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By E. Açma

Sivas-Divrigi flotation plant has a capacity of 90,000 tpy. Beneficiation of the tailings of iron ore magnetic separator seems to be attractive, because of its Cu, Co, and Ni contents. In the experimental work, sulfidic flotation concentrate is produced from these tailings. A roasting-leaching-H2S precipitation procedure is used to treat this concentrate, containing 0.55% Cu, 0.51% Co, 0.74% Ni, and 0.027% Zn. Sulfatizing roasting is carried out in a rotary furnace at 690°C. Roasted product is leached with 10 gpl HzSOl at 70°C and 30% pulp density. For the precipitation of desired metal, H2S is bubbled through the concentrated solution of repeated leaching, under controlled temperature and pH. Final metal recoveries of 91% Cu, 91% Co, and 50% Ni, and 92% Zn are attained. Roasting gases with their 13% SO2 content are suitable for H2SO4 production and the leach residues can be integrated with the iron ore processing plant as they contain 57.4% Fe and very low non-ferrous metals.

Jan 1, 1993

By Xinlei Jia, Wenming Guo, Yanling Zhang

A large amount of stainless steel dust rich in Fe, Cr, and Ni has been being generated in China. Smelting treatment is accepted as a practical method for the recovery/reutilization of these second resources, during which Fe, Cr, and Ni is reduced into one metal phase and then separated from the residue slag. Based on the typical compositions of stainless steel dust, the residual slag can be termed as CaO-SiO2-MgO-Al2O3 system. In this paper, the activity coefficients of Cr in Fe-Cr-Ni-C (-Si/Al) melt and the properties of CaO-SiO2-MgO-Al2O3- 1%CrO system thermodynamically approached. Then, in laboratory experiments, the recovery ratios of Cr and its distribution behaviors between Fe-Cr-Ni-C melt and CaO-SiO2-MgO-Al2O3 slag system were examined.

Jan 1, 2015

By Jyothi Rajesh Kumar, Jin-Young Lee

21st century is electronic revolution in human lives as well as energy is one of the most significant tasks. Rare earth elements (REEs) occupy a key role in daily life as well as high-tech industrial applications. REEs are one of the energy critical elements; for sustainable growth, it depends on multiple extraction and separation technologies including solvent extraction and ionic liquid-based extraction methods.

Mar 1, 2017

By Michael J. Virnig, Kathryn C. Sole, Murdoch W. MacKenzie, Michael R. Davis

A solvent-extraction process has been developed for the removal of copper cyanide complexes from aqueous copper/gold cyanide solutions formed in gold-recovery circuits that treat ores containing cyanide-soluble copper. The process uses LIX® 7820, one of the LIX® 7800 reagent series developed by Henkel. It is based on a mixture of Aliquat® 336, a quaternary amine, modified with an alkylphenol, 4--nonylphenol. Extraction and stripping data for the base metal cyanides and thiocyanate are presented. Methods for the recove1y of copper and cyanide from the upgraded strip liquor are reviewed. A flowsheet based on this chemistry and a preliminary economic evaluation of a solvent-extraction circuit combined with the cyanide-recovery process developed by Metallgesellschaft Natural Resources (MNR) are also presented.

Jan 1, 1999

By F. M. Doyle, K. Sreenivasarao

Copper and cadmium metal has been recovered from dilute (3 X 10-4 mol/dm3 ) chloride solutions by ion flotation with dodecysulfate, followed by electrolysis. This approach should facilitate treatment of effluents too dilute for effective direct electrolysis. . The adsorption density of metal dodecylsulfate complexes on bubble surfaces was estimated from surface, tension data, and compared well with experimentally-observed metal removal kinetics, and ultimate recoveries. Copper and cadmium were recovered by electrolyzing the foamate, using steel wool cathodes and a graphite anode. The stability constants of the copper and cadmium dodecysulfate complexes are estimated, and used to analyze the thermodynamics of electrolysis. Dodecysulfate was unaffected by the electrolysis process, and hence could be recycled to ion flotation. A conceptual flowsheet for an overall effluent-treatment process is presented.

Jan 1, 1997

By Brian Burdett, Terry I. Mudder, Robert T. Richins, James A. Stevenson, Michael M. Botz, Alan L. Wilder

The first Cyanisorb process was constructed in 1991 at the Golden Cross Mine in Waihi, New Zealand to recover cyanide from CIL tailings. The Golden Cross operation consists of an open-pit and underground gold mine with a conventional crushing, grinding and CIL circuit with Merrill Crowe zinc precipitation for gold recovery. Prior to disposal in the tailings pond, slurry tailings are stripped of cyanide at a pH of approxi­mately 7.5 using the Cyanisorb process. Mill throughput is approximately 2,500 tons per day (TPD), and CIL slurry tailings average 37% solids with a specific gravity of 1.27. CIL tailings WAD cyanide average 150 mg/L. The Cyanisorb process recovers approximately 85% of tailings WAD cyanide, produc­ing a slurry effluent with approximately 20 mg/L WAD cyanide. A second Cyanisorb process was commissioned at the NERCO DeLamar silver mine in southwest Idaho in May, 1992. The ore milling and silver recovery operation consists of crushing, grinding, a CIP circuit and Merrill Crowe zinc precipi­tation for silver recovery. Cyanide recovery is from clarified tailings with WAD cyanide ranging from 3 50 mg/L to 600 mg/L, producing an effluent with less than 30 mg/L to 60 mg/L WAD cyanide. Due to the presence of zinc-cyanide complexes in mill tailings resulting from the Merrill Crowe process, cyanide is stripped at a pH of approximately 5.5.

Jan 1, 1995

By Alan Fricker, Bill Owers

Cyprus Gold NZ Ltd will be recovering residual cyanide from their CIT, operation in New Zealand. The process will use air to strip the cyanide from the acidified barren pulp. DSffi. Industrial Development, who were involved in the bench and pilot studies for Cyprus, have extended the concept to pregnant pulp. The stripping of pregnant pulp eliminates the substantial loss of cyanide through carbon catalysed oxidation during the adsorption stage. A 50% increase in cyanide recovery was obtained from an extensive laboratory investigation. The presence of a cyanide recovery circuit enables leaching to be conducted, without detriment, at pHs at least as low as 9, with consequential 50% reductions in the consumption of lime and sulphuric acid. There should be a small reduction in carbon consumption, and a significant improvement in the quality of the final effiuent, at least in terms of cyanide, cyanates, copper, zinc and sulphur. A small but significant increase in gold recovery can be expected too. There is a net economic advantage of NZ$1.20/tonne of ore by stripping pregnant rather than barren pulp.

Jan 1, 1990

By Toyohisa Fujita, Mitsuo Mamiya, W. Tai Yen, Hiroki Kogita

Green algae taken from an acidic mine drainage and blue-green algae taken from an alkaline hot spring stream were collected and tested for their ability to recover or remove dilute metal ions. Experimental results demonstrated that unwashed blue-green algae and washed green algae effectively adsorbed base metals ions and eluted them at pH 1. It was also found that washed and dried algae adsorbed precious metal ions more effectively than unwashed algae. For example, the washed and dried blue-green algae was capable of adsorbing 0.31 kg of gold per kg of algae. The gold from tetrachloroaurate solution which was adsorbed on washed blue- green algae was found to change to a metallic state following initial metal binding. In the case of a dilute gold complex solution leached with thiourea, only a small amount of gold could be captured by algae. Further experiments were conducted on components of the algae, such as alginic acid, agar, cellulose and chitin and mixtures of these components, in order to determine their contribution to metal adsorption characteristics. However, a mixture of these two components demonstrated both good adsorption and desorption characteristics indicating an interaction between the individual components.

Jan 1, 1995

By Amir Rehmat

The Institute of Gas Technology has developed a fluidized-bed process for recovering direct reduced iron from blast furnace flue dust a material currently considered to be a waste from the iron and steel industry. In the process, a portion of the carbon in the flue dust is combusted to supply energy for the endothermic reaction between carbon and steam. The reaction produces reducing gases comprised of carbon monoxide and hydrogen both of which react with iron oxides to produce reduced iron. Up to 95 percent of the iron oxides contained in the waste stream can be reduced to elemental iron. The vitiated reducing gases emanating from the process can be used as fuel in the plant. The yield of iron depends upon the quantity of iron oxide present in the flue dust and generally ranges from 20 to 30 percent of the waste stream. The investment cost estimated for a single processing train dedicated to one steel plant can be recovered in less than one year.

Jan 1, 1996

Namakwa Sands, an Anglo Operations Limited subsidiary, is a world-class producer of heavy minerals. A layer of duricrust imposes a pseudo-stratigraphy to the primary deposit and has sterilized part of the generally unconsolidated ore in the open cast mine. The bulk of this ore cannot be treated by the present infrastructure, which employs conventional mineral separation technology. The mineralogy of the cementing agent consists of magnesium and calcium silicates and minor carbonates in addition to clay minerals such as sepiolite and those from the smectite group. Although the duricrust ore is friable and can be easily crushed, the significant clay-sized slime fraction produced, in particular the highly sorptive sepiolite, adversely affects mineral separation. The geometallurgical challenge is to cost-effectively remove the slimes from the ore before it is delivered to the concentrator.

Jan 1, 2007

By Ho-Sung Yoon, Jyothi Rajesh Kumar, Chul-Joo Kim, Sung-Don Kim

A recovery process for rare earths (REs) such as dysprosium and neodymium from the leach liquor of permanent magnet scrap (PMS) was developed. The two hydrometallurgical routes namely liquid-liquid extraction (solvent extraction) and selective stripping were implemented. The present study deals with the separation and recovery process development by using organo-phosphorous based extractant di-(2-ethylhexyl phosphoric acid (D2EHPA) as reagent for REs processing. Initial studies considered the influence of time on the extraction process, as well as pH and extractant concentration effects. This suggested the aqueous mechanism and separation factors played a role in process during development. McCabe-Thiele diagrams for extraction isotherms were developed. Counter current extraction (CCE) using various phase ratios influenced metals separation. Maximum loading capacity of the D2EHPA was determined. The loaded organic generated by the CCE process was water washed followed by a scrubbing process to remove the other metal ion from targeted metal. Finally, a stripping process was tested using various mineral acids.

Jan 1, 2015

By C. J. Van Niekerk

When gold plant residues are cycloned for producing a coarse product for backfilling the gold and uranium values are upgraded in the backfill product. Gravity concentration, wet high intensity magnetic separation and froth flotation were investigated as first-stage recovery processes to recover these economic values from backfill prior to placement underground. This paper addresses the recovery of values from flotation concentrates and also details the economic feasibility of a treatment route including flotation, followed by roasting of flotation concentrate to liberate gold entrapped in pyrite and reverse gold leaching of the calcine so produced.

Jan 1, 1988

By E. Allain

Extraction of basic metals from sulfides by conventional pyrometallurgical processing leads to the emission of SO2. To avoid this inconvenient, low temperature selective chlorination of sulfide concentrates could be an alternative. However, such process generates hazardous chlorides SxCly. A part of sulfur chlorides such as SCI2 can be recycled as a chlorinating agent of metal sulfides. Hydrolysis of sulfur chlorides, using a solution containing Na2S.9H2O, led to the recovery of more than 90 pct of elemental sulfur. Reduction of SxCly by hydrogen was investigated between 300 °C and 800 °C. About 70 and 90 pct of elemental sulfur were recovered from SC12 and S2C12, respectively. A flow sheet for the chlorination of metal sulfides and the treatment of sulfur chlorides was suggested.

Jan 1, 1998

By C. J. Lewis

Considerable amounts of the world's known reserves of elemental sulfur are found near the surface in areas of volcanic activity both active and inactive. Because such deposits cannot in general-be mined by the well-known Frasch process, and because other methods of recovery have not proven to be economically competitive except in isolated instances, at present these reserves remain relatively undeveloped. However, projections of world sulfur demand indicate that new sources of marketable sulfur will be needed in future years 2/, 19/. For this reason, recovery of elemental sulfur from these near-surface deposits is of continuing interest. Solvent extraction as an approach to recovery of elemental sulfur from open pit-mined ores of these non-Frasch deposits has received considerable attention particularly at the research and development level 3 /, 7/, l l /, 16/, 21/,23/, 29/ This method has been and continues to be attractive because it presents the potential of high sulfur recovery and purity of product coupled with a relatively simple process flowsheet in which low energy requirements and reasonable operating costs are thought to be possible. However, the physical and chemical characteristics of the native-sulfur ores, of elemental sulfur, and of the known solvents, have presented difficulties in the development of solvent extraction processes. Up to the present time, viable processes have not been realized within the framework of sulfur marketing conditions.

Jan 1, 1970

By A. Whillier

Recovery of energy from the water going down mine shafts by A. WHILLIER, Pr. Eng., Se. D. (M.I.T.) (Fellow) The influence of energy-recovery systems on the rise in temperature of water going down mines is examined. It is concluded that the, cost benefit of such systems, deriving partially from the reduced temperature rise in situations where cold water IS sent underground from surface, would more than justify the installation cost.

Jan 4, 1977

By S. K. Pan, M. P. Srivastava, N. Prasad

"Dalli mines of Bhilai Steel Plant, India is fully mechanized iron ore mine having wet processing system. It has a capacity to treat 5 Mt of ROM. In processing circuit of Dalli mines, scrubbing, wet screening and classification operation is being carried out. Average slime generation for the last five years is about 14% of ROM. As the mining has reached to the lower benches, fines generation is more. As a result, very fine and heavy particles, which settle fast, are being discarded with the slime to tailing pond. These heavy and faster settling particles were causing jamming in the thickeners.Laboratory investigations were carried out at Research and Development Centre for Iron and Steel (RDCIS) to suggest a suitable scheme to recover high quality fines so that the availability of thickener can improve. The slime samples were first treated in a floatex density separator. The concentrate obtained from the floatex density separator was treated in hydrocyclone. Laboratory investigations indicated that the slime with 49% Fe, 12.7% silica and 10.7% alumina can be upgraded to 62.1% Fe, 3.3% silica and 2% alumina with 36% material recovery. Based on the laboratory studies ,a system was installed at Dalli minesThe general arrangement of the system is shown in Fig. below."

Jan 1, 2003

Large deposits of eudialyte, a low grade zirconium bearing mineral, occur on the Southern Coast of Greenland in the Ilimaussaq intrusion. Various processes were tested in the laboratory to recover eudialyte from these ores, including flotation, leaching, gravity and magnetic separation. A combination of dry and wet magnetic separations has the advantage of simplicity and the least environmental impact for the location. This paper summarizes the results of laboratory testwork to develop a two-stage treatment process to recover the eudialyte by magnetic separation.

Jan 1, 1993

By C. A. Morais, L. V. Resende

"The technological development observed in recent years has stimulated the application of rare earth (RE) elements. Amongst their various applications it is well worth mentioning their use in electronics, superconductors, nuclear medicine, as well as in special inks - as those used in radar invisible airplanes. TV and computer monitor screens present as coating a powder containing some rare earth elements, mainly Europium and Yttrium. The recovery of the RE elements from electronic scrap is extremely important as the economic and environmental issues are concerned. This paper describes the study of the Eu and Y recovery from e-scraps. The first step of the process was the leaching of the powder obtained by manually scraping the inside surface of the screen. After the optimization of the leaching, the dissolution of Eu and Y was higher than 98 w/t% and a pregnant sulfuric liquor containing 11.9 g L-1 Y and 0.72 g L-1 Eu was obtained. The second step was the separation of the metals found in the liquor by the solvent extraction technique. The separation of Eu and Y was carried out in a counter current circuit compound of 3 extraction stages, 7 scrubbing stages and 15 stripping stages. DEHPA was used as the extractant, whereas a diluted sulfuric acid solution was applied as scrubbing agent and a hydrochloric acid solution at high concentration was used as the stripping agent.INTRODUCTIONThe rare earths (RE) are a moderately abundant group of 17 elements composed of lanthanides, scandium and yttrium. Amongst the RE, promethium (Pm) is extremely rare, however several of the RE elements are not very rare and occur dispersed in a variety of forms (Greenwood & Earnshaw, 1984; Tyler, 2004).The innumerable applications of the RE elements are based on their particular properties, mainly their spectroscopic and magnetic properties (Martins & Isolani, 2005). The technological development observed in recent years has stimulated the application of rare earth (RE) elements. They have been used in agriculture, electronics, superconductors, nuclear medicine, automobile industry, special inks – as those used in radar invisible airplanes, X-ray screens, high intensity mercury vapour light bulbs, neutron scintilators, charged-particle detectors and optical memory reading systems (Maestro & Huguenin, 1995; Nagaosa & Binghua, 1997; Sánchez et al., 1999)."

Jan 1, 2012

By M. A. Rabah

This study aims to recover europium, yttrium metals, some valuable salts or oxides from the white powder (apatite) coating the inner surface of spent florescent lamps (SFLs). Pressure leaching using sulphuric/nitric acid successfully dissolved the metals of interest. Europium or yttrium metals were obtained by hydrogen reduction of their oxides. Addition of potassium thiocyanate converted the dissolved sulphates to thiocyanates. Selective separation of Eu and Y was then carried out by solvent extraction from the thiocyanate solution. The used solvent was trimethyl-benzylammonium chloride. N-trihutylphosphate in 1 M nitric acid was used to strip the metal loaded in the organic phase. Results showed that the quality of the cleaned glass tubes of the SFL met the standard requirement for the lamp manufacture. The white powder (WP) is composed of calcium sulphate 35.2%, phosphate 61.5% and oxides of europium and yttrium 1.65%wt. respectively. Autoclave digestion of the WP for 4 h at 120°C and 500 kPa in sulphuric acid/nitric acid mixture dissolved 96.4% of yttrium and 92.8% of europium. The conversion rate of sulphate to thiocyanate was favoured at low temperature. Stripping of Eu and Y from the loaded organic phase behaved in an opposite way. A metal separation factor of 9.4 was obtained. ate recovered europium and yttrium salts were selectively separated using ethyl alcohol or dilute nitric acid. Yttrium was very soluble while europium was not. Europium and yttrium metals were obtained by hydrogen gas reduction at 850°C and 1575°C respectively.

Jan 1, 2004

By J. Drelich, J. Pletka

Lost foam casting is a process in which a polymeric material is formed into the shape of the part to be cast. Parts that are more complex are fabricated by simply gluing several patterns together. The pattern is then coated with a refractory material consisting of a mineral mixture and binders. Finally, hot metal is poured into the pattern, evaporating the expanded polystyrene and taking the shape of the coating shell. Prior to casting, a significant number of the patterns are damaged and inevitably landfilled. In this study, a process was developed for the recovery of expanded polystyrene from the coating and glue contaminants. The process consists of shredding, impact comminution, size classification and pneumatic separation. It is successful in separating up to 97% of the contaminants, while recovering 95% of the polystyrene. Key words: Casting, Lost foam process, Expanded polystyrene recovery

Jan 1, 2003