severe injuries and fatalities resulting from ground failures while maintaining or increasing productivity.

Jan 1, 2005

Traditional methods for monitoring, and hence controlling, pyrometallurgical processes rely heavily upon the skill and experience of operators. A skilled operator will usually achieve consistent, though often conservative, results, whilst an un-skilled operator will require considerable time and training to achieve the same results. Semtech Metallurgy AB have demonstrated that continuous and precise control of pyrometallurgical processes can be achieved through on-line analysis of pyrometallurgical flame off-gas using optical spectroscopy. The feasibility of the technology has been demonstrated on a large number of full-scale tests at production plants and by several commercial installations. Evidence suggests that installation of this technology, called Semtech Optical Production Control (OPC), has resulted in considerable economic benefits to the plant efficiency and asset life. These economic benefits are believed to be a direct result of improved objective on-line control. Technically the following benefits have been demonstrated: improved metal grade control, reduced metal losses, reduced processing time, and improved personnel safety. SemtechÆs OPC is a non-intrusive technology which relies on the fact that the composition of the vapour phase above a high temperature melt is closely related to the instantaneous status of the melt. This enables on-line real-time analysis of the furnace melt to accurately determine melt status and in particular reaction endpoints. Originally developed for on-line monitoring of copper converting in a Pierce-Smith vessel the field of applications for the technology is steadily growing. This paper introduces the Semtech OPC technology; discusses various applications and outlines the demonstrated benefits.

Jan 1, 2002

By Yinan Zhang, Y. Luo

Most of the reported coal spontaneous combustion events occur in surface and underground mines where low rank coals (i.e., subbituminous and lower for this particular studies) are extracted indicating their high propensities for spontaneous combustion. Low rank coals have high moisture content (15 to 45%) and are capable of absorbing more moisture in dried condition. However, it is hard to induce the initial stage of self-heating process for the low rank coal using the current laboratory R70 testing method — a method widely used in the coal industry. Like a sponge, dry low rank coals can absorb water vapor in the air while the heat contained in the moist air is transferred to coal and served as the required activation energy to initiate the coal self-heating process. In order to prove this theorem and quantify the effects, the R70 adiabatic oxidation testing method has been improved to introduce a controlled moist flow into the coal reaction vessel. Tests using the new method and its setup on low rank coals showed that the initial self-heating process of coal sample can be greatly accelerated by the added water vapor — impossible with the regular R70 method. Once the self-heating is sustained, the removal of air moisture can further accelerate the process.

Sep 17, 2021

By Harry Dobroski

Communications with moving tracked vehicles in a rail haulage mine pose a difficult problem. These communications take place from dispatcher to vehicles or from vehicle to vehicle via the trolley line, which is a very poor communications line. As a result, deadspots and high-signal areas can occur anywhere along the line, or signal can decrease simply as a function of distance. An analysis is made of the trolley line as a communications line, and methods of improving its characteristics are discussed. Data from inmine experiments are presented, showing actual improvements in communications. Recent Bureau developments in new hardware are also discussed. These include an adaptive speaker control for existing carrier phones and a new generation of improved carrier phones.

By M Noakes

EcoTechnology refers to a series of potential metallurgical processes for complex ores, concentrates, tailings and slags that are all based on an initial chlorination step at low to moderate temperatures probably in a fluid bed chlorinator (FBC). Examples of the research and development (R&D) results are provided in this paper for a high grade Au/Sb Leach Tailings (EcoGold<sub>®</sub> Process), a very refractory sulphide Au concentrate, a refractory gold calcine tailings, a Cu/Au tailings (EcoCopper<sub>®</sub> Process), bulk polymetallic sulphide concentrates and polymetallic sulphide/oxide complex ores (EcoZinc<sub>®</sub> Process and EcoLead<sub>®</sub> Process). R&D on over thirty different ore types has been conducted at a bench scale as discussed. Latterly a dedicated pilot plant was designed and constructed by EcoTech Mining Pty Ltd (EML) and several of the different feed stock results have been confirmed by pilot plant testing. It is planned to scale up to a commercial demonstration plant. To demonstrate the versatility of EcoTechnology, bench and pilot plant test results on five of the projects are used as case studies as follows: Fosterville ‘leach tailing’, VIC; Wiluna flotation concentrate – BIOX Feed, WA; Wiluna calcine facility tailings, WA; Mt Morgan Cu/Au tailings, QLD; Polymetallic sulphide concentrates from Pegmont Deposit, QLD and Polymetallic sulphide/oxide ores from Commonwealth Mine Project, NSW. CITATION: Noakes, M, 2018. Improved recoveries and environmental outcomes from complex ores utilising EcoTechnology, in Proceedings Complex Orebodies Conference 2018, pp 122–123 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

By Keith S. Liddell

Gold in many ores occurs in sulphides, which, if the gold is finely disseminated, renders the ore refractory and therefore not amenable to the simple process of milling and cyanidation. Traditional methods of treatment of these refractory ores is to produce a sulphidic flotation concentrate which is roasted to form a porous calcine from which the gold is recovered by cyanidation. The roasting process imposes a constraint of a minimum sulphur grade of the concentrate on the flotation plant, which may lead to a lower gold recovery being achieved in the flotation section. Thermal decomposition of the concentrate by roasting means that the sulphur contained therein has to be treated and disposed of in an environmentally acceptable manner; and, if arsenopyrite is present in the concentrate the environ- mental aspects will be worsened. It has long been recognized that finer milling of gold-bearing materials improves the liberation of gold, especially when the gold particles are very fine. After extensive laboratory and pilot plant investigations (Liddell, Patents), a suitable mill has been developed for the mining industry by Metprotech, which is capable of producing very fine grinds (down to 90 percent passing one m if necessary). In the course of the investigations it has been found that a large number of gold-bearing materials are amenable to fine milling. A specific advantage that fine milling of sulphidic materials has over oxidative processes such as roasting and bacterial leaching is that the sulphides are not decomposed and there is therefore not a sulphur disposal problem. Furthermore, the milled sulphides can become a future sulphur feed source, and can be reclaimed if necessary. A further feature of the Metprotech process is that it is possible to add cyanide to the mill feed

Jan 1, 1988

By G K. Searle

In Australia, coal mines have generally not adopted filling to increase mining recovery. The aim of this project, entitled æImproved recovery in highwall mining using backfillÆ, was to examine the feasibility of using fill to improve recovery in highwall mining. Current fill practice was reviewed for metalliferous as well as coal mining, both here in Australia and overseas, for its applicability to highwall mining. Studies were then made at a conceptual level to determine whether fill could be economically used, to determine appropriate sources for fill and to trial key aspects of fill behaviour. A review of filling methods led to conceptual studies being undertaken on seven filling methods and these studies demonstrated that fill could be used to improve recovery. These studies were then further refined. Selected filling materials have been reviewed and laboratory tests have been made on these to assess their suitability.

Jan 1, 1998

By Broderick E. Davis

Each year, about 45 Mt (50 million st) of flotation tailings are discarded in Florida phosphate operations. These tailings only contain about 4% of the phosphate in the ore. However, more than half of the phosphate in the tailings is concentrated in the +600 µm (+28 mesh) size fraction at grades of up to 20% P205. Many phosphate producers have attempted to solve this problem by floating the +425 µm (+35 mesh) flotation feed separately. However, phosphate recoveries in these circuits are typically only 60%. For seven sampled phosphate operations, the phosphate content of the +600 µm (+28 mesh) fatty acid tailings ranged from 15% to 25% P205. In every case, the +600 µm (+28 mesh) fatty acid tailings was higher in grade than the overall flotation feed. Attempts to efficiently recover this coarse phosphate have apparently been unsuccessful at these seven phosphate operations. Recovery of this coarse phosphate would provide an additional 900 kt to 2.5 Mt (I to 2.7 million st) of phosphate annually and add an additional year to the reserves of these important deposits. A typical central Florida phosphate matrix is composed of three different mixtures of minerals. The +1.18 mm (+ 16 mesh) portion is chiefly phosphate pebbles and is beneficiated by sizing. The -106 µm (-150 mesh) portion contains virtually all of the clay minerals and is discarded in the hydrocyclone overflow. The -l mm +106 µm (-16 +150 mesh) material is a mixture of quartz and phosphate minerals.

Jan 1, 1993

By B. E. Davis

A problem that has continued to plague the Florida phosphate industry is the loss of coarse phosphate in the flotation circuit. Attempts to remedy this problem such as floating the coarse material (plus 425 µ m) in a separate circuit have resulted in limited success, but recovery is still not optimum. The Bureau of Mines is investigating ways to improve the recovery of coarse phosphate through improvements in the conditioning step. Studies to optimize conditioning parameters such as agitation energy, conditioning time, conditioner solids, and residual clay content have resulted in improved P2O5 recovery. Optimizing these and other conditioning parameters resulted in a rougher concentrate grading 30 pct P2O5 with a P2O5 recovery of 97 pct.

Jan 1, 1993

By Steven I. Olson

Since the introduction of froth flotation, the Florida Phosphate Industry has faced the challenge of coarse particle -850 +425µm (-20 +35 Tyler mesh) beneficiation. Several techniques have been used to upgrade this difficult size range. This paper discusses one approach that has met with success; namely, improved fractional recoveries through enhanced areation and improved material transport characteristics via larger than standard flotation cell mechanisms.

Jan 1, 1981

? The economic health and national security of the U.S. depends on the continued availability of, and access to, reliable and affordable energy and mineral resources. However, America is hindered by a costly, inefficient and often redundant regulatory structure that thwarts domestic investment, expansion and job creation. The annual cost of federal regulations in the U.S. increased to more than $1.75 trillion in 2008; averaging $8000 per employee.(The Impact of Regulatory Costs on Small Finns, SBA, 2010) ? The complexity, uncertainty and delays within the current permitting system places the U.S. at a competitive disadvantage with many other countries that have both abundant mineral resources and a more welcoming business and regulatory climate. As a result, American and international mining companies often move overseas or across borders to invest capital, create local employment, and produce the critical minerals America must then import at higher cost, while sacrificing employment and economic stimulus. ? According to Behre Dolbear, the U.S. is ranked lowest globally due to the lengthy permitting period required before mine development can commence. (Where not to Invest, 2010).

Jan 1, 2011