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By R. E. Johnson, J. E. Dutrizac, B. R. Palmer

Silver sulphide (acanthite) and lead sulphide (galena) dissolve relatively rapidly in FeCl3 media with the formation of elemental sulphur and soluble silver and lead chlorides. Parabolic kinetics are observed, and the leaching rates are controlled by the outward diffusion of the AgCl and PbCl2 reaction products through the constantly thickening elemental sulphur layer formed on the sulphide. Hence, both leaching rates are strongly dependent on those variables which affect the solubility of AgCl or PbCl2 at the reaction interface. The rates therefore increase with increasing temperature and total chloride ion concentration, but decrease in the presence of elevated concentrations of AgCl or PbCl2. By contrast, neither sulphide is significantly attacked by ferric sulphate media, even at high Eh values. Although the reasons for the refractory behaviour of Ag2S in sulphate media remain unknown, the low rate of PbS attack is attributable to the passivating layer of PbSO4 and elemental sulphur formed on the surface of the galena.

Jan 1, 1993

By Paul W. Weiblen, Louis J. Cabri, Rolando Lastra

"Preliminary tests were done to determine whether comminution by electric-pulse disaggregation, or E-PD (cf. Rudashevsky et al; 1995), was more effective than using conventional crushing for Merensky Reef ore. A hand sample of the Merensky Reef was sawn in two: then one sub-sample was comminuted to .2 mm using E-PD at the University of Minnesota, and the other sub-sample was crushed to .2 mm using a conventional jaw crusher at CANMET.The products of the electric-pulse disaggregation and jaw crusher were fractionated by sieving and by a separation using a heavy liquid with a specific gravity of 3.3, because the proportion of platinum-group minerals (PGM) and sulphides to silicate minerals is very low. Thus, four mineral separates were produced: .2000 + 833 µm, -833 +208 µm, -208-µm float and -208-µm sink. All the mineral separates were studied by image analysis (Lastra et al; 1998). The main objective was to determine the liberation of gangue (silicate minerals), chromite, pyrrhotite, chalcopyrite, pentlandite and PGM. In the case of the PGM, a specific image analysis program was written to search and measure these minerals.The results show that the liberation obtained for gangue was similar (~99%) using either method of comminution. However, the liberation obtained for chromite (~89% vs. ~38%), pentlandite (~50% vs. 1%), pyrrhotite (~56% vs. ~38%), and PGM (~56% vs. ~1%) by E-PD was higher than that obtained by conventional jaw crusher, whereas the liberation obtained for chalcopyrite (~20% vs. ~71%) by E-PD was lower. Nevertheless, the image analysis of the products also showed that the PGM are strongly associated with pentlandite. Thus, for the Merensky Reef, liberation of pentlandite from the gangue minerals and chromite is important to recover more of the PGM. This maybe be significant because, in addition to increased recovery of platinum-group minerals (PGM), Merensky Reef pentlandite also contains significant quantities of valuable platinum-group elements like Pd and Rh (Cabri, 1981; Cabri 1988, Kinloch 1982, Peyerl 1983). Hence, the results indicate that for the Merensky Reef, electric-pulse disaggregation would represent a better comminution operation than a conventional jaw crusher would. In addition, the greatly improved liberation for chromite may find application for the PGM-rich UG2 chromitite."

Jan 1, 2003

By Paul W. Weiblen, Louis J. Cabri, Rolando Lastra

"Preliminary tests were done to determine whether comminution by electric-pulse disaggregation, or EPD (cf. Rudashevsky et al; 1995), was more effective than using conventional crushing for Merensky Reef ore. A hand sample of the Merensky Reef was sawn in two: then one sub-sample was comminuted to – 2 mm using E-PD at the University of Minnesota, and the other sub-sample was crushed to –2 mm using a conventional jaw crusher at CANMET.The products of the electric-pulse disaggregation and jaw crusher were fractionated by sieving and by a separation using a heavy liquid with a specific gravity of 3.3, because the proportion of platinum-group minerals (PGM) and sulphides to silicate minerals is very low. Thus, four mineral separates were produced: –2000 + 833 µm, -833 +208 µm, -208-µm float and -208-µm sink. All the mineral separates were studied by image analysis (Lastra et al; 1998). The main objective was to determine the liberation of gangue (silicate minerals), chromite, pyrrhotite, chalcopyrite, pentlandite and PGM. In the case of the PGM, a specific image analysis program was written to search and measure these minerals."

Jan 1, 2003

By B C. McLellan

The decline of ore grades on land, increasing demand and high prices for various minerals have led to an increased interest in mining the deep ocean sea floor. The potential deep ocean reserves are vast and in some circumstances the grades are high enough to consider mining. However, the consequences of such mining are as yet uncertain. This paper will present the results of a comparative assessment of life cycle impacts of deep ocean minerals. Two alternative extraction technologies from different deep ocean resource types were examined and key commodities are considered. Initial results indicate that the energy requirements will be higher than the average land-based resources, but may fall within the range of the deepest terrestrial mines.CITATION:McLellan, B C, 2015. Comparative life cycle impacts of deep ocean minerals and land-based counterparts, in Proceedings Third International Future Mining Conference, pp 253–260 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 4, 2015

By Natália de Oliveira Roque Maciel

Atualmente uma das maiores preocupações da humanidade está relacionada as questões ambientais, o que tem motivado a pesquisa e o desenvolvimento de materiais provenientes de recursos renováveis e ambientalmente amigáveis. A despeito disso, este trabalho objetiva comparar a resistência de compósitos desenvolvidos com fibras naturais e, portanto, ambientalmente amigável e de compósitos desenvolvidos com fibras de vidro, que por sua vez apresentam impactos ambientais desde a fabricação até o descarte. Foram fabricados 13 corpos de provas para amostras contendo 0% de fibra, 30% de fibra de curauá e 30% de fibra de vidro na matriz epoxídica e ensaiado na máquina de tração. Os resultados obtidos apresentam valores bastante superiores para as amostras contendo fibras de vidro, contudo, ao relacionar a tensão do compósito com a respectiva densidade da fibra, foi possível constatar que os compósitos com fibras naturais chegam a apresentar resultados superiores aos compósitos fabricados com fibras de vidro. É possível concluir, portanto, que do ponto de vista da propriedade mecânica em questão é possível substituir as fibras de vidro por fibras de curauá.

Aug 17, 2017

By A. W. Stradling, M. J. Fairweather

"The selective flotation of lead, zinc and iron sulphide minerals is key to the economic performance of concentrators treating zinc-lead ores. Diagnostic metallurgy is a tool to quantify mineral behaviour as a function of particle size and liberation. The result of such analysis may be used to select preferred strategies to improve metallurgical performance. The zinc flotation circuits at three Teck Cominco operations: Sullivan, Polaris and Red Dog are compared here. This paper analyses operating data from each of these circuits. The effects of mineralogy and performance by particle size are emphasized. Metallurgical performance at these three concentrators varies substantially. Liberation size is the major factor in determining metallurgical performance. Complex mineralogy requires a fine grind to achieve effective liberation. Fine grinding results in offsetting decreases in concentrate grade through entrainment. The economic treatment of complex fine-grained deposits requires optimisation of regrind size for liberation without unduly compromising concentrate grade through gangue entrainment.INTRODUCTIONUntil recently Teck Cominco Metals Ltd. operated three mines treating zinc-lead ore. In order of increasing mineralogical complexity they are: the Polaris Mine on Little Cornwallis Island in Nunavut in the eastern Arctic, the Sullivan Mine in southeastern British Columbia and the Red Dog Mine in northwestern Alaska. Both the Polaris and Sullivan Mines have recently ceased to operate due to depletion of ore reserves.The ore type and associated gangue, mineralogy and iron solid solution vary significantly between these deposits. Table 1 summarizes some of the important differences"

Jan 1, 2003

By Zohreh Kazemi Motlagh, Evan J. Owen, Virginia T. McLemore, Jakob Newcomer

Five-element style deposits are unusual hydrothermal systems that are typically characterized by a nickel-cobalt-arsenic- silver-bismuth metal assemblage. This mineralization is often represented by abundant native silver, arsenic, or bismuth, and followed by nickel, cobalt, and iron arsenides (skutterudite, safflorite, nickeline, rammelsbergite, and lollingite). The Black Hawk district in Grant County, New Mexico is one of the few examples of this mineralization style in the United States. Despite the differences in formation temperature, depth of emplacement, and host rocks between five-element style deposits worldwide, there are commonalities in mineralogy, ore texture, and composition. A detailed exploration of the native metal and arsenide phases will be performed to compare ore forming fluids between systems and the effects on styles of mineralization and paragenesis, as well as to aid in broader classification of the deposit style. Mineralogy and mineral relationships of the Black Hawk District and other five-element deposits worldwide will be characterized by reflected light petrography, scanning electron microscopy, X-ray diffraction, and electron microprobe analysis. Mineralogical phase diagrams will be generated to better understand the driving processes and evolution of the systems through native metal and arsenide precipitation.

Feb 1, 2024

By Byron R. Berger

Epithermal Ag-Au deposits form at low to moderate temperatures in near-surface environments. Historically, these deposits have been the source of high-grade ores. Increases in the market prices for gold and silver make lower-grade ores economically viable when available in large tonnages. Both the high-grade and bulk-tonnage ores are a consequence of the same processes, and general models of epithermal systems can be useful in the search for new precious-metal resources. A detailed study of deposits at Round Mountain, Nevada; Balei, Russia; Creede, Colorado; Guanajuato, Mexico; and Chanarcillo, Chile, indicates that the hydrodynamics of the fluid systems as determined by fracture geometries, the permeability, and composition of the host rocks are the key factors in the creation of both high-grade and bulk-tonnage epithermal deposits. End-member models that explain the range of observed deposit characteristics are: (1) the hot-springs deposition model; (2) the stacked-cell convection model (where mineral deposition occurs laterally along the interface of two partially separated fluid reservoirs); and, (3) the closed-cell convection model (where deposition occurs in vertical zones due to the relatively unimpeded vertical flow of hydrothermal fluids). Boiling and fluid mixing appear to be agents of precious-metal deposition with the self-sealing of the hydrothermal system being an important adjunct to boiling. Imaginative application of model concepts in exploration has led and can lead to the discovery of new high-grade and/or bulk-tonnage precious-metal deposits.

Jan 1, 1982

By Robert Hunt

(New York Meeting, February, 1913.) I HAVE frequently stated that while the chemical composition of steel is important, yet even greater importance is connected with the mechanical and heat treatment of the metal. During the past year I encountered such a positive example of that fact that I deem it worth putting upon record. A prominent railway system divided an order for open-hearth steel rails between two steel works, both of which are under the control of the one corporation; giving to one about 18,000 tons, and to the other 7,500 tons of the same section and to be made under the same specifications. The rolling results obtained in the two mills varied so widely that a study of the figures is intensely interesting and serves to illustrate the advantages obtained by careful ingot casting, and, quite as pertinently, the possible benefits of careful subsequent heating and rolling with moderate reductions in the rolling process. The smaller order was rolled complete in four installments during the same months that the larger order was being made in six separate installments; but, to permit of exact comparisons, the totals of the four installments (completing the order with the mill which I will call A) are given with the totals of the first four installments of the larger order, made by the mill designated as B. These rolling results are:

Jan 5, 1913

Some of the major factors affecting ore reserve estimation in gold mines are discussed together with their impact on computational methods.The major priority in ore reserve estimation is to get sampling and geological problems resolved. Poor basic information cannot be remedied by mathematical methods.Generally the more complex a deposit becomes the greater the need for subjective assessment and the less applicable are more complex ore reserve methodologies.

Jan 1, 1984

By Nicola Baldo, Marco Pasetto

"The paper presents the results of a laboratory study, conducted at the Experimental Road Laboratory of the University of Padova, in order to verify the possibility to use different types of electric arc furnace (EAF) steel slags – in substitution of the natural aggregates – in the composition of both dense graded and porous asphalt mixes for flexible road pavements. The research has been articulated in a preliminary study of the chemical, physical, and mechanical properties of the EAF steel slags, and in the following mix design and performance characterization of the bituminous concretes, through stiffness modulus tests at various temperatures and permanent deformation (creep) tests. All the mixtures with EAF slags have satisfied the requisites for acceptance standardized for the road sector, thus resulting as suitable for use in the construction of infrastructures, moreover presenting higher mechanical characteristics than those of the corresponding asphalts with full natural aggregate. IntroductionSteel is produced industrially employing two main technologies: the integral cycle, which starts from mineral iron, and the electric cycle, which uses scrap metal. A consistent amount of the steel produced in Italy (approx. 55%) comes from Electric Arc Furnaces (EAF), which every year, alongside the steel, produce approximately 2 million tons of slag. The recycling of this waste product to produce new high-quality raw materials would reduce both the exploitation of limited natural resources and the amounts of refuse. In the European Union, 60% of slag from EAF is still today disposed of in dumps. The extremely diverse origins of scrap metal (waste from mechanical manufacturing, industrial and civil demolition, car bodywork, etc.) means that the by-products generated by the smelting, slags and ashes, contain different elements, in varying composition, also depending on the type of steel to be produced and the consequent adding of binding and melting elements during the production process. For this reason, iron and steel industry electric furnace slag - unlike the blast furnace dross utilised in cement works, which has a more uniform composition as it comes from a more standardised cycle – has been viewed in the past with some diffidence and so, at least in Italy, the possibilities of its re-use have never been fully developed."

Jan 1, 2008

By G C. Snedden

Tandem row stator arrangements are common in the last stage of multirow, gas turbine compressors. Tandem row stators, or stator and de-swirler vane combinations are used to relieve the loading on the stator but ensure axial flow leaving the compressor. In this paper a standard 40” (1016 mm) ventilation fan in the Air Blow Fan’s range is modified to utilise the plate support struts on the barrel to relieve the aerodynamic loading on the aerofoil stator. Performance maps for both versions of the fan were generated using computational fluid dynamics and are compared across a wide range of rotor setting angles showing a clear advantage of approximately 2 per cent in efficiency for the tandem blade design. In addition, the area of high efficiency that represents the practically usable area of the map extends over a greater area in terms of flow rate and total pressure rise.

Oct 12, 2022

By René Bustamante

The subject of this paper is a comparative evaluation of different copper smelting gas cooling techniques, using "productivity and quality" criteria. The first section presents a brief description of the operation of the radiant and the evaporative cooling systems, focusing on the differences between each other, in particular regarding. a) mass and energy balances; b) gas flow, temperature and composition; c) dust concentration and recovery. This section includes a brief discussion of the "client-server chain", i.e. the links between the cooling equipment and the down-and up-stream operations. More in particular, the up-stream server relationship impacts on the operating stability of the furnace, and in turn on furnace down-time and Cu production losses; and the down-stream client relationship affects the operation of the electrostatic precipitators, in terms of workload and cost of handling larger quantities of dust of a given dust size The second section deals with the development of indexes to measure and compare value added through the "utilization, productivity and quality" that can be expected of both cooling methods at the physical and economic levels, and the impact on the overall smelter productivity and the final cost composition of copper. The final section presents the results and includes a discussion of the comparative advantages and disadvantages of both cooling systems.

Jan 1, 1999

By W. R. Webster

SINCE the delivery of our paper on Some Comparative Properties of Tough-pitch and Phosphorized Copper,1 a new brand known as "oxygen-free high-conductivity copper" (brand OFHC) has become available to consumers. It was thought desirable to make a comparison between the properties of this material and those of the materials covered by our original paper and its discussion. FIG. 1.-CHARACTERISTIC ANNEALING CURVES OF VARIOUS TYPES OF COPPER. Preliminary tests had indicated some notable differences. A billet of oxygen-free high-conductivity copper was taken from regular production. A chemical analysis of the particular billet was not made, but the producer of the material has given as typical the analysis shown in Table 1. The

Jan 1, 1933

By Takagi T, Seetharam R, Sie SH, Naito K

Tin-polymetallic vein type deposits are one of the major source of metal producers in the Circum Pacific Belt. This type of deposit is of great importance for the modem electronics and medical industries because of their high content of rare metals (especially indium and bismuth). We have studied two representatives, Tosham of India (Cu-In-Bi-Sn-W-Ag-Au), and Mount Pleasant of Canada (Zn-Cu-In-Bi-Sn-W), using proton and electron microprobes in order to delineate the distribution of medical/high-tech rare metals. The electron microprobe study showed that major indium carrier in such type of deposit are roquesite (CulnSZ), sphalerite, stannite and a Cu-Zn-Fe-In-Sn-S mineral; and that indium is incorporated in sulfides by coupled substitution like Cu + In = 2(Zn + Fe). The proton microprobe showed that indium at trace levels is also present in chalcopyrite and pyrite. In addition, zinc, copper, arsenic, antimony, selenium, tin, and bismuth are common in chalcopyrite and pyrite. Arsenopyrite contains nickel, copper, zinc, silver, tin, antimony and bismuth. In chalcopyrite and pyrite, zinc, arsenic, indium, bismuth and lead are higher in Mount Pleasant ore, but silver is higher at Tosham. Also thallium and gold were found only in Tosham pyrite. The Tosham deposit is genetically related to S-type magma, while the Mount Pleasant deposit is related to A-type granite. Tosham ore contains zinc-bearing biotites that coexist with chalcopyrite in ore bodies but Mount Pleasant ore lacks such biotite. We propose that the difference in elemental abundance between the two deposits are caused by the different character of source magma and different mineral associations of the ore body.

Jan 1, 1995

By S H. Sie, R Seetharam, K Naito, T Takagi

Tin-polymetallic vein type deposits are one of the major source of metal producers in the Circum Pacific Belt. This type of deposit is of great importance for the modem electronics and medical industries because of their high content of rare metals (especially indium and bismuth). We have studied two representatives, Tosham of India (Cu-In-Bi-Sn-W-Ag-Au), and Mount Pleasant of Canada (Zn-Cu-In-Bi-Sn-W), using proton and electron microprobes in order to delineate the distribution of medicallhigh-tech rare metals. The electron microprobe study showed that major indium carrier in such type of deposit are roquesite (CulnS2), sphalerite, stannite and a Cu-Zn-Fe-In-Sn-S mineral; and that indium is incorporated in sulfides by coupled substitution like Cu + In = 2(Zn + Fe). The proton microprobe showed that indium at trace levels is also present in chalcopyrite and pyrite. In addition, zinc, copper, arsenic, antimony, selenium, tin, and bismuth are common in chalcopyrite and pyrite. Arsenopyrite contains nickel, copper, zinc, silver, tin, antimony and bismuth. In chalcopyrite and pyrite, zinc, arsenic, indium, bismuth and lead are higher in Mount Pleasant ore, but silver is higher at Tosham. Also thallium and gold were found only in Tosham pyrite. The Tosham deposit is genetically related to S-type magma, while the Mount Pleasant deposit is related to A-type granite. Tosham ore contains zinc-bearing biotites that coexist with chalcopyrite in ore bodies but Mount Pleasant ore lacks such biotite. We propose that the difference in elemental abundance between the two deposits are caused by the different character of source magma and different mineral associations of the ore body.

Jan 1, 1995

By M. Gouet-Kaplan, J. A. Finch, S. Gélinas

Methylisobutyl carbinol (MIBC) and methoxy polypropylene glycol (Dowfroth 250) bubble thin films were characterized by composition and thickness determinations, using FT-IR spectroscopy and UV-Visible spectrophotometry, respectively. The infrared investigation indicates that the role of frother molecules in creating bubble thin films is based on their effectiveness in inducing H-bonding reorganization of the surrounding free water molecules into a coherent network. From UV-Visible interference patterns, it is found that MIBC forms films with a measured critical end thickness of less than 160 nm, compared to 612 ± 30 nm for Dowfroth 250. The observed values of the free water layer thickness are comparable at 5.65 ± 0.28 µm for MIBC and 6.75 ± 0.34 µm for Dowfroth 250. A higher stability of an MIBC bubble over a Dowfroth 250 bubble is related to the different polarization and orientation of the molecules sustaining the boundary surface water network. The findings are used to explain the different action and associated froth characteristics of the two common industrial frothing agents.

Jan 1, 2006

By John Devine

DURING the past few years the Bureau of Mines has been studying hydrogen-sulfide corrosion in the petroleum and natural-gas industries. Early work was confined to investigating the various practical, or operat-ing, factors that control the corrosion reaction when ordinary mild steel is being attacked. In that work it was shown that, if the optimum operating conditions1 are obtainable, . gas containing hydrogen sulfide can be handled at ordinary temperatures without serious corrosion resulting. However, frequently "sour" gas must be handled under other than optimum operating conditions, and combating corrosion then becomes a problem to be considered more during the construction of a system than during its subsequent operation. That is, where economi-cally practicable in such cases the designer will seek to substitute for mild steel other steels or ferrous metals more resistant to corrosion by hydro-gen sulfide. The comparative resistance of various commercial steels and alloy steels to corrosion by hydrogen sulfide at elevated temperatures has been reported systematically by previous investigators,2 but similar information for corrosion at ordinary temperatures is available only from scattered sources, representing different methods of testing. As the value of comparative corrosion tests depends largely upon the use of a

Jan 1, 1934

By T QUINLAN

A resource estimate uses data obtained by sampling an orebody. An example is described in which a random drilling pattern did not provide a representative set of assays, and the estimated resource was significantly less than the mine production. It is believed that a better estimate would have been made if the exploration holes had been drilled on a regular grid.

Jan 1, 1992

By D. B. Grove

THE heavy media separation process plays an outstanding role in the concentration of 4000 tons of zinc ore per day at the Mascot mill of the American Zinc Co. of Tennessee. Of the total tonnage, 72 pct is treated in the heavy media separation plant to reject 56 pct of the ore as a coarse tailing, which has a ready market. Concentrates from this separation are beneficiated further by jigging and flotation. Approximately 25 pct of the total zinc concentrate production is made in the jig mill. Jig tailings are ground and pumped to the flotation circuit where the balance of the production is made. Fig. 1 shows a generalized flowsheet of the mill.

Jan 8, 1951