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By Y. C. Avniel, T. E. Warner

"It is important to be able to measure sulphur and nitrogen in molten iron and steel on-line. Unfortunately, there are no solid electrolytes which are stable under oxidising conditions and in which the ions of these species are mobile. In this paper, novel applications of beta alumina electrolytes are described and the results compared with data in the literature. Excellent agreement was obtained confirming this approach as a viable method of detecting elements whose ions are not mobile in solid electrolytes.IntroductionIn the past two decades, the rate of many processes in steelmaking have increased substantially. The sophistication of chemical analysis has also increased but analytical equipment is frequently positioned a significant distance from the operating plant which dictates that time is spent taking a sample, sending it to the analytical facility, preparation of the analytical sample prior to insertion into the equipment. In many cases, the time taken for analysis can exceed the time taken for the actual process and is now the rate defining step. Furthermore, most analytical methods are unable to distinguish between the amount of element which is dissolved in the steel and that contained in precipitates. Even if the analytical equipment could separate these two, the distribution would have changed between the molten steel and the cast sample. It would be an advantage to analyse on-line for impurities in molten metals."

Jan 1, 1997

By P. Hajiani

Rare earth elements (REEs) are critical materials in many leading-edge technology products. However, REE separation outside China has remained a challenge in addressing environmental concerns of current production. The author has worked on a technique employing the emphasised variability in the electrophoretic mobility (μi) of REE for the purpose of REE separation. In continuation of the results presented in IMPC 2016 [1], this contribution summarizes the progress achieved in 2016 and 2017. The major goal was to increase the REEs concentration by a factor of 1000 and to attenuate the consequent drawbacks, specifically joule heating effect. Amphiprotic hydroxylic solvent was selected to replace water, which has a major impact on the complexation mechanism and buffer requirement. Non-aqueous media result in a significant drop in the specific molar conductivity of the electrolyte, whilst μi reduces several times only. Moreover, a quasi-steady state electrophoretic separation in conjunction with temperature gradient focusing is adapted to improve scalability.

Sanes are utilized to make molds for metal castings in the foundry industry. Approximately a half ton of sand is disposed of for each ton of metal cast in this country. The purpose of this investigation was to study and develop a process to separate chromite sand and silica sand from reclaimed sands for a steel foundry. Physical separations were utilized to yield silica and chromite sands with desirable molding properties. Several different separation methods, including electrostatic, magnetic, and various gravitational approaches were examined. Experimental results are presented. A method was developed to separate chromite sand from silica sand after mechanical or thermal reclamation. The reclaimed sands are passed through a rare earth magnetic separator to separate chromite sand and magnetic impurities from non-magnetic silica sand. Chromite sand can be recovered from magnetic silica sand or magnetic impurities very effectively using a wet concentrating table. The applicabilities of the separation methods are discussed.

Jan 1, 1995

By Juan Patricio Ibáñez

Separation of arsenic and copper from Cu-As-H2S04 electrolytes by electrodialysis has been investigated at room temperature. The effects of current density and pH were studied. An arsenic-free copper solution was obtained for all the tested conditions. The transport efficiency for copper ions was found to be higher than 98% after 3 hours' test. Transport of arsenic and copper through the ion exchange membranes was increased by increasing pH and current density. Solution pH was found to be a key parameter for the separation process, since it controls the speciation of the ions to be transported and the formation of unwanted precipitates which reduce the global efficiency of the electrodialysis process. The main conclusion is that electrodialysis is a promising technique to be used in separating and/or concentrating ions of interest in copper electrometallurgy.

Jan 1, 2003

By Martha Gellner, Lutz Wuschke, Hans-Georg Jackel, Urs A. Peuker

"Electric vehicles are an alternative to the existing combustion engine driven cars. According to the EU Battery Directive a substantial recycling rate of at least 50 wt.-% has to be met for aged batteries since 2006. Existing recycling techniques are based on energy intensive pyro- and hydrometallurgical process, which are not able to recover all components. Aluminum and lithium for instance are slagged. The EU-Project “ABattReLife” investigated possibilities for a mechanical processing in order to create a sustainable process and a closed material loop from grave to cradle. After a sufficient liberation of the Li-ion batteries, components like the doped carbon black fraction (mainly lamination of electrode foils), the separator foil and the housing material can comparatively easily be separated from the other components by screening and air sifting. The remaining mixture consists of anode and cathode foils which have a similar free-settling ratio and are more difficult to separate from each other. A second comminution and compaction step modifies the particle size and shape as well as the degree of delamination. These changes influence the density of the electrode foils in order to improve the separation efficiency. Yield and purity of the generated metal concentrates were parameters to show if the separation was successful. The specific energy consumption for the different methods of processing was estimated in order to benchmark the cost-benefit ratio for each one.The studies have been accomplished with a zig zag sifter (model TUBAF), a hammer mill (model HM 340 Jehmlich) and with a Petkus-Sifter. Finally a process flow sheet was developed for a Li-ion battery recycling plant in pilot scale."

Jan 1, 2016

By M. Abdollahy

Solvent extraction of gallium from Bayer solution of Jajarm Alumina plant was investigated us-ing Kelex100 as extractant. Taguchi experimental design method was used in order to optimize the separation factor of Ga and Al. Optimum conditions were obtained as follows: Temperatuer: 65°C, volume ratio of aqueous phase to organic phase: 3.0:1.0, process time: 60min and organic phase containing 15vol.% Kelex100, 5vol.% isodecanol in kerosene. In this conditions, 74% gallium and 0.3% aluminum was extracted and separation factor was obtained 828.63.

Jan 1, 2014

By Dai Yongnian

"The feasibility to vacuum distillation of a crude metal or an alloy was discussed. The equilibrium relationship between vapor phase and liquid phase in A-B system - - - - - PA/PB =BAa*/b has been derived. The separation coefficient, BA = rAPA/(rBPB) is a judgment criterion. By calculation PA/PB, the equilibrium composition diagram of vapor phase and liquid phase was drawn. By use of the equation derived by M. Olette, the relationship among the volatilization amounts of various impurities in a crude metal (yi) was further solved. 1-(X/100)= C =(1-Y1/100)1/02i . From yi value obtained in practice, 2i, Pi and then can be calcu-lated. The correct volatilization order of various impurities was obtained. These results can be applied to determine the practical conditions (temperture, vacuum degree, type of distilla¬tion furnace, times of distillation and control of product composition) in distillation of a crude metal or an alloy.INTRODUCTIONRefining and separation of various impurities from nonferrous crude metals by vacuum distillation have many the advantages of high metal recovery, impurities recovered in metallic state, flowsheet simplified, good enviromental protection, low operation costs and in complex equipment. So in recent years this method has been adopted widely.Vacuum distillation has also been studied and used in separation of various elements from non-ferrous alloys and the area of its application is being extended rapidly.At this situation, some problems have been put up: What kind of impurities can be removed from crude metals? What kind of alloys can be separated by vacuum distillation? In present paper, attemps have been made to answer these problems and combine with practical results to analyse some valuable data obtained from testwork on vacuum distillation of crude tin and Pb-Sn alloy."

Jan 1, 1988

On my arrival in New York after the Russian examinations John D. Ryan, president of Anaconda, asked me what my plans were. I told him I wanted to be useful somehow in the World War that we had entered while I was away, but I did not know how. Ryan and Thayer told me that the new American Air Corps was gathering a group of executives, most of them young, to go to France as Army officers to help with the industrial side of our aviation activities. This would include construction of military airports, maintenance, and supply for our rapidly growing Air Corps. They thought I might be accepted in this group of about 30. It seemed to be just what I wanted, and I put in my application at once. My application was accepted about three weeks later and I was told to come to Washington to take physical and other tests and to meet others of the group. I liked them. They were a cross section of competent American manufacturers, bankers, automobile executives, and merchants. I was the only miner. I had many discussions in the days in Washington with members of our organization and others I knew who were going into war service. Attitudes were very different from those 55 years later. There was no discussion as to whether war was right or wrong. We were in it and must do all we could to help. At the same time there was a holdover from the days when, at least for the elite, war was high adventure. Even the most high-minded did not then realize that war is a horrible form of wholesale murder and, in 1917, it would have been treason to suggest this. I had two weeks before our industrial group was to start work which gave me time for a hurried trip to Berkeley where Dorothy and I announced our engagement.

Jan 1, 1976

By AIME AIME

A DOCUMENT of progress and of great interest to engineers is the report of the Military Affairs Committee of 'the Engineering Council, which has just been accepted and sent to the secretary of War. It provides .a plan whereby civilian engineers holding commissions in the Reserve Corps may; with their con- sent, be called into service of the army during peace at any time, either with troops in the field or in a consulting capacity on any government engineering work. The Military Affairs Committee finds ample authority in the military bill passed by Congress on June 4, 1920, for this arrangement and also for extending the privilege to military engineer, officer-s of the regular army to engage in civilian work during times of peace. It is hoped that the Secretary of War will adopt the suggestions and put the program outlined into effect. This is a constructive piece of work comparable to the efforts of the military Committee before the war which developed so much in the way of preparedness, particularly in the program of military lectures which, held in the auditorium in the Engineering Societies Building, became so popular that each lecture had

Jan 1, 1920

The preamble to the mining Act sets out that such Act is to provide for the encouragement and regulation of mining within the State of Queensland. This paper will attempt to follow the legislative path of such aim and in particular to show what part Mining Wardens play in the administration of the Mining Act.The Mining Act empowers the Governor in Council to constitute Mining Districts and Mining Fields and to appoint any duly qualified officer of the Public Service of Queensland to be a Warden or a Mining Registrar. As a matter of practice Stipendiary Magistrates who hold office in the major centre within a Mining District are appointed Wardens and Clerks of the Court are appointed Mining Registrars. In some districts where there is no Stipendiary Magistrate the Clerk of the Court is appointed an Acting Warden with all the powers of a Warden. Every Warden so appointed is a Warden for the whole State.To achieve impartiality Section 74 of the Mining Act provides that a Warden shall not hold or be entitled (directly or indirectly) to the benefits of any share or interest in a mining tenement or mining venture and provides a penalty of $1000 or imprisonment for six months or both, for contravention of such section.

Jan 1, 1986

By Peter Cali

There is one organization in Sweden, The Swedish Deep Stabilization Research Centre, which has been working with these questions and there is also a project, Eurosoilstab, within European Union to take a manual for deep stabilization.

Feb 10, 2003

By George Burke

Of the three projects, particularly the extensive Nimitz II (downtown) project, a single system, which was part of the operation, was used to control the spoil. Spoil control was continuous with the work since a vacuum truck and crew was used to suck up the spoils as they came out of the borehole. So, the whole job was kept clean both during operations and at the end of the shifts. On the Sand Island project, a double system was used. Larger spoil quantities were contained within the shaft limits during the work and the cleanup or disposal of the spoils was performed during excavation.

Feb 10, 2003

By Helen Ahnberg

The scope of the present paper is limited to report the experimental evidence and not for describing the analytical assumptions. However, the idea behind the experimental program is that the deterioration may be caused by the leaching of Ca from the treated soil to surrounding soil or water driven by the difference in the Ca ion concentration. As a consequence of Ca leaching, it may be natural to expect the expansion of micro void space within the treated soil. In a saturated condition, the water inflow into the treated soil may accompany the leaching phenomenon. We measured the water content within the treated soil. But there is not much difference in water content within the soil.

Feb 10, 2003

By Peter Iovino

Unfortunately, I don't know the unit cost per cubic yard of treatment. I reflected on that yesterday and I don't think that we considered the use of micropiles. They could have been an option. The challenge may have been picking up some of the lateral load but I think the micropiles could have been installed on a batter and perhaps extended to rock. We could have considered them, but I do not believe we explored micropiles as an option for this project.

Feb 10, 2003

By Stefan Dahlin

The laboratory tests indicated low permeability but as I said, as a rule, the permeability in the field has been found to be higher. A high permeability has also been found when doing back calculations of rates of settlements in different cases. But as I also said, there's a need for further studies in this area.

Feb 10, 2003

By Mitsuhiro Shibazki

I can't answer that question but I am looking at Andy, my co-author, and he says we didn't measure it. No movement. If I understand it correctly, how do we handle lateral forces in shear? The main columns were designed as pin connections so there wasn't a moment in the shear between the pile cap and the columns the steel reinforcing was used to resist that. I am not aware of how we would have installed those, it is possible to try and submerge them all if the jet grout is still fluid. They were higher than design. You are correct.

Feb 10, 2003

By Mary Ellen Bruce

Let me first address the issue of the wet grab samples. The wet grab samples that were attempted to take on the Central Artery were hindered by the fact that the way the mixing was being done was only by injecting grout on the way out, during withdrawal of the mixing tools. They would auger down to the required depth (usually with some water being injected), which took anywhere from 45 minutes to an hour, and then when coming out, the grout would be injected with grout. That was leaving a column of grout in the center where the shaft had been (i.e. inside of the blades of the mixing tools), which would end up being something like a foot in diameter because the pipe that was used for the drill shaft was a foot in diameter. So we had 10 inches to a foot of almost pure grout in the middle of our column and then we had 2 feet on either side that was mixed soil cement. So when they went down with the wet grab sampler not knowing where that was in the column sometimes they/we were getting strengths of 1500 psi, and sometimes they/we were getting strength of 500 psi or 100 psi. So what was it that we were taking into the wet grab sampler? In those cases you don't really know, but it wasn't representative of the core samples we were taking. We were purposely not coring in the center because we knew that was going to be high cement content, almost pure grout. So the issue of wet grab sampling particularly on this project, the Central Artery Project, was that we didn't really know what we were sampling. What becomes an issue with wet grab sampling in other projects is that you have to have another device (machine) in most cases, a cherry picker crane or something similar that can raise and lower with a beam that is used to forces the sampler down into the freshly mixed soil-cement. And regarding economics, is it more economical to have that crane standing by with its operator or to have a drill rig to come along later and do the coring and take the material out that's fairly identical to what you're finding in situ? The complaint of micro-fracturing in the core samples as you're taking the cores was raised by Seiko as causing large strength reductions. But, if you're doing it carefully, then I don't think that's much of an issue anymore, on research basis perhaps but not on a practical level.

Feb 10, 2003

By Dennis Wrixon

It was a little bit exceeded. The decision was the uniform settlement is measured at each one corner and the highest one corner is the important one. And in addition there is a differential settlement of 2.1 mm allowed. So we reached about 7.8 or 7.9 mm with the highest corner and in addition 2.1 so it was a little too much. But behind there is a very difficult calculation of the authorities where all of the displacements are combined together and there are of course some more factors of safety in these settlements.

Feb 10, 2003

By Jim Bruce

No answer required. From the drilling equipment suppliers, but the specifications must be tailored to be project-specific. Yes, the sonic technique is very interesting as we said, and it is not so much as an issue of the magnitude of power, it's about the efficient use of the power. The efficiency of the machine is not necessarily related to size so it is best to talk to the two contractors that supply the service about that. I think it can be scaled down but it is quite a big head, so therefore there are practical limitations on the size of the door it can walk through and also the size of the casings and rods that it can use. You might defeat the economic advantages if you were to use too short casing lengths. Boart Longyear have a low head room machine that can work within an 8 foot verical clearance.

Feb 10, 2003

By Douglas Heenan

The fracture orientations were inferred based on theory and previous experience. The fracture pattern was not monitored during the project. Grout volume was recorded at each sleeve port and real time movement monitoring of the building foundation was performed.

Feb 10, 2003