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By Donald M. Liddell

ALTHOUGH the midday lunches of business associations have been re-echoing the phrases that re- search would lead us out of the depression and that the last place to economize is on research, nevertheless most executives apparently concluded that it was their neighbor who ought not to economize in research, and that in their own plants what had been discovered in 1929-30 was sufficient to lead them out of the wilderness. At any rate, I have discovered much less that seems worth noting, and compared with 1931, the report volume of the committee members is off about 40 per cent, and compared with 1929, about 80 per cent. Evidently there is some hookup with the +tee1 industry as to output, and the Report Reading Committee should investigate this and the relative use of commas and periods.

Jan 1, 1933

By Zay Jeffries

HOSTILITIES in Europe, Asia, and northern Africa were responsible for dislocations in rare-metal supplies during 1940. Although the consumption of some of the rare metals is small the dislocations may be relatively large. In some cases these are advantageous to North America and in others they are disadvantageous. Specific instances will be cited later. Barium T HIN films of barium metal on special steel balls greatly improve the life and reduce the friction of rotating anodes in highly evacuated small X-ray tubes and make possible the operation of these anodes at relatively high temperatures. These remarkable results are described in an article by Atlee, Wilson, and Filmer in the Journal of Applied Physics for September, 1940. Oil could not be used because of the high temperatures on the one hand and its volatility on the other. Fig. 3 shows diagramatically the rotating anode and the method of coating the steel balls with barium. The letters K.I.C. refer to "Kemet Iron Clad." The K.I.C. wire was mounted so that the barium could be evaporated by direct passage of the electric current. At high temperatures the barium dif-

Jan 1, 1941

By B. D. Saklatwalla

FOR the proper understanding of the inclusion of certain elements in this review it seems necessary to state the meaning of "rare metals." Certain elements occur in deposits limited in extent or concentration, so that the extraction of the element in relation to market conditions becomes uneconomical. Others may occur in extensive and rich deposits but the reduction of the metal may be difficult and costly. Both these conditions effect the same result, namely, make the metal rare and costly. As an example of the first kind may be mentioned radium and of the second, calcium.

Jan 1, 1939

By Colin G. ink

OUTSTANDI'NG in progress among the less familiar 'metals during 1936 is the electrolytic production of 99.9 per cent manganese meta1 readily and many quantity. Strictly speaking, manganese should not' be classed as 'a rare metal, since there is 800 times as much manganese in the earth's crust as there is zinc or lead. But manganese' as a metal is rare, just as titanium metal is rare though titanium is five times as abundant in the earth's crust as manganese.

Jan 1, 1937

By Zay Jeffries

A SURVEY of rare metals and minerals for the past year places uranium as one of two partners, the other being the neutron, in what historians will probably say is the greatest discovery in physics at least during the year and probably for a consider- ably longer period. The uranium atom has been made to divide into parts somewhat after the style of reproduction of the amoeba. When an amoeba divides into two parts, however, it produces two amoebae substantially alike and each substantially like the parent: furthermore, there is no considerable change of energy when this happens. When the uranium atom divides it yields other atoms such as barium and krypton with the complete destruction of the original uranium atom but with the liberation of a tremendous amount of energy. This will be discussed more at length later.

Jan 1, 1940

By Frank L. Hess

BERYLLIUM is demanding more of the limelight, and the output of beryllium copper (containing 2% to~ 3 per cent of beryllium) seems to have grown 60 per cent above that of 1936, which was double that of 1935. There is increasing interest in beryllium-aluminum alloys and small quantities are being marketed at $50 per lb. for the contained beryllium. Other alloys also can be produced. Further price decreases for beryllium copper (now $23 per lb. for the contained beryllium) seem , possible and desirable. No difficulty has been experienced in obtaining beryl and a 'reserve stock has been built up. One supplier heretofore found reliable has offered to furnish 200 tons per month. Supplies during 1937 have come from the Black Hills in South Dakota, Colorado. India, and South America

Jan 1, 1938

By Paul M. Tyler, Colin G. Fink

THE field of rare metals is so broad that progress can be reported upon many important fronts. Not satisfied with the 92 elements that Mendeleeff and his followers have accepted as legitimate, scientists are trying now to complicate matters by making new elements. Enrico Fermi announced the fabrication of "Element 93". Uranium, instead of being allowed to disintegrate slowly according to its normal habit, was bombarded with neutrons until some of them seemed to have stuck in the nucleus. To understand just what is alleged to have happened all one has to do is to line up the elements in their usual order of ascending atomic weight and imagine, as physicists do, that each atom is a little solar orbit comprising a central mass or planet about which other masses revolve like satellites. Ordinary hydrogen, being very light, consists of only one positively charged proton center, with only one positively charged electron revolving about it. Other atones are progressively more complicated until we come to uranium, which has a relatively big center and 92 particles revolving around it.

Jan 1, 1935

By AIME AIME

THE meeting" of the Rare Minerals and Metals Committee was held Monday afternoon, Feb. 17; Donald M. Lidclell, chairman, presiding. The first paper (T. P. 279), "Progress in the Use of Tantalum," by George W. Sears, was read by Mr. Smyth. Dr. Sears' paper contains an interesting summary of the uses, alloys and ores of tantalum and a resume of present method of reduction. The uses of tantalum is based on its extreme rise to the reaction of even the strong mineral acids, its great avidity for the common gases and its capacity for transforming alternating to direct current. Tantalum, as an alloy material, has received considerable study and many alloys have been reported. Among them three types appear to .be most prominent, alloys of high melting point, hard alloys and acid rising alloys. As the estimated quantity of tantalum in the earth's crust is less than that of gold, it must be looked upon as n rare metal. Australia is the greatest producer and the Black Hills of South Dakota produce minor amounts. As the one type of mineral available contains both tantalum and columbium, the extracting and metallurgy of tantalum are difficult chemical processes. Greater simplicity in this and the development of a market for columbium would undoubtedly be of great benefit to the tantalum industry, andl make for a greater use of tantalum produced.

Jan 1, 1930

By Hasan Kolayli

Zeolites are common secondary components of a variety of igneous rocks. However it is extremely rare to reach such abundances to form a rock. An unusual rock composed almost entirely of natrolite, a zeolite mineral, has been discovered ; in a mountainous terrain called the Kop mountain range in the eastern Turkey. In the region, country rocks are essentially metamorphic rocks. These unique rocks are resulted through metasomatic changes acted on microdioritic and andesitic parent rocks occurring generally as dikes and stocks in the country rocks consisting chiefly of serpentinized harzburgites. These metasomatic rocks are investigated with respect to their mineralogical, petrographical, and geochemical characteristics. These products consisting dominantly of natrolite are termed "natrolitite" and those containing additional pargasite, an amphibol mineral, are termed "pargasite-bearing natrolitite or pargasitic natrolitite ". The dikes and stocks show concentric zoning, each of which has distinct chemical and mineralogical compositions: Na2O and H2O contents show enrichment outward from the core to chill zones whereas, SiO2 and CaO show depletion. Mineralogically, plagioclase variety, abundance and chemistry change outwards from the center due to partial to complete replacement of natrolite: anorthite contents of plagioclases decrease outward, which is indicated by A1203 and CaO decrease and SiO2 and Na2O increase, showing inverse relationship with increasing natrolite content.

Jan 1, 2005

By J M. Palin

Hydrothermal scheelite precipitated in fault-veins at Paradise, Bonnie Jean, Davidson's and Glenorchy mines display chemical variability involving REE patterns that are transitional between two end-member types. Type I is a MREE-enriched pattern with no or a small positive Eu anomaly. Type II is a flat to MREE-depleted pattern with a strong positive Eu anomaly. The chemical inhomogeneity of these scheelites can be explained by a model of fractional precipitation of REE, with preferential removal of MREE from the fluid during precipitation of scheelite. Irrespective of the mechanism responsible for scheelite precipitation, the source of dissolved constituents is different for scheelites from the Paradise Mine. Bonnie Jean, Davidson's and Glenorchy scheelites formed from LREE-enriched fluids whereas Paradise scheelites precipitated from fluids that were lower in LREE. These inferred fluid characteristics cannot be linked unambiguously to specific source rocks in the region, but could suggest that scheelite deposited in the Paradise fault-vein reflects a more mafic source of REE possibly greenschists, whereas the REE in scheelite from the other mines suggest a more felsic source.

Jan 1, 2003

By I. Garba

The Bin Yauri deposit in the Zuru schist belt of northwestern Nigeria is a vein-type quartz-sulphide-carbonate gold mineralisation hosted by a brittle fault zone. The occurrence of the mineralisation in a contact zone of a Pan-African granitoid was believed to be sufficient evidence of deposition from magmatic fluids. However, studies may now indicate a metamorphic source for the mineralising fluids. A study of rare earth element geochemsitry was used to investigate the nature of the fluid-rock processes involved and identify the sources of the auriferous mineralising fluids.

Jan 12, 1992

By Haydar Güneş

In this study, a hydrometallurgical process was evaluated for the recovery of Nd from a Nd-Fe-B magnet. Each leaching test was performed at the solid (weight) to liquid (volume) ratio of 1:50 and was mixed at 400 rpm at ambient temperature. The effects of 3 different acids (HCl, HNO3, and H2SO4) on the extraction of Nd were investigated and H2SO4 was found to be more effective than other acid solutions. Under the optimal conditions, pregnant leach solution was produced with H2SO4 for subsequent Nd precipitation testing. Each precipitation test was carried out using 100 mL of feed solution mixed at 600 rpm at 25°C. NaOH and H2C2O4 were used for Nd precipitation. The highest Nd was precipitated as Nd2(C2O4)3, 10H2O with C2H2O4 at 20 min.

By Z. Jin, D. DePaoli, P. Zhang

"Phosphorite, or phosphate rock, is the most significant secondary rare-earth resource. It contains high amounts of phosphate-bearing minerals along with low contents of rare earth elements (REEs). In Florida, about 19 Mt of phosphate rock are mined annually and most are used to manufacture fertilizers using a wet process, in which sulfuric acid reacts with phosphates to produce phosphoric acid and phosphogypsum. In the wet process, REEs are also leached out into solution and eventually get lost in the leaching residue and phosphate fertilizer. Recovering REEs from Florida phosphate rock in the wet process will be beneficial to broadening rare-earth availability, improving the quality of phosphoric acid product and protecting the environment.This study focuses on the influences of wet-process operating conditions on REE leaching efficiency. The results indicate that REE leaching efficiency increases with phosphoric acid addition in the initial pulp. At a temperature of 75 °C, a stoichiometric ratio of sulfuric acid (H2 SO4 ) to calcium oxide (CaO) of 1.05 and a weight ratio of liquid to solid of 3.5, REE leaching efficiency reached a relatively high value of 52.82 percent. The trends of REE leaching efficiency were similar to those for phosphoric acid (P2O5 ). Extensive tests on the leaching residue showed that during leaching, about 90 percent of the REEs were released from the phosphate rock but only 52.82 percent ended up in the leaching solution. This phenomenon can be attributed to two factors: (1) the effect of phosphate ions (PO4 3-) in the solution, which caused REE ions to form REE phosphates and be precipitated into the leaching residue, and (2) the influence of large amounts of anions such as sulfate (SO4 2-), dihydrogen phosphate (H2 PO4 -) and hydrogen phosphate (HPO4 2-) anions as well as the polar molecule H3 PO4 , which surrounded the REE cations and formed an ion atmosphere that prevented the PO4 3- from contacting and combining with REE cations. Interaction of these two opposite effects determined the REE distribution between leaching solution and residue."

Jan 1, 2017

By B. R. Arvidson

Rare-earth elements have some unique properties that are used in many common applications, such as TV screens and lighters. In the 1970's, rare-earths began to be used in a new generation of magnetic materials that have very unique characteristics. Not only were these stronger in the sense of attraction force between a magnet and mild steel (high induction, B), the coercivity (He) is extremely high. This property makes the magnetization of the magnet body composed of a rare-earth element alloy very stable, i.e., it cannot easily be demagnetized.

Jan 1, 1998

By Edward R. Rose

This paper summarizes and emphasizes the potential importance of Canadian rare-earth occurrences, and recommends that efforts to locate and evaluate rare-earth deposits should be increased. Increasing world markets, depending on intensive applied research into the numerous unique and remarkable chemical and physical properties of the rare-earth elements (REE), are developing; their properties and uses are becoming better known; methods of separation are much improved. The REE group comprises a Cerium (Light) subgroup of 7 metals and an Yttrium (Heavy) subgroup of 9 metals. REE are trace elements in many rocks and minerals, and major constituents of more than 50 rare-earth minerals, many of which are difficult to detect and identify. They occur preferentially in acidic and alkaline igneous and metamorphic rocks, including carbonatites, as well as in placer deposits, certain uranium deposits, phosphate rocks and others. The main ores now are bastnaesite (in Precambrian carbonatite), monazite and xenotime (in Recent beach sands) as well as uraninite and brannerite (in Huronian quartz-pebble conglomerate) and loperite (perovskite) and apatite (in alkaline complexes). World resources are summarized. Twenty mines in 1973 produced an estimated world total of about 31,000 tons of contained rare-earth oxides (REO), 19,341 tons of which came from one mine at Mountain Pass, California. A selected fifteen, of 315 or more Canadian occurrences, are briefly described and compared, and their relative merits indicated. Their abundance and variety suggest the possibility of finding high-grade deposits in many geological terranes in Canada.

Jan 1, 1979

By Itsuki Uehara, Hiroyuki T. Takeshita, Tetsuo Sakai, Nobuhiro Kuriyama, Hideaki Tanaka

"AB5 type hydrogen storage alloys (A: rare earths, B: transition metals) are extensively applied to a negative electrode of a nickel metal hydride (Ni-MH) rechargeable battery for portable electric equipments, electric vehicles, hybrid vehicles etc. Performance of a hydrogen storage alloy electrode is affected by various factors, microstructure and surface composition of the alloy and structure of the electrode as well as composition of the alloy. Control of those factors enables us to commercialize the Ni-MH battery in various field.IntroductionA Nickel-metal hydride (Ni-MH) battery has been extensively developed because of (1) good compatibility with a nickel cadmium (Ni-Cd) battery, (2) high energy density (1.5-2 times higher per unit volume than a Ni-Cd battery) and high dischargeability, and (3) low environmental pollution. The charge/ discharge reactions can be written as [l, 2,3]:(+) Ni(OH)2+OH- = NiOOH+H2O+e· (E=+0.490V NHE),(-) l/6LaNi5+H2O+e-· = 1/6LaNi5H6+OH- (E=-0.828V NHE),where E° is a standard potential of an electrode vs. normal hydrogen electrode (NHE). Because of the above advantages of a Ni-MH battery, the battery have been widely used as a power source of portable computers, cellular phones, electric vehicles (Toyota ""LAV4L EV"", Honda ""EV Plus"" etc.) etc. Some hybride vehicles (Toyota ""Prius"" and Honda ""INSIGHT"") and fuel cell vhehicles (Toyota ""FCEV"") are power-assisted by a high-power Ni-MH battery. In 1999, the production of Ni-MH batteries reached 870 million cells in Japan. Most of commercialized NiMH batteries are incorporated with rare-earth-based AB5-type hydrogen storage alloy as a negative_ electrode. The production of rare-earth-based alloy is estimated to be approximately 8000 tons.The battery performances of the Ni-MH battery, for example, capacity, durability (cycle life), dischargeability (kinetics) and selfdischarge, ate closely related to the metal hydride· (MH) electrode, especially, the hydrogen storage alloy in the electrode. Substitution of alloy components, heat treatment, and surface treatment in order to change surface and bulk structure of hydrogen storage alloys have been examined by us and many reseachers in order to improve the performances of MH electrodes. This paper is a review of our and their efforts to improve performances of MH electrodes."

Jan 1, 2000

By S. Vijayan

Despite the limited demand for rare-earth elements, as well as yttrium and scandium, in conventional applications, the emergence of ne~ high-technology applications such as supermagnets, lasers and superconductors is expected to result in significant demand for some of these elements. This paper examines the anticipated applications and demands for rare-earth elements over the next decade and their implications on the utilization of available resources. Process methods for the recovery of rare-earth elements from conventional and unconventional resources are reviewed in the context of their growing demand. Challenges facing the industries in meeting this opportunity are also discussed.

Jan 1, 1988

By S. F. Cheng

Among the many extraordinary features of the rare earths are their magnetic and magnetoelastic properties. The rare earths, e.g. Tb, Dy, Nd, Sm, are known worldwide for their large magnetocrystalline anisotropy and magnetization, which has led to the importance of magnetic rare earths as vital ingredients of modem permanent magnets. In this paper, we focus on the strain dependence of these giant effects which gives rise to huge magnetostrictions, magnetomechanical couplings, and ?E effects. Magnetostrictions greater than 10-3 have been measured at temperatures as high as 500 K. At low temperatures magnetostrictions reaches -1%. ?E effects - 10. No other solid state material has matched these values. A proper balance of magnetic anisotropy and magnetostriction, plus a proper choice of crystal axes lead to alloys which can switch large quantities of energy between the internal (magnetic) and external (mechanical) states with the application of small triggering magnetic fields. In addition to the traditional use of these materials in transduction, they are particularly valuable for smart systems where reliability and robustness are needed such as active structure stiffening and active vibration control.

Jan 1, 1997

By D. E. Woolley

The rate of reduction of iron oxide from calcia-silica-alumina slag by carbon in liquid iron has been measured over the temperature range 1400-1600°C by monitoring the rate of carbon monoxide (CO) evolution. Slags containing ferric iron have been used in order to study the reduction of both ferric and ferrous cations. Results show that ferric iron is reduced before ferrous iron, so that the ferrous iron concentration increases initially. It is also shown that the rate constant, k, decreases at low reaction rates, or, equivalently, at low concentrations. The authors conclude that the reaction occurs in two periods. During the first period, ferric iron is reduced to ferrous iron. During the second period, ferrous iron is reduced to metallic iron, and the rate-limiting step during the second period is the mass transfer of ferrous cations in the slag phase to the slag-metal interface.

Jan 1, 1998

By B. J. Arnold

Coal froth flotation cells typically receive little attention in coal preparation plants. They process only a small portion of the total coal feed (perhaps 5-1 0% of the total plant feed in the United States), they are viewed as a way to take the load off the refuse thickener, and their operation is not well-understood by cleaning plant operators. Operating parameters are set based on the equipment supplier information, and reagent dosages are set at the recommendation of the latest chemical vendor. The cells then operate day in and day out, recovering coal and producing a product that may not meet ash or sulfur specifications or that may be the wrong percent solids for downstream dewatering operations. If improvements can be made to this circuit, then the whole plant will benefit. Paying attention to rate and residence time and the wealth of data from the literature or from a series of targeted laboratory tests can give operators the key to improving the performance of froth flotation cells AND overall plant performance. This paper provides an overview of froth flotation rate and residence time data and gives practical suggestions for specifying and using laboratory tests to improve froth flotation performance. Suggestions for improving froth cell performance are also given based on available literature data.

Jan 1, 1999