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By M. V. K. Reddy

A differential flotation process for recovery of molybdenite from chalcopyrite concentrates produced at Rakha Copper Concentrator, Bihar, India has been developed. The flowsheet is simple, and relatively inexpensive and yields a concentrate assaying not less than 45% Mo at a recovery of minimum 65%, starting from chalcopyrite concentrate assaying 0.4% Mo. The consumption of the main depressant used, sodium sulphide is not more than 25 kg/t of copper concentrate processed without steaming; and with steaming the consumption was brought dorm to less than 12 kg/t of concentrate. Further reduction is possible by optimization of steaming parameters. Based on laboratory experimental results, further tests were conducted on concentrator site and process design parameters were established for design of commercial plant.

Jan 1, 1982

By P. Huang

Chitosan was tested as a depressant in the differential flotation separation of chalcopyrite and galena. The micro-flotation results showed that chitosan selectively depressed chalcopyrite while galena was floated by potassium ethyl xanthate in acidic solutions. With the addition of 0.67 mg/L chitosan (CT) in the slurry of chalcopyrite-galena mixtures at pH 4, the recovery of galena was 95% while that of chalcopyrite was 30%, indicating that chitosan could potentially be used in differential Cu-Pb sulfide separation. Furthermore, the study of chitosan with either low (LCT) or high molecular weight (HCT) in the differential flotation indicated that better separation was achieved by the chitosan with lower molecular weight (LCT). ToF-SIMS was employed to study the distribution of CT on the surface of chalcopyrite-galena mixtures by ion mass spectra analysis and surface imaging, which showed that CT adsorbed heavily on chalcopyrite but barely adsorbed on galena. The positive ion ToF-SIMS spectra provided information on the surface composition of chalcopyrite-galena mixtures after CT treatment. It appears that the selective adsorption of CT on chalcopyrite was originated from the strong interaction between NH3+ and Cu. Keywords: differential flotation, micro-flotation

Sep 1, 2012

By Leon Banks

THE- Missouri-Kansas Zinc Corpn., operating in the Waco district, 15 miles northwest of Joplin, Mo., owns large tailing piles made during milling operations of the years 1918-28 by the Butte-Kansas, Acme, and Barnsdall mining companies, whose holdings have been purchased and consolidated under, the ownership of the Missouri-Kansas Zinc Corpn. These tailings had been considered too low in value to be worth retreating by the ordinary methods. C. Erb Wuensch, consulting engineer of the Missouri-Kansas Zinc Corpn., noted the difference in the type of tailing from upper-level and lower-level ore. The latter contained hard lime chats. He also found that mill losses had been due to particles of blende on the corners or sides of the chats and to the existence of soft, porous, cellular, lime chats containing varying amounts of blende. He conceived the idea that a quick grind in rolls or ball mills might change the type of the material so that jigging could make a clean tailing for discard and a partly concentrated product sufficient in blende content to justify the expense of fine grinding in ball mills to free the mineral entirely. A laboratory was equipped with the necessary machines and the writers were assigned the problem of developing a method of retreating the tailings.

Jan 1, 1929

By Milton E. Wadsworth, Edward M. Eyring

Better understanding of solid surfaces and their associated adsorption products is of both academic and practical value. The study of detergents and their behavior in cleaning surfaces is fundamentally related to the nature of the products adsorbed and their ability to compete for certain surfaces. Similarly in flotation, the nature of the adsorbate before and after adsorption is basic to clear understanding of the process. The recently developed pellet technique employing infrared spectroscopy provides a powerful tool for the study of solid surfaces. Absorption bands, which are infrared-active, may be observed for adsorbed products. Also any changes in the surface substrate that occur as a result of adsorption may be detected by means of differential spectra

May 1, 1956

By Steven E. Mischler, Jon C. Volkwein

A diesel particulate matter analyzer capable of direct, real-time measurement of engine exhaust particulate is necessary to effectively institute source control technology currently being used on diesel equipment and to ensure that the control measures are working. To investigate the potential of a differential pressure monitor to measure diesel particulate matter in undiluted exhaust, samples were collected from three different diesel engines-Kubota, Isuzu, and Deutz-running under 12 different RPM and load scenarios. These measurements were compared to elemental carbon concentrations in the sampled exhaust as determined by using the NIOSH 5040 analytical method. Elemental carbon is used as a surrogate measurement for diesel particulate matter. The results of the two data sets were then compared using a linear regression analysis. The coefficient of determination (or R2) was calculated to be 0.98, 0.94, and 0.74 for the Kubota, Deutz, and Isuzu engines, respectively. R2 values of this magnitude indicate that this method can be successful in estimating elemental carbon emissions in the engines tested. In addition, for replicate samples, the coefficient of variation ranged from 7.1% to 10.2% with an average of 8.5%. These data indicate that this method could prove useful to mechanics as they work to maintain engines and DPM control technologies.

By Carl Floe

THE possibility of separating the various constituents of mixed ores or metalliferous products by differentially producing their soluble sulfates has not received the consideration that it deserves. The production of the soluble sulfate may be accomplished by baking the ore with sulfuric acid or by treating it with gases containing oxides of sulfur. This paper is primarily concerned with the first method. The procedure used was to mix the material with a solution containing a definite weight of sulfuric acid, baking the mixture at various tempera-tures and then leaching out the soluble sulfate with water. The amount of acid used was calculated to produce certain desired soluble sulfates. The temperature of baking depended on the decomposition points of the sulfates involved. The object was to prevent the formation of or to decompose certain sulfates while leaving a maximum quantity of another sulfate in a water-soluble form. This procedure has two possible advantages over the ordinary method of leaching with an aqueous solution of sulfuric acid. First, a more selective leach may be obtained, and second, the higher temperatures and stronger acid concentrations involved will permit a better recovery of materials that are difficultly soluble in relatively dilute aqueous sulfuric acid solutions. The method of sulfuric acid baking followed by water leaching is not new, as it has been applied in the treatment of various metalliferous materials such as the recovery of cadmium from flue dust1, the re-treat-ment of zinc leach residues2 and the working up of electrolytic slimes3.

Jan 1, 1936

By Ruixiang Wang, Jinhui Li, Youjun Xiao, Daoling Xiong, Hao Chen

"Leaching solution prepared from spent battery materials contains large quantities of valuable metals, such as Cu, Ni, Co, Mn and Fe. Therefore, recovery of valuable metals from acidic polymetallic aqueous solutions is of great importance for every plant. In this work, a method is introduced of recovery of Ni, Co and Mn from polymetallic solution prepared by leaching spent battery material. The basic concept includes copper was removed through replacement by iron powder followed by iron precipitation in goethite method. The experimental results show that Cu can be removed 99% at least through replacement by Fe powder, and the removal of Fe can achieve 99% by goethite method. At the same time, the loss of Ni, Co and Mn are about 2%, 3 % and 2%, respectively. The process of differential removal of metals can be selected as the treatment alternative that combines simplicity, efficiency and reliability with low capital and maintenance costs. The purified solution which only contains Ni, Co and Mn can be used to prepare NixCoyMnz ternary system precursor.1 IntroductionNickel and Cobalt are very important metals which are applied in many fields, such as energy material and support material for some new material field. The world demands for such metals is progressively increasing, while raw resources are being depleted and with the constraints raised by the Law and related legislation assigned to protect the environment from hazardous wastes in the world. Nowadays study on reutilization of waste materials has great significance for achieving secondary resources recycling and preventing environmental pollution. There are many hydrometallurgy methods applied for dealing with these wastes, while they usually contain large quantities of valuable metals, such as Cu, Co, Mn and Ni, as well as impurities, such as Fe, Zn, and etc. Therefore, proper treatment of these leaching solutions prior to their discharge is of great importance, so that the contained valuable metals can be recovered.Separation and extraction of metals from leaching solution can use some methods through solvent extraction[l,2], ion exchange[3,4], precipitation with sulfide[ 5] or alkali[ 6] and electrolytic recovery[?]. Among the appropriate treatment alternatives, replacement and differential precipitation is the most attractive treatment that combines simplicity, efficiency and reliability with low capital and maintenance costs."

Jan 1, 2011

By C. Demir, M. S. Celik, I. Gülgonul

Na-feldspar (albite) and K-feldspar (microcline or orthoclase) are major feldspar minerals with identical crystal structures and physicochemical properties. Flotation appears to be a unique method of separating these minerals. Fundamental studies on amine/feldspar system in the presence of monovalent salts showed that separation of these feldspar minerals by flotation is possible at certain concentration of monovalent salts in HF medium and natural pH. A comparison between natural pH and HF medium indicates that the latter provides a better selectivity at the expense of higher collector requirement. A general mechanism for both systems involving an ion exchange between the uncommon ions and adsorption of the common ions is proposed to be responsible for creating differences in the charge of albite and microcline unto which amine adsorbs.

Jan 1, 2002

By William I. Watson

Problems encountered in beneficiating mineral raw materials become increasingly difficult as there is a shift to lower grade and more complex raw materials, and because of the economic need to strive for ever higher recoveries, higher grade products, and lower processing costs. Methods of attacking the many problems should include not only the familiar chemical and physical tests and equipment, but such techniques as X-ray analysis, infra-red analysis, differential thermal analysis, and the use of electron and X-ray microscopes. Many people in the mineral-treating field are unfamiliar with these newer methods and techniques. The differential thermal analysis method, in particular, does not seem to be very well known, even though it offers interesting possibilities in the study of many ore treatment problems.

Jan 7, 1959

By A. J. MacRae

Metallurgical furnaces are made up of complex multi-component systems that must function either together or in parallel for safe, and reliable operation. Thermal expansion of single material components experience induced stresses during heating and cooling, which can lead to cracking or failure. Multi component elements and systems can experience significant thermally induced stresses during both steady state and transient temperature conditions. Examples pertaining to temperature effects on refractory, copper cooling blocks, furnace shells, and complete systems will be discussed. The purpose of the paper is to highlight how stresses and strains are developed due to differential thermal expansion.

Jan 1, 2015

By D T. Froedge

A new system for acquiring blast vibration data and a method for presenting that data in such a way that there can be an extraordinarily enhanced insight into the understanding of vibrations produced by blasting is described in this paper.

Jan 1, 1989

By J. K. Whyatt, B. G. White

Various methods of monitoring slip movements on bedding planes, as well as examination of rock burst damage in stopes, suggests that rock bursts in the Lucky Friday Mine are closely associated with these movements. Slip displacements along bedding simultaneously reduce the physical dimensions of stopes and increase compressive stress along stope margins. Such changes, in turn, contribute directly to rock bursts and the sudden failure of volumes of rock and cemented sandfill surrounding stopes. The distribution of seismicity and several mining-induced and premining structures resemble those described in South African gold mines. These suggest fundamental similarities in seismic sources and mechanisms of rock burst damage.

By S. C. Hollister

An evaluation of the function of the engineer, so that means whereby education can best serve his needs can be adopted.

Jan 2, 1950

By Waldemar Lindgren

THE purpose of this paper is to present certain facts relating to Cordilleran differentiation and metallization. Theoretical discussions concerning the exact modus operandi of differentiation, the causes that led up to it, and the original distribution of the magmas have been omitted because the author feels that his knowledge is deficient. These subjects have been adequately treated in the admirable works of Iddings, Daly, Harker, Tyrrell, Shand, and Wolff. The facts here set forth seem to indicate that differentiation and metallization form one continuous process during the eastward movement of the magmas, culminating in the alkaline province of the eastern border of the Cordilleran Ranges.

Jan 1, 1933

By W. C. Lacy

A WIDE variety of metalliferous deposits in Peru shows a close and consistent relationship to intrusive and extrusive igneous rocks. This relation- ship furnishes a clue to the composition of ore-bearing fluids and to the timing in separation of these fluids from differentiation magma. Conclusions presented here are based on ten years' study of a large number of metalliferous deposits in Peru. The most important of these areas are shown in Fig. 1.

Jan 5, 1957

By Moore R. F, Macias L. F

The Filbara region of northwestern Western Australia contains several known occurrences of mafic/ultramafic rock assemblages which may host platinum group element (POE) mineralisation. This paper deals with occurrences at Munni Munni and Andover. The Munni Munni complex is of particular interest because it is known to contain PGE mineralisation and is currently undergoing active exploration. The US/Australia Joint Scanner Project of October 1985 collected airborne scanner data for the BMR over Munni Munni. Such an ultramafic-mafic complex had not been previously researched with advanced remote sensing instrumentation. Extensive investigation of data from the NSOO1 (Thematic Mapper Simulator) scanner resulted in successful differentiation of gabbroic and ultramafic rocks, and also subdivision within the ultramafies. Similar differentiation could not be achieved using conventional Landsat MSS imagery and aerial photography. Encouraged by those results and in support of BMR field research into the mafic-ultramafic suites of the region, data from the Landsat Thematic Mapper (TM) instrument were investigated to attempt differentiation of the ultramafic and mafic rocks in the Andover complex some 50 km to the northeast of Munni Munni.

Jan 1, 1988

By James J. Tansey

A Deep Foundations Institute meeting with the University of Michigan at Ann Arbor in March of 1984 featured legal rights under Differing Site Conditions. A workshop conducted by the authors and Gerard Ittig, Esq. added to the value of the symposium. This paper will be of interest to your attorneys in any subsurface disputes.

Jan 1, 1985

By Jürg Künzle

Underground construction is a matter of dealing with the inherent uncertainty of subsurface geology. If the encountered conditions are less favorable than the expected ones, the execution of excavation, support, ground treatment or lining works is likely to require more or different efforts than anticipated, thereby delaying the works and increasing the costs. The 2019 first edition of the FIDIC Emerald Book model contract (FEB) addresses many of the issues to which underground works give rise, including those related to differing site conditions (DSC). This paper examines how under the FEB disputes arising from or in connection with DSC could or should be avoided.

Jun 13, 2021

By Peter J. Tarkoy

The use of personal computers (PCs) is increasing in underground construction applications, specifically, for estimating, record keeping, construction performance analysis, project cost reporting, and the effective application of construction experience for estimating and aggressive bidding. Applications particularly suited to the PC are analyses of construction performance and differing site condition claims. The advantages of using a PC in the analysis of differing site conditions claims is that the PC: requires quantitative and factual data, allows vast data manipulations, calculations, and sorting, and provides a simple graphic representation of complex data and issues. The restrictions imposed by a PC are conducive to the focus on essential facts, issues, quantitative analyses, and inherently, the truth. As computer thinking is established, a clearer, more precise and accurate focus on the elements of a differing site condition is essential for successful evaluation and presentation.

Jan 1, 1987

By J. Ling, L. Racine, P. Cousin, A. R. Laplante

"The problem of gold recovery by gravity from high density gangues is first discussed from a fundamental perspective. Three potential difficulties are presented: poor liberation and fine gold particle size, concentrate bed erosion by coarse dense particles, and slow percolation of gold particle through the high density gangue bed. Two case studies are presented to illustrate the impact of these three problems on circuit performance and the feasibility of gravity recovery. It is concluded that careful testing can determine the scope of the first problem and feed preparation can limit the extent of the second. The third problem is clearly the most serious and results in lower gravity recoverable gold recoveries than would be achieved with the same recovery effort on a low density gangue application.IntroductionSince the commercialisation of the Knelson Concentrator in 1980, gold gravity recovery has experienced a surge in interest, in Canada and the United States first, then Australia, Zimbabwe and Russia, and finally worldwide. Table I details number of units sold in various countries, which corresponds approximately to their importance as gold producers 1. Exceptions. such as the low rank of South Africa or the importance of Zimbabwe, despite the much higher gold throughput of the former, are generally the result of differences in the effectiveness of the local marketing strategies, as well as a reflection of the ""philosophy of recovery"" prevalent in the country.The impact of the Knelson has not been felt equally in all plants. Typically, a highly successful application falls into the following categories: (a) alluvial or hard rock recovery for which gravity is the sole recovery method, (b) hard-rock free gold milling with ores which have a very high gravity-recoverable gold (GRG) content, (c) low grade sulphide copper-gold ores which include flotation ahead of cyanidation and (d) free-milling gold ores ahead of Other applications can be successful, but are not as common. The ""explosion"" of centrifuge concentration, of which the Knelson is the most successful but by no means the sole model, has created a certain euphoria which can be summarized as ""gravity recovery will improve the profitability of gold milling, no matter what."" This presentation is about applications that are not so successful, or even downright unsuccessful. The rationale is not to down-play gold gravity recovery, but to set it in its rightful position: metallurgically, it is not appropriate all of the times; it can become inappropriate if poorly designed; and it can be metallurgically possible but economically unjustifiable. In this paper, this will be illustrated and explained rather than demonstrated, with the use of both industrial plant surveys and laboratory test work. Alternate gravity approaches will be suggested."

Jan 1, 1997