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By Yuexin Han, Jie Liu, Shuai Yuan, Yanjun Li

"In order to improve recovery efficiency of iron minerals from iron ore tailings and to reduce its connected environmental pollution, this article investigated the reducing roasting of iron ore tailing in a laboratory fluidized magnetization roasting reactor to optimize the roasting method and conditions. The examined parameters included roasting temperature, roasting time and reducing atmosphere. The parameters evaluating magnetizing roast efficiency and theoretical value were determined. X-ray diffraction (XRD) analysis was used to investigate the conversion of iron phase after roasting. The results show that the best magnetizing roast conditions are roasting temperature of 540?, holding time of 15min, and CO concentration of 20%. The magnetization conversion ratio of roasting products is over 80%, under the best magnetic separation condition, the concentrate grade of iron is 65.61 % and the recovery of iron is 83.77 %. The XRD analysis shows that Fe exists in hematite and siderite before roasting and exists in magnetite after roasting. The technique not only recovers the iron minerals from tailings with good economic benefit, but also reduces the environmental pollution of tailings accumulation.INTRODUCTION Iron ore tailings are the solid wastes generated during the beneficiation process of iron ore concentration and are one of the main pollution concerns in the mining industry (Das et al., 1996). Continuous development of the iron and steel industry has led to the increasing amount of iron ore tailings; there are over 300 million tons of iron ore tailings discharged per year (Rao et al., 2016). The huge amount of stockpiled iron ore tailings brings a series of environmental and social problems. Comprehensive utilization of iron ore tailings can not only reduce environmental load but also conserve resources, promoting sustainable development of the society. In recent years, iron ore tailings as secondary resources have received considerable attention in many countries in the word and numbers of studies on utilization of iron ore tailings were carried out, such as recycling the valuable minerals (Datta et al., 1996; Jia et al., 2013; Panda et al., 2018), used in construction material compositions as alternative source of raw materials (Das et al., 2012; Zhou et al., 2012; Luo et al., 2016) and other utilization. The iron minerals were recovery by magnetization roasting (Rao et al., 2016; Yang et al., 2013; Yang et al., 2011) and flotation (Kumar and Mandre, 2016). By comparison the reduction roasting has more advantages, but it was found that the conventional roasting equipment was inefficient, high energy consumption and un-economically applied on an industrial-scale."

Jan 1, 2018

By A. McLean, Q. R. Yang, Y. D. Yang, G. F. Zhang, P. Wu

A considerable amount of waste slag from the pyrite roasting process is discharged every year. Recovery of iron from the waste slag is of great interest for comprehensive use of mineral resource, reduction of environment impact and improvement of economical benefit to related companies. The objectives of the present work are focused on: (1) Compare various procedures for recovery of iron from the waste slag and select a best procedure for industrial trial which is roasting of the waste slag under reducing condition followed by magnetic separation; (2) Investigate the optimum conditions for maximum recovery of iron from the waste slag. The experimental result shows that under the treatment condition found in this work about 36 to 40% of the iron oxide was recovered from the waste slag, where the iron content in the concentrate is 57%. The total recovery ratio of iron, up to 70%, from the waste slag was achieved. After the treatment, sulphur content in the waste slag was reduced significantly and gangue materials, such as SiO2, Al2O3 and TiO2, were reduced effectively.

Jan 1, 2011

By M Gerards, M Steinberg, T Graham

The quality and quantity of Australia’s secondary deposits, which include tailings streams and tailings dams, are higher than most countries’ primary deposits. In addition, these secondary deposits have already been mined and processed, meaning that the recovery of high-grade product requires low capital and operating costs.The most widely used process for the recovery of these valuable fine and ultra-fine hematite iron particles is the wet high-intensity magnetic separation technique, originally developed by Dr Jones over 55 years ago. Many of the original machines are still working today.The aim of this paper is to demonstrate the capabilities in terms of grade and yield of using sophisticated magnetic separation modules. All results and figures are obtained from test work and design and engineering work with material from the Pilbara. In addition, consideration is given to dewatering of iron ore product and tailings.Two types of tailings have been identified for processing. Firstly, tailings that have already been deposited in a tailings storage facility, and secondly, live tailings streams from an existing wet iron ore beneficiation plant. In both cases, the technical and practical results are shown along with relevant flow sheets and plant layouts. Finally, this paper highlights the total predicted power and water consumption, capital requirements and projected operating expenses.The results show that the operating costs are significantly lower than the mining and processing operations that are required for an equivalent amount of iron ore. The recovery of iron depends on various factors but is within the 30–50 per cent range at an equivalent grade to the mainstream product. Another significant benefit is that the magnetic separation process is water positive, meaning that water is released rather than added in the process.The processing of the Pilbara’s secondary deposits will therefore result in an overall reduction in operating costs, an increase in product yield from a plant, extend the life-of-mine and offer environmental benefits by reducing the tailings footprint and water usage.The quality and quantity of Australia’s secondary iron ore deposits and tailings are such that many other countries would judge these as equivalent to primary deposits. Furthermore, these tailings are already mined, available and liberated to such an extent that the recovery of a valuable product is highly economical in terms of capital expenses and operating expenses.CITATION:Steinberg, M, Graham, T and Gerards, M, 2015. Recovery of iron ore fines and ultrafines from tailings by using wet high-intensity magnetic separation – JONES WHIMS, in Proceedings Iron Ore 2015, pp 191–196 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By Y. Wong

The quality and quantity of secondary deposits, which include tailings streams and tailings dams, are increasing around the globe. The tailings are already mined, available and liberated to such an extent that the recovery of a valuable product is highly economical in terms of CAPEX & OPEX. The most widely used process for the recovery of these valuable ultra-fine haematite iron particles is the Wet High Intensity Magnetic Separation technique, originally developed by Dr. Jones over 55 years ago. Many of the original machines are still working today. The aim of this paper is to demonstrate the capabilities in terms of grade and yield of using sophisticated magnetic separation modules. All results and figures are obtained from test works, design- and engineering works. Two types of tailings have been identified for processing. Firstly, tailings that have already been deposited in a Tailings Storage Facility, and secondly, live tailings streams from an existing wet iron ore beneficiation plant. In both cases, the technical and practical results are shown along with relevant flow sheets and plant layouts. Finally, this paper highlights the total predicted power- and water consumptions, capital requirements and projected operating expenses. The results show that the operating costs are significantly lower than the mining and processing operations which are required for an equivalent amount of iron ore. The recovery % of iron depends on various factors but is within the 30–50% range, at an equivalent grade to the mainstream product. Another significant benefit is that the magnetic separation process is water positive, meaning that water is released rather than added in the process. The processing of secondary deposits will therefore result in an overall reduction in operating costs, an increase in product yield from a plant, extend the mine life and offer environmental benefits by reducing the tailings footprint and water usage.

Jan 1, 2016

By Nikhil Dhawan, Veeranjaneyulu Rayapudi, Singh Rahulkumar Sunil

The ever-increasing demand for steel and the subsequent depletion of high-grade ores requires the massive utilization of low-grade iron ores. In the present study, an iron ore slime sample containing 56.1% Fe was investigated using physical beneficiation, carbothermal reduction, and a microwave-assisted process; however, physical beneficiation and microwave exposure were found to be inefficient as they yielded lower iron recovery. Using coconut shell as an alternative reductant was found to be promising and does not lead to the formation of higher iron oxides, such as fayalite and wustite phases. The microwave-assisted carbothermal reduction was found at par with conventional reduction, saving time and heating. The optimum magnetic concentrate obtained in both carbothermal reduction routes (microwave and muffle furnace: Fe grade, Fe recovery, and yield of 64.3, 97, and 84%, and 67, 99, and 83%, respectively) are suitable for alternative iron-making or blast furnace units.

By Nikhil Dhawan, Veeranjaneyulu Rayapudi, Singh Rahulkumar Sunil

The ever-increasing demand for steel and the subsequent depletion of high-grade ores requires the massive utilization of low-grade iron ores. In the present study, an iron ore slime sample containing 56.1% Fe was investigated using physical beneficiation, carbothermal reduction, and a microwave-assisted process; however, physical beneficiation and microwave exposure were found to be inefficient as they yielded lower iron recovery. Using coconut shell as an alternative reductant was found to be promising and does not lead to the formation of higher iron oxides, such as fayalite and wustite phases. The microwave-assisted carbothermal reduction was found at par with conventional reduction, saving time and heating. The optimum magnetic concentrate obtained in both carbothermal reduction routes (microwave and muffle furnace: Fe grade, Fe recovery, and yield of 64.3, 97, and 84%, and 67, 99, and 83%, respectively) are suitable for alternative iron-making or blast furnace units.

By P S. R Reddy, V N. Misra

The iron ore deposits in India are rich in iron content but usually contains high alumina and silica. The current industrial practice results three products namely lump, fines and slimes. The lump and fines with or without beneficiation are directly fed to the blast furnace and sintering plant respectively while the super fines or slimes are presently discarded as tailings. Around eight million tonnes of iron ore slimes estimated as being 15 - 20 per cent by weight of run of mine ore containing ~48 - 62 per cent Fe, is discarded every year causing huge loss to the Indian iron ore industry. In addition, these slimes stored in massive tailing ponds pose enormous environmental and ecological problems. Extensive investigations have been carried out on three iron ore slimes generated at Barsua, Bolani and Meghahatuburu iron ore mines of India. The studies include physical, chemical, mineralogical characterisation and beneficiation studies adopting conventional hydroclyclone and wet high intensity magnetic separator. The characterisation studies have indicated that most of the gangue minerals are accumulated in finer fractions. The studies on hydrocyclone and magnetic separation had indicated that an iron concentrate of 61 - 65 per cent Fe could be obtained by recovering 59 - 78 per cent of the iron values present in the slimes. Depending on the nature of the slimes the alumina and silica levels have been brought down to 2.5 and 1.0 per cent respectively. The effects of different operating and design variables along with detailed characterisation studies have been highlighted.

Jan 1, 2002

By Cz. Mora, A. Pawelczyk, D. Hreniak, P. Nowak, A. Dyonizy, S. Strek, W. Strek, K. Grabas, A. Ostrowski

Globalization and a growing demand for limited raw material resources have forced changes in the approach to the supply chain. This is particularly true in the case of rare earths, which are regarded as one of the most important development indicators of modern technologies. To ensure a secure supply of commodities, the European economies have been prompted to investigate REE recovery from sources which until recently, for technical or economic reasons, were considered not sufficiently attractive. An interesting example is apatite phosphogypsum waste dumps. The REE content in these waste dumps averages around 0.5-1 %. One of the most important phosphogypsum locations in Poland is the Lower Silesia region where a phosphoric acid Chemical Plant "Wizów" operated for several dozen years. In this work, rare earths are leached from the phosphogypsum crystalline structure by a chemical treatment and can then be separated into individual chemical compounds. The technology used in these recovery tests, matches up to a coherent European raw materials policy supporting effective management of resources and promoting waste materials recycling.

Jan 1, 2014

By J. L. Watson

n the U.S., lead has been produced via blast furnace processing for over a century, and the slags from that pyro-metallurgical process have been accumulating on industrial sites over that extended period. Lead blast furnace slags typically contain both lead and zinc compounds in an iron-silicate matrix, and it appears highly likely that such materials will have to be processed in the near future to meet with EPA regulations. Thus it is appropriate to investigate possible processing routes to render the slags non-hazardous and simultaneously to recover metal values to partially off-set the inherent high cost of processing such materials. There are two major processing alternatives: one being pyrometallurgical and the other hydrometallurgical. The research reported here investigates leaching/solution purification/recovery processes for lead and presents experimental data for the treatment of lead blast furnace slags from S.E. Missouri. The results of the research suggest that both lead and zinc can be removed effectively from the slag, and that metallic lead can be recovered directly from the organic extractant utilized for solution purification.

Jan 1, 1995

By M. K. Mohan

Lead recovery from process solutions contributes not only to the conservation of resources but also clean environment. Zeolites are natural aluminosilicates, which finds applications as catalysts and in wastewater treatment. In the present investigation, studies were taken up on the processing of Pb from process solutions by zeolites. Effects of pH of the solution, time and type of zeolite viz. chabazite, mordenite, erionite and clinoptilolite on the removal of Pb from solutions was investigated. Rate of sorption was found to depend on the pH of the solution and about 99 pct. recovery was observed at pH 6. Optimal conditions were established for the maximum recovery of lead from process solutions. Possible sorption mechanisms were proposed. The calculated adsorption constants calculated from Langmuir and Freundlich equations showed that the adsorption of lead on chabazite was strong.

Jan 1, 1999

By J. Rastas

The recovery of lead, silver and gold from existing and potential zinc process residues using a sulfidization-flotation method was investigated on a laboratory scale. The following residues were tested: neutral leach residue, high acid leach residue, and hematite residues. The sulfidization of lead and silver is carried out at low pH by the addition of a stoichiometric amount of sulfide at a controlled rate. To increase the particle size of the sulfides, seeding with synthetic lead and silver sulfides -is employed. The flotation is carried out at pH 2-4 using low pH-collectors such as dithiophosphates and dithiophosphinates. Special attention must be paid to the role of oxygen in the conditioning stage. The effect of different parameters on both the sulfidization and the flotation has been evaluated. Recoveries of 85-90, 90-95 and about 80 % were obtained for lead, silver and gold, respectively. Typically, concentrates containing 50-60 % lead, 3-5 kg/t silver and 10-15 git gold were produced.

Jan 1, 1990

By Rajashekhar Marti, York R. Smith

Lithium is anticipated to be a key, strategic material in the clean technology economy. The majority of lithium reserves are contained in continental brines and sea water (>60%). Currently the most economical approach to recover lithium from such resources is through selective adsorption. Spinel type lithium manganese oxide and lithium titanium oxide have demonstrated to be excellent candidate materials (after de-lithiation). However, due to the small size of the powders, they have limited industrial application and require immobilization. In this work, we examine the application of novel manganese oxide nanowire composites for the extraction of lithium from dilute solutions. Manganese oxide nanowires were synthesized and simultaneously immobilized on diatomaceous earth via hydrothermal method. Lithium manganese oxide were then formed by solid-state reaction, de-lithiated and tested for lithium ion adsorption.

Mar 1, 2018

By G. D. Rosales, P. F. A. Braga, S. C. A. França, C. P. Pinto

The growing market demand for lithium is mainly due to its use in the manufacture of batteries for electric or hybrid vehicles and portable equipment (smartphones, tablets, power tools, notebooks, etc.). Currently there is great interest in finding new sources of lithium and technologies for its utilisation. Li-S batteries have received attention due to their theoretically high specific energy density, which is 3 to 5 times greater than that of Li-ion batteries. Unlike Li-ion batteries, of which the main raw materials are lithium carbonate and lithium hydroxide, the main raw material for Li-S batteries is lithium chloride. The anode used in Li-S batteries is metallic lithium, produced by a molten lithium chloride electrolysis process. The extraction of lithium from pegmatites such as spodumene, previously abandoned in the 1990s for being uneconomical, has become attractive due to the increase in prices as well as the need for greater lithium purity of products made from lithium-bearing minerals. The main methods used for lithium recovery from spodumene ore include the sulfuric acid process, the alkaline process (lime or limestone as raw material) and the chlorination roasting process. Thermodynamic modelling using HSC software 5.1 was conducted to predict different reactions that could occur during chlorination roasting of the spodumene/MgCl2+CaCl2 system. Lithium extraction from the solid obtained after the chlorination roasting was also investigated. The results of thermodynamic analysis provided a better understanding of the chlorination roasting process for lithium extraction. Metallurgical tests with a mass ratio of 1:6 (spodumene:chlorides) and molar ratio of 2:1 (MgCl2:CaCl2) allowed over 95% recovery of the lithium contained in the spodumene concentrate. Keywords: Spodumene, lithium chloride, chlorination roasting

Jan 1, 2020

By Rajashekhar Marthi

Lithium is a key component for future electric vehicle batteries and energy storage. The future availability of lithium to meet the growing demands remains in question. Around 60% of lithium resources exist in the form of continental brines. Traditional methods to recover lithium from brines use solar concentration with precipitation and have found limitations in lithium extraction due to interference of Mg in high Mg/Li brines. Thus, there is a need for highly selective adsorbents. Recently, spinel structured delithiated lithium manganese oxides have demonstrated promising results. However, due to the small particle sizes, it is economically difficult to recover the adsorbents and thereby limits industrial applications. In our work, LiMn2O4 ion sieve was synthesized and immobilized on diatomaceous earth. Fundamental adsorption studies were carried out in lithium buffer solutions to understand the nature of adsorption and kinetics. The adsorbents were also tested for recycle stability, as well as recovery of lithium from Great Salt Lake water samples.

By T. Gouri Charan, G. V. Rao

A spherical agglomeration process for the separation of scheelite fines of less than 30 µm in very low concentration of 0.04% WO3 in a binary mixture with quartz fines of less than 30 pm has been described. A concentrate containing 14% WO, with more than 90% recoveries could be achieved by means of anionic sodium sulfo succinate collector at pH 3.5 and also with commonly used anionic sodium oleate at pH 10.5 as per the conceptual flowsheet suggested. Such a process is envisaged as commercial potential for the recovery of fine-grained scheelite present in the tailings of gold plants as found in India.

Jan 1, 1991

By G. M. Ross, I. M. Ross, J. A. Scott

"The otherwise waste heat in many water streams in the mining industry can be used to provide space heating of adjacent infrastructure including laboratories, workshops, and offices. This can be achieved by using heat pump systems, which can work as a replacement or in conjunction with existing space heating. In the example investigated—process cooling streams at an ore smelter—the analysis provided illustrates that annual heating costs can be 19% lower and a simultaneous 62% reduction in CO2 emissions can be achieved.RÉSUMÉ Dans l’industrie minière, la chaleur qui serait normalement perdue des circuits d’eau pourrait servir à chauffer des structures adjacentes incluant les laboratoires, les ateliers et les bureaux. Cela pourrait se faire en utilisant des systèmes de thermopompes, qui pourraient remplacer ou s’ajouter au chauffage existant. Dans l’exemple étudié, des circuits de refroidissement de procédé à une fonderie, l’analyse fournie illustre qu’il est possible de réduire les coûts annuels de chauffage de 19 % et d’obtenir une réduction simultanée de 62 % des émissions de CO2."

Jan 1, 2016

By Timothy C. Smith, S. Andrew Jacobs, Douglas E. Gonzales, Sandy J. Schexnailder, Carl Urban

At the Schwartzwalder Mine (Cotter Corporation, Golden, Colorado) ion exchange resins have been used in mine water treatment experiments. The experiments, initiated in October 1979 and currently in progress, demonstrate that mine water uranium values can be reduced to levels as low as 10 ppb. Duolite® A-101D, a strongly basic anion exchange resin, was tested in laboratory-scale columns (1 inch diameter) initially and then in pilot-scale columns (4 inch diameter), using both co-current and counter-current operational modes. Observations and conclusions resulting from these studies can be summarized as follows: (1) Duolite® A-101D appears to have successfully extracted uranium at influent levels of approximately 2.0 ppm over multiple loading and elution cycles, consistently producing effluent concentrations as low as 10 ppb uranium. (2) Based upon present test data, counter-current regeneration appears to be the key to successful operation. Upflow loading and downflow elution are the preferred modes for service and regeneration, respectively. (3) Filtration is a necessary pretreatment to remove fine clay and inorganic precipitates that will foul the resin, causing excessive pressure drop and poor loading and elution kinetics. (4) This waste treatment application is unique in that it offers the opportunity to recover some or all of the capital investment in the treatment facility

Jan 1, 1980

By Kuiting Wang, Jinshan Liu, Ninglei Sun, Aiguo Dong, Yeda Lu

"Eliminating the environmental threat caused by waste effluent containing magnesium sulfate derived from the process of nickel laterite sulfuric acid leaching and subsequent nickel precipitation is always a focus in the metallurgy field. A new flowsheet whose procedures include vaporization, crystallization, two stages precipitation of magnesium, causticizing treatment of filtrate and ammonia recycle was investigated. Both the details of the flowsheet and its application are described in this article. It is confirmed to be an effective and economical method to prevent the pollution by the waste effluent, simultaneity, a series of magnesium products recovered during the process own good economic returns.IntroductionSulfuric acid leaching is the conventional procedure of extraction valuable metals from ores in hydrometallurgy field. During the process of nickel laterite sulfuric acid leaching, several metals, including Ni, Co, Al Mn, Fe, Mg etc., migrate into the leachate in the form of soluble metal sulfate. After subsequent procedure of purification, precipitation of Ni and Co and neutralization, an enormous stream of waste effluent which contains a concentration of approx. 15-40g/L Mg is exhausted. Such solution containing magnesium sulfate is toxic, which causes diarrhea for both human and animals. On the other hand, large amount of sulfate acid was consumed during the process of leaching by the compound of Mg, which increases cost of a hydro nickel plant.In arid areas, the waste effluent mentioned above is treated via evaporate pond owning large acreage, which needs not only the appropriate meteorologic condition, but occupies much land. In coastal areas, it is directly discharged to the sea, which probably deteriorates ecological system of offshore strip. The most widespread method to treat with the waste effluent is neutralization by lime cream, the residues of which containing magnesium hydroxide and gypsum are transported to residues pool. Neutralization is a simple process, but it never recycles the Mg and sulfate anion into new application, meanwhile, the residues are potential threat to the environment."

Jan 1, 2012

By D. R. Buist

The Taharoa plant of New Zealand Steel Mining Limited extracts a 57% Fe titano-magnetite concentrate from a large mineral sand deposit 90 miles south of Auckland on the west coast of New Zealand's North Island. The plant consists of an 18-inch suction cutter dredge which feeds a 750 TPH floating separation plant. An initial gravity/ size separation is obtained using cone concentrators. Finished concentrate is produced by a combination of conventional drum magnetic separators and top fed wet Mortsell magnetic separators. Concentrate is stockpiled by cyclone, and reclaimed by a bull- dozer and tunnel system. Repulped concentrate is pumped by sub- marine pipeline to slurry tankers anchored at a single buoy one mile offshore. Current concentrate production rate is in excess of one million metric tons per year.

Jan 1, 1973

By T. C. Murphy, W. Taciuk

In 1966, the Iron Ore Company of Canada commissioned a wet magnetic scavanging plant for the recovery of fine magnetite values p.resent in spiral tailings discharged from a spiral gravity separation process. The plant includes dewatering, grinding, classification, thickening, mini-wedge screening, and primary, secondary and tertiary wet magnetic separation stages. The source of feed varies in quantity and quality, so the original design included variable operational procedures to deal with these conditions.

Jan 1, 1972