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By J. Zhai, Z. Yin

"The electrokinetic and flotation behaviors of ilmenite using lead ions as the activator and sodium oleate as the collector were studied. The results of microflotation show that the flotability of ilmenite can be improved by lead ions obviously. The isoelectric point of ilmenite increases from 5.32 to 7.7 after the addition of lead ions because of the adsorption of Pb2+ and Pb(OH)+. The results of zeta potential measurements and the collector adsorption density calculation show that the adsorption of sodium oleate on the ilmenite surface via chemisorptions in addition to electrostatic interactions. Besides, the adsorption density calculation results show that as the addition of lead ions as the activator, the adsorption amounts of collector are greater than those without activation which is in aggrement with the flotation behaviors. INTRODUCTION Ilmenite, as an oxide mineral of formula FeTiO3, is usually used as the main resource of the extraction of titanium (Bulatovic and Wyslouzil, 1999). There are many researches showing that the conventional methods, such as gravity separation, magnetic separation and flotation, do not work efficiently as expected (Mehdilo et al., 2015; Zhu et al., 2011). Nowadays, to produce ilmenite concentration feasibly and efficiently, these separation methods above are combined for a reason that the raw ilmenite ores are characteristic of poor, fine and complicated. Moreover, surface modification, such as surface dissolution method, microwave irradiation and oxidation roasting, is applied to improve the flotability of ilmenite currently (Welham and Llewellyn, 1998; Zhang and Ostrovski, 2002). Generally, fatty acid salts are used as the collector for the flotation of oxide minerals and sodium oleate is usually used as the collector for the flotation of imenite ores (Fuerstenau and Pradip, 2005). The mechanism, such as individual ion electrostatic adsorption, chemical adsorption, ion–molecule dimeric complex adsorption, and the coadsorption of ion and molecule, have not been discussed systematically using sodium oleate as the collector in the flotation of ilmenite (Somasundaran, 1983). Under the activation circumstance using the lead ion as the activator and sodium oleate as the collector, the interaction mechanism seems to be still unclear. In the present study, the interaction mechanism between ilmenite and sodium oleate using lead ion as the activator are studied by microflotation, zeta potential measurements and adsorption density calculation. EXPERIMENTAL Materials and reagents Pure ilmenite minerals were obtained from Panzhihua, Sichuan province, China. The minerals were ground in a porcelain mill with an agate ball. Following that, the prosucts were sieved, and the samples of -0.074+0.038 mm size fraction were used for the microflotation experiments. The results of XRF show that the content of titanium element is 30.58%, showing that the purity of ilmenite is above 90%. On the basis of the results of XRF, it is determined that the purity of ilmenite is very high and meets the needs of microflotation"

Jan 1, 2017

By B. Das

he flotation studies on hematite were carried out using di (2-ethylhexyl) Phosphoric acid (D2EHPA) as the collector. The possible mineral reagent interaction was studied through electrokinetic and dissolution studies. The shift in zeta potential (PZC) and decrease in dissolution of iron in the presence of D2EHPA indicated that D2EHPA was specifically adsorbed on hematite surface. The adsorption imparted necessary hydrophobicity for flotation of hematite. Hematite could be floated selectively from hematite and quartz synthetic mixture. Key words: Hematite, D2EHPA, flotation, electrokinetics, dissolution.

Jan 1, 2003

By C. Liu

Zeta potentials and settling rates of an oil sands tailings sample taken from Syncrude Canada Ltd's Aurora Stacker Pilot Operation were studied. Two clay minerals, kaolinite and illite, were also studied since these are the major constituent minerals in the fine oil sands tailings. Process water, decanted water as well as distilled water were used. It was observed that the zeta potentials of the tailings solids showed maximum negative values in process water at pH 8-10, which coincides with the pH of commercial hot water bitumen extraction process. The settling rates of the tailings sample were very low, at 0.008 m/hr in decanted water and 0.04 m/hr in process water. The rates were increased to 1.0 m/hr in decanted water and 0.13 m/hr in process water at an addition of 50 g/t Ciba AF1235. Although the settling rate was higher the supernatant was cloudier in decanted water than in process water. Further increase in the dosages of Ciba AF1235 did not increase the settling rates in decanted water but gradually increased it in process water, reaching 0.46 m/hr at 100 g/t. The results indicated that lower concentrations of Ca2+ and Mg2 (in decanted water) benefited settling rates but did not benefit supernatant clarity. Test results also indicated that Ciba AF1235 caused selective flocculation of the tailings sample, since the top sediments had higher illite and lower quartz contents than the bottom sediments.

Jan 1, 2006

By E. Kusaka, M. EL Salmawy

"The electrokinetic behavior of EL Maghara coal has been investigated in the presence of nonyl and octyl nonionic surfactants containing polyethoxy of different sizes with trade names of Triton-X100 (TX-100), Triton-X 705 (TX-705), Triton WR-1339 (TWR-1339) and Brij 58. The electrokinetic behavior was determined by zeta potential measurements. Zeta potential measurements were conducted by Laser-Doppler electrophoresis technique using zetamaster. The results show that the zeta potential of Egyptian coal varies with pH value, the hydrocarbon chain and number of ethoxy groups in the hydrophilic group of the surfactant. It was found that the polymeric surfactants reduce the negative values of zeta potential of coal. The shift of PZC of coal upon deashing appears to be closely relevant to silicate mineral removal."

Jan 1, 2014

By R. W. Smith

A number of investigators have studied the electrokinetic potential (?) of kaolinite as a function of pH. (1,2,3,4,5) These investigators all agree that the ? is negative except at quite acid pH values. The actual shapes of the curves reported by the several authors vary considerably. In spite of the general negative character of kaolinite the mineral has a rather high anion exchange capacity. (6,7,8) The cation exchange capacity is the lowest for the clay minerals. (6) It has been shown that anionic surfactants adsorb readily onto the mineral even up to neutrality, often in quantities exceeding the reported anion exchange capacity. (7,8) At least part of the anionic adsorption should be onto positive edge sites thought to exist on the mineral. (9,10) In the present study ? of kaolinite was measured as a function of pH using both the streaming potential (sp) and microelectrophoresis (m.e.p.) methods. In addition ? was measured at various pH values as functions of sodium dodecyl sulfate (SDS) and trimethyldodecylammonium chloride (TMDAC) concentrations. In some experiments decyl alcohol (DA) was added.

Jan 1, 1968

By David W. Cannon, Russell V. Mann

In a dispersion of particles in liquid a net charge will develop at the particle-liquid interface. This surface charge is usually due to the adsorption of charged material from solution. The existence of this surface charge gives rise to the formation of the electric double layer of counter-ions which surrond the charged particle. The particle surface charge and the electrostatic repulsion which exists between similarly charged particles is the primary stabilization mechanism for lyophobic colloids (1). The separation of charge which occurs at the particle-liquid interface gives rise to several dynamic phenomena associated with colloidal systems or with solid-liquid interfaces in general. These phenomena are known as electrokinetic phenomena and the four classic electrokinetic phenomena are; electrophoresis, electroosmosis, streaming potential, and sedimentation or Dorn potential. The actual driving force for electrokinetic phenomena is not the surface charge per se, but the charge at the interface between the liquid which is hydrodynamically bound to the particle surface and the bulk fluid. This interface is known as the slipping plane or the plane of shear and the potential at this interface is the zeta potential (2). The factors linking the electrokinetic phenomena is that they involve a relative motion between the liquid and the charged particle or solid surface and the driving force is the zeta potential of the solid. In addition to the four classic electrokinetic phenomena there are two additional electrokinetic effects in disperse systems; the electro-acoustic effects. When an alternating electric field is applied to a cooloidal dispersion the particles will move in the field due to their net zeta potential. If there is a density difference between the particles and the fluid this motion will result in the development of an acoustic wave. The effect was discovered at Matec and has been termed the Electrokinetic Sonic Amplitude or ESA (3). ESA is the pressure amplitude generated by the colloid per unit applied electric field strength and has SI units of pascals per volt per meter. When an alternating pressure field (acoustic wave) is applied to a colloidal dispersion the inverse of the ESA effects occurs. A density difference between the disperse phase and the continuous phase leads to a relative motion between the particles and the surrounding liquid. This means that there will be a periodic displacement between the charged particle and the oppositely charged counter-ions in the electric double year. This displacement results in the development of an alternating dipole moment at the frequency of the applied field. This effect is termed the Ultrasonic Vibration Potential or UVP and was first predicted for electrolyte solutions by Debye in 1933 (4). UVP is measured in units of volts per unit velocity amplitude of the applied acoustic field or volts per meter per second. In 1938, Rutgers (5) and Hermans (6) pointed out that the effect would also be present in colloidal dispersions. A detailed theory for UVP effects in colloids, also called CVP, was first presented by Enderby in 1951 (7). Extensive studies of the UVP in electrolytes have been carried out by Yeager et al (8). Recently, O'Brien (9) has developed a general theoretical treatment of electro- acoustic effects in colloids and has derived a reciprocal relation linking ESA and CVP effects. The most commonly studied electrokinetic phenomena is electrophoresis. Electrophoresis is the movement of charges particles in an applied electric field. The velocity of the particle divided by the applied electric field strength is the electrophoretic mobility of the particle. The zeta potential can be calculated from this mobility (2). The magnitude of both the ESA and CVP effects are directly proportional to the electrophoretic mobility of the particles. The mobility determined by the two electro-acoustic effects is the dynamic or AC mobility of the particles.

Jan 1, 1990

By J. P. McKinney

A mathematical model is presented for the electrokinetic dewatering of suspensions of phosphatic clays. The modeling approach couples a boundary-element model for solution of Laplace?s equation to a recently developed constitutive equation that relates the change in solids content with applied electric field and time. The observation that the electric field controls both the maximum solids content achievable and the time required to reach that value is shown to severely constrain the application of electrokinetic dewatering strategies to an entire clay settling area. The approach, however, may be feasible for implementation as part of a continuous plant process.

Jan 1, 2011

By Julie Q. Shang

The electrokinetic (EK) technology for dewatering of two tailings from the uranium mines in Northern Saskatchewan is studied in bench scale experiments. The study includes four phases: 1. Characterization of two uranium mine tailings; 2. Assessment of voltage loss on the coated Ti anode and water interface. 3. EK cell test series to measure electrokinetic permeability (ke) of two tailings; 4. EK dewatering test series to study electrokinetic enhanced gravity dewatering on two tailings samples. The results have demonstrated that both tailings responded positively to the EK process. For the tailings containing gypsum, the EK dewatering should be a short term process (within one hour) with anode conditioning (pH adjustment). The tailings containing clay minerals responded well to EK dewatering, in which pH adjustment is optional and will further enhance the EK flow. Both tailings as tested have low hydraulic conductivity and are particularly suitable for EK dewatering and consolidation.

Aug 1, 2010

By Wright D. J

Successful heap leaching depends on three major factors: 1. Chemical conditions appropriate for the dissolution of the valuable metal; 2. Contact between the leach solution and the valuable metal particles; and 3. Movement of the leach solution through, and out of, the heap. Given that appropriate chemical conditions can be provided, and the individual particles have sufficient permeability to allow solute/solvent contact, the problem of getting the solution to and from the particles remains. Non-uniform percolation of solution throughout the heap, caused by the presence of fines, is a common problem which occurs, to some extent, with all heap leachable ore. The conventional solution to this problem is agglomeration, which involves the attachment of fine particles to larger particles, effectively modifying the size distribution by preventing the fine particles from acting on their own. While agglomeration must be considered as an extremely effective technique with virtually no limit to its application from a technical point of view, its application is limited by economic considerations. A new technique has been developed which is not only a low cost alternative to agglomeration, but also has the potential for enabling the application of low cost heap and vat leach techniques to a significantly wider range of ores than current practice would suggest. The new technique, known as Electrokinetic Leaching, utilises electro-osmotic flow to enhance percolation through the heap. This paper describes and presents results of the laboratory testing, pilot heap operation and commercial application of Electrokinetic Leaching of a low grade gold ore and a tailings deposit. Comparative cost analyses between conventional and the alternative processing techniques are presented.

Jan 1, 1994

By David Wright, Colin Burns

Successful leaching of gold depends on appropriate chemical conditions; contact between leach solution and the gold particles; separation of the leach solution from the solids and extraction of the valuable ion from the solution. Irrespective of the leaching method employed the chemical conditions required are similar as is the dependence of solu­tion/gold contact on liberation. The various leaching methods available vary in the means by which gold/solution contact and solid/liquid separation are achieved. The essential difference between heap or vat leaching techniques and those involving agitation of a slurry is dependence on percolation for effective gold/solution contact. The most significant factor preventing uniform percolation is the presence of fines or clays. The quantity and character of the fines fraction is ore type dependent and may result from crushing, degradation during stacking or leaching, or the natural size distribution of the ore. The problems associated with fines can be aggravated during stacking and preparation of the heap. Segregation during stacking can result in concentration of fine particles at the centre of heaps. Further concentration of fines may also occur during irrigation by the movement of the fine particles with the solution. The end result is that the areas in which fines are concentrated become areas of low permeability. The contact between leach solution and the ore in such areas is, at best, slowed down dramatically and, in some cases, prevented altogether. The consequences of this phenomena are slow leaching and a reduction in recovery. The conventional solution to this problem is well known. Agglomeration of ore prior to heap leaching is practised widely. The effect of agglomeration is to immobilise the fines by causing them to adhere either to each other or to larger ore particles. The net effect is that the ore behaves as if no fines were present. The use of agglomeration is limited only by its cost, the most significant components of which are the cost of binding agent, commonly cement, and the capital cost of the agglomerating equipment.

Jan 1, 1995

By S. W. Ihle, L. J. Warren

A sample of garnet from the scheelite ore body on King Island, Tasmania, Australia, was upgraded and ground to produce an ultrafine portion suitable for micro-electrophoresis. X-ray and chemical analysis identified the garnet as andradite with some admixed grossular. At neutral pH the garnet particles were negatively charged, their zeta potential becoming rapidly more negative with increasing pH. An iso-electric point was found at pH 3.5. The effects on the zeta-potential of various electrolytes, hydrolyzable metal ions, and flotation collectors were also studied.

Jan 1, 1976

By Healy T. W, Dixon D. R

The present study 'of pure ZnS and NiS and ZnS (marmatite) by detailed electrokinetic methods has shown that by careful control of experimental parameters much new' information on sulphide-water interfaces can be obtained. Time-dependent processes of alteration of sulphide surfaces are foHowed by electrokinetic methods and indicate that the isoelectric point of the surface depends on elemental sulphur coverage, oxidation product coverage, and the conditions which promote or minimize such reaotions in the presence and absence of activator.

Jan 1, 1977

By W. Wilmans

Electrokinetic dewatering of kimberlite slime under constant direct curents of 0,5 to 2 A and dewatering under constant applied potentia Is of 16,5 to 46,5 V are considered. The combined efects of electrophoresis and the addition of 8,3 x 10-3 M Mg2+ ions on the one hand, and 1 to 10 p.p.m. of the anionic polyacrylamide flocculant Praestol 2935 on the other, were investigated in a 3-litre Perspex electrophoretic cel. .The electro-osmotic dewatering experiments were conducted in a 3-litre Perspex electro-osmotic cel at various electrode spacings, as well as with a moving anode (top electrode). During electrophoretic dewatering, the zeta potential of the kimberlite particles did not change significantly, whereas the pH and temperature showed marked increases with time. The addition of Praestol 2935 enhanced the setling of the sludge bed owing to the additional effect of flocculation. The addition of electrolyte Mg (CIO4)2 retarded the separation process, partly as a result of gel formation in the slurry. During the electro-osmotic experiments, the rate of dewatering was found to be approximately proportional to the applied constant direct current, and to be independent of the electrode spacing. In general, electro-osmotic dewatering seemed to be more energy-efficient than electrophoretic dewatering.

Jan 1, 1987

By I-Min Lu

An electric field was applied to a metal-bearing kaolinite specimen to investigate the efficiency of electro-osmosis in removing heavy metals from contaminated soils. The electric field induces a flow of water through the porous medium, called electro-osmosis, which is superimposed on the hydraulic flow. Because the electro-osmotic flow is relatively stronger in smaller pores, it can enhance the displacement of contaminated solution by fluid convection. Furthermore local changes in pH caused by the electrode reactions can affect adsorption equilibria and the distribution of solutes between the solution and the solid surfaces. The electro-osmosis experiments were conducted by applying either a constant current or a constant voltage across 8-cm inside diameter, 25 to 30-cm long specimens of kaolinite clay with graphite electrodes. Samples of the pore fluid and of the clay were analyzed to determine metal content, pH, and conductivity as functions of time and position. Results show that removal of heavy metals from soil can be accomplished effectively by electrokinetic treatment of sufficient duration. Approximately 95% of the lead was removed after 189 days.

Jan 1, 1996

By Thomas W. Chapman, Shi-Chern Yen, I-Min Lu

"An electric field was applied to a metal-bearing kaolinite specimen to investigate the efficiency of electro-osmosis in removing heavy metals from contaminated soils. The electric field induces a flow of water through the porous medium, called electro-osmosis, which is superimposed on the hydraulic flow. Because the electro-osmotic flow is relatively stronger in smaller pores, it can enhance the displacement of contaminated solution by fluid convection. Furthermore, local changes in pH caused by the electrode reactions can affect adsorption equilibria and the distribution of solutes between the solution and the solid surfaces.The electro-osmosis experiments were conducted by applying either a constant current or a constant voltage across 8-cm inside diameter, 25 to 30-cm long specimens of kaolinite clay with graphite electrodes. Samples of the pore fluid and of the clay were analyzed to determine metal content, pH, and conductivity as functions of time and position. Results show that removal of heavy metals from soil can be accomplished effectively by electrokinetic treatment of sufficient duration. Approximately 95% of the lead was removed after 189 days.IntroductionRemediation of soils contaminated with toxic chemicals is a difficult and expensive task. Washing or leaching are not particularly effective if the contaminate is sequestered in small pores; hydraulic flows of water pass through larger pores leaving the smaller pores relatively untouched. Electro-osmosis appears to be the most promising new technology for removing heavy metals and organic substances from contaminated soils (Segal, 1980; Hamed et al., 1991, Masliyah, 1994).Electro-osmosis is one of several electrokinetic phenomena that occur through the interactions among an electric field, fluid motion, solute adsorption, and the existence of a net charge on a solid-fluid interface (Newman, 1991, Masliyah, 1994). Electro-osmosis refers to the fluid flow in a porous medium that results when an electric field acts on the mobile region of the electrical double layer, the solution-side region of charge separation that exists at the pore walls."

Jan 1, 1996

By Tasuma Suzuki

Electrokinetic/permeable reactive barrier system is a promising in situ soil and ground water remediation technique to reduce toxic NO3- into less toxic NH4+. Using granular zero-valent iron (Fe0) as a reductant, the first objective of this study was to investigate the influence of the solid-liquid ratio and aqueouspHon NO3- reduction. The results obtained from a series of batch experiments showed that NO3- reduction was enhanced by either increasing solid-liquid ratio or decreasing aqueous pH. Based on insights obtained from batch experiments, the second objective of this study was set to design the remediation conditions of the electrokinetic/Fe0permeable reactive barrier system to maximize the NO3- reduction efficiency. Experimental results showed that the effectiveness of the system strongly depended on the Fe0 percentage in the reactive barrier, the pH in the anode reservoir, and the applied voltage, which were consistent with the results obtained from batch experiments. Under optimized treatment conditions, nearly 100 % NO3-was reduced into NH4+ in the permeable reactive barrier and collected in the cathode reservoir. Insights obtained from this study provided fundamental information on roles each of remediation design parameters plays, and will be useful to optimize the remediation conditions. Keywords: electrokinetic remediation, permeable reactive barrier, zero-valent iron, nitrate

Sep 1, 2012

By P. K. Rozakeas

It has been experimentally demonstrated that the application of electrokinetic techniques in the continuous flow of coal-water suspensions within a helical anode-cathode pipe geometry effectively causes a significant reduction in the wall shear stress. This reduction in the frictional force at the cathodic pipe wall surface is attributed to a decrease in the concentration of coal particles in this flow region caused by the migration of negatively charged coal particles towards the anodic surface(s). The disadvantage of flow-intrusive geometries is the reduction in effective flow area as well as an increase in frictional surface area caused by the placement of the anode(s) within the flow region. Experimental data is presented for a non-intrusive helical anode-cathode geometry embedded in the pipe wall which shows that a reduction in pumping energy of approximately an order of magnitude is possible. A sample of sub-bituminous black coal fines having a mean particle size of approximately 17 microns was used to prepare coal-water suspensions with a solids concentration of 50%(w/w). The practical and economic implications of this work relate to an enhanced method of long distance transportation of slurries in pipes as well as an alternative technique for continuously separating solid-liquid suspensions.

Jan 1, 2014

Quickly and cheaply consolidate underground slimes to facilitate their use as backfill and permit their easy handling for other reasons. Approach: The slurry containing slimes is pumped into active stopes and electrokinetically dewatered to provide consolidated back fill. How It Works: To densify slimes electro-kinetically two electrodes are placed in the material to be dewatered and densified. Typically, the electrodes are pieces of wire mesh fencing. One is placed on the bottom, and the other is suspended in the slurry near the surface. Figure 1 is a simplified section of a test. A d-c voltage of 100 to 400 volts is applied across the slurry. This causes the solid particles which are in suspension in the water (usually these are negatively charged) to migrate toward the anode; simultaneously, the water moves toward the cathode. Water immediately adjacent to the negatively charged solid particle surfaces contains an excess of dissolved positive ions. When these ions are attracted to the electrode and move towards it, they also exert

Jan 1, 1976

By F. J. Tavera

A study on the electro kinetics of lead carbonate, silica, and alumina, in aqueous media was carried out at different pH values. The behavior of potential was determined for these species in the pH range between 3 and 12. Homocoagulation of lead carbonate in aqueous media is analyzed at its isoelectrical point. Lead carbonate heterocoagulation is analyzed with silica, alumina, and silica ? alumina mixtures at low pH values. The experimental results are considered for their possible application to treat residual water polluted with lead.

Jan 1, 2006

By G. A. Nyamekye

Two major Inco matte constituents, chalcocite and heazlewoodite, are separated by differential flotation with diphenylguanidine as collector. A new reagent system involving the use of dextrin as a modifying agent which provides better selectivity has been studied for the last three years. Adsorption tests reveal that while dextrin exhibits high affinity towards heazlewoodite, the adsorption isotherm for dextrin on chalcocite shows only weak interactions. Our electrokinetic measurements confirm such conclusions. Since dextrin interaction with solid surfaces seems to be especially strong when such surfaces are covered by hydroxide layer, our electrokinetic measurements are in line with other researchers' findings who postulated that copper hydroxide is not a stable product on the surface of copper sulphides.

Jan 1, 1992