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By J. M. Tannenbaum

A depth-sensing micro-indentation technique is developed for evaluating mechanical properties of materials at elevated temperatures (to 1200°C). System description and design considerations of the test apparatus are described. Based on Hertzian spherical indentation approach, the micro-indentation test apparatus is capable of determining Young?s modulus and creep strength of test materials with flat, tubular, or curved architectures from room to 1200°C under either air or controlled gaseous environments. Calibration tests were conducted on a H13 Tool Steel coupon from 22°C to 500°C and single crystal Haynes 230 alloy at 1000°C with excellent agreement to the literature values. Indentation creep tests of Haynes 230 alloy were carried out at 1200°C with preliminary results showing good correlation to creep exponents. Further system refinements will be investigated, and additional testing will be conducted.

Jan 1, 2010

By C. A. Fleming, R. G. Williamson

Process development for Eskay Creek began in early 1990 at Lakefield Research, and was initially focused on producing a high-grade/high-recovery concentrate for sale. Owing to the significant base metal sulphide (Cu, Zn, Pb) content of the ore, such a product would have made an attractive feed to a copper smelter, while a gravity and/or flotation flowsheet would have circumvented many of the environmental permitting problems that were anticipated. In the event, it was found that neither gravity nor flotation (nor even a combination of the two) was able to produce a discardable tailing and, in late 1990, attention shifted to the development of a hydrometallurgical flowsheet.

Jan 1, 1995

By J. R. Klaehn, M. Shi, T. E. Lister, L. A. Diaz, J. S. McNally

Since 2019, approximately two dozen international battery recycling companies have been operating at the commercial or pilot scale [1]. However, current process capacity does not exceed 100,000 tons of end-of-life (EOL) lithium-ion batteries (LIB) per year, and the current recycling rate is only about 5% in North America [2-3]. Recycling metals from EOL LIBs is not only essential to waste minimization and environmental stewardship, but also a source of critical materials, which can contribute towards supply chain stabilization. LIB recycling can be roughly divided into three categories: direct recycling, pyrometallurgy, and hydrometallurgy. Direct recycling seeks to retain as much of the manufactured effort with minimum chemical processing [4]. The evolution of battery designs and chemical compositions are challenges to this approach [5-6]. Pyrometallurgical processes are robust and flexible allowing a broad spectrum of batteries with minimum pre-processing requirements. Some of the matrix issues are solved through combustion of some constituents. Smelting is strongly tied to fossil energy and air emissions are a concern. In addition, pyrometallurgical processes are not stand alone, as hydrometallurgical refining normally required to separate and recover the metals of interest (Co, Ni, and Cu) from the produced alloy and Li from the slag [7]. Hydrometallurgical processes can be highly selective and efficient in recovering high purity materials [8]. In general, hydrometallurgical processes are considered cleaner and less costly than high temperature processes [4,9-10]. Extensive chemical consumption and waste generation significantly increase the operating costs and overall environmental impact of the hydrometallurgical processes [11]. Leaching of metals from LIBs is dominated by the mixture of sulfuric acid (1 to 4 M H2SO4) and hydrogen peroxide (1 to 15 wt.% H2O2) [10]. Although organic acids have been tested as lower environmental impact alternatives, the reported pulp density operations are low < 60 g/L [10-11]. For the H2SO4/H2O2 leachates, high leaching efficiencies >90% are reported for Co, Ni, Mn, and Li from cathode materials at temperatures over 40 ⁰C and pulp densities between 30 to 200 g/L [9-10]. H2O2 acts as reducing agent to convert Co+3 and Mn+4 into their soluble forms, Co+2 and Mn+2 [12]. Despite the claims of H2O2 being a clean reducing agent [13], production of H2O2 has significant environmental impacts as determined by life-cycle analyses [13-14]. Moreover, the costs and risks associated with H2O2 transportation and storage cannot be ignored [15].

Mar 2, 2022

By Masaki Imamura

A novel hydrometallurgical process for copper concentrate treatment has been developed by Niihama Research Laboratories of Sumitomo Metal Mining Co., Ltd. The process has numerous advantages with respect to the operational and environmental aspects. For example, copper is leached effectively from chalcopyrite concentrates by chlorine gas under atmospheric pressure. The copper in the leach solution is then separated from iron and silver by solvent extraction and undergoes electrowinning for its recovery as a highly pure copper metal; this does not require any further purification. Moreover, iron metal can be produced from the purified raffinate by electrowinning without generating a large volume of goethite or hematite, which are solid wastes generated due to iron rejection in common hydrometallurgical processes. This process can also realize the efficient recovery of precious metals. The results of batch testing and continuous-operation testing are presented in this paper.

Jan 1, 2006

By Edward F. Oxford

The area described in this paper lies along the inner margin of the Coastal&apos; Plain in Twiggs County, near the exact center of the State of Georgia. Twiggs is one of four counties which produces approximately 75 per cent of the nationals output of kaolin used in the paper trade. In this vicinity the land surface is characterized by coastal plain hills with elevations ranging from about 250 feet, above mean sea level in the flood plain of: the Ocmulgee River to about 550 feet above mean sea level on the hill tops. Surface drainage in the area is southwestward to the Ocmulgee River, the tributaries of which have dissected the land surface exposing thick sections of the upper parts of the hills of Eocene (Ocala Limestone and Barnwell formation) limestone, sand, marl and clay, and in the lower parts of the hills Cretaceous (Tuscaloosa Formation) kaolin, kaolinitic clay, sandy clay, sand and, gravel. The contact between these two principal groups of geologic units is rather easil distinguished as the top of the kaolinitic beds. It is described in detail and mapped in published geologic reports for the area (LaMoreaux, 1946).

Jan 1, 1968

By Mohammad Ranjbar, Zahra Manafi, FAZAELIPOOR MOHAMMAD HASSAN, HAMGHAVANDI MOHAMMAD RANJBAR, Mahin Schaffie

Bioleaching has an increasingly important place among available mining technologies as biological processes have emerged as alternatives for metal recovery, especially for metals like gold and copper. An important disadvantage of bioleaching is the slow reaction rates, with microbial attack times often lasting weeks. Therefore, applicable research is required to improve these rates. From previous research, copper bioleaching has been divided into two specific regimes: (1) surface reaction controlling step and (2) mix of surface reaction and diffusion controlling steps. The presented model, which includes the effects of both these regimes, predicted the results of copper bioleaching recovery with good accuracy.

By Mohammad Ranjbar Hamghavandi, Mohammad Ranjbar, Zahra Manafi, Mohammad Hassan Fazaelipoor, Mahin Schaffie

The present study introduces a new approach to understand the copper dissolution rate and to find an adapted mathematical statement for particle shrinkage rate in a batch bioleaching system. Four size classes of a chalcopyrite concentrate, namely [D1 : (−54 + 44)μm, D2 : (−44 + 38)μm, D3 : (−38 + 25)μm and D4 : (−25)μm], were used in the batch bioleaching tests by applying a mixed culture of moderately thermophilic microorganisms. The pulp density and temperature were 8 (%w/v) and 50 °C, respectively. Findings delineated that the bioleaching time can be divided into two specific time intervals: first, the surface reactions were the prevailing controlling step; second, the prevailing mechanism was diffusion through the product layer, whereas the overall rate of the process may be related to both through a Q factor using a mixed model. A mathematical model was developed based on particle size distribution (PSD) and a kinetic model. Experimental validation of the mixed model was accomplished by the representative sample with d80 = 54 microns. Results showed that the PSD of the specific sample was in good agreement with Rosin–Rammler function. Besides, the simulation result of the conversion fraction had the best conformity with the experimental data (with a maximum error of approximately 7%). This paper should be considered as an initial part of a larger, global model for chalcopyrite concentrate bioleaching.

By Zhongxue Li, Cuiping Li, Xiaoyun Hu, Yiqing Zhao, Huaying Wang

"Under the auspices of World Federation of Engineering Organizations’ Committee on Engineering and the Environment (WFEO-CEE) and Society for Mining, Metallurgy and Exploration (SME) Task Force on Sustainability and Mining (TFSM), and aimed at helping raise global understanding on and promote capacity building of risk management, this paper presents a framework and prototype of toolbox or knowledge warehouse for facilitating the application of risk analysis, mitigation and management techniques (RAMT) in the mining and minerals sector. The conception, design and implementation of the intended system of knowledge warehouse of risk analysis, mitigation and management techniques (KWoRAMT) are outlined. The system architecture of KWoRAMT is based on a browser/server (B/S) structured platform with web oriented interfaces and composed of data base, knowledge warehouse, searching mechanisms, and risk assessment methodologies. The knowledge sources for KWoRAMT will come from the TFSM expertise and Internet, including laws and regulations, codes of practice, standards, guidelines and best practices. The functions and outcomes of KWoRAMT consist of guided navigations with web links, categorized risk tools, annotated best practices with cases, and integrated risk approaches and solutions based on typical risk methods. Risk categories include those impacting on mine safety, mine occupational health, and mine community environment throughout the whole of mine life cycle from exploration, construction, and exploitation and processing to post-mining closure. Mining associated hazards will be identified and linked by vulnerability onto risk receptors through pathways. Risk management techniques for assessing impacts and consequences of mining induced hazards will be categorized with their pros and cons or strengths and weaknesses. Best practices and significant cases including experiences and lessons with problems, solutions, and recommendations on how solutions would be derived will be illustrated. Integrated risk approaches based upon typical methods will be developed for alternatives and actions."

Jan 1, 2014

By R. Vogt, H. C. Mult, F. L. Wilke

INTRODUCTION At present, the capability of production planning software based on Linear Programming (LP) is still limited to the optimization of the single LP-run. This is due to the LP-model itself which cannot consider the interdependencies between individual LP- runs. With regard to planning of selective mining this limited way of optimization frequently leads to situations, where the remaining and accessible ore blocks do no longer allow to produce ROM-ore in the qualitative composition required by the ore processing plant. However, many of the aspects taken into consideration when setting up production plans built from mutually dependent LP-runs cannot be modelled in a system of linear equations. They are thus unsuited for treatment with LP and have to be taken care of by the planning engineer without any assistance by the system. The KBS currently under development is intended to assist the planning engineer in designing a production plan under special consideration of the combination of consecutive LP-runs and blending beds. It is not necessarily intended to find the optimum solution within a given planning situation which is, anyway, hard to determine due to the multitude of influences. The objective is rather to work out a good and - from the practical point of view - feasible production plan. The new aspect with respect to mine planning is the integration of expert knowledge and experiences via the KBS into the planning process in order to support the planning engineer. The planning system is being developed in close cooperation with an iron-ore open pit mine. COMPONENTS OF THE PLANNING SYSTEM The software is being developed on a workstation under UNIX and comprises the components LP, CAD-module and the KBS. The applied multi-goal LP-algorithm is an in-house development of the Department of Mining Engineering at Technical University Berlin. It was already successfully implemented within other mine planning programmes and was only slightly adapted to the specific needs of the present system. Within individual LP- runs it finds the optimum qualitative composition of ore production in the sense of the selected optimizing criterion and under the given restrictions: i.e. it determines tonnages to be mined from blocks in order to optimally meet the requirements of the ore pro- cessing plant. A CAD-module based on the commercial SURPAC package in combination with a simulation device is used to graphically depict the block model and progress of mining. Both LP-algorithm and CAD-package are integrated in the KBS. It has been decided to use the shell NEXPERT OBJECT as it is a hybrid system which supports both rule-based and object-oriented knowledge representation. MINE-MODEL AND LP-MODEL KBS have to be tailor-made for specific planning problems. Therefore, it had to be decided which specifications of the iron-ore mine should be represented in the model. As the limited possibilities of a university institute do not allow to develop a KBS for mine planning which is ready to use in industry, it was decided to concentrate on those characteristics that can be regarded as typical for iron-ore surface mines and that seemed to be suited for treatment with knowledge-based techniques. The following chapter summarizes the most important features of the mine model. The description of the requirements to the mine&apos;s sales products is followed by an outline of the applied LP-model. Mine model • The model of the mine as it is used for planning consists of • the block model of the deposit, • the mobile equipment, • stockpiles and blending bed and • the requirements to the sales products. The deposit is described by a block model which contains data on the chemical composition, LOI, grain size and tonnages. Grain size was included as it is important for the two sales products of the mine. Furthermore, it is known whichs blocks require and which don&apos;t require blasting; this is relevant to the assignment of loading equipment to individual blocks. The blocks are devided in three categories: • ore, which will directly be taken to the blending bed; • waste, which will be put on the waste dump; and • blocks which will be either transported to the blending bed, to stockpiles or to the waste dump depending on the specific planning situation. This decision is made during planning. Neighboring blocks are combined in mining areas to which the loading equipment is individually assigned. Mobile equipment comprises shovels and wheel-loaders as well as trucks. The characteristics of the loading equipment are important for their ability to load different blocks and for the permissible degree of their re-positioning etc. The mine disposes of a blending bed for homogenization of the production, of a waste dump, and of several stockpiles with different ore qualities. The requirement to make only limited use of the stockpiles for economic reasons is included in the KBS. According to long term planning two commercial products have to be produced, which differ both in grain size and qualitative composition (TABLE 1). Their mass-proportions in the blending bed have to be within a fixed range. Not considered in long term planning is the occasional need for lump ore, which occurs at very short notice and has to be produced in a "campaign-like" manner. This requires the total re-arrangement of all plans for on- coming blending beds and would therefore be ideally suited for

Jan 1, 1996

By L. Mahony

This paper describes the design, construction and commissioning testing program for a laboratory facility at the School of Mining Engineering, UNSW, Australia, aimed at evaluating reinforcement tendon performance when subjected to shear loading. The project has been financially supported through the coal industry ACARP research initiative. The single failure plane design adopted in the test rig has been successful in allowing shear loading to be directly applied to fully installed (and where relevant, pre-tensioned) rock bolts. Initial results are extremely encouraging, and illustrate a significant axial component of load development as shearing takes place - particular in lower strength, softer material types. The paper also outlines future plans for use of this facility.

Jan 1, 2005

By D Morgan, D Sato, B Lumsden, S Senanayake

Laboratory flotation tests on fresh cyclone overflow samples are a useful tool to troubleshoot and indeed to improve plant performance; however, reproducibility between laboratory flotation test and plant performance is important for interpretation of the laboratory tests and hence their usefulness. Chemical reproducibility can be achieved with the addition of the required reagents; however, reproducing the physics of forces and energy in a 5 L cell compared to a 50 000 L plant cell or a 500 000 L plant cell is not generally studied or discussed. For some tests such as collector evaluation the physics of the flotation process may not be critical, but for some evaluations in the laboratory, it can be important.All flotation plants suffer from losses of valuable &lt;20 µm mineral. Selective mineral aggregation has long been recommended to improve the poor flotation recovery of &lt;20 µm sulfide minerals; however, successfully testing any type of selective sulfide mineral aggregation’s effect on flotation recovery in the laboratory on practical plant samples requires reproducing plant cell physics. The energy input per litre and the forces in a laboratory cell are vastly different to a plant cell. Reproducibility between laboratory and plant tests requires that these differences be minimised. The physics of the laboratory flotation cell is particularly important when fine mineral aggregation tests are carried out.This paper outlines a modified laboratory aggregation and flotation method that closely reproduces plant performance in a laboratory test.CITATION:Sato, D, Lumsden, B, Senanayake, S and Morgan, D, 2014. Development of a laboratory flotation method to test plant mineral aggregation, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 173–178 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By C. Massola, E. E. M. N. de Guzmán, M. G. Bergermana

The abrasiveness of a mineral or rock is an extremely important topic in the mining industry and is generally measured by the Bond abrasion index (AI). However, to determine such an index by the Bond test requires 1,600 g of sample with particle sizes ranging from ½” to ¾”, which are not available in certain situations, such as ore prospecting, drilling, and geometallurgical studies. In order to investigate the abrasiveness of smaller-sized sample materials, a modified LCPC test was developed, which allows testing fine materials (i.e., 1.0 mm or smaller) to predict wear in ore processing circuits and anticipate possible failures resulting from changes in abrasive characteristics of the ore being processed. The results for 16 different materials indicated a good correlation with the AI and the modified LCPC, resulting in a reliable alternative for the AI. Keywords: Bond Abrasion Index (AI), LCPC, abrasiveness

Jan 1, 2020

By D. B. Mazzinghy, L. C. de R. Machado, H. Delboni, M. G. Bergerman

"The use of vertical stirred mills in the mining industry has increased remarkably over the past few decades, as a result of growing requirement for finer ore grinding. This equipment delivers higher energy efficiency in fine grinding operations when compared to conventional tubular mills. Methods for designing vertical stirred mills involve operational experience, pilot plants and bench tests. An important issue is that these tests require, at a laboratory scale, at least 10–20 kg of material, depending on its density, which is not available in many cases, particularly in the early stages of greenfield projects. For the regrind of flotation concentrates, several bench scale flotation cycles are required to generate such a sample. This paper describes the development of a laboratory jar mill test using a 6”x8” jar – smaller than that commonly used – based on the overall specific energy method, which requires significantly less mass compared with existing tests. The proposed test has proven to be more practical than tests normally used, requiring about a quarter of the mass, and also shows good adherence to industrial results for the studied iron ore processing plant. INTRODUCTION A significant demand for finer grinding has been noticed over the past few decades in several mining projects to achieve the mineral liberation required for the concentration of valuable minerals. However, the finer the product size, the greater the grinding energy consumption, resulting in an overall increase in operating costs, which may reach or even exceed 50% of the mineral processing cost (VIEIRA, PERES, 2013; DANIEL, LEWIS-GREY, 2011). Comminution technology can have a major impact on subsequent ore concentration stages (DANIEL, LEWIS-GREY, 2011; MARSDEN, 2009; NAPIER-MUNN, 2012; PEASE et al., 2010), which further strengthens the importance of proper technology and equipment selection. Adequate grinding circuit selection and design is thus a key aspect associated with mining projects."

Jan 1, 2018

By Trevits MA

The United States Steel Corp. in cooperation with the United States Government is conducting a large-scale methane drainage field demonstration using stimulated vertical boreholes drilled in advance of mining. A grid pattern of 23 boreholes, isolating approximately 1.5 km2 of coalbed area, has been drilled to the lower bench of the Mary Lee coalbed, Jefferson County, Alabama. Upon completion of drilling operations, various hydraulic stimulation treatments utilizing nitrogen-generated foam, water, and gelled fluid were performed to enhance the rate of methane gas removal. Production from the grid pattern began in September 1977 and continued as the last borehole was placed on production during October 1980. To date, in excess of 33,800,000 m3 of methane gas has been drained as a result of this effort. Underground mining operations were approximately 3.2 km from the grid pattern when production began and have currently progressed to within 1.6 km. Underground interception of the grid is expected in 1986.

Jan 1, 1982

By K. Soldenhoff

Mantra Resources Ltd is developing the Mkuju River project is southern Tanzania. The uranium deposit, hosted in ?Karoo? sandstone, is surface outcropping with the majority of uranium mineralisation occurring in the finer clay component of the ore. A flowsheet, consisting of ore beneficiation, acid leaching, RIP uranium recovery and direct precipitation of the uranium product, was developed and successfully demonstrated in continuous mini-plant operations at ANSTO. The selected flowsheet overcomes the difficult slurry rheology, arising from the clay component of the ore, by eliminating the need for a CCD plant. The RIP process was found to contribute to a high uranium extraction, by eliminating ?preg-robbing?, at a relatively low acid addition in leach, with the potential to eliminate ferric ion and oxidant additions.

Aug 1, 2010

By T. L. Carstensen

The Miami In-situ mine of BHP Copper is located in Globe-Miami, Arizona. The mine leaches mineralized leach capping over a supergene enriched sulfide deposit, and has produced over 500 million lbs of copper during the last 50 years. The Miami unit has identified several opportunities to enhance and expand in-situ production. A computer block model consisting of strict geologic controls, mineralogy, and metallurgical data was developed to assist in the determination of the leachable copper resource. An understanding of the accessibility and solubility of the resource to leaching solutions and the integration of hydrogeologic and hydrometallurgical information was necessary for completion of this project.

Jan 1, 1997

The minerals industry contributes to the economic growth, prosperity and quality of life of nations, particularly in areas where there might be limited opportunities for employment in other sectors. However, notwithstanding their economic importance, the minerals extraction and processing industries are considered to have significant impacts on the surrounding environment. In recent years many mines have implemented modern monitoring technology and modelling of the monitored environmental parameters to provide scientifically proven indicators about the state of the environment. The flexibility required by the minerals industry to respond dynamically to a changing natural, social and economic environment has become a major consideration. Whilst the notion of continuous improvement is embodied within most environmental management systems, what is now required is a structured audit trail which tracks the flow of resources through the production process to the ultimate environmental impact associated with their consumption, transformation and disposal. Imperial College is coordinating an EC funded project, which is developing a methodology to minimise the ?full life-cycle? impact of metalliferous mining projects, adopting an integrated approach to production and process design, and the costs involved. In order to develop a life cycle assessment (LCA) system that will incorporate different types of data related to the minerals extraction operations, a data inventory was designed and coded in an object-relational database model. The calculation procedures accounting for the input/output balance of the alternative scenarios for mining production, processing, waste disposal, monitoring, and their financial implications are being programmed into a software system. This paper presents the rational and innovative aspects of this work. The methodology developed for the life cycle database is illustrated for the mining production and gaseous emissions components of the system.

Jan 1, 2003

By W. M. Hart, Q. H. Shen, J. S. Chen, S. S. Peng

The automatic data-acquisition systems that are now available can continuously monitor and record changes in leg pressure and changes in advancing ram stroke in every shield. These systems can record shearer position at any moment during a mining operation. The data obtained can be used to improve production and maintenance management and can be used to provide better roof control at the longwall face. Research now being conducted jointly by West Virginia University and Cyprus Amax Coal Co. is aimed at developing a longwall-management system (LMS) for mine operators. The LMS software package, which works in the Microsoft Windows NT environment, performs data interpretation and analysis, production management, maintenance management and ground-control management for longwall mining.

Jan 1, 1997

By W. M. Hart

The current Automatic Data Acquisition system developed by some support manufacturers makes it possible to continuously monitor and record changes in leg pressure and advancing ram stroke in every shield, and shearer position at any moment during the mining operation. In order to effectively use the massive data obtained from this system for improving production and maintenance managements as well as providing better roof control at a longwall face, the research currently conducted jointly by West Virginia University and Cyprus-Amax Coal Co. attempts to develop a Longwall Management System for mine operators. The LMS software package runs on a MS Windows NT environment and consists of four sub-systems: (1) Data Interpretation and Analysis; (2) Production Management; (3) Maintenance Management; and (4) Ground Control. This paper presents the details of each sub-system.

Jan 1, 1995

By Farzaneh Abedini, Narain Hariharan, Lucas C. McFarlane, Nikolas A. Romaniuk, Tiffany Thayne

The use of dewatered mine tailings as backfill material (commonly referred to as ‘paste’ backfill), is the most practiced form of backfill in Canada providing significant environmental benefits by reducing the size of external tailings facilities and improved economics through enhanced resource recovery. Paste backfill operations reuse filtered mine tailings with a cementitious binder and water to create a slurry that is hydraulically transported to refill underground stopes, later forming a structural network of cemented tailings in the mine stopes. Unlike typical structural applications that utilize General Use (GU) Portland cement; modern paste backfill operations maximize strength performance by blending Portland cement with ground granulated blast furnace slag (GGBFS) or other supplementary cementitious materials (SCMs). GGBFS and other SCMs offer key performance benefits and carbon reductions; however, the availability of these SCMs is rapidly dwindling in today’s carbon-constrained economy. This paper examines the development of an alternative binder system that provides similar performance and carbon reduction to that of GGBFS for mine backfill operations. The binder utilizes the chemical reaction between a reactive source of aluminosilicates and available calcium from calcium oxide or calcium hydroxide to replace between 50 to 100% of GGBFS. The performance of the binder is examined with insights into the hydration mechanisms that generate mechanical strength in the cemented paste network. Paste backfill slurries require precise engineering to create a material that maintains flowability during pipeline transport and generates enough strength to meet operational targets once placed in the stopes. Engineering of such slurries requires large amounts of water to be added to the binder-tailings matrix, far exceeding the typical water to binder ratios used in concrete mix designs. This characteristic of paste backfill warrants great emphasis on understanding the hydration mechanisms of the binder used in the paste backfill system. GU cement is typically composed of 50-70% tricalcium silicate and 15-30% dicalcium silicate.  The hydration mechanisms of these compounds consume 4 to 6 units of water to mineralize into calcium silicate hydrate cemented phases that result in compressive strength development. Cementitious aluminate and aluminosilicate phases make up 5-20% of GU cement and aid in secondary performance characteristics such as set time. Certain calcium aluminate hydrate phases such as monocarboaluminate and ettringite mineralize 10 to 32 units of water into their crystalline structure. Hydration products such as ettringite are traditionally avoided in construction applications due to their propensity for volumetric expansion after cement setting, leading to micro-fissures and subsequent strength degradation (known as ‘sulfate attack’). This paper proposes that such hydration products benefit the strength development in paste backfill slurries with the aforementioned characteristics due to their greater potential to mineralize free water. The newly developed calcium aluminosilicate binder is designed to replace 50-100% GGBFS or other SCMs used in paste backfill systems and meet operational strength requirements by providing exceptional hydration characteristics through cementitious reactions. Additionally, the aluminosilicates used have a minimal carbon footprint and a secure supply outlook, thereby allowing mine operators access to a low-carbon binder option throughout the mine’s lifespan.

May 4, 2025