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By T. J. Langan, M. Ramajayam, T. Dorin

"6xxx-series Al alloys are the most commonly used alloys in the automotive industry as they have an appropriate balance of strength, corrosion resistance and formability. The main strengthening phase in these alloys is the ß’-Mg2Si precipitates. One opportunity to achieve stronger 6xxx-series Al alloys, without affecting corrosion and formability, is the use of Sc. The main challenge of using Sc in 6xxx-series lies in the heat treatment, which must be designed to allow for a fine precipitation of both Al3Sc and ß’-Mg2Si. In this work, two model alloys are used, an Al-Sc-Zr and an Al-Mg-Si-Cu-Sc-Zr, to explore the impact of the 6xxx-series key elements (Mg, Si and Cu) on the Al3Sc precipitates. Transmission electron microscopy and atom probe tomography are used to investigate the precipitates present in the microstructure after casting. We find that higher Si content results in the formation of dispersoids upon casting. The average composition of these dispersoids is (Al0.8,Si0.2)3 (Sc0.888,Zr0.024,Mg0.08,Cu0.008). A closer look at the solid solution reveals that most of the Sc and Zr is supersaturated after casting even in the presence of Mg, Si and Cu. We discuss the impact of these results on the design of a suitable heat treatment for 6xxx-series alloys with Sc.INTRODUCTION The most common strategy to strengthen aluminum (Al) alloys is by micro-alloying to form a fine distribution of precipitates (Gladman, 1999). Whilst precipitates enhance the strength, this is often done to the detriment of ductility and corrosion performance (Davis, 1999). The 6xxx-series Al alloys are heavily used in the automotive industry as they offer an appropriate balance of strength, ductility and corrosion resistance (W. S. Miller et al., 2000). The strength increment in these alloys comes from the formation of the ß’–Mg2Si and the quaternary Q’ phase (Chakrabarti & Laughlin, 2004; Polmear, St. John, Nie, & Qian, 2017). One opportunity to achieve stronger 6xxx-series alloys, whilst keeping good balance of corrosion resistance and formability, is the use of small additions of scandium (Sc). Sc is one of the most potent strengtheners in Al alloys (Dorin, Ramajayam, Vahid, & Langan, 2018; Røyset & Ryum, 2005). Most of the strengthening benefits from Sc come from the formation of fine Al3Sc dispersoids. The following strengthening mechanisms apply to Sc: 1) Solid solution strengthening, 2) precipitation hardening, 3) inhibiting recrystallization, 4) assisting nucleation of other strengthening phases (Dorin, Ramajayam, Lamb, & Langan, 2017). As compared to other dispersoid phases, Al3Sc dispersoids have good electrochemical compatibility with Al alloys and hence do not affect their corrosion resistance (Cavanaugh, Birbilis, Buchheit, & Bovard, 2007). The coarsening resistance of Al3Sc is often improved by adding zirconium (Zr), as it forms a Zr rich shell around Al3Sc which prevents Sc from moving across the interface."

Jan 1, 2018

By Yuanbo Zhang, Daoyuan Zhang, Youlian Zhou, Guanghui Li, Tao Jiang

"Modified humic acid (MHA) has been developed by Central South University (CSU) and authorized in China. It has been reported that MHA is an effective binder for oxidized pellets prepared from specularite concentrates. In this research, effects of MHA binder on roasting behaviors of the specularite pellets are studied. MHA is an organic binder, containing much carbon, hydrogen, oxygen, etc. During the roasting, MHA can provide some heat because of combustion of hydrocarbon, which is beneficial for the recrystallization of Fe2O3 in the specularite pellets at high temperature. Simultaneously, part of hematite particles within the pellets are firstly reduced to magnetite, then, magnetite is oxidized into secondary hematite, which obviously improves the roasting performance of specularite pellets.IntroductionOxidized pellets have been widely used in steel production as a kind of high quality burden for blast furnace ironmaking [1]. In recent years, production of oxidized pellets is developing very fast. Therefore, the supply of high quality magnetite concentrates, which is the most suitable for pellet production, becomes scarce. It is imperative to pursue new alternative materials for oxidized pellet production [2]. Specularite concentrates have attracted widespread attention due to the advantages of high total Fe grade and low impurity content. However, due to the poor ballability and firing performance, specularite has not yet been widely applied into pellet production [3, 4]."

Jan 1, 2012

By F. Chevarin

The reaction of O2 with the carbon anode is considered as the main parasitic chemical reaction affecting Hall-Heroult process anodes. The current study aims at investigating the influence of the microstructure of baked anode on its overconsumption. Samples were removed from different positions of an industrial anode. Density, porosity, Lc and BET specific surface area were measured. The anode reactivity was evaluated based on the weight losses for the samples resulting from the reaction of anode with air at 550°C after 7h. The essential parameters determined to control the air reactivity are closed porosity, Lc and pores with a pore entrance radius of 1.5, 8.5 and 12 p.m. The knowledge of effects of these parameters allows better understanding of the reactivity of anodes and consequently reduction of their overconsumption in electrolysis bath.

Jan 1, 2011

By W. Qin

The nucleation of d hydride in Zircaloy-4 has been studied using electron backscatter diffraction. Hydrides prefer to nucleate at intergranular rather than intragranular sites. (0001) a -Zr//(111) d -ZrHx is the most common crystallographic relationship. The hydride platelets are generally interlinked each other and form a chain-like configuration. Based on thermodynamic model, the formation mechanisms of the hydrides at different sites and the interlinked structure were analyzed. We found that the misorientation of two adjacent grains has a crucial effect on hydride nucleation sites, and the tensile stress near the tips of hydride platelets is a key factor affecting the appearance of interlinked structure.

Aug 1, 2010

By John M. L Lewis, Antoine F. Mulaba-Bafubiandi

In the irradiation of ore particles by microwave energy preferential absorption of this energy occurs in minerals having specific dielectric properties (Bradshaw, 1999). This leads to a selective heating of the various components of within the ore particle matrix. The result is a differential thermal expansion of such components and the resulting induced stresses become ideally concentrated at mineral grain boundaries (Kingman et al., 2000). Dependent upon the relative composition of absorbent, opaque and reflective components this may lead to enhancement of the inter-granular fracture of the ore particles in the initial comminution process (Fandrich et al., 1997). The potential is thus a greater proportion of free mineral grain within the fractured ore particle that may lead to improvement in subsequent mineral separation processes. As the composition of the ore dictates the result of such a treatment (Kingman et al., 2000) it is essential to evaluate the response of each ore sample on an individual basis. This paper reports on results obtained from two ore samples: the one being the zinc ore from the Black Mountain mine (South Africa) and the other a pre-concentrated sample of handpicked cobalt?copper mixed oxide ore from the Gecamines (DRC). The equipment and methods used to simulate the comminution of the samples and evaluate the level of the value liberation will be described along with the results obtained. Using King (1975), Kanellopoulous and Ball (1975), and Gungor and Atalay (1998), a comparison between the behaviour upon microwave irradiation of sulphide and mixed oxide ores leads to conclude that while the technique (i.e. microwave irradiation) is appropriate to the zinc sulphide ore, it does not seem to lead to exceptional results for the oxide.

Jan 1, 2005

By Z. Q. Zhang

The iron ore from Yichang in China assaying 41.64% Fe and 1.02% P is a low grade and high phosphorus oolitic hematite ore. The separation of iron minerals from gangue minerals in the ore by conventional processing techniques is ineffective owing to their close similar properties. The modification of iron minerals by microwave-assisted reduction was investigated in order to improve separability of the ore. The effects of microwave-assisted reduction on the subsequent low intensity magnetic separation and floatation were examined. The results show that the main factors affecting the reduction and separation process are grinding size, reduction temperature and reductant. Fine grinding of the microwave-treated ore to smaller than 0.074mm was found to be imperative due to the tiny dissemination characteristics of iron oxide minerals. After magnetizing reduction by microwave heating at 500?, the magnetic concentrate containing 58.36% Fe and 0.67% P can be obtained with the Fe recovery of 91.28%. Magnetizing reduction drops the floatability of iron oxide minerals, thus reverse flotation is fit for upgrading the magnetic concentrate to contain 62.13% Fe and 0.21% P with Fe recovery of 81.59%. Compared with present microwave-assisted reduction technique of carbon reductant, using a waste iron powder as reductant is a novel and effective technique without the green house effect caused by the release of CO and CO2. Waste iron powder with a faster response to microwave heating then coke and charcoal can be recovered by magnetic separation in a low cost and plays the role of reductant and microwave heating accelerator.

Jan 1, 2014

By Ethan Steward, Kyle Perry

Blast resistant structural design continues to be a research area of major concern for governments around the world due to explosive threats from both state and non-state actors. Glass and aluminum curtain wall systems are commonly used to clad the exterior of government and commercial structures, allowing light into the building, regulating the interior environment, and providing an aesthetically pleasing exterior. These systems are likely to fail when exposed to sudden, high-pressure events such as the purposeful or accidental detonation of explosives. Engineers have designed blast resistant curtain walls and structural elements to reduce the likelihood and severity of failure, but the design tools and testing mechanisms commonly used in the process may not accurately model or simulate actual blast conditions at all ranges. In blast resistant structural design, the origin of a shock wave is typically assumed to be in the far-field, creating a wave that is nearly planar and parallel to at least one face of the target. Shock is applied evenly and immediately across the entire impacted surface. However, the source of real-life blasts is often very close to the target structure, and the assumption of far-field planar shock does not always apply. Mid-field blasts exhibit qualities different from those assumed about far-field shocks, specifically a hemispherical shock that produces different peak pressures, impulse curves, oblique reflections, and Mach stems across a target. This paper will examine mid-field shock effects from scaled distances of 2.5 to 4 13 (6.3 to 10.1 13) on a tall, scaled target by measuring reflected and incident pressure, impulse, and shock velocity across the target. Results will be compared to theoretical blast parameter equations and empirical data used by the industry. Possible effects of mid-field blasts on structures and further research ideas will be suggested.

Jan 21, 2025

By Madaah Hosseini H. R., P. Abachi, S. Miraghaei

In this study, the effects of milling time, chemical composition and heat treatment on microstructure and magnetic properties of nanocrystalline Fe-Si (6.5-25 at.% Si) alloys prepared by mechanical alloying have been investigated. The results show that increasing the milling time or the Si content, decreases the lattice parameter and increases the internal microstrain. The prepared powders mainly consist of micron-sized particles with an average grain size of less than 20 nm. The specific saturation magnetization values are slightly less than those of single crystal or conventional Fe-Si alloys and decrease as Si content increases. The coercive force values of the nanocrystalline as-milled powders are much higher than those of corresponding Fe-Si bulk alloys with a minimum at 13.5 at.% Si. The values of coercive force decreased after annealing but it seams that the residual strain developed during milling is not the major contributing factor to the higher values of coercive force in the mechanically alloyed powders and nanocrystals behave as single-domain particles without exchange interaction between them.

Jan 1, 2006

By Donald W. Gentry

This article introduces mine planning as a complex process based on the quantitative and qualitative assessment of a myriad of independent and inter-or co- dependent variables. The interdependent variables of particular interest in this paper are those associated with mine planning activities that impact metallurgical processing plant performance and costs. These variables are identified and examples are provided to substantiate the argument that the magnitude and sensitivity of these variables must be formally assessed and analyzed to determine their potential impact on overall economics.

Jan 1, 1991

By P. T. Bissert, L. Yan, M. D. Klein

"Since 2008, the U.S. Mine Safety and Health Administration (MSHA) has required the installation of refuge alternatives (RAs) in underground coal mines (MSHA, 2008). MSHA requires that RAs provide an environment with breathable air for entrapped miners for a 96-hour period. Heat buildup inside an occupied RA is a serious concern. Without a means to dissipate the heat and humidity generated by the occupants and the carbon dioxide scrubbing system, the temperature and humidity inside RAs could lead to severe discomfort or heat stress depending on the mine ambient temperature before and during occupation of the RA. In its 2006 report, the West Virginia Mine Safety Technology Task Force (2006) recommended an apparent temperature limit of 35 °C (95 °F) for RAs. In Title 30 Code of Federal Regulations Part 7.504, or 30 CFR 7.504, MSHA specifies a maximum apparent temperature of 35 °C (95 °F) inside an occupied RA (MSHA, 2016). The apparent temperature is calculated using both air temperature and relative humidity (Steadman, 1979).Calculations can be used to deter-mine if the air within an occupied RA will reach the apparent temperature limit. In these calculations, the mine temperature could be assumed to re-main constant. With this assumption, the effects of the mine strata thermal mass and thermal conductivity on the heat buildup in an RA are ignored. Re-search conducted by the U.S. National Institute for Occupational Safety and Health (NIOSH) shows that the mine air and strata temperatures surrounding an RA increase when subjected to the heat of an occupied RA (Yantek, 2014). Thus, calculations performed with the assumption that the mine temperature is constant would underpredict the resulting dry-bulb temperature and apparent temperature for a given RA occupancy. The mine air temperature has been used as the basis for RA temperature calculations. However, there has been no research to confirm that the mine air temperature is the appropriate basis."

Apr 1, 2017

By Ronald E. Yarbrough

As a result of concern for the citizens of the State of Illinois who owned structures above underground mine workings, the Illinois State Legislature passed House Bill 158 in 1978. This bill amends the Illinois lnsurance Code and creates the Mine Subsidence Reinsurance Fund which is an insurance pool that is to receive a state appropriation of $500,000 as "start-up" money. One hundred thousand dollars has been paid to the fund as of October, 1982. The Fund is to return this appropriation to the State and is to remain self-supporting from premiums. The Fund utilized a pre-existing institution, which also was an insurance pool, the "Fair Plan Facility" and its governing Board, consisting primarily of insurance executives, to administer the program. The Mine Subsidence lnsurance Act went into effect October 1, 1979, and the bill provides that property owners in the State of Illinois may purchase up to $50,000 of mine subsidence insurance which is attached to their fire insurance policy. The deductible is normally 2%, but cannot be less than $250 or more than $500. The annual rate structure for residential structures in 1981 for $50,000 coverage is $10 (frame), and $12 (masonry). The rate structure for commercial buildings is based on the value of the building and the rates for $50,000 maximum coverage is adjusted upward. The insurance was mandated by the State Department of lnsurance and rolled onto the insurance policies of the homeowners in 34 counties which had been recognized as having sufficient exposure to subsidence damage to be covered by the Act. One percent or more of the land surface is undermined in each of the 34 counties. In the other counties undermined in the State of Illinois, insurance is available to the homeowner upon request to the private insurance carrier.

Jan 1, 1982

By Michael W. Neill, O&apos

Drilling slurry has become an effective aid to the construction of drilled shafts in caving and/or waterbearing soils. Historically, drilling slurry made of bentonitic clay and water was first used in the US in water well drilling as early as 1889. In coastal Texas drilled shaft contractors began using slurry, often made of on-site clay mixed with potable water, in the years following World War II, on a relatively routine basis. This type of slurry was used to "process" boreholes, in which the borehole was drilled "in the dry" until water or unstable soil was encountered, after which water and on-site clay were introduced into the borehole and mixed in place with the auger or other drilling tool. Drilling then continued under a slurry consisting of the uncontrolled mixture of clay and water until the excavation had reached a relatively impermeable and cohesive material. At this point, a steel casing was dropped into the hole and sealed into the lower stratum of impermeable geomaterial (soil or rock). The slurry inside the casing was bailed or pumped out, drilling continued to plan depth in the dry, a reinforcing cage was set in the partially cased borehole, concrete was placed and the casing was withdrawn. Some soil-slurry was undoubtedly trapped between the casing and the borehole wall, but the quality of that slurry was usually of no concern, because engineers of the period usually viewed drilled shafts as nothing more than deeply buried footings. Any unejected slurry would only serve to lower side shearing resistance, not yet considered in design, but would have no effect on end bearing. In the 1960 's the effectiveness of soil-slurry came into question because it was often ineffective in maintaining borehole stability at marginal drilling sites and because the economy of using shaft resistance, in addition to end

Jan 1, 1991

By ZhiLong ZHAO, Lin Lin, Zhancheng Guo, Jingtao GAO, Huiqing Tang

Grain sticking often occurs in the fluidized bed reduction of f ine iron ore, which is closely related to the precipitation morphology of metallic iron on the surface of ore particles. In this work, simulating the gas-solid reduction process of iron ore, in situ observations were carried out to investigate effects of doping mineral oxides on the precipitation morphology evolution of metallic iron during reduction of iron oxides with CO. Results indicate that the precipitation morphology of metallic iron is related to the quantity of doped mineral oxides. The minimum mole fraction of doped oxide ( xyOA N ) that can inhibit the growth of iron whiskers is related to its cation radius ( Ax r ), extranuclear electronic layers ( Ax n ) and valence electrons ( Ax q ). Their relation can be expressed as:

Jan 1, 2016

By G. Ansong, P. K. Achireko

The authors present a new mineral price model, compare it with time series and naive models, and analyze the effects of the forecasting models on mineral project evaluation. Mineral commodity prices are volatile, which means that the results of evaluation tools that do not treat the stochasticity of metal prices rigorously may be misleading. But, in mine valuation, commodity price forecasts are required to assess the economic viability of a project. In this study, a new mineral forecasting method, called the MNDRVG-MFNN-RM model, which incorporates randomness, neural networks and regression models, is introduced. The MNDRVG-MFNN-RM model, a naive method and time series model were used to forecast gold prices for two successive years for the evaluation of a proposed open-pit mine. The MNDRVG-MFNN-RM model yielded the best results among the three methods. It produced the true optimum pit limits and an optimum pit value slightly less than the true optimum value. The main novelty of the methodology is the simulation and rigorous analysis of the randomness property associated with mineral prices to reduce the estimation and forecast errors, an important contribution to mineral venture evaluation, mine planning and design.

Jan 1, 2000

By Anton Sroka

The German hard coal production predominantly derives from underground multiseam mining activities. Beside common surface damages, ?inner mine damages? on underground infrastructures (i.e. main roads, cross cuts and shafts) due to mining excavations occur to an increasing extent. As these "inner mine damages" dramatically increased because of the development towards high performance longwall mining technologies, this matter raised to be a severe problem concerning mining economics. To protect durable and long lasting underground infrastructures, precautionary measures such as suitable mine layouts, adapted planning of mining operations and moderate face advances have to be considered. Some examples of "inner mine damages" recorded by means of mine surveying methods are given in this paper. An empirical-mathematical model based on the principles of mining subsidence engineering methods will be introduced. This model allows to minimize ?inner mine damages? and helps to support and optimize mining processes.

Jan 1, 1999

By Francis Breton, Lei Pan, Kun Liu

"Effects of Fe, Cu and Mg minor alloying elements on creep properties of 8xxx aluminum conductor alloys were investigated by conducting compressive creep tests at 100 ºC under a constant load of 69 MPa. The microstructural evolution was studied using an optical microscope and electron backscatter diffraction technique. The creep properties were characterized by the primary creep strain in the first stage and the minimum creep rate in the second stage of creep deformation. Results showed that additions of all three minor alloying elements (Fe, Cu and Mg) demonstrated a beneficial effect on the creep resistance but individual alloying elements exhibited different impacts on creep properties. The additions of Fe and Mg showed a strong impact on both the primary creep strain and minimum creep rate, while the Cu addition displayed a favorable effect on the primary creep strain but no impact on the minimum creep rate. Microstructure observation revealed that with increasing Fe contents, the volume fraction of fine intermetallic dispersoids gradually increased while the subgrain size and misorientation angle became smaller, providing strong barriers to the dislocation and grain boundary movements. The addition of Cu moderately reduced the subgrain size and misorientation angle and in combination of solid solution strengthening it promoted the retardation of the creep deformation during the primary stage.INTRODUCTIONThe 8xxx aluminum conductor alloys offer significant advantages such as low density, high conductivity to weight ratio and low price over copper conductors and become an attractive candidate in electrical engineering and building wiring (McQueen, Chia, & Starke, 1986; Birol, 2009; Engler, Laptyeva, & Wang, 2013). The mass resistivity of aluminum conductors is one-half of copper conductors. Thus, only one-half the weight of aluminum is required for equivalent capacities. Therefore, this unique property coupled with a relatively low price of aluminum offers significant economic advantage to develop aluminum conductor alloys for electrical applications in the electrical wire industry."

Jan 1, 2016

By Charles de Abreu Martins

An experimental investigation was conducted using laboratory-processed, 0.12C–1.70Mn–0.2V steels with different Cr or Mo additions aiming to evaluate this influence on the microstructure and mechanical properties hot rolled steels. Steels were processed in a pilot rolling equipment, simulating a typical thermomechanical processing, with finishing rolling steps above Ar3, followed by accelerated cooling and 723 K (450 Celsius) coiling temperature. Microstructures and precipitates were analyzed using OM, SEM and TEM, while mechanical properties were evaluated by tensile and hole expansion tests. Since Cr and Mo increase hardenability of austenite, and as a consequence, the volume fraction of the acicular constituents increases with gradual additions of Cr or Mo. Moreover, Cr or Mo impacted V precipitation process, reducing average size of particles. At 0.50%Mo, V precipitation was inhibited. Effects of this microstructure evolution on the final mechanical properties were also analyzed, as well as a comparison between Cr and Mo effects, with Mo presenting more effective influence.

Jul 30, 2018

By Y. P. Chugh, R. A. Missavage

Moisture has been known to influence strata failures in coal mines for a long the. A concise review of what is known about effects of moisture on strata control with emphasis on the Illinois basin coal mines is presented in this paper. Some approaches to mitigate the effects of moisture-leaving coal in the roof, guniting, shotcreting, application of sealants-are then briefly discussed.

Jan 1, 1982

By C. Dale Elifrits

Observations made from laboratory analysis of samples of fine-grained argillaceous materials (shales) subjected to various changes in moisture content have been correlated to loss of strength in the rock material. This reaction to a change in in-situ conditions (subsequent to mining) at a mine site combined with the observed relationships of surface-disturbing subsidence features at locations where the predominant overburden material is fine-grained, provides a predictive tool for the subsidence engineer.

Jan 1, 1983

By C. D. Elifrits, N. B. Aughenbaugh

Laboratory tests of samples of fine- grained, argellaceous rocks, commonly referred to as shales, have shown that various changes in their moisture content can be correlated with loss of strength. This reaction to a change of in situ conditions at abandoned mine sites when combined with the field relationships at locations where the predominant overburden material is fine-grained, argellaceous, and fractured provides a predictive tool for engineers dealing with subsidence problems. Such a tool should enable engineers to recognize areas that are prone to be affected by surface disturbing subsidence features.

Jan 1, 1987