Search Documents

By S. P. Singh, Turgut Yalcin

The physical characteristics of blasted rock are fundamental variables affecting the economics of mining operations and are in fact the basis for evaluating the quality of a blast. A study was designed with the objective of quantifying the effect of muck size distribution on scooping operations in a mine.

Jan 1, 2002

By P. Srinivasan

Corrosion is a major operational problem in amine-treating plants causing significant expenditures each year, Corrosion may become more severe when the amine plants contain process contaminants ? namely heat-stable salts. The heat-stable salts enter the plants with feed-gas streams and makeup-solution, and/or are produced within the plants by reactions of alkanolamine and available carboxylic-acid anions, This work investigated interaction corrosion effects that may exist in amine-treating plants containing a mixture of heat-stable salts, The investigation was experimentally carried out in a 5 kmol/m3 monoethanolamine (MEA) solution containing 0,20 mol/mol carbon dioxide (CO2) loading at 80°C under atmospheric pressure using carbon steel 1018, Six heat-stable salts, including formate, oxalate, bicine, acetate, thiosulfate and chloride, were tested with a series of salt combinations, Potentiodynamic Polarization, Tafel Extrapolation, and Cyclic Polarization were used for revealing corrosion behavior, determining corrosion rate, and examining the pitting tendency, respectively, Results show that thiosulfate induces the most corrosive environment when present either individually or in the form of salt mixtures.

Jan 1, 2005

By David D. Spencer

As in many other areas of the Mexican economy, the legal rules applicable to mining in Mexico have been changing fast. Mexico's mining sector is opening up to levels of international participation that were unforeseeable just a few years ago. Over the last several years, Mexico has made dramatic changes in its trade and investment policies. Many of these changes have their roots in the administrations of Miguel de la Madrid and perhaps even Jose Lopez Portillo. However, the current administration of President Carlos Salinas must be given credit for articulating, advancing, promulgating and implementing these changes. Just a few short years ago, few people believed Mexico would repeal so many of its restrictions on foreign investment and lower its average tariff level from something around 100% to less than 10%, where it is today. NAFTA and mining The North American Free Trade Agreement (NAFTA) is the most comprehensive international expression of Mexico's new policies. Except perhaps for the agreements establishing the European Union, NAFTA is the most detailed trade agreement ever written, consisting of about 2000 pages. The provisions of NAFTA with the greatest relevance to the mining industry include the chapters on investment and government procurement. Many mining companies may also find the temporary work provisions relevant. Finally, no discussion of NAFTA and the mining industry would be complete without some mention of the North American Agreement on Environmental Cooperation, the so-called Environmental Side Agreement.

Jan 1, 1994

By W. Murray Small

Nickel plays an important role in determining the properties of many stainless steels and superalloys. Cobalt also contributes significantly to the performance of certain grades of superalloys. A major technical aspect, in which both of these metallic elements are involved, concerns the solubility of nitrogen in these classes of alloys. Beyond certain content limits, dissolved nitrogen may contribute to the deleterious mechanical behavior by these alloys. It is therefore essential to control the level of this element during alloy processing. In this paper, results from several experimental studies have been assembled and are analyzed to describe phenomena related to the individual effects of nickel and cobalt on the solution of nitrogen in several groups of alloys. Both solid and liquid alloy systems are considered. This information may be used as a guide to limit or control the presence of this interstitial element in alloys.

Jan 1, 1993

By F. Siciliano, D. Bai, S. Yue, A. M. Elwazri

The influence of niobium addition and very low temperature (`cool') deformation on the microstructure and properties of low carbon microalloyed steels was investigated. In this work, the specimens were heated at 1200°C and held at this temperature for 20 minutes. Some specimens were aged at 400°C for times ranging from 10 minutes to 10 hours followed by air-cooling. Others were subjected to deformation at 400°C (`cool deformation') prior to aging. It was observed that the proportion of acicular ferrite was increased as the amount of Nb was increased. It was found that cool deformation increased both yield and tensile strengths significantly compared to that of the aged only specimens.

Jan 1, 2005

By Qin Hua, Xiangru Chen, Qijie Zhai, Yongsheng Yan, Liang Chang

"In this paper, pure bainite ductile iron and their alloying form of 0.2wt% niobium were prepared by a controlled cooling heat-treatment. The effect of niobium alloying on the microstructure, hardness and impact toughness of bainite ductile iron was studied. The results show that adding niobium effectively improves the hardness and toughness of bainite ductile iron. The hardness and the impact toughness of niobium-alloyed bainite ductile iron were investigated by varying the temperature at which samples were fed to the incubator.IntroductionThere are two essential methods to prepare the bainite ductile iron: isothermal quenching [I-31, and alloying [4• 51• Isothermal quenching process is very time and energy consumable, concerned as a high cost technique for mass production. Besides, there are certain limitations on the size and shape of castings in this process. In addition, it potentially harms the environment. As for the alloying, Ni, Mo, and Cu have to be utilized to obtain bainite. However, the large demand and high cost of Ni makes it not feasible in practice.It is well known that niobium can promote the formation of carbon compound, and improves the stability ofundercooled austenite, which is preferred to the increase of the hardenability. Previous studies showed that niobium could refine the grain and improve the mechanical properties of gray cast iron [6-81 • Therefore, in the present work, the effects of niobium and the temperature at which samples were fed to the incubator on the microstructures and properties of niobium alloyed bainite ductile iron were investigated."

Jan 1, 2014

By Xiangru Chen, Qijie Zhai, Wei Zhang, Haicheng Li, Chao Yang

In this paper, ductile iron material with different content of niobium was prepared by a scientific melting method. Image Analysis Software was used to studied the effect of niobium microalloying on both pearlite content and pearlite lamellar spacing in ductile iron quantitatively. The results showed that the addition of a small amount of niobium could increase the pearlite content and decrease pearlite lamellar spacing of ductile iron effectively.

Jan 1, 2015

By A. L. Martikainen

In fluctuating airflow, continuous air velocity recording is the most reliable method of air velocity measurement. It allows for fast recognition of changes and the calculation of long-term averages. Also, it enables the mine operator to identify when the airflow has decreased to a point requiring action. Using ultrasonic anemometers provides an accurate option for continuous air velocity monitoring. This paper provides information about the effect of common obstructions in underground mining on air velocity readings. Stationary and moving obstructions are used to represent workers and equipment that would cause discrepancies in measured airflow. Also, it is important to know how large of a sample size is required to ensure reasonable accuracy of results. Statistical analysis is used to evaluate the required sample size. The sampling procedure is further studied by comparing two different sample rates. The results show that obstructions provide noticeable differences in air velocity measurements. Also, movement of obstructions can be recognized from changes in results. Surprisingly small sample sizes provide reliable air velocity information. Standard sample rates are found to be suitable for the underground environment.

Jan 1, 2011

By C. D. Taylor, A. L. Mazzella, A. L. Martikainen

In fluctuating airflow, continuous air velocity recording is the most reliable method of air velocity measurement. It allows for fast recognition of changes and the calculation of long-term averages. Also, it enables the mine operator to identify when the airflow has decreased to a point requiring action. Using ultrasonic anemometers provides an accurate option for continuous air velocity monitoring. This paper provides information about the effect of common obstructions in underground mining on air velocity readings. Stationary and moving obstructions are used to represent workers and equipment that would cause discrepancies in measured airflow. Also, it is important to know how large of a sample size is required to ensure reasonable accuracy of results. Statistical analysis is used to evaluate the required sample size. The sampling procedure is further studied by comparing two different sample rates. The results show that obstructions provide noticeable differences in air velocity measurements. Also, movement of obstructions can be recognized from changes in results. Surprisingly small sample sizes provide reliable air velocity information. Standard sample rates are found to be suitable for the underground environment.

Jan 1, 2011

By S K. Ray

Open fire in a mine gallery causes large-scale damage to property and sometimes precious lives. Such fires produce two distinct effects, the throttle effect and the buoyancy effect. These effects disturb the ventilation system of the mine. To understand the complex dynamic phenomenon of open fire and its effect on ventilation systems, a mine fire model gallery has been designed and constructed at Central Mining Research Institute, Dhanbad. Two sets of experiments at air velocities of 1 and 1.5 m/s were conducted in the gallery using coal samples from the Dobrana seam of the Raniganj coalfields. After about an hour of development of fully-fledged fire, heavy backlash, with smoke and fumes, was observed. At the time of backlash occurring the gallery was divided into two zones. In the region of the gallery from the base up to 1.4 m the airflow was normal, in the remaining upper portion the airflow was the reverse. Air quantity reduced substantially, while pressure dropped across the fire zone, the products of combustion (POC) and temperature increased during the period of the throttle effect. It has been revealed from these studies that with an increase in airflow, pressure drops across the fire zone, POC, temperature and reduction in airflow increases. This paper addresses the important design features of the gallery, the instrumentation system, the experimental procedure and assesses the effect of open fires on mine ventilation systems.

Jan 1, 2005

"INTRODUCTIONThe Kidd Creek Concentrator is located 28 kilometers east of the city of Timmins, Ontario. Two types of ore are treated; 'A' type, a copper-zinc-low silver ore producing copper and zinc concentrates, and 'C' type, a copper-lead-zinc-high silver ore producing copper, lead and zinc concentrates.The ore is processed at a combined rate of 12,400 metric tonnes per day through four parallel grinding and flotation divisions. Three divisions treat the 'A' type ore and the fourth treats the 'C' ore. Each division is fed from its own fine ore bin.This paper reviews the grinding section with specific emphasis on grinding media consumption and the factors affecting it as related to 'A' type ore. At Kidd Creek there was an awareness that grinding media consumption varied on a weekly and monthly basis. The reasons for this variation was usually attributed to ore hardness as evidenced by short term variations in the circuit feedrate and head assays. However, there has been a diversity of opinion published in recent years regarding the factors contributing to steel consumption. This initiated a study of historical Kidd Creek operating data, from the period 1970 to 1986 inclusive, to determine the effect of various operating parameters on media consumption. The results of the study could then be used as a baseline for future media consumption testwork."

Jan 1, 1988

By P. A. Olubambi

The effect of ore mineralogy on the bioleaching of metals from complex sulphides was studied by investigating the bioleaching of zinc and copper from a bulk complex sulphide ore from Ishiagu, Nigeria, using mixed cultures of Thiobacillus ferrooxidans, Thiobacillus thiooxidans and Leptospirillum in mechanically stirred reactors at varying particle sizes. Mineral phases within the varied particle sizes of -53, 53, 75 and 106µm were identified using X-Ray Diffraction (XRD), while the elemental distribution within the varied particles sizes was determined by X-Ray Fluorescence (XRF) and Optical Emission Spectrometry using Inductively Coupled Plasma- Optical Emission Spectrometer (ICP-OES). Bulk ore and the leached residues were examined by X-Ray Diffraction. The highest bioleaching recoveries were obtained at particle size of 75µm, while particle size of 106µm gave the least recoveries. Lower recoveries at particle sizes of 53 and -53µm were as a result of their higher silica and siderite content which affects pH, iron mobility and oxidation.

Jan 1, 2006

By T C. Ooi, L Lu

Owing to ongoing development of new orebodies and changes to existing mining operations, new ore types with distinct mineralogy, porosity and textures are generated as feed for iron and steelmaking. Moreover, further product differentiation occurs as fine ores are increasingly beneficiated to achieve grade. A study was necessary to characterise a suite of iron ore fines in terms of their propensity for formation of quasi-particles and green bed permeability prior to sintering. In this study, two Marra Mamba bedded iron deposit (BID) samples, one Pisolitic channel iron deposit (CID) samples, two dense hematite samples (coarse and fine grained microplaty hematite), one hematite-goethite BID samples and one hematite-goethite bedded/detrital iron deposit (BID-DID) composite sample were investigated. Both Marra Mamba fines and Pisolitic fines exhibit the highest green bed permeability followed closely by hematite-goethite fines, fine microplaty hematite fines, hematite-goethite BID-DID composite fines and coarse microplaty hematite fines at a moderate sintering bed depth of 500 mm. While porous fines generally form better quasi-particles upon granulation than dense fines, the amount of moisture addition increased due to the moisture saturation of the porous fines. As sinter strands become ever larger and deeper, it was necessary to examine the granulation performance of these ore types at a range of bed depths ranging from 300 to 900 mm. On average, the green bed permeability achieved by different ore types, decreased by approximately 7.5 - 9 Japanese Permeability Unit (JPU) as the bed height was increased from 500 mm to 900 mm. In order mitigate the effect of lower bed permeability of the deeper beds, small additions of hydrated lime were investigated as a binding agent to facilitate the formation of strong micro-pellets. With the addition of three per cent hydrated lime, equivalent to approximately 2.3 per cent burnt lime, the majority of fines achieved adequate permeability for deeper bed sintering, with the exception of coarse microplaty hematite fines. In simulated coastal steelmaking sinter blends, it was found that the overall granulation performance of the blend is contributed to by individual fines constituting the blend. Therefore fines possessing favourable granulating properties impart better granulation to the blend as a whole.CITATION:Ooi, T C and Lu, L, 2013. Effects of ore type and binder addition on the formation of quasi-particles and green bed permeability at different sintering bed depths, in Proceedings Iron Ore 2013 , pp 459-466 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By Youze Xu

The effect of oxalic acid, acetic acid, citric acid and EDTA on extraction of Cr (?) in soils contaminated by chromium- containing slag was investigated using a batch of incubation experiment. The results show that the pH value decreases more obvious with the increase of the amount of organic acid. The amount of Cr (?) extracted increases with increasing the amount of organic acid. When the ratio of organic acids to total Cr was 5:1, citric acid revealed the highest extraction effectiveness, followed by EDTA, oxalic acid and acetic acid, respectively. The amounts of Cr(?) extracted by citric acid, EDTA, oxalic acid and acetic acid increased by 439%, 244%, 215% and 162%.

Jan 1, 2009

By Douglas Tesarik, Mark K. Larson, Habte Abraham, Heather E. Lawson

Dynamic failures, or "bumps", remain an imperative safety concern in underground coal mining, despite significant advancements in engineering controls. While many factors have been empirically linked to the occurrence of dynamic failure events, identifying a consistent, repeatable set of criteria within a field setting has proven elusive; conditions generally associated with dynamic failure might produce an event at one site, but not another. Conversely and more troubling, dynamic failure could occur where relatively few of these factors exist. The presence of spatially discrete, stiff roof units, such as paleo channels, are one such feature that has been linked to the occurrence of dynamic failure events. However, an empirical stratigraphic review investigating the relative frequency of discrete units in bumping versus non-bumping deposits indicates that no significant difference exists based on this criterion alone, and that instead an apparent relationship exists between reportable bump history and the overall character of the host rock with respect to stiffness. Due to the complexity of the bump problem, however, these results are not conclusive, as they do not take into account any variable other than the presence or absence of stiff members in the roof lithology; To weight the relative impact of changes in a single variable, such as the thickness or location of sandstone members, it must be examined in isolation-i.e. in a setting where all other variables are held constant. Numerical modelling provides this setting, and the effects of variability in a stiff discrete member in a hypothetical longwall mining scenario are investigated within the context of three stratigraphic "types'', as determined by the ratio of stiff to compliant stratigraphic members; Compliant, Intermediate and Stiff A modelling experiment examines changes in rupture potential in stiff roof units for each stratigraphic type as discrete unit thickness and location are manipulated through a range of values. Results suggest that the stiff-to-compliant ratio of the host rock has an impact on the relative stress-inducing effects of discrete stiff members. In other words, it is necessary to consider both the thickness and the distance to the seam, within the context of the host rock, to accurately anticipate areas of elevated rupture induced hazard; acknowledging the presence of a discrete unit within the overburden in general terms is an insufficient indicator of risk. Through modelling of anticipated changes in the placement and dimensions of discrete units within their stratigraphic setting, elevated rupture-induced bump hazard can be anticipated on a case by case basis. Were similar modelling studies conducted at mine sites in tandem with tracking of problematic discrete stiff units, areas of elevated rupture risk could be anticipated in advance of mining. Developing this predictive capability beyond identifying rupture potential in discrete roof members is essential to the eventual elimination of dynamic failure related worker injuries and fatalities. As stress is a necessary component in the occurrence of dynamic failure events, this finding helps to refine our understanding of the role of individual stiff, strong roof members in bumping phenomena, and suggests that a more holistic view of overburden lithology, combined with site-specific numerical modelling, may be necessary to achieve greater miner safety.

Jan 1, 2016

By J. W. Bolton

THIS paper discusses some fundamental metallurgical principles involved in production of sound cast bronze. In a previous paper the writers advanced the theory that "oxidation" in bronze castings is due to incipient shrinkage, and showed the effect of reducing melting atmospheres. In the present paper the effects of certain impurities and of actual oxidizing conditions are shown. The appendix deals with the appearance of various inclusions. For many years the prevailing opinion has been that unsoundness, dark colored fractures and other phenomena accompanying porosity and weakness in bronzes are due to oxidation. The actual troubles are caused by fissures of intercrystalline type, which are often mistaken for intercrystalline films. These weaken the metal and make it porous. Grave doubt regarding the accuracy of the oxidation theory appears when several research papers presented within the last 10 years are reviewed critically. In 1919, Comstock conducted metallographic researches, attempting to identify "oxides" in synthetically prepared metals. He found that oxides of tin, aluminum, zinc, etc. are different from the intercrystalline films (or cavities) to which porosity is due. Apparently he believed that these "oxide films" may be caused by volatile oxides of zinc or of phosphorus or by dissolved gases thrown out of solution during solidi-fication of the metal. In 1923, Woyski and Boeck3 definitely questioned the accuracy of the oxidation theory and indicated the danger from reducing atmospheres. They say that "oxidation, gassing and shrinkage may produce effects very similar."

Jan 1, 1930

By Shiou-Chuan Sun

THE effects of oxidation on the flotation behavior of sulphide minerals have been extensively studied,1-3 but no similar study has been made of coals. Coals of bituminous and lower rank undergo atmospheric oxidation during mining and storage, and their degree of oxidizing increases with temperature4,5 and time of exposure.6 The problem of recovering fine oxidized coal from culm piles, rivers, and streams by froth flotation has become increasingly important to the coal industry as well as to those concerned with air and stream pollution. This paper describes the flotation behavior of oxidized and unoxidized coals and carbons in the presence of oily collectors and presents the reagents found effective in the flotation of oxidized coals and carbons. Except where otherwise stated, flotation tests were performed in a 50-g Denver flotation cell. Solid feed for each test was 30 g, and the pulp dilution was kept at 8.5. The -65 mesh coal sample was wetted by agitation with water in the flotation cell for 6 min, then conditioned with a predetermined amount of collector for 2 min, and finally floated with pine oil as frother for 3 min.

Jan 4, 1954

By Enid C. Plante, K. L. Sutherland

PRACTICAL metallurgists are unanimous in stating that oxidation of mined sulphide ore adversely affects separation of the constituent minerals under standard conditions in a mill. Frequently, the need for different operating conditions in different plants is attributed either to the extent of oxidation of the mineral surfaces or to soluble oxidation products. The investigations reported in this paper study the effect of oxidation on the primary condition necessary for flotation, namely that of adhesion of an air bubble to the mineral. OXIDATION PRODUCTS FROM SULPHIDE MINERALS Weinig and Carpenter1 state that the relative rates of oxidation of some sulphides are: FeAsS > FeS2 > CuFeS2 > ZnS >PbS > Cu2S tetrahedrite. They also show that oxidation is rapid at first, that sulphides of older geological formations are more stable than those of recent date and that mixtures oxidize more rapidly than any one mineral alone. The more rapid oxidation of mixtures is borne out by results of Gottschalk and Buehler2 who found that PbS, ZnS and CuS oxidized 8 to 20 times faster when pyrite was present. Only the end products of oxidation, sulphate and the metal ion, were identified in these tests. Gaudin3 states that pyrite is difficult to oxidize in the laboratory. Winchell,4 using pyrite containing 99.98 pct FeS2, allowed water to percolate through a bed of this ground material. At the end of three months only a trace of Fe +++and S04- were found. Even after 10 months the quantity of Fe+++ was only 7.8 mg and S04- 25.5 mg per liter of percolating solution. Carmichael5 confirmed Winchell's results on the slow oxidation of pyrite. Usually the oxidation of sulphide surfaces has been conducted in neutral or acid solutions, the acidity being caused by the oxidation products. Eliseev and Nagirnyak6 found that treatment of pure pyrite with lime gave only thiosulphate, but considered it possible that thiosulphate was obtained not by oxidation of the pyrite itself, but by oxidation of calcium disulphide. Mitrofanov7 suggested that thiosulphate was formed by the following process: oxidation of sulphide to give free sulphur (this frequently happens with marcasite), followed by oxidation of the sulphur to sulphur dioxide and reaction of the sulphur dioxide with sulphur to give thiosulphate. Ferric and ferrous hydroxides, or similar compounds, were shown to be present. The Research Staff of the United Verde Copper Co.8 treated ore from the United Verde mine with lime. Thiosulphate, sulphide and polysulphides were stated to be

Jan 1, 1947

By Peter K. Liaw, Charlie R. Brooks, David C. Joy, Wei Zhao

In this paper, effects of oxidation, porosity and fiber-fabric stacking sequence on flexural strength of a continuous silicon carbide fiber (SiCr) fabric-reinforced SiC ceramic-matrix composite (CFCC) were studied. The failure mechanisms were correlated with flexural strengths of CFCC samples, both before and after oxidation. Microstructures and fractography were investigated using scanning electron microscopy (SEM). The chemical change after oxidation, such as Si, C, and 0, and their distributions, were detected by the SEM energy-dispersive X-ray spectroscopy (EDXS) line-scan chemical analysis technique. These effects on the strength of the CFCC can be attributed to following reasons: (i) The decrease in the flexural strength after oxidation is mainly due to degradation of the strength of Nicalon fibers and the damage of fiber/matrix interface both caused by high-temperature chemical reactions, (ii) Porosity is not too important in affecting the strength of the CFCC, when the bonding of the forced flow chemical vapor infiltration (FCVI)-SiC matrix is stronger than that of the fiber/matrix interface. However, a higher porosity content will be harmful, because higher porosity will both decrease the effective elastic modulus of the FCVI-SiC and make pore-linkage easier to occur, which is more likely to cause premature failure, (iii) The variation in the lamina stacking sequence of the CFCC changes the elastic stress distributions along the thickness direction of specimens, the magnitude of ceramic matrix-cracking stress, the effective elastic moduli of the laminate, and different crack initiation sites as well as different failure modes, and thus, leading to the scatter in the flexural strength of the CFCC.

Jan 1, 1998

By Yuanbo Zhang, Xiaoming Mao, Zhixiong You, Zhenyu Fan, Tao Jiang

"It is generally known that the formation of calcium ferrite is favorable during the iron ore sintering, which dominatingly contributes to the improvement of strength and reducibility of the finished sinters. In this study, effects of roasting temperature and 02 content of inlet gas on the sintering mineralization properties of typical iron ores, including hematite, limonite, specularite and magnetite, were investigated. The results showed the amount of calcium ferrite initially increased then decreased with the increase of the roasting temperature. The temperature of maximum calcium ferrite generation amount for different iron ores was determined as follows: hematite and limonite was 1275 °C, whereas specularite and magnetite was 1250 °C. Increasing 02 content of inlet gas was advantageous to the generation of calcium ferrite during the sintering. The sequence of 02 content affecting the mineralization properties of different iron ores was determined as follows: magnetite > hematite > specularite > limonite.IntroductionThe mineralization property of iron ore plays a significant role in the mineral composition and microstructure of finished sinters, which determine the quality and output of the sinters [1-2]. The mineralization process of sinters is composed of solid-phase reaction, formation of liquid-phase and crystallization. The formation and crystallization of liquid-phase is the foundation to the mineralization as the quality of the sinter is poor when concreted by solid-phase consolidation [3-4]. With respect to the iron ore sintering, liquid-phase regarded as bonding phase is generated between the iron ores and fluxes at high temperature [5]. Calcium ferrite is the most favorable liquid-phase among the bonding phases which dominatingly contributes to the improvement of strength and reducibility of the finished sinters [6-8]. Especially for high iron-low silicon sintering and high basicity sintering, making sure sufficient calcium ferrite quantity and reasonable distribution is crucial to the sinters [9-10]. Therefore, carrying out the researches on the high temperature reaction properties of iron ores is of great significance [11]."

Jan 1, 2013