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By S. R. Stopic

The EU-financed INTREAT Project (Integrated treatment of industrial wastes to¬wards prevention of regional water resources contamination) addresses the environmental pollution associated with solid and liquid wastes/effluents produced by complex sulphide ore mining and metallurgical activities. The results concerning the electrolytic recovery of cop¬per from effluents formed after mixing of streams from Copper Refining, Precious Metals Plant and Electrolyte Regeneration in the Balkan Area will be shown. The waste water is characterized by low pH values and high contents of heavy metals, such as Cu, Ni, Bi, As, Sb. The majority of these waste water flow untreated into the natural water streams and through the network of existing rivers, which end up in the river Danube. The influence of current density and flow rate on the deposition rate, the quality of copper and the process efficiency will be presented. The full continuous process is based on cells with rotating disc cathodes and represents a pre-treatment step before common neutralisation in a cascade line

Jan 1, 2007

By N. J. Bunce, B. Vollick, A. F. Souza, D. Bejan, P. Maharaj, C. Shamshoom

"Copper electrodeposition from synthetic and authentic acid mine drainage (AMD) is inhibited by ferric iron (Fe(III)), through re-oxidation of copper. Polarization to –2.5 V versus standard hydrogen electrode prevents the dissolution of predeposited copper from the cathode. Above pH 1, copper deposition is independent of Fe(III) concentration to approximately 25 g/L. Fe(III) is reduced to ferrous iron (Fe(II)), with a high combined current efficiency for iron and copper reduction. In a divided cell, the conversion of Fe(III) to Fe(II) is almost quantitative, with efficient transfer of acidity from catholyte to anolyte. Prospects for developing electrochemical technology for complete remediation of AMD are discussed.RÉSUMÉ En raison de la réoxydation du cuivre, le fer ferrique (Fe(III)) nuit à l’électrodéposition du cuivre à partir de drainage minier acide (DMA) véritable et synthétique. Une polarisation à -2,5 V par rapport à l’électrode standard d’hydrogène empêche la dissolution du cuivre déjà déposé de la cathode. À un pH supérieur à 1, la déposition du cuivre est indépendante de la concentration en Fe(III) jusqu’à environ 25 g/L. Le fer ferrique est réduit en fer ferreux (Fe(II)) avec une efficacité combinée élevée pour la réduction du fer et du cuivre. Dans une cellule divisée, la conversion de Fe(III) en Fe(II) est près de la quantité théorique, avec un transfert efficient de l’acidité de catholyte à anolyte. Les perspectives de développement d’une technologie électrochimique pour la remédiation complète du DMA sont discutées."

Jan 1, 2016

By C. A. Hansen

INTRODUCTION It has been the experience of the writer, during some. five years' work with electrolytic zinc, that the zinc cell is perhaps more- sensitive to impurities in the electrolyte than the analytical methods as yet developed for the chemical identification and determination of these impurities; but that, when proper purification methods have been applied to a given solution, the behavior of the cell is quite independent of the original sources from which the zinc sulphate has been derived. It has also appeared that the behavior of the zinc cell is the best and surest check on the correctness and thoroughness of the purification methods used, because it indicates the presence of both current impurities. and cumulative impurities derived from the leaching of the ore; it also in

Jan 3, 1918

By C. A. Hansen

ROASTING FERRUGINOUS ZINC-SULFIDE ORES IN 1912, Mr. J. B. Ideating was developing an electrolytic-zinc process for application to the ores of the Bully Hill mines of the General Electric Co. These ores consist of blende and pyrite so finely crystallized and so intimately mixed that no mechanical separation of the individual minerals had been found possible. The ore was reduced to about 60 mesh and roasted in a hand-rabbled reverberatory furnace preparatory to leaching with sulfuric acid. The extractions obtained were quite irregular, varying from a minimum of about 70 per cent. to a maximum of about 90 per cent. This irregularity led to the construction of a small electrically heated roasting furnace, and to the study of roasting under definitely controllable conditions. From time to time, these studies have been extended to other ores. Several commercial-plant operators profess to have gained useful information from the results of these studies and it is hoped that their usefulness may be extended by this publication. EXPERIMENTAL ELECTRIC ROASTING FURNACE The furnace used for experimental work is shown in Fig. 1. One fire-clay sagger, or pot, was set within another and the space between the two filled with Silox heat insulation. The hearth is a cast-iron plate with an imbedded ribbon of nichrome wire; this wire heater is connected to a potential regulator, which permits a very close voltage control. A mechanically driven arm is fitted with rabble blades so arranged that a uniformly thick ore bed may be maintained indefinitely. This arm is usually driven at about one revolution per minute but its speed of rotation can be varied as desired. Compressed air is led into the furnace through a meter, and it was found necessary to preheat the air in order to secure the definitely isothermal conditions sought.

Jan 8, 1919

C. A. HANSEN (communicated appendix*).-Since the above paper was written, tests have been conducted with a view to securing a sounder basis for discussing the effects of temperature on the behavior of the zinc cell. The following data, while making no pretense to great accuracy, are still reasonably close. Cells were operated with the same feed solutions, but at varying temperatures, the latter being controlled by means of immersed steam coils. Current efficiencies obtained indicate that the corrosion rate

Jan 11, 1918

By U. C. Tainton

The paper reviews the evolution of electrolytic zinc, describing some of the major obstacles that have been encountered and overcome. The chief remaining limitations of present-day standard practice are: Difficulty of obtaining high extractions, especially from low-grade and complex ores; filtration troubles, if ores contain much soluble silica; and irregularities in electrolysis, if more than certain limited amounts of antimony, arsenic, cobalt; etc., are present in the ores. These factors dictate a relatively high-grade plant feed, thus subjecting the electroytic-zinc process to the same kind of limitations as the zinc smelter. The "high acid process," in which both acid strength and current density are raised to about four times the usual figures, is described. This system concentrates both plant and operations, allows a simple type of flow sheet, and. minimizes some of the difficulties above mentioned. The large-scale operation of the process is described. SOME time ago, at a meeting of the Institute Prof. J. W. Richards1 said, "I take exception to the statement that all the factors in the production of electrolytic zinc were known long ago. There is possible in my opinion an improvement of perhaps 50 per cent. in the new electrolytic processes." An examination of the literature of the subject will show the justness of Professor Richards' contention. The work of the earlier investigators was carried on in the shadow of difficulties that, today, are hardly more than memories. We seldom hear now of zinc sponge, that bête noir of the electrolytic-zinc pioneers. Zinc sponge, was the name given to a peculiar, soft, black, non-adherent form of zinc deposit that was utterly useless for melting into ingot form. At the big plant at Cockle Creek, New South Wales, in 1897, Edgar Ashcroft2 said that the solution in the plant would suddenly, and without ascertainable cause, go "bad" and begin to deposit spongy zinc. The most delicate, even spectroscopic, methods of analysis were unable to detect any difference between "good solution and "bad" solution; either form might change to the other on being kept for a while. When it is added that an outbreak of this insidious disease (which. appeared to

Jan 2, 1924

By W. H. Hannay

Introduction The subject matter of this paper will be treated under two heads: (1) experimental work and the development of the purification system, and (2) the operation of the commercial plant. During 1927-28, a two-ton slag-retreating plant was in operation at the smelter for experimental purposes. Details of this operation and of the commercial plant are presented in a paper by G. E. Murray, read before the Annual General Meeting of the Institute in April, 1933 (1). A point which has considerable bearing on the subject of the present paper, and which was not emphasized by Mr. Murray, is the concentration of volatile impurities in the zinc oxide fume produced. The result of the operation of the slag fuming furnace is largely to confine in a closed circuit all the minor constituents of the Sullivan concentrates, both lead and zinc. They pass into the feed of the zinc fuming furnace, with the result that all impurities which volatilize-such as arsenic, antimony, tin, fluorine, etc.-report in the zinc oxide product. The accompanying condensed flow-sheet (Figure 1) will illustrate this. The only outlet for impurities which is not shown is the small tonnage which passes the Cottrell plants. The flow-sheet would indicate the possibility of building up a prohibitive concentration of cathodic impurities in the oxide leaching plant feed. However, after three years' continuous operation this has not occurred. Should this condition arise at some future date, discard of some tonnage of blast furnace slag is indicated. In Mr. Murray's paper, the much greater flexibility of blast furnace operation, due to the slag fuming furnace, is stressed, particularly as to the lead content of the slag. The requirements of our lead refinery call for a bullion containing about 0.70 percent antimony.

Jan 1, 1934

By George Steintveit

Det Norske Zinkicompani A/S was established in 1924, on the initiative of the Compagnie Royale Asturienne des Mines. Experimental electrothermic zinc production was carried out on industrial scale for a two-year period, but the problems of electrothermic smelting were not solved. A license for the electrolytic zinc production process was then obtained from the Anaconda Copper Mining Co. A plant for electrolytic zinc production was built, near the small fjord town of Odda in Hardanger, West Norway, The production was based on zinc ore from Spain, and cheap local hydro-electric power. The plant came into operation in 1929. Annual capacity, 36,000 tons. In 1964 a long-term agreement was concluded with Boliden AB by which Det Norske Zinkkompani is secured the raw materials basis for an expansion of the annual capacity to 100,000 tons of zinc, Since World War II, the company has been pursuing extensive research and development programs. As a result, various sections have been rebuilt: nev unloading and storage facilities, a 250 ton per day Fluid Bed Roaster with contact plant, new continuous leaching system, integrating the Jarosite Residue Process, new solution purification section - upgrading the solution quality for a 600 Amp/m2 current density Tank Room operation -, installation of induction furnaces for cathode melting with casting machines and automatic stacking of slabs. Simultaneously, instrumentation, and methods of automatic control have been developed and introduced, providing conditions for optimal plant operations.

Jan 1, 1970

By O. H. Banes

The electrolytic zinc plant of the American Zinc Company located at Sauget, Illinois started operations in April 1941. The plant had a designed capacity of 45(T) per day. The original flow sheet was quite simple, incorporating the low density process. Through the years the capacity of the plant has been increased to the current design of 214(T) cathodes per day. This paper describes the current operation along with typical metallurgical data.

Jan 1, 1970

By Frederick Laist

ABOUT six years ago the Anaconda Copper Mining Co. decided to investigate the possibility of extracting zinc from the ores of certain mines in the Butte district. These ores are of a complex character and contain so much iron and lead that the concentrate contains only 33 to 35 per cent. zinc. Investigations showed that while a high-grade concentrate could not be obtained by ordinary methods, such as tabling and magnetic treatment, a fair grade could be made by the Horwood process. In this method, the concentrate resulting from the flotation of all of the sulfides is given a light roast and this calcine is subjected to flotation in the presence of a large amount of sulfuric acid; the resulting concentrate contains most of the zinc and a residue contains most of the iron. The fact that the lead, copper, and silver are divided approximately equally between the zinc concentrate and the iron residue and the large consumption of acid, which ranged from 50 to 100 lb. (22 to 45 kg.) per ton of concentrates, were serious objections to this plan. The zinc recovery, moreover, was low, as a considerable percentage invariably accompanied the iron. While a profit might be made on the ores by the use of this process, it was thought that other and more promising methods might be devised. After carefully studying the field and doing some laboratory work on various processes that had been suggested, it was decided that the electrolysis of sulfate solutions was the most promising. We soon found, as have other investigators, that the only way to obtain a good zinc deposit is to have the electrolyte free from all metals more electro-negative than zinc, such as copper, cadmium, lead, arsenic, antimony, etc. Arsenic and antimony are particularly injurious, causing very poor current efficiency and small yield per horsepower when present in amounts so small as almost to defy detection-1 mg. or less per liter.

Jan 10, 1920

By Martin JD, McNicol JH

The electrolytic zinc plant at Port Pirie South Australia, was designed and constructed to treat zinc oxide fume recovered by treatment of lead blast furnace slag in two fuming furnaces, The plant was commissioned in late 1967. The equipment installed and the oper- ating procedures adopted,'are described in some detail.

Jan 1, 1975

By M. Olper, M. Maccagni

"The crude zinc oxides (CZO) produced in any thennal process dealing with EAF dust also contain lead, cadmium, and a considerable amount of halides (chlorides and fluorides). The high halide contents make these crude zinc oxides less and less attractive, both technically and economically, and a further refining procedure is nece'ssary to meet the zinc and zinc oxide market requirements.Hydrometallurgical techniques commercially used to dehalogenate the crude zinc oxides are not effective enough to upgrade the crude zinc oxides to the required specification for their direct use in the traditional sulphuric electrolysis by primary zinc producers.The EZINEX® PROCESS has solved the problem of the halides contained in the crude zinc oxides. This process is the only proven technology electrowinning zinc from a chloridebased electrolyte in a conventional cell house. This paper discusses the process economics taking the data from feasibility studies of different size commercial plants."

Jan 1, 2000

By P. A. Treasure

The EMEW® cell has been developed to overcome a number of inherent limitations in conventional electrowinning technology, particularly the high cost and restricted process windows characteristic of conventional hardware. The technology has been widely demonstrated to achieve high performance for various metals under chemical conditions well outside the limits required for efficient operation of conventional cells. This process flexibility offers significant opportunities for cost savings. in recovery of zinc from primary and secondary sources. The EMEW® technology is now available on a fully engineered basis, as a versatile commercial alternative to conventional electrowinning hardware. Application of the EMEW® cell for recovery of secondary zinc material offers significant advantages to the recycling industry. For example, a selective caustic leach can be used where there are high levels of iron or other contaminants in the target material. The reagent requirement is minimal as most of the caustic is regenerated in the bell and zinc dust that may be required for electrolyte purification is produced in the cell. A high purity zinc powder or cathode is produced in the cell. In the case of acidic zinc electrolytes, the cell is capable of operating over a much wider range of operating conditions than a conventional cell.

Jan 1, 2000

J. L. McK. YARDLEY,* Pittsburgh, Pa. (written dlscussion ?) .-It is interesting to observe how closely Mr. Hansen agrees with other investigators to the effect that the art of electrolytic zinc has left the realm of mystery. In his introduction, lie has said practically what Thomas French said in his paper "The Future of Electrolytic Zinc. "1 The successful electrolysis of zinc from sulphate solutions has not been an easy matter, and it is only within recent years that the difficult problem of depositing high-grade zinc has been satisfactorily: accomplished on a commercial basis. The principal requisite is. that the electrolyte shall be quite free from certain impurities. The methods by which freedom from these impurities is assured are now very well understood, and with experienced superintendents there is little difficulty in obtaining a high efficiency in that part of the process. When certain underlying principles are recognized, the difficulty encountered in dealing with the filtration of the acid and slimy solutions also largely disappears, although it has been a very serious one to the uninitiated. In the dissolving of the zinc from the roasted ore, there is nothing which any competent chemical' engineer cannot undertake, and any other operations connected with the electrolytic process are either of little or no difficulty, or are common to the retort process. Mr. Hansen also agrees with R. G. Hall's statement in " Some Economic Factors in the Production of Electrolytic Zinc:"2

Jan 10, 1918

By I. Chatterjee, M. Misra

The principle of microwave drying of fine coal is based on the selective absorption of microwaves by water. Coal is a poor absorber of microwaves. As a result, water can be removed from fine coal by selectively heating water molecules. One of the difficult problems during microwave heating is the exact determination of temperature in the core of the materials. The electromagnetic energy absorption in coal/water mixtures during microwave drying is controlled by several factors including the dielectric properties of the constituents. In this paper, electromagnetic and thermal models of coal are presented that can predict the energy absorption and temperature distribution during microwave drying.

Jan 1, 1992

By David G. Paton

"Electromagnetic surveys were conducted at the BXL Bulk Explosives Limited Mixing Plant andsurrounding area to characterize runoff from the site and possible impacts of salinity. The BXL Plant is located at the edge of a depressional area and any escape of soluble ions, such as nitrates, would have ended up in the slough to the west of the plant. Two electromagnetic (EM) instruments were used in the survey. A Geonics EM 3 1 was used in October 1997 and in June 1998, a new multifrequency instrument, a GSSI GEM 300 was also tested. Both instruments were individually mounted on a plastic sled with Teflon runners and towed with an ATV quad. Position was determined using a Trimble Pro XL global positioning system (GPS) with a real time correction mode Landstar receiver for an accuracy of about *l m. Both GPS and EM instruments were set to collect data at 1 second intervals. The quadrature maps for both instruments showed essentially the same information, namely of very high conductivity, appearing to emanate from the mixing plant. The levels of conductivity were highest where the saline water appeared to pool, at the southern end of the slough. Soil sampling locations were identified from the EM maps and navigated to using the real time GPS. Composite samples were collected by hand using a Dutch auger, from two locations, in increments of O-1 5, 15-30, 30-60 and 60- 90 cm. The analysis of the soil samples indicated a complete absence of nitrate or ammonium ions; the major anion was sulphate, indicating naturally saline subsoil conditions. The GEM 300 made the collection of data more efficient, as only one pass was required to collect the data from four depth intervals. The EM survey combined with the real time GPS allowed rapid characterization of the site with respect to soil salinity and proved to be cost-effective for Phase l/ Phase 2 site assessments and targeting sampling locations."

Jan 1, 1999

By J. Durkin

The Bureau of Mines has conducted field studies in coal mines throughout the United States to determine the effectiveness of electromagnetic techniques in locating miners trapped underground following a mine accident. Data from these tests have been used to generate models of expected signal and noise distributions as found above these mines. These distributions have aided in placing the expected performance of a through-the-earth electromagnetic communications technique into a probabilistic framework. Results show that at a 10% false-alarm rate, the expected probability o detecting a miner's signal" from a depth of 1000 ft is 54% at 500 ft it is 95%. These depths exceed the actual depths of 90 and 50%, respectively, of United States coal mines. Sensitivity studies have shown that at depth of 1000 ft, the probability of detection will improve approximately 2% for each dB of increase in signal-to-noise (SNR) ratio.

By A. J. Farstad, R. G. Olsen

The Coal Mine Health and Safety Act of 1969, passed by Congress in the wake of the disaster at Farmington, West Virginia, led to an extensive study by the National Academy of Engineering of the problems involved in coal mine safety. One of the results of this report and subsequent research conducted by the U. S. Bureau of Mines has been the investigation of electromagnetic techniques for the location of trapped miners after a mine emergency. The Westinghouse Georesearch Laboratory has been involved in both the 2 theoretical and field studies relating to this problem. A compact personal beacon transmitter has been developed which can be attached to and powered by a miner's lamp battery. A compatible lightweight loop antenna package has also been developed which can be easily carried on a miner's belt. This antenna can be quickly deployed on the mine tunnel floor. For the purpose of calculating its electromagnetic fields on the earth's surface, the loop can be considered to be a magnetic dipole buried in the earth. (The earth is assumed to be homogeneous and to have a conductivity of s mhos/m.) The surface of the earth is assumed to be uniformily sloping and the transmitter dipole oriented as in Figure 1. The fields on the earth's surface can be computed by using a superposition of the fields of a 4 vertical magnetic dipole3 and of a horizontal magnetic dipole in proportions which depend on the slope of the terrain. In the case of level terrain a null in the horizontal magnetic 5 field occurs on the surface directly above the dipole. This null is designated as the apparent source location and is the criterion by which the source is located. The criterion was tested at two hardrock mines and two coal mines in the fall of 1972. The apparent source locations were compared to actual locations determined by conventional surveying techniques. It was found that due to nonlevel terrain the apparent and actual source locations differed by up to 13 meters. This discrepancy can be resolved by an examination of the fields of a source beneath uniformly sloping terrain. Figure 2 shows the experimental and theoretical results for a

Jan 1, 1973

By L. Yan, B. Lambie, J. Srednicki, J. Carr

Electromagnetic emissions from electrical devices may interfere with electronic safety systems or other devices in the mining environment. This electromagnetic interference (EMI) may cause unwanted changes in the performance of the affected devices and may cause safety issues for miners. To minimize the risk of EMI, the National Institute for Occupational Safety and Health (NIOSH) has conducted research quantifying the electromagnetic emissions of several types of equipment that might be used in the mining environment. Previous research has shown that welding arcs can give off ultraviolet (UV) emissions, visible light, and infrared (IR) emissions that can cause health problem on skin and eyes. In this study, the electromagnetic emissions of the shielded metal arc welding (SMAW) process were monitored and measured. Several factors including operating mode (AC, DC positive or DC+, DC negative or DC-), current setting (low, medium, high, maximum), and electrode type were investigated to compare their effect on emission level. The test shows that the emission level from the welding process can be affected by those factors. The test data also shows that, among those factors, the operating mode has more influence on emission level than do current setting and electrode type. The information in this paper can be useful for the mining industry to better understand the emission in the 9-kHz to 500-MHz frequency range from a SMAW welder.

Feb 1, 2023

By D. A. Hill

Introduction The fields of an infinite line source in the presence of a conducting half-space have been examined by Wait and Spies (1971). In any real communication link using a current-carrying cable for the transmitting antenna, the cable is of finite length. Here we examine the fields of a finite length cable carrying a constant current in the presence of a homogeneous conducting half-space. The constant current assumption is valid at sufficiently low frequencies when an insulated cable is grounded at the end points (Wait, 1952; Sunde, 1968). Here we examine both surface and buried cables since both downlink and uplink communication links are of interest. Also, we examine both frequency and time solutions since either CW or pulsed communications may be used. Finally, it is necessary to include both magnetic and electric field solutions since reception could be with either loops or dipoles. Since the finite cable solution is more complicated than both the infinite line source and the short dipole solutions, we explore under what conditions a cable appears to be either infinitely long or very short. Some special cases, such as- the low frequency limit, permit analytical solutions which exhibit the dependence on various parameters, such as cable length, quite clearly. Frequency Domain Subsurface Fields The geometry of a line source of length 2[l] located on a conducting half-space with the observer in the half-space is shown in Figure 1. The fields

Jan 1, 1973