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By Douglas Glenn Stalheim

The uniformity of the final cross sectional microstructure and subsequent final mechanical properties and shape of structural steels is dependent on the type or types of recrystallization behaviors that are created. There are three main recrystallization behaviors that are the foundation of the metallurgy created during production. Alloy design and subsequent processing design strategy drive how much of each recrystallization behavior is created through the cross section of the product. Carbon manganese steels create only one basic behavior while the addition of microalloys, in particular niobium, can add two additional behaviors. The behaviors are intertwined with each other and build upon each other. The three behaviors are Type I, static recrystallization, Type II, no-recrystallization, and Type III, metadynamic/dynamic recrystallization. How much of each behavior is generated through the cross section through the production influences the final transformed microstructure and corresponding mechanical properties and shape performance. This paper will discuss the three behaviors, how they are generated, how to identify which behavior is occurring through modeling or actual mill data. Actual examples from production will be discussed.

Aug 16, 2017

By H. V. R. von Rhaden

Systematic quantitative X-ray diffraction analyses performed on diamond-drill cores originating from the Aandenk formation at the Loraine Gold Mine, located in the Welkom goldfield, Orange Free State, South Africa, have revealed the presence of a number of phyllosilicate mineral assemblages which have not hitherto been reported from this region. Rectorite, a regularly interstratified 1:1 mica-montmorillonite "swelling clay", is found to occur together with paragonite, muscovite, pyrophyllite, kaolinite, and chlorite in highly-altered friable rocks. The presence of rectorite in mill feeds may have potentially serious implications with respect to gold recovery. Quantitative X-ray diffraction analysis for phyllosilicates can be used as an aid to correlation, and also to guide the widths of stopes in underground mining. Rectorite has a unique mode of origin, which is discussed.

Jan 1, 1991

By James P. Bennett

The U.S. Bureau of Mines, Tuscaloosa Research Center, is conducting a review of the usage of different types of refractories, the current industrial practices to recycle/dispose of spent refractories, and the concerns associated with these practices. This information will serve as the technical basis for initiating a research program to recycle or find alternate uses for spent refractory materials. Approximately 1.6 million metric tons of clay based and 1.2 million metric tons of non-clay based refractory materials were manufactured in the United States in 1992 alone, representing a value of almost 2 billion dollars. Landfill has been and remains the disposal means of choice. Issues such as environmental regulations, concerns over landfill disposal, future liability, and product stewardship programs have brought about increased emphasis for recycling or alternate material use. Information on refractory consumption and the issues associated with recycling or disposing of used materials will be discussed, including current recycling practices.

Jan 1, 1995

By Frank Field, Randolph Kirchain, Elisa Alonso, Richard Roth, Nathan Fleming

"High material prices and price uncertainty can be harmful to manufacturing firms. Increased use of recycled materials, industry-wide, can lower both material prices and price variability; moreover, increased recycling decreases the use of primary material, which mitigates price increases due to scarcity effects. These stabilizing and price lowering effects are explored using an Aluminum industry model. We show that (a) increased recycling leads to smaller price fluctuations in the presence of a primary metal supply perturbation, and (b) that the more substitutable the secondary metal is for the primary metal, the lower the overall material price is.IntroductionThe price of an industrial metal is expected to be a function of both the marginal cost of extraction and its scarcity[l-2]: where scarcity can be defined as the degree to which anticipated demand exceeds the known supply. Recycling end-of-life metal increases the apparent supply of the metal, or-in a functionally equivalent, but alternative conception-lowers the demand for primary metal; this lowers primary metal scarcity and should, theoretically, reduce its price. To the extent that this theoretical prediction holds true, recycling can provide benefits to consumers of industrial metals in the form of lower prices.Using a platinum industry model, prior work by Alonso[3] has shown that increased industrywide recycling can reduce metal price volatility because the secondary metal production (a) offsets virgin metal depletion, and (b) responds to supply-demand balance fluctuations more rapidly than the primary market. However, Platinum is not a typical industrial metal in the sense that secondary metal is perfectly substitutable for primary metal: Both primary and secondary platinum metal are functionally equivalent and have a common price. Other metals, such as secondary aluminum which is used as an example case in this study, contain varying degrees of other elements that were either intentionally added, or were inadvertently mixed in with the metal during the scrap recovery process. Consequently, different grades of scrap exist that have different profiles of elements in their composition. Depending on their particular profile of elements, more or less of a given grade can be used as a mass fraction of the final alloy-the secondary metal is not perfectly substitutable for the primary metal. For the purposes of this paper, the aluminum mass fraction of the final alloy that can be made up of secondary aluminum is termed the secondary substitutability of that grade in that alloy."

Jan 1, 2011

By S. Fiore, M. C. Zanetti, C. Clerici

The processes and fluxes of a cast iron foundry plant located in the North of Italy were analyzed in order to determine the amount and kind of wastes produced from the different activities. The main fractions are the molding sands, furnace muds and powders coming from the dust abatement plant, the exhaust lime, the furnace refractory, the metallic shotting and the sludges and powders coming from the dust abatement plant of molding lines for a total production equal to 800 t/d. All wastes were sampled and particle-size and chemically characterized to evaluate the best recycling or reuse solutions. Wastes were sieved and divided in three categories according to the particle-size dimensions: below 0.1 mm, between 0.1 and 0.6 mm and above 0.6 mm. The fraction above 0.6 mm dimension underwent magnetic separation to recover and quantify the potentially available iron fraction. The fraction between 0.1 mm and 0.6 mm was chemically characterized in order to understand if it could be fed to the sand regeneration plant. The below 0.1 mm fraction was characterized to evaluate the following recycling and reuse solutions: additive for molding sands and/or raw material for the concrete industry.

Jan 1, 2003

By N. Razavinia

Most mining and metallurgical industries produce relatively large quantities of low grade waste heat which they vent, for the most part, to the environment. To date, little is being done to recover some of this heat and transform it from low grade to a high grade energy form such as electricity. A few decades back this was also true of paper, plastics and metals. Recycling was not a prominent activity. Today, we all know that it is and that recycling is a must for sustainable development. To this end, we feel that we are now at that point in time when the recycling of waste heat to electricity must be given serious consideration. By recycling waste heat one can achieve at least one if not two of the following benefits: 1) reduction in the carbon footprint ? by improving the overall energy efficiency of a process, and 2) production of electricity at an economically viable cost. We have developed a process that captures, concentrates and converts (3 C?s) waste heat to electricity. The process comprises 3 distinct interacting units. The first unit captures and concentrates waste heat using heat pipe technology. The second unit converts some of the concentrated heat to mechanical work which can then be readily converted to electricity. This unit is based on the classical piston/cylinder engine arrangement that is widely used by consumers to power systems with compressed air, for example. The third unit of the process dissipates the heat that the engine cannot convert to high grade energy. It also uses heat pipe technology to achieve this. The combination of the 3 units forms a unique system for recycling waste heat. This paper describes the system and it presents some results that show how the system can be made to be economically viable.

Aug 1, 2013

By Franklin H. Sharp, Kenneth L. Clifford

During the last few years the New Lead Belt of Southeastern Missouri has become the main source of lead in the United States. It also produces significant amounts of zinc, copper and silver. The mines are located on a narrow, mineralized trend extending southward from Viburnum, MG. for about 35 miles. The ore occurs as replacement deposits in the Bonneterre lime- stone formation which is about 1000 ft below the surface. In most of the mines, enough water is produced to supply the milling requirements without any reuse. There are dry areas, however, and at least two mills must rely on water reclaimed from their tailings lake to augment the mine water. These mills have no choice but to utilize recycled mill water.

Jan 7, 1973

By Lifeng Zhang

Printed circuited boards contain considerable quantities of valuable metal, while also containing many environmental pollutants making them unsuitable for landfill. In this study the decomposition of common plastics used in printed circuit boards were studied. Polytetrafluoroethylene (PTFE), polyvinyl chloride (PVC) and polyethylene (PE) were heated in both C02 and argon atmospheres using a thermo-gravimetric furnace (TG) coupled to a mass spectrometer (MS). Soda ash Na2C03 and baking soda NaHC03 were used as reactants. The degradation temperatures and evolved gases are presented for single plastics and mixtures. Mixed plastics are shown to behave as a sum of the individual plastics. The mass loss temperature is the same in CO2 and argon. However, less residue is formed when heated in CO2.

Jan 1, 2008

By P. Henry

A novel electrochemical cell has been developed for the recovery of MnO2 from residue of pyrolusite ore leading loaded with Fe, Al Ni, Co and Si impurities, This new process can be considered as an alternative to the traditional methods : S02, H2O2 or bioleaching. It has been observed to proceed fairly rapidly and could prove to be a more economically viable process, as well as being more environmentally acceptable. Electrochemical characterization and kinetic studies have shown that MnO2 is effectively leached by electrogenerated ferrous ions at high current density from a pulp containing less than 5 g8 Fe. The chemical reactions are : Cathode (inox) : 2F23+ + 2e ? 2 Fe2+ Bulk: MnO2 + 2 fe2+ 4H+ ? Mn2+ + 2 Fe3+ + 2 H2O Anode (Pb-Ag) : H2O ? ½ O2 + 2H+ + 2e Global: MnO2 +2H+ Fe2+ = Mn2+ + H2O + 1/2 O2 The catholyte (MnO2 pulp) circulates upward in the expanded mesh cathode separated from the sulfuric acid solution anolyte by a separator which shows high mechanical resistance, low porosity, low potential drop, and reasonable cost. Laboratory and mini-pilot tests have led to the construction of an OT crating pilot plant (100 kg/hr) able to leach more than 95% of Mn, Ni, Co at 1000-1200 A/m2, 50°C with high faradic yield (> 95 %) and low power consumption (3.2 kWh/kg kWh/kg &4D). New applications like the treatment of spent Zn-Mn batteries, polluted soils, spent catalysts and oxide ore (cobalt, nickel) with electrogenerated redox species are now investigated at a laboratory and mini-pilot scale.

Jan 1, 2000

By J. Fogarty, J. Sofra

The mobile telecommunications sector is one of the fastest growing industries worldwide. However, increasingly stringent environmental regulations are placing pressure on manufacturers to accept responsibility for end of life products. The companies are therefore exploring avenues to recover the valuable components contained within the mobile telecommunications devices thus reducing the quantities of toxic components going to landfill. Batteries used to power the devices, are typically based on either nickel-cadmium, nickel metal hydride, or lithium ion cells. They contain toxic metals including nickel, cadmium, lithium, potassium, lead, and cobalt in a complicated arrangement of battery cells surrounded by a metals then plastic casing. The Ausmelt Catalytic Waste Converter (CWC) for waste treatment and recycling is well suited to processing all three mobile phone battery types for the recovery of valuable metals in marketable products that can be recycled to industry without turning out harmful levels of toxic emissions. Ausmelt recently demonstrated the capabilities of its CWC by continuously processing 4.5 tonnes of nickel-cadmium batteries. Using Ausmelt's pilot plant facility in Australia, the nickel-cadmium batteries were processed to produce a nickel iron sulphide (matte), a cadmium fume and a final slag which satisfied CS toxicity leach test criteria and was safe f<~r disposal to landfill. This paper explores the commercial development of the Ausmelt CWC for treating each of the three battery types in light of (a) the outcomes of the recent demonstration, and (b) the current and expected future availability of batteries for processing.

Jan 1, 2000

Societal influences, needs, and uses for recyclable materials are becoming increasingly important business and economic factors in the traditional natural resource companies. Several metals (such as steel, aluminium, zinc, lead and cadmium) are amenable ro recycle which eliminates solid waste generation and decreases the depletion of natural resources. In recent years, the non-ferrous industries have begun to recycle more materials and the next decade will see even larger recycle efforts. In addition to the traditonal recyclable materials, existing metallurgical plants are, or should be, able to handle and recycle materials viewed as &apos;hazardous&apos;. Unfortunately, some national and regional regulations hinder, and in some cases prevent, the recycling of certain materials. Zinc Corporation of America (ZCA) is currently the largest producer of zinc metal in the USA and one of the world&apos;s largest producers of value-added zinc products. Over the last few years, ZCA has become one of the world&apos;s largest recyclers of zinc from various diverse materials. ZCA considers these recyclable materials as valuable &apos;land mines&apos; that provide economic alternatives to the depletion of natural resources while serving society in the minimisation of solid waste disposal. Using the current production facilities of ZCA as a model, this paper overviews the recycling of zinc-bearing materials with special emphasis on: 1. the amenability for recycle within ZCA&apos;s pyrometallurgical and hydrometallurgical operations, 2. the quantities and economics of recycle, 3. the problems of recycling hindered by current national and regional regulations, 4. the concepts of total recycle rather than just recovering zinc while generating a modified solid waste, and 5. the motivators for recycling.

Jan 1, 1993

By F. K. Ikumapayi

An approach to environmental sustainability and improved process economy, in sulphide minerals production is recycling of process water in flotation of complex sulphide ores, although the chemistry of process water may be a critical issue to flotation efficiency. The influence of major components of calcium and sulphate ions in process water on xanthate collector adsorption and flotation response using pure chalcopyrite, galena and sphalerite minerals were investigated by Hallimond flotation, zeta-potential measurement, FTIR and XPS spectroscopy studies, while bench scale flotation tests were also carried out using complex sulphide ores. The impact of the species in flotation was comprehended using deionised water, tap water, process water and simulated water containing equivalent amount of calcium and sulphate species in process water. Hallimond flotation results showed a decrease of chalcopyrite and galena recovery in process water and also in the presence of calcium and sulphate ions in both deionised and process waters, whereas sphalerite does not respond to flotation. The adsorption of calcium and metal ions but not sulphate ions on the minerals is evidenced by zeta-potential data. FTIR and XPS studies revealed the presence of surface oxidized sulfoxy species and surface calcium carbonates on chalcopyrite in the presence of process water and water containing calcium ions, surface oxidized sulfoxy and carbonate species on galena in the presence of deionised water, process water and water containing calcium and sulphate ions, all at flotation pH 10.5, and these surface species influenced xanthate adsorption. The presence of surface oxidized sulfoxy and carbonate species at the sphalerite flotation pH 11.5 were seen in the presence of deionised water, process water and water containing calcium and sulphate ions, but the surface species does not influence xanthate adsorption. Bench scale flotation using two different complex sulphide ores showed that chalcopyrite, galena and sphalerite recoveries are better in process water than tap water. The studies showed that the process water can be recycled in flotation with no detrimental effect on grade and recovery of sulphide minerals. Keywords: sulphide minerals, flotation, zeta-potential, FTIR, XPS

Sep 1, 2012

By Larry M. Southwick

Steel mill electric arc furnace dust is a RCRA listed hazardous waste and its treatment and/or disposal are regulated by a complex set of rules. These regulations were originally established to encourage recovery and recycling of valuable components. For EAF dust, the more valuable constituents include zinc, lead, cadmium and iron. In fact, current trends are in the opposite direction, as the regulations have complicated the ability to commercialize new treatment technologies and created substantial roadblocks and liabilities for processors. As a result, almost half of the EAF dust generated in 1997 will be landfilled. The problems are compounded by difficult processing requirements, less than sterling examples of technology development and mechanical and operating problems. This paper explores some options to simplify the processing requirements and thereby easing difficulties in commercializing new technologies and expediting the recycling of recovered metals. Dust processing usually includes a simple step followed by two complicated steps. The simple step is fuming of heavy metals away from iron and other residues. The complex steps are (1) separating and purifying the heavy metals and (2) upgrading the iron residue. The first complex step can be simplified by producing an intermediate product that is amenable to processing by zinc refiners. This route benefits from the currently underutilized (by dust processors) resource offered by refiners, who have experience in and existing processes for separation and purification of zinc-based heavy metals. Various processes and their associated product options are reviewed and compared. Future directions for dust processing developments are suggested.

Jan 1, 1998

By S Logan, J Pu, J Milsom, G McDonald

Management of environmental issues is an integral part of the mine decommissioning process. In Queensland, miners must comply with environmental aspects of the Mineral Resources Act and Contaminated Land legislation. Successful decommissioning involves the integration of a final Plan of Operations, decommissioning report addressing the mineÆs commitments included in its Environmental Management Overview Strategy (EMOS), and Site Contamination Report for relinquishment of leases under the Contaminated Land Act (1991). Niugini MiningÆs Red Dome Mine is proceeding through the decommissioning process. This paper discusses the important environmental management issues including sampling programs, management of culturally significant areas, assessment of background concentrations of target analytes, the use of historical reviews and risk assessment techniques, the timing of works, and the remediation/management of large areas of impacted land. The importance of a clear communications plan between key stakeholders is also discussed.

Jan 1, 1998

By L. M. Southwick

"The history of extractive metallurgy is replete with examples of commercializing new processing technologies. The successes are widely reported, but failures seldom are. This is unfortunate, for usually we can learn more specifics on how to succeed in technology development by studying and thoroughly understanding their failures. Frequently one encounters a red herring that caused the whole effort to fail. A thorough and objective due diligence up front would have identified those red herrings and prevented the pursuit of a bad idea and the resulting destruction of capital. Due diligent analyzes performed before construction of three such bad ideas will be discussed. One is an EAF dust process, which pursued the red herrings of a poor understanding of the business, a naïve view of past experience, and false confidence in the technology. Another will examine the effort to commercialize a new pressure copper leach process that followed the red herrings of inadequate testing of the raw material, application of processing conditions that were inherently unsafe, and an improper assessment of the inherent advantages of past developments. The last is an alternative iron-making process, where the red herrings were incomplete and superficial assessment of prior pilot plant and demonstration plant tests, an assumption that the commercialization model of “build it and we will make it run” was viable, and a technology whose technical fatal flaws had already been identified. Unfortunately, capital destruction often also closes the window to more intelligent pursuit of technology development. TECHNOLOGY COMMERCIALIZATIONThe development and commercialization of new technology is a vital part of keeping industry profitable, able to deal with new sorts of feed stocks and current with economic, product, operational and environmental requirements. This is a difficult task in the best of times, and can be compounded when the developers become enamored of a particularly favorable characteristic of the project or of the product. These “red herrings” divert project focus away from the arduous path to success and, in the end, result in project failure."

Jan 1, 2012

By J. B. Mawdsley

"The Red Lake Gold Shore mine is 4/5 mile west of the town of Red Lake, Ontario, and a mile northwest of the Howey mine. It came into production in August 1936, and in a little over 2 years produced 21,099.58 oz. gold from 83,949 tons milled.An investigation of this deposit was made by the writer during parts of September and October, 1937t. The geology of the deposit is also discussed by H. C. Horwood(2) , and the characteristics of the ore were investigated by the Bureau of Mines, Ottawa (1).The orebodies are pipe like and close together, in a north-northwesterly trending zone of dykes, veins, and shear zones in a granodiorite stock, just south of a pronounced valley with a trend of N.65°E. believed to lie along a strong shear zone and fault . The dykes, veins, and mineralization are believed to have been successively emplaced along structures having three general trends and that were due to compressive stresses that alternated, at least four times, from west of north to east of north. In common with many other gold deposits, the gold mineralization here occurred late and followed the last east-of-north stresses.WALL-ROCKSThe mine is within the Dome stock, % mile from its southeast margin. Near the mine the rock is a pink hornblende-biotite granodiorite, grading within short distances, but not abruptly, into a dark grey variety. Near the workings at least, scattered small inclusions form about ½ to 5 per cent of this body. Most of them are fine-grained, angular, or partly rounded, greenstone fragments, but some have been partly granitized and feldspar has been developed in them."

Jan 1, 1954

By Sherwin Kelly

RED LAKE has suffered from its over-zealous friends, who had something to gain by their zealousness and were, for the time being, friends indeed. Now, what was once hailed as a new El Dorado is anathema to many. Neither extreme view was justi-fied, and in time a new gold district may be expected to develop slowly, but surely. The marvel is that little streaks of valuable metal are ever uncovered by the few men who roam that tre-mendous, almost unexplored area that is the "North Country." The area to be explored is so immense, and the men who can do it so few, that once they leave the "steel," take their canoes and packs, and disappear into the bush, they may travel the innumerable watercourses that are the highways of the wilderness for days or weeks, and never see one of their own kind. Patricia, for example, is one of the mining districts of Northern Ontario, lying at the western side of the

Jan 8, 1927

By AIME AIME

MANY producers have held that the only workable quicksilver ore is easily recognized by its .cinnabar content. In most cases this is true. A noticeable exception is a. particular opalite deposit where part of the ore now being mined in considerable quantity shows only the yellow mineral, calomel, or its alteration products. This mineral, on exposure to the sunlight, quickly becomes coated with gray or black layers that may be removed by scraping to reveal the yellow mineral beneath. The blackening of this mercuric chloride on exposure to sunlight shows reaction to form metallic mercury, which is usually plainly present in this class of ore.

Jan 1, 1929

By J Coombes

There is much debate on the Competent Persons qualifying criteria for providing classified resource estimates for public reporting. The CRIRSCO family of codes including the JORC Code, SAMREC, PERC and NI43–101, require Competent Persons to have at least five years ‘relevant’ experience and belong to professional bodies. These codes provide further, albeit vague, guidelines to assist individuals with their personal decision to take on the mantle of ‘Competent Person’. There is a risk, however, that these qualifying criteria can result in ill-prepared Competent Persons whose actions and recommendations would undermine their own reputation and that of the organisations that employ them; the integrity of the profession and the principles based reporting systems; as well as the stability of stock markets that rely on these estimates.Based on doctoral study on the development of professional competency within the mining industry, this paper presents an evaluation of the suitability of the current qualifying criteria as well as an analysis of alternative criteria. The research included a series of interviews with industry experts and an online survey of resource geologists. Semi-structured interviews provided a sense of experts’ expectations and interpretation of the current definition of ‘Competent Person’. The comprehensive online survey included a self-assessment, a series of situational questions designed to evaluate responses to typical resource geology scenarios and a set of open-ended questions relating to factors contributing to competency development.A summary of the data analysis, interpretation of the results and a set of recommendations for revised ‘Competent Person’ qualifying criteria are presented. This paper contributes to the conversation on what makes a person suitably qualified to report classified resource estimates and provides practical targets that can be used in the professional development of resource geologists.CITATION:Coombes, J, 2014. Redefining Competent Persons criteria for resource geologists, in Proceedings Ninth International Mining Geology Conference 2014 , pp 153–158 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

By Issa S. AI-Kharusy

Oxidation/reduction (REDOX) alloy media, as used in wastewater treatment, is founded on the exchange of electrons. Because of this electron exchange, many contaminants are converted to harmless components which require no further treatment. Other types of contaminants are removed from the waste stream by electrochemically bonding to the alloy medium. This paper discusses the REDOX reactions, the role of the alloy medium in various treatment processes, and describes specific applications of REDOX alloy media for the removal and minimization of waste. The characteristics and handling of spent treatment media is also reviewed as a further consideration in waste minimization.

Jan 1, 1996