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Hazardous waste has often very complicated chemical compositions in a variety of physical forms and is normally processed in rotary kiln incinerators. Due to large variations in waste types and difficulties in feed characterization, the complex transport processes within the incinerator are not well understood, and the incineration process meets challenges in a smooth operation, and expects various uncertainties in the process chemistry and emission control. For better understanding of the incineration process, simulation was carried out by using Computational Fluid-dynamics (CFD) to characterize temperature and species distribution in the incinerator. In order to catch certain aspects of thermal and chemical behavior, a novel approach is proposed to represent approximately the waste streams and the subsequent combustion process. Hazardous waste in various forms from an industrial-rotary-kiln waste incinerator is firstly converted to a hydrocarbon-based virtual fuel mixture with approximately the same HIC molar ratio and calorific value. The simulation of the combustion process of the simplified hazardous waste was proceeded with a combustion model. The distribution of temperature and chemical species especially the remaining CO in the system is preliminarily investigated. Distribution of CO concentration, as a good indicator of emission level for the incineration process, could be used to evaluate the emission control. The predicted temperature distribution has been compared with available measurement data from an operating rotary kiln waste incinerator at A VR-Chieme, in the Netherlands. Reasonable agreement has been reached between the measured and predicted temperature data. [n the next step, measurement of species distribution in the system is planned to further validate the combustion model.

Jan 1, 2003

By Markus A. Reuter, Joep Verwoerd, Marc J. A. Pijnenborg, Yongxiang Yang

"Incineration is a proven disposal technology for all waste materials with heat release potentials, and provides high degree of toxic destruction and control for a broad range of hazardous materials. In the Netherlands, all the hazardous wastes are processed at AVR-Chemie located at the Rotterdam harbour, through rotary kiln incinerators. The newly enforced regulations from the European Union with stricter emission levels require a better understanding of the incineration process and improved process control. However, the transport phenomena and combustion processes within the kiln system are very complex and not well understood. In order to get better understanding of the incineration process, research has been carried out to study the fluid flow and combustion behaviour of the incineration system. Computational Fluid-dynamics (CFD) was used to simulate the gas flow and waste combustion process, and temperature measurements of the operating rotary kiln incinerator were conducted to validate the CFD model. This paper will present the latest results from the current research project for simulating gas flow and combustion heat transfer for a wide range of hazardous waste streams.The simulation of the waste incineration process was carried out using a general-purpose CFD code Phoenics. The rotary kiln and the secondary combustion chamber (SCC), with a waste processing capacity of 50,000 ton/y and an energy input of 30 – 40 MW, is translated into a CFD model. The model includes a k-e turbulence model and a global gas-phase combustion model (3-gas or 7-gas combustion model). The 3- gas model (Simple Chemically-Reacting System, SCRS) predicts only the thermal effect of the fuel combustion, and only one global fuel is used, therefore, real chemical species are not taken into account. In the 7-gas combustion model, (an Extended SCRS, ESCRS), different forms of waste fed into the incinerator have been modelled into a mixture of a general hydrocarbon fuel C3H4 and other components such as CO, CO2 and H2O. Thus, all the incoming fuel streams with different compositions and calorific values can be properly converted into separate inlets. The combustion of the waste is assumed to take place only in gas phase in two steps: (1) primary combustion of the main fuel component C3H4 to form CO and H2, (2) secondary combustion of CO and H2O to form CO2 and H2O. The rate of each combustion reaction is assumed to be controlled by turbulent mixing of fuel and oxidant (air or oxygen), i.e. the Eddy-Break-up (EBU) model. The resulted temperature field was validated with temperature measurement data, and the simulated temperature distribution from both 3-gas and 7-gas model have reasonable agreement with the measured data."

Jan 1, 2003

By Ralph Sherman

THE remarkable increase in the distribution of the small underfeed stoker for use in furnaces and boilers in small industrial plants, apartment houses and homes has brought producers and distributors of bituminous coal to consider the problem of which coals and which sizes are best suited to this market. Many papers have also appeared, mostly in the trade journals, discussing the problem of the combustion of various coals and various sizes of coal in small stokers. Much difference of opinion has been apparent in these articles; due often, it would appear, to a mis-understanding of the fundamentals of the process of combustion in the stoker fuel bed. During the past year and a half, a program of research has been conducted at Battelle Memorial Institute: (1) On the process of combus-tion in the fuel bed of the small stoker, sponsored by Battelle Memorial Institute, and (2) on the relation of the characteristics of bituminous coals to their performance on small underfeed stokers, sponsored by Bituminous Coal Research, Inc. As a result of this program of research, two publica-tions have been made, one1 dealing with the problem of clinker formation, and the other2 with the relation of the size of the coal fed to the stoker hopper to that of the coal that reaches the retort to be burned. The experimental research on the relation of size to the performance of the coal is being actively continued. A publication of Bituminous Coal Research, Inc. presenting the data obtained on the performance of several sizes of four typical bituminous coals will appear shortly. Because of the early appearance of that publication, the present paper includes few numerical data. The purpose of this paper is to follow the coal from the hopper through the furnace with a discussion of the various actions that occur, in the hope that it will lead to a clearer understanding of the relation of the type of coal, the size of coal, and other characteristics, to the performance. The authors do not pretend to have obtained the answers to all the complex questions involved; many unanswered questions will be proposed on which future research work is planned.

Jan 1, 1936

A laminar-flow furnace was used to study the combustion of four flotation concentrates (chalcopyrite, pyrite, galena, and sphalerite) in air at temperatures up to 1400¦C. A special- Iv developed two-colour pyrometer was used to measure the temperature of individual chalco- pvrite and pyrite particles as they underwent combustion. Chalcopyrite and pyrite ignited with very high rates of reaction at air tempera- tures above 480 and 600¦C respectively, forming molten products. Galena and sphalerite required temperatures in excess of 700 and 1200¦ respect- ively to attain equivalent rates of reaction. The high rates of reaction for galena and spha- lerite were caused by vaporization. Temperature measurements for chalcopyrite and pyrite are reported here, together with vaporization measurements for chalcopyrite, galena, and Sphalerito

Jan 1, 1980

By N. H. Coates

The Bureau of Mines designed, constructed, and operated an 18-inch- diameter, fluidized-bed combustor for highly caking coals to evaluate the method for possible application to power generation. In initial tests, combustion was carried on successfully, with carbon losses as low as 0.8 percent. Coal ash was not satisfactory as a bed material, but mullite proved to be acceptable. Overall heat-transfer coefficients from the bed (-20 + 50 mesh mullite) to a water-cooled tube were about 75 Btu/hr-ft2- °F.

Jan 1, 1970

By W. G. Davenport

All Outokumpu flash furnaces burn some hydrocarbon fuel. Hydrocarbon combustion supplements heat from Fe and S oxidation and provides local heating in cool; parts of the furnace. Adjustment of hydrocarbon fuel combustion rate is an effective way of controlling furnace temperature. More oxygen and more oxidation of Fe?and S in the flash furnace continue to diminish the need for1hydrocarbon fuel. Still, as Tables 2.1 and 3.1 show, all flash furnaces use it. Oil is the most common fuel -natural gas, coal and coke are also used. This chapter demonstrates how hydrocarbon fuel is included in our flash furnace matrix. It shows that: (a) three new variables, mass hydrocarbonfoel. mass CO2 in offgas and mass H2O in offgas are inserted (b) carbon and hydrogen balances are added (c) hydrocarbon fuel quantity is specified (d) ,the oxygen balance is modified to include CO2 and H2O (e) the enthalpy balance is modified to include hydrocarbon fuel, CO2 and H20.

Jan 1, 2001

By A. W. Scaroni, C. Y. Tsai

The effect of particle size and composition on the pyrolysis and combustion of a pulverized bituminous coal in an entrained-flow reactor has been investigated. Predicted time-temperature histories of the coal particles and experimental weight loss data indicate a strong coupling of heat and mass transfer to the pyrolysis and combustion rates. A higher combustion rate following ignition was observed as particle size was increased to 112 µm (about 140 mesh). This is related to a higher particle temperature after ignition for the larger particles. Although the heating rate before ignition decreases with increasing particle size, higher slip velocities and surrounding gas temperatures for the larger particles promote early ignition. The presence of liptinite in the coal increases the weight loss rate before and immediately after ignition. Similar behavior was observed for pyrolysis. Fractions of an HVA bituminous coal that were rich in mineral matter or semi-fusinite were found to have a higher heterogeneous char combustion rate than vitrinite-rich samples.

Jan 1, 1987

By M. Radwan

This research reports on the synthesis of advanced silicon-based structural ceramics from mixtures composed of natural sand (Sinai white sand), reclaimed silicon and graphite by the nitriding combustion synthesis method. With pulverized sand (? 40 m), we found that the nitriding combustion can be realized at self-sustaining mode in the SiO2?Si?C system under 3 MPa nitrogen pressure. Depending on the composition of the starting mixtures, single-phase silicon oxynitride (Si2N2O) powder as well as new Si3N4?Si2N2O and Si2N2O?SiC composite powders with controllable chemical compositions were successfully developed. The measured thermograms of various combusted mixtures and the thermodynamic characteristics of possible exothermic reactions in this system were discussed to explain the nitriding combustion behaviour and mechanism. Near-full dense Si2N2O were fabricated from synthesized Si2N2O powder with 5 wt % oxide additive by the spark plasma sintering (SPS) method at 1600 °C. The dense Si2N2O samples had good mechanical properties (18.7 GPa Vickers hardness, 3.3 MPa m1/2 fracture toughness and 363 MPa strength) and excellent chemical and oxidation resistance. The synthesized composite powders were also densified to high densities (> 90 % of theoretical values) by SPS technique. The results obtained in this study can be seen as a new route to prepare important silicon-based structural ceramic powders with various compositions/properties from cheap starting materials which makes them potential for wide range of applications.

Jan 1, 2006

By Z. I. Zaki

Synthesis of TiC /A1203 Composite from TiO2, Al and graphite using combustion technique has been investigated at different initial temperatures; room, 400 and 600 °C. The effect of initial temperature on the composition of the product, wave velocity and combustion temperature of the reaction was studied. The measured combustion temperature and wave velocity were increased with increasing the initial temperature of the combustion reaction. The maximum wave velocity obtained was 5.9mms-1 when conducting the combustion reaction at initial temperature of 600 °C. Oxidation resistance of the obtained composite was also studied at the temperature range 300-800 °C. No oxidation is detected before 400 °C while it takes place effectively at 700 °C forming different titanium oxides. Wave velocity measurements method was used to calculate the activation energy of the reaction between the starting materials. It was found to be 316.34 kJ mol 1 at the temperature range that was studied.

Jan 1, 2007

By Carlos G. Philips J.

El presente texto señala el proceso de combustión del carbón en el horno ciclónico. Por tal motivo, se describe el principio de operación, donde el combustible se quema a altas temperaturas y la mayor parte de la ceniza se retiene de forma líquida en el área húmeda del horno ciclónico, evitando su paso al caldero y la contaminación del aire. En cuanto a los combustibles empleados, no se ha encontrado la adaptabilidad de un quemador que pueda operar simultáneamente con combustibles sólidos, líquidos o gaseosos, aunque es posible adaptarlo al uso de varios tipos de combustibles: carbón bitúminoso, lignito, antracita, así como también petróleo y gas natural. Los calderos usados dividen el horno del caldero en dos secciones, una alta y otra baja. Entre las características de la operación tenemos la resistencia, fuerza auxiliar, molienda del carbón. Finalmente, en el proceso de eliminación del sistema de horno ciclónico, se utilizan los tanques para ceniza fundida dado que operan a presión a fin de no detener el caldero cuando se extrae la ceniza fundida.

Aug 20, 1965

By Juliana Gonçalves Pohlmann

A redução das emissões de CO2 pela substituição parcial de carvões por um combustível renovável como a biomassa é um assunto de crescente interesse na siderurgia. As emissões de CO2 na etapa de redução podem ser reduzidas pelo uso de biomassa como combustível ou pela queima em condições de oxi-combustão. Este trabalho visa investigar a combustibilidade de eucaliptos termicamente tratados em laboratório em atmosferas convencional (O2/N2) e de oxi-combustão (O2/CO2), comparando com uma moinha de carvão vegetal e carvões típicos do processo de injeção em altos-fornos (PCI). Os testes de combustibilidade foram conduzidos em um forno de queda livre (DTF) a 1.300°C com diferentes proporções de O2/N2 e O2/CO2. Os chars do DTF foram caracterizados quanto à aparência ao microscópio, área superficial e reatividade. Os eucaliptos termicamente tratados apresentaram as maiores combustibilidades, seguidos pela moinha e pelos carvões. Os chars das biomassas apresentaram estruturas mais reativas do que os chars dos carvões, e maiores áreas superficiais e reatividades. As poucas diferenças de combustibilidade e reatividade devido à atmosfera de oxi-combustão indicaram que, se aplicada ao alto-forno, esta tecnologia pode não ocasionar efeitos negativos no comportamento de carvões e biomassas.

Aug 16, 2017

By Pablo dos Santos Pina

O alto custo do coque na produção de zinco no Forno Waelz da Votorantim Metais Zinco, em Juiz de Fora, ensejou a realização de testes em parceria com o SENAI CIMATEC para utilização de combustíveis alternativos na Planta Piloto, com o objetivo de mapear a viabilidade técnica e financeira para utilização na Planta Industrial. Ao longo dos testes foram utilizados: cavaco de eucalipto, chip de pneu e moinha de carvão vegetal. Os testes foram realizados com sucesso, apresentando oportunidades de substituição do coque usado atualmente por combustíveis alternativos, com potencial de ganho financeiro para VMZ JF. Este potencial precisa ser validado em testes em escala industrial.

Aug 17, 2017

By Filipe Arthur Firmino Monhol

O setor de mineração gasta milhões de dólares com a utilização de combustíveis fósseis nos seus mais variados processos, como, por exemplo, em fornos de pelotização. Paralelamente a isso, a humanidade está produzindo cada vez mais resíduos e nestes existe um potencial energético que não pode ser negligenciado devido a situação de grande demanda em que se encontra a sociedade. Assim, a reciclagem energética desses resíduos pode aliar os conceitos de sustentabilidade e economia. A utilização de resíduos como fonte energética pode, assim, além de gerar uma grande economia ao setor, aumenta significativamente a contribuição ambiental do mesmo. Portanto esse trabalho faz uma análise de viabilidade do uso de resíduos sólidos, que são transformados em combustíveis fluidos através das tecnologias da gaseificação e da pirólise, para utilização em fornos de pelotização de minério de ferro. Diferentes tipos de resíduos são propostos. Foram realizados alguns ensaios para se obter a capacidade energética desses materiais. Os resíduos se mostraram altamente energéticos e uma excelente alternativa à demanda industrial.

Aug 8, 2018

By AIME AIME

THE technical material in hand and the plans under way for the 141st meeting of the Institute clearly indicate a well-rounded program of unusual excellence. The meeting will be held in the Engineering Societies Building, Feb. 15 to 18, and while it is too early to announce definitely the time of the various sessions much of the detail has been organized up to that point. Every group in the Institute membership will find much of special interest, and several features should prove generally attractive. The various committees in charge of the lighter side of the meeting are hard at work to emulate the standard established last February In this connection and in this paragraph it will suffice to say-there will be a Smoker-dinner! The Committee on Mining Methods plans two sessions for which these papers are in prospect:

Jan 1, 1932

By Raúl Gomero Cuadra

El presente texto revisa el Plan de acción sobre la Salud de los trabajadores realizado entre el período de 2015- 2025 de la Organización Mundial de la Salud. El plan elaborado contiene los ejes de acción estratégicos, objetivos específicos e indicadores dirigidos a la protección de los trabajadores, la promoción de la salud y el bienestar de los mismos, con énfasis en las poblaciones laborales en condiciones de empleo inequitativas y los que están expuestos a condiciones de trabajo peligrosas. Así también se difunde las acciones que buscan disminuir los riesgos del trabajo y las enfermedades no transmisibles en los sectores económicos críticos, el acceso a la salud y la cobertura universal de salud y los determinantes sociales de la salud de los trabajadores.

Apr 1, 2017

By Roger Díaz de Cossio

El presente artículo describe algunos aspectos de la educación de la carrera profesional de ingeniería en Europa. Para ello, se obtuvo información de educadores de países como: Inglaterra, Francia, España, Italia, Alemania, Portugal, Bélgica, Suecia, Polonia, Yugoeslavia, Finlandía, Austria y Holanda, donde se evaluó la cantidad de años reales para obtener de título de Ingeniero Civil, en qué niveles está dividida la educación de ingenieros en el país; el nivel de matemáticas que debe poseer un ingeniero al recibir el primer grado; los posibles estudios postprofesionales que existen respecto a la carrera; el número de estudiantes por cada escuela de ingeniería, métodos de enseñanza, y el porcentaje de materias básicas para alguna ingeniería, los materias de aplicación y las herramientas comprenden los programas de las escuelas de ingenierías.

Jan 1, 1969

By Charles Stahl

El presente texto describe la comercialización de la plata a corto y mediano plazo. El periodo de corto plazo se refiere a cualquier negociación dentro de un período de 5 minutos y tres semanas, mientras que la de mediano plazo, es la transacción que se produce entre dos y tres meses. Para la comercialización de metales es necesario la confianza y la paciencia como habildidad para el éxito de la negociacion, de forma que se tiene que comerciar con un equilbrio y sin excesos.

Jan 1, 1984

By Luis Remy Valdivieso

Las minas de Marcona, principales productores de mineral de fierro del Perú, están ubicadas a 400 km, en línea recta al Sur-Este de Lima. Debido a la geología del terreno, los minerales eran virtualmente desconocidos hasta 1952. Ya, con la explotación geológica completa efectuada durante los úitimos diez años, se ha probado que la oxidación y el intemperismo han causado alteración en el tipo de minerales presentes. Asimismo, la gran mayoría de los minerales tiene un alto contenido de azufre que los hacen económicos. En ese sentido, el presente texto señala la comercialización de los minerales en Marcona, donde las pruebas metalúrgicas demostraron que tales minerales pueden ser sometidos a un tratamiento que los convierte en productos comerciales. Por ello, ante el requerimiento más exigente de los compradores referido a especificaciones físicas y químicas del mineral, la Marcona Mining Company decidió instalar una planta de beneficio capaz de impartir a los minerales provenientes de las minas que explota el más alto grado de pureza conocido actualmente. Así, la planta de San Nicolás produce cuatro tipos distintos de mineral de fierro para uso en altos hornos o bien en hornos de sinter, y como consecuencia, se aseguró la vida al distrito minero de Marcona.

Jan 1, 1965

By Alan Mayton, N. Kumar Kittusamy, Christopher Jobes, Farid Amirouche

Industrial equipment exposes individuals to whole-body vibration (WBV) and mechanical shock. This exposure can negatively impact their health, safety, comfort, and working efficiency and performance. Accordingly, proper seat design is an important consideration in reducing the adverse effects of WBV exposure to vehicle operators. Since the human body is sensitive to low frequency WBV, ride quality is a basic and important element of good seat design. When designing a suitable seat, it is essential to understand vibration exposure environment of workers and how well they can tolerate this environment [1]. This is particularly true in the mining industry. Mayton et al. [2] reported on a low-coal shuttle car seat design that underwent limited, yet successful underground mine trials. Building on this work, a follow-up study compared NIOSH and existing seat designs on low- and mid-coal seam shuttle cars. The NIOSH seat designs included viscoelastic foam, which has properties similar to those found in a mechanical spring/damper suspension system. The seats also included an adjustable lumbar support and a fore-aft seat adjustment. The NIOSH seat designs contrast with the existing seat design, which have little or no lumbar support and include inexpensive foam padding of the type commonly used in furniture. This paper will focus on the seat designs for the mid-coal seam shuttle car and compare subjective comfort data collected from five vehicle operators with ISO 2631 – based reduced comfort boundary (RCB) analysis of recorded vibration levels. Methods Experimental data were collected using three different tools: triaxial accelerometers, pre-amplifiers, and filters connected to a data recorder; a visual analog scale (VAS); and a short questionnaire. Researchers recorded quantitative or objective vehicle vibration data to determine the input and output acceleration at the operator cab floor and operator seat interface. Qualitative or subjective data, collected with the VAS, allowed researchers to obtain the operators’ immediate impressions of shock, vibration, and discomfort levels for the vehicle ride on each of the seat designs. Each shuttle car operator made six round trips with the vehicle each seat. The shuttle car operator marked the VAS on the first, third, and sixth round trip of the trials for each seat. A round trip consisted of traveling to the coal face with no load and returning to the load discharge location with a full load of coal. Results Total overall average ratings for the five vehicle operators of the mid-coal seam shuttle car, showed that operators sensed from 45 to 87% less discomfort with NIOSH seat designs compared to the existing seat design. Using a 95% CI, researchers computed a strong positive correlation for discomfort. Figure 1 illustrates the RCB analysis method for one of two NIOSH seat designs.

Jan 6, 2006

By R. Bainbridge

"IntroductionTHE LEAD SMELTING Department of The Consolidated Mining •and Smelting Company of Canada, Limited (Cominco), at Trail, B.C. treats materials from numerous sources for the recovery of lead, •and, of secondary importance, for the .recovery of sulphur as S02• The Department's sintering section has a .capacity of 1,500 tons daily. This section is being replaced by •a new charge-•handling and sintering plant with a daily capacity of 2,000 tons of finished sinter. Materials handled in the sintering section comprise concentrates, ores, and fluxes from Company mines and from 'custom' (independent) producers, together with intermediate products from various plants of Cominco'•s Metallurgical Division, all of which must be treated to, make up a chemically balanced charge of a predetermined lead content for the sintering plant.As received, 80 •per .cent of these materials are finer than 200 mesh, and one-quarter of the tonnage (dry basis) is a slurry .at 30 to 40 per cent moisture. This slurry, a -residue from the electrolytic zinc operation, was, for many years, partially dried before being mixed with other dry materials to make up the sinterplant charge.Some experimental work carried out in 1937 indicated that the metallurgy of the sintering operation could be improved by adopting a technique of 'wet-mixing' followed by controlled drying and nodulizing."

Jan 1, 1953