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By K. Fair

Using an agitated column 203 mm (8") diameter by 1829 mm (72") tall with independent agitation units for the gas dispersion zone and the collection zones, respectively, permitted the independent evaluation of the attachment and the detachment mechanisms for the chalcopyrite/ silica system. Three particle size fractions were used in this study, i.e. coarse (+75 µ m), intermediate (-75 µ m + 10 µ m) and fines (-10 µ m). The optimum selection of the two agitation zones for the three particle size fractions were determined as a function of grade, recovery, residence time and air superficial gas velocity.

Jan 1, 1990

By Arthur F. Taggart

IN 1900, Elmore found that if an acidulated pulp was stirred up. with an oil which was relatively insoluble in and lighter than water, and the mixture was allowed to stratify, much of the sulfide would be found hanging to the lower surface of the floating body of oil and could be skimmed off or overflowed with it. The action of the flotation agent here is twofold, first to select the sulfide from-the gangue-what today is called collection-and second, to buoy the collected sulfide away from the gangue.. The action in collecting is illustrated by Fig. 1, which contrasts the behavior of drops of oil brought, under water, to the surfaces of gangue and sulfide particles, respectively. The oil displaces water from the surface of the sulfide; the water displaces oil from the gangue surface. If, instead of considering the solid particles the fixed parts of the system of oil, water and solids, we consider the oil and water fixed and the solids presented, to the surface of contact, the condition will be as shown in Fig. 2; the. sulfide tends to. be drawn into the interface and the gangue to be excluded. The sulfide particles are held in the oil-water surface by the tension of this surface. The buoyant effect is supplied by the oil droplets in bringing the sulfides to the water surface, but not in holding them, there. GAS As BUOYANT MEDIUM OF FLOTATION In 1906 Sulman, Picard and Ballot discovered a practical and substantially fool-proof method of doing what Everson, in 1886, and Froment, DeBavay, Bessel and Elmore had been doing in the intervening years, viz.: using gas in place of oil as the buoyant medium for flotation, but retaining oil as the agent. To. all of these inventors "oil," with no qualification as to its kind and no true understanding of its function, was the important thing. But they placed on the oil an additional burden; viz.: froth-making, and it soon became apparent that not. all oils were suitable for the dual purpose. As a matter of fact, it is probable 'that each of these inventors knew only one suitable oil at the time he wrote his patent, but used the generic term in the patent with the usual idea

Jan 1, 1928

By Arthur Taggart

IN 1900, Elmore found that if an acidulated pulp was stirred up with an oil which was relatively insoluble in and lighter than water, and the mixture was al-lowed to stratify, much of the sulfide would be found hanging to the lower surface of the floating body of oil and could be skimmed off or overflowed with it. The action of the flotation agent here is two-fold, first to select the sulfide from the gangue-what to-day is called collection-and second, to buoy the col-lected sulfide away from the gangue. The action in collecting is illustrated by Fig. 1, which contrasts the behavior of drops of oil brought, under water, to the surfaces of gangue and sulfide particles, respectively. The oil displaces water from the surface of the sulfide; the water displaces oil from the gangue surface. If, instead of considering the solid particles the fixed parts of the system of oil, water and solids, we consider the oil and water fixed and the solids pre-sented to the surface of contact, the condition will be as shown in Fig. 2 ; the sulfide tends to be drawn into the interface and the gangue to be excluded. The sul-fide particles are held in the oil-water surface by the tension of this surface. The buoyant effect is supplied by the oil droplets in bringing the sulfides to the water surface, but not in holding them there.

Jan 6, 1928

By Graeme Heyes, Warren J. Bruckard, Michael A. Somerville

"A limited series of laboratory batch flotation tests was conducted on a suite of calcium-ferrite-based slags made in laboratory smelting trials. The smelting tests were conducted as part of a wider CSIRO Minerals’ research project aimed at developing a single-stage continuous copper-making process. The objective of the flotation work was to maximise copper recovery and iron rejection from slags made in the process.The slags treated included a reduced low copper slag, an oxidised high copper slag composite, and a very reduced low copper self-pulverising slag. The copper content of the slags varied from 2.9% to 14% Cu. The copper was present as metallic copper, oxide copper and copper-calcium ferrite phases with the phase mix related to smelting conditions. The slags were crushed, ground, wet-screened at 355 or 210 µm to remove coarse metallic particles of copper, and floated at natural pH (about pH 11) using reagents and conditions appropriate for the selective recovery of the copper phases.In rougher/scavenger tests on the reduced low copper and self-pulverising slags copper recoveries above 92% were obtained with copper enrichment ratios varying between 2.3 and 2.9. For the oxidised high copper slag copper recoveries were poorer - only 47% of the copper was recovered with an enrichment ratio of 3.3. The presence of the slow floating copper-ferrite phases in the slags limited further (selective) copper recovery. Ageing of the high copper slag, that is, a significant delay between grinding and flotation, resulted in a deterioration of the copper flotation response.The critical parameter affecting the flotation of copper from direct converting slags was found to be the form of the copper in the slag. Slags containing a higher proportion of the more desirable form of copper for flotation will provide the best opportunity for high copper recoveries to be consistently obtained, allowing improvements in the economics of the overall copper-making process."

Jan 1, 2003

By T. W. West

INTRODUCTION This paper presents an assessment of conventional flotation technology. In addition it presents some ideas which can be used to change the perception of what may be done with conventional flotation equipment to maximize its efficiency. Perspective of Conventional Flotation Technology 1. Flotation in many coal preparation plants is defined as something between a necessary evil and a non-viable concept because: -Too much art is required on a continuous basis to achieve uniformly acceptable results. -It is expensive, the capital cost in dollars per ton of circuit feed for flotation and dewatering is high. -It is a difficult process to use when SO2 reduction governs system design and equipment selection. -It creates a product (fine coal froth) that is difficult to dewater in the presence of BTU/lb as-received pressures. -It is a difficult process to control from a management standpoint, there are no dependable set points to rely on. 2. Many froth cell circuits are 0.5m x 0 (nominal 28 M x 0) feed which is sourced from screen/cyclone underflows. The original intent was to obtain maximum yield at acceptable product quality and moisture using disc filters. (See Figure #1) 3. An alternate to conventional flotation and its perceived to be limits of efficiency, capital costs, etc. is to move towards such developing flotation technologies as column flotation, reverse flotation, and microbubbles. A lot of work is being done to move these concepts thru pilot stages into full scale, commercial plant operation. The majority of the coal producers and coal preparation plant designers view these concepts as being in the development/pilot plant stages. OBJECTIVES Based on the preceeding comments of the perspectives of the coal producers and plant designers, the options are limited. They can make do with what they have available to them in the way of industry standard equipment and practices or they can move forward with developing technology. I feel there is a third option: what can we really do today with what is available to us, without reinventing the wheel? APPROACH 1. When processing coal against ash and SO2 restrictions, the fine clean coal stream can be the best stream on the clean coal conveyor due to the release by size and the ability to create a high BTU/low sulfur (dry basis) product. 2. Targets: -Consistent raw coal size consist in the plant feed . -Do not put pyrites in the froth cells. -Adjust criteria defining good flotation away from yield towards maximum BTU recovery at minimum ash. -Limit the froth cell feed size consist to 0.15 mm x 0 (nominal 100M x 0). -Establish and maintain a correct, consistent percent solids in the froth cell feed. -Select flotation reagents with care. -Introduce reagents in the proper sequence.

Jan 1, 1988

By Michael Drozd

Introduction Flotation is a recovery process that utilizes natural or chemically-introduced hydrophobicity of minerals to separate ore from gangue by attaching the ore particles to bubbles. Flotation has been known since 1906, when it was patented by E. L. Sulman, H. G. K. Pickard and John Ballot. Flotation's first documented plant use was in 1911, when it was used on gravity tailings from a zinc plant. Cyanide leaching was first patented in 1887. Most early precious metals flotation was linked to lead or copper concentrates. Most precious metal flotation is linked to sulfide recovery and utilizes such reagents as xanthates, dithiophosphates and thiocarbanilides. But the involvement of flotation in precious metals recovery does not have to be limited to active flotation of the gold and silver bearing minerals. Flotation can be used to remove interfering minerals, such as carbon, or cyanicides, such as copper, arsenic bearing minerals or other cyanide complexing minerals. Cyanide Leaching The use of cyanide to recover precious metals is the backbone of the industry. The various recovery processes that use cyanide are: 1. Leaching-Counter Current Decantation(CCD) Merrill-Crowe 2. Carbon-in-pulp (CIP) 3. Carbon-in-leach (CIL) 4. Vat leaching 5. Heap leaching These processes are selected depending on ore grade, ore leaching characteristics, reserve size and capital limitations. Ore grade is used as the first criteria to determine the type of cyanide plant required. However, the reserve size can determine whether a ground ore alternative is used. The ore leaching characteristics may indicate that the higher recovery, associated with a process that employs grinding, is the only economic recovery alternative. There are some extremely large leaching plants with grades that would be non-economic for some existing heap leach plants. Many factors, such as strip ratios, metal recovery and reserve size, determine what the ultimate plant design will be. The exact processing scheme that is used, is a multifaceted decision matrix, which gives the process metallurgist some job security. Precious Metal Recovery Using Flotation Flotation recovery can conceivably be used on any ore that has been ground. Many operations utilize gravity separation on the ore to remove native gold from the ore prior to sending it to cyanide leaching. On certain ores, where the gold is in visible nuggets or particles, this processing alternative is advantageous because the native gold cyanide recovery is

Jan 1, 1993

By P. W. Bridgman

FLOW and fracture are admittedly complicated phenomena of which we are yet only partially masters. There is not even universal agreement as to the details of the language best adapted merely to describe the phenomena, to say nothing of any theory. Certain points of view, however, are widely held, and there are certain general expectations as to what sort of procedures will prove permissible. A complete description of any situation involving fracture would demand a complete history of all the variables in the control of the experimenter. The experimenter endeavors so to choose his independent variables that they are adequate to determine completely the situation in the sense that when an experiment is repeated on the same initial material and with the independent variables running through the same sequence, all the other measurable properties of the system will also run through the same course. It is, I think, the universal conviction that when we are dealing with phenomena of flow and fracture, the most important of the necessary variables are the external forces acting on the various parts of the body; when the force history repeats, with certain obvious restrictions such as that temperature must be constant and non- mechanical forces, such as magnetic field, must be small enough to be ineffective, then the history of all measurable properties will repeat; in particular the alteration of geometrical shape due to flow will run through the same course, and when fracture comes, the character of the fracture will be reproduced. Complete mastery of merely the descriptive aspects of flow and fracture would demand the ability to predict the entire course of flow and complete characterization of the final fracture for every possible combination of forces, varying in time in all possible ways, when applied to bodies of all possible shapes. This full situation is obviously of prohibitive complexity. The first stage in reduction to manage- able simplicity is to resolve the total situation into the sum of contributions made by small elements. Our thesis is that if each of the elements is adequately characterized, the behavior of the whole system is fixed. The element is usually taken of a simple geometrical shape, suggested by the mathematics best adapted to the particular situation. The forces acting across the faces of the elements are ultimately determined by the forces acting across the free faces of the whole system. The detailed process of finding the precise forces on the faces of all the elements in terms of the external forces involves the use of a special mathematical invention, the stress, a constructional quantity consisting of six components. The stress at any point in the body is determined by both the external force system and by the physical properties of the body at all points; quite different stresses prevail at the interior of bodies of the same shape under the same external forces in the elastic and plastic ranges. The forces on the faces of any element are, however, uniquely determined by the stress system at the element. Our fundamental thesis

Jan 1, 1944

By Donald J. Hallbom

Limonitic nickel laterites slurries exhibit complex rheological properties including time dependency that varies from thixotropy to rheopexy. Chronic problems may occur if plant designers and operators fail to take time dependency into account. Stress decay tests indicate that laterite slurry takes roughly two minutes to approach steady state after a step change in the shear rate. As a result, most rheometer measurements are taken at a non-equilibrium state, making evaluation difficult. Two minutes is also long relative to the time that a unit of slurry in a processing plant is at any given shear state, so the slurry may never reach equilibrium. This paper presents a method to describe the rheology of laterite slurry using a Flow Array, which describes the rheology using an array of instantaneous flow curves crossed by an equilibrium flow curve. A rate equation for structural change in non-equilibrium conditions allows time dependence to be efficiently modeled. This flow array allows the flow behavior of time- dependent slurry to be predicted in non-equilibrium conditions using a simple time-step methodology. Keywords: Rheology. nickel laterite, hydraulic transport, pressure acid leach, flow array

Jan 1, 2004

By Darold Woodward, Stefan Haydn, Petr Pospisil

Most fatalities in tunnel fires are caused by the spread of toxic smoke. Controlling the spread of smoke is crucial to provide a survivable environment for emergency egress. A properly designed and tuned feedback control loop is required to achieve a target flow that is slow enough to allow pedestrians to escape under different boundary conditions. Feedback control loops are also helpful in optimizing energy consumption under moving traffic conditions. A reliable feedback flow control system requires sophisticated engineering knowhow and experience, careful selection of instruments and controlled variables, and thoughtful implementation from design through field testing and commissioning.

Dec 1, 2022

By Aïda Espinola

This work is part of a research program concerning the study of heavy metal removal and selective recovery from electroplating waste waters in the Guanabara Bay ecosystem, preventing the potential noxious retarded effect of landfill, specially in a country of heavy rainfall. A flow-throw cell was employed to adapt to the limits established by the local legislation for disposal in rivers and seas. The cell design is presented and preliminary results show that this cell may be applicable for the decontamination from copper.

Jan 1, 1994

By Walter Kauzmann

ALL viscous or plastic flow of incompressible matter is the result of shear strain; the changing shape of any body that is being plastically deformed can be completely described in terms of the shear strain occurring at each point in the body.[t] Furthermore, the relative amounts of shear strain occurring in different parts of a body under stress depend upon the relative rates of shear strain at those different points, so that if the dependence of the shear rate of any material on the temperature, shear stress, previous history, etc., were understood, the principles of plastic deformation would be known, and we could calculate how a body made of a given material, having a given shape, and subject to a specified system of forces, would change its shape with time. It may be said, then, that the problem of plasticity resolves itself into, first, the problem of the rates of pure shear processes, and second, the application of what is known about pure shear to actual cases. It is the purpose of this work to investigate the former problem -i.e., the dependence of shear rates on temperature, stress, etc.-from the standpoint of recent developments in the field of chemical-rate theory and with particular reference to the phenomena occurring in the creep of metals and in the plastic flow of crystalline solids in general. It is left for the mechanical engineer, and perhaps the expert in hydrodynamics, to deal with the problem of applications1 RESOLUTION OF MACROSCOPIC SHEAR INTO MICROSCOPIC MOVEMENTS; RESEMBLANCE TO CHEMICAL REACTIONS Just as any large body is made up of many small units, or atoms, so macroscopically observable shear is the result of many microscopic unit shear processes; just as the understanding of the behavior of large bodies demands the understanding of the atoms of which it is made, so the understanding of macroscopic shear demands the understanding of these fundamental unit processes. The study of shear from this "atomistic" point of view has made considerable progress. There has been fairly complete understanding of shear processes in gases for a long time, at least for nonturbulent flow, as a chapter on gaseous viscosity in any text on the kinetic theory of gases will prove. In recent years Andrade2 and Eyring3 have presented important theories for the flow of liquids and amorphous solids. Becker,4 Orowan,5 Taylor,6 Burgers,7 and Kanter8 have considered the

Jan 1, 1941

By Walter Kauzman

ALL viscous or plastic flow of incompressible matter is the result of shear strain; the changing shape of any body that is being plastically deformed can be completely described in terms of the shear strain occurring at each point in the body.[t] Furthermore, the relative amounts of shear strain occurring in different parts of a body under stress depend upon the relative rates of shear strain at those different points, so that if the dependence of the shear rate of any material on the temperature, shear stress, previous history, etc., were understood, the principles of plastic deformation would be known, and we could calculate how a body made of a given material, having a given shape, and subject to a specified system of forces, would change its shape with time. It may be said, then, that the problem of plasticity resolves itself into, first, the problem of the rates of pure shear processes, and second, the application of what is known about pure shear to actual cases. It is the purpose of this work to investigate the former problem -i.e., the dependence of shear rates on temperature, stress, etc.-from the standpoint of recent developments in the field of chemical-rate theory and with particular reference to the phenomena occurring in the creep of metals and in the plastic flow of crystalline solids in general. It is left for the mechanical engineer, and perhaps the expert in hydrodynamics, to deal with the problem of applications.1 RESOLUTION OF MACROSCOPIC SHEAR INTO MICROSCOPIC MOVEMENTS; RESEMBLANCE TO CHEMICAL REACTIONS Just as any large body is made up of many small units, or atoms, so macroscopically observable shear is the result of many microscopic unit shear processes; just as the understanding of the behavior of large bodies demands the understanding of the atoms of which it is made, so the understanding of macroscopic shear demands the understanding of these fundamental unit processes. The study of shear from this "atomistic" point of view has made considerable progress. There has been fairly complete understanding of shear processes in gases for a long time, at least for nonturbulent flow, as a chapter on gaseous viscosity in any text on the kinetic theory of gases will prove. In recent years Andrade2 and Eyring3 have presented important theories for the flow of liquids and amorphous solids. Becker,4 Orowan,5 Taylor,6 Burgers,7 and Kanter8 have considered the

Jan 1, 1941

By Adrian C. Deneys, David G. C. Robertson

"Fluid flow phenomena on the surface of a molten slag have been documented using video photography in a laboratory scale D.C. arc furnace. The flow on the surface of the slag appeared to be electromagnetically influenced. This was confirmed by varying the position of the anode, which changed the direction of flow on the surface of the slag. Temperature measurements in the bath also confirmed the change in the directional nature of the fluid flow induced by the arc.During some periods, solids were fed into the arc attachment zone (AAZ) down the center of the hollow graphite electrode. Significant movement of the arc around the basal annular surface of the hollow electrode takes place. The point of attachment of an arc on a hollow electrode was more variable than an arc attached to a solid graphite electrode. Video images showed that the solids were rapidly incorporated into the bulk of the slag. Temperature measurements confirmed the existence of a superheated slag layer at the slag-gas interface, which allowed the solids to be rapidly incorporated into the melt.This work has been conducted to study fluid flow, temperatures, and solid behavior during feeding, in the arc attachment zone of a D.C. arc furnace. The work also has relevance to optimizing furnace design for pyrometallurgical slag cleaning processes."

Jan 1, 1999

By G. W. Zhang

Ultra-fine Stirred Mill is a kind of high energy efficient equipment for ultra-fine grinding, and has been the mainstream equipment in the submicron powder and slurry industry. This paper mainly describes flow-field numerical simulation of the three popular ultra-fine grinding mills: (respective-ly as) Disc Stirred Mill, Pin Stirred Mill and Spiral Stirred Mill, by means of the software Computational Fluid Dynamics (CFD). In the flow-field numerical simulation, the velocity gradient, shear rate dispersion of the flow-field, the viscosity dissipation rate were analyzed with CFD. It is discovered that Pin Stirred Mill has the highest velocity gradient in circular directions and the most homogeneous distribution of shear rate among the three. Flow-field numerical simulation provides a new way (and means to) for the parameter optimization design and project enlargement of Ultra-fine Stirred Mill. The experiments were also carried out, the results are consistent with the results of the simulation analysis. For example, in GCC grinding experiments under the same conditions, the specific energy consumption of Pin Stirred Mill with 3600L in volume is 15%~17% less, and its processing capability is 13%~15% better than Disc Stirred Mill. Now with its optimized structure and excellent performances, more than ten sets Pin Stirred Mill with 3600L in volume have been used in industrial production in Shandong, Guangdong and Hunan province.

Jan 1, 2014

By Deepak Malhotra

This paper discusses the need for periodic auditing of mineral processing flowsheets and the potential benefits a company can gain from a study of this nature. A carefully designed flowsheet auditing can have a significant impact on the metallurgical performance in the plant. Several case studies illustrating the potential benefits that can be attained from flowsheet auditing of mineral processing plants are discussed.

Jan 1, 1986

By Manqiu Xu, Peter Wells, Gord Bacon

"A methodology is proposed for milling flowsheet design using flotation rate, selectivity and residence time distribution data. The flotation rate data and the difference in flotation rates between the main minerals to be separated are determined from laboratory batch tests. The residence time distribution (RTD) data is calculated using the tanks-in-series model assuming each flotation cell is a perfect reactor. The rate, selectivity and RTD data can be used to calculate the optimum flotation cell number in a bank for rougher/scavenger in a commercial plant.This methodology is demonstrated in a case study of a nickel sulfide ore. It is shown that miniplant rougher/scavenger data can be closely predicted from a batch test using the proposed methodology.INTRODUCTIONIt has been the trend in the past several decades that large flotation cells are increasingly used. This is largely driven by the economics as ore grades are getting lower and the rate of ore processing must be increased in order to keep mining operations economically viable. The development and evaluation of 250 to 500 m3 WEMCO SmartCell and Outokumpu TankCell flotation machines are well in progress. There are many advantages in using large cells: fewer cells, less floor space, lower power cost (although this is now being questioned for fine particle flotation), simpler circuit, simpler control, and lower auxiliary equipment cost (Arbiter, 1999). As flotation cells are getting larger, the importance of cell hydrodynamics, namely, air/slurry dispersion, power intensity, froth transfer, residence time distribution (RTD) and short-circuiting are being fully recognized (Jonaitis, 1999; Weber, et al., 1999; Gomez and Finch, 2002). It is not the intention of this paper to discuss flotation cell scale-up. The intention is to answer what is the optimum number and size of cells in a flotation bank for a given throughput. Figure 1 illustrates this problem facing design engineers. The same mean residence time required for a given throughput can be achieved in a single large cell, or many smaller cells in a row. A few cells of large size may be more cost-effective but they may not be as effective as more cells of smaller size in achieving the optimum metallurgy."

Jan 1, 2005

By S. R. Amos, N. O. Lotter, A. L. Hannaford, J. F. Oliveira, D. W. Broughton

"Ivanplats Ltd appointed Xstrata Process Support to perform the flowsheeting development work for their hypogene and supergene geomet units of the Kamoa Copper deposit, located in the Democratic Republic of the Congo. Through systematic flowsheet development using modern Process Mineralogy, the optimised milestone flowsheet delivered a saleable concentrate grade of 32.8% Cu at 85.4% recovery with hypogene ore, and a saleable concentrate grade of 45.1% Cu at a recovery of 83.4% for supergene ore. The significant value of this development is that a single flowsheet will treat both hypogene and supergene ores and produce saleable concentrates. Further work to advance the flowsheet performance has been identified for investigation in the near future.INTRODUCTIONLocation and Description of the Kamoa DepositThe Kamoa copper resource is located some 40 km west of the city of Kolwezi, in the south west of the Katanga Province of the Democratic Republic of the Congo, in the region of Central Africa. Drilling at Kamoa in 2008-2009 had discovered laterally continuous, sediment-hosted, high-grade stratiform copper mineralisation in a newly discovered copper district that forms a previously unrecognised western extension of the famous Central African Copperbelt – which hosts such world-class deposits as Kolwezi, Tenke-Fungurume, Konkola and Nchanga. This discovery showed that the western end of the Copperbelt in the Congo does not terminate at Kolwezi (Friedland & Broughton, 2009). The resource contains hypogene and supergene geomet units with a transitional zone located inbetween the (upper) supergene and the (lower) hypogene. In the hypogene unit, the major copper sulphides are bornite, chalcopyrite and chalcocite, whilst in the supergene, the sequence is led by chalcocite, then bornite, and finally chalcopyrite. Covellite is present in both units as a minor copper sulphide. Both geomet units will be mined and treated in one concentrator, either as blends or as campaigns."

Jan 1, 2013

By K. P. Wright

THREE OF the gold mines in the Red Lake Camp operates fluid bed roasters in their milling circuits. The mines are Campbell Red Lake, Cochenour Willans, and Dickenson. The roasters are used for the autogenous roasting of a flotation concentrate for subsequent gold recovery by cyanidation. Cochenour and Dickenson operate single stage reactors, whilst Campbell use a two-stage system. Ore treated by the mines is similar in that the major part of the gold is associated with arsenopyrite. Other sulphides present are pyrite, pyrrhotite, stibnite and sphalerite. Gangue minerals are mainly quartz, with carbonates and talc. Mineralization is, for the most part, extremely fine, and there is intimate association between sulphides and quartz, so much so, th at a picked specimen of apparently massive arsenopyrite will frequently contain as much as 80 per cent gangue. Gold recovery by straight cyanidation on this type of ore would not be higher than 80 per cent and

Jan 1, 1961

By Matthew John M. Krane

"The macrosegregation patterns and convective behavior of a Pb-5wt%Sb-35wt%Sn alloy are studied using new numerical treatments of solid particle motion and of transport phenomena occurring during the solidification of ternary metal systems. At this composition, the solidification which occurs while the local liquid composition is in the (Pb)-(SbSn) binary eutectic trough has a significant effect on these phenomena. The effects of this solidification path on fluid flow and macrosegregation are compared to the more familiar binary alloy patterns and the effect of solid particle transport is evaluated. The final predictions of macrosegregation are compared to measured composition profiles. IntroductionThe macroscopic maldistribution of alloy constituents during solidification, commonly called macrosegregation, is a defect which occurs in real metal processing systems. This nonuniformity of species distribution, especially when it forms a high composition gradient or a poor distribution of secondary phases, can lead to areas of high stress concentration, which contribute to cracking during extrusion or forging of wrought alloys or when an as-cast piece is severely loaded in service [1, 2]. Macrosegregation studies in binary systems have become quite common since the introduction of single-domain numerical models which feature one set of conservation equations and boundary conditions for an entire, fixed computational domain containing solid, liquid and multiphase regions. A complete review up to 1995 has been presented by Prescott and Incropera [3]. However, most commercial alloys generally have more than two species in amounts significant enough to affect the convective flows which lead to macrosegregation and other defects. The formation of secondary solid phases, including eutectic and peritectic reactions, also may occur in commercial metal alloys and should be treated using appropriate thermodynamic models."

Jan 1, 1999

By M. Leva

WITH the development of new processes for the production of synthetic liquid fuels, an extensive literature search was undertaken to uncover fundamental relationships between fluid and heat flows and the operating variables of new types of converters. Examination of published correlations revealed that considerable uncertainty existed in the correlation of the operating variables of such equipment with the pressure drops which could be expected through packed and fluidized systems; correlations proposed in the literature differed from each other frequently by as much as 75 to 100 percent. Because new processes, especially more recent modifications of the original Fischer-Tropsch process, must compete with old, firmly established processes on the basis of unit product cost, the pressure-drop correlations in the literature were considered to be too inaccurate for use in calculating the energy required to pass fluids through packed beds. The following study was begun in 1946 to develop correlations that would be suitable for the design of new equipment in which fluids are brought into contact with granular materials. To arrive at general relationships, systems were chosen that did not involve chemical reactions, and a, particular effort was made to give the correlations only in terms of quantities that are ordinarily available from general process and design specifications.

Jan 1, 1951