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By R. E. Brewer

Pilot scale flotation tests were conducted with a 1-ft-diam column at the Barrick Resources (USA) Mercur mine, Tooele County, UT, to scavenge unleached (0.01 to 0.018 oz/st) gold values from the tailings of a carbon-in-leach (CIL) circuit. The optimal recovery was 35 pct of the unamenable-to-leaching gold, at a grade of 0.353 ounces of gold per short ton, using a mixture of dithiophosphate, xanthate, and diesel fuel as a collector. This was achieved by floating approximately 1.6 wt pct of the CIL tailings. The gold values are believed to be contained in arsenic-bearing minerals, attrited carbon, and carbonaceous material in the ore. Redox potentials were measured with a gold electrode during the conditioning stage prior to flotation. The correlation between flotation recovery and redox potential values could be used to control reagent additions. Treatment of a previously leached and weathered tailings material, averaging about 0.055 ounces of gold per short ton, was also investigated using the column. The tailings were first water leached at approximately 600 C, and the water-leached tailings, which contained approximately 0.03 ounces of gold per short ton, were then fed to the column flotation unit. The effects of pH and sodium sulfide addition on gold flotation recovery and redox potentials were examined. maximum gold recovery, 36 pct, was achieved at pH 8.5 with a sodium sulfide addition of 0.18 lb/st.

Jan 1, 1989

By F. Riedel

In May 2009 a test work programme was carried out at the sorting laboratory of CommodasUltrasort in Germany which was aimed at establishing the efficiency of X- ray transmission sorting for the recovery of unliberated diamonds in a size range of +8mm. A PRO Tertiary XRT belt sorter with a working width of 600mm and a belt speed of -3mJs was used for the test work. Dual energy X-ray transmission sorting is a type of sensor-based sorting which uses an X-ray scanning system, The attenuation of the transmitting X-rays is measured at two different energy levels, Thereby it is possible to eliminate the effect of the particle thickness on the measurement result. The effective measurement results in a classification by elemental order based on the periodic table.

Jan 1, 2010

By Fathi Habashi

"A process is proposed for the treatment of phosphate rock for the recovery of uranium and the lanthanides. The process assures the production of phosphatic fertilizers without polluting the environment with radioactive material.IntroductionWhile many processes for uranium recovery from phosphoric acid produced by the H2S04 route are known and utilised commercially, little is known about uranium recovery from phosphoric acid produced by the HN03 route1. Advantages of the latter route are both the elimination of the gypsum disposal problem, and the possibility of radium disposal in a controlled way2. Further, the lanthanides originally present in the rock can be recovered if the nitric acid route is used; they will be mostly lost in the gypsum produced by the sulphuric acid route3. In the present work a scheme for the recovery of uranium and the lanthanides from phosphate rock without interfering with the normal route for fertiliser production is proposed using HN03 as a leaching agent. Attention was also given to uranium decay products and their separation so that they might not contaminate the fertiliser4. Further, an attempt was made to defluorinate the leach solution in order to upgrade the fertiliser and at the same time recover the fluorine5. Rapid analytical methods for the determination of uranium, radium, and lanthanides in phosphate rock were developed6,7."

Jan 1, 1997

By T. Sreenivas

This paper describes results of laboratory studies on recovery of dissolved uranium values from alkaline leach slurries of a medium-grade uranium ore from Gogi (Karnataka, India) using the resin-in-pulp (RIP) process. Besides anionic carbonate complex of uranium, the other major ionic constituents of the leach solution are CO32-, HCO3-, SO42- and MoO42-. The total dissolved solutes (TDS) are about 45 g/L. Various commercially available strong bases anionic resin-in-pulp (RIP) grade resins ? both macroporous and gel type, were studied with respect to their loading capacity. Parametric variation studies were then carried out with the short-listed resins. Results of the semi-continuous counter-current extraction and elution tests indicated extraction efficiency of about 98% and practically complete elution of the loaded uranium values with NaCl eluant using a gel type polystyrene based resin grafted with quaternary ammonium ion. Keywords: uranium, hydrometallurgy, ion exchange, resin-in-pulp

Sep 1, 2012

By D?Arcy R. George

A survey of the copper mining industry in Western United States revealed that uranium is almost universally present in the solutions resulting from leaching the waste ore dumps to recover copper. The U308 content ranges from about 2 to 15 ppm and a potential production of up to 1,000 tons of U3O8 per year is indicated. A six-week pilot plant test at the Bingham Canyon mine of Kennecott Copper Corporation showed that the uranium is readily recoverable by ion exchange techniques. The design of the new types of countercurrent ion exchange columns and operation of the pilot plant are described.

Jan 1, 1967

By Fred J. Hurst

In 1934, Irvin Lavine (A), University of North Dakota, stated that the low-rank coals (lignite and subbituminous) of this country represent a vast tonnage of fuel of commercial value and predicted that some day they will play an important role in our economic welfare. Lavine also pointed out that one of the major problems with efficient utilization of the low-rank coals is their high moisture content. Following the discovery of uranium-bearing lignite in the Williston basin of North and South Dakota in 1948 by D. G. Wyant and E. P. Beroni, detailed investigations were conducted (primarily during 1950 to 1954) by members of the U. S. Geological Survey to evaluate the geologic factors and economic possibilities of the radioactive lignites as a source of uranium. The information gained in these studies and summarized in several papers indicated that a large potential reserve of uranium is contained in the subbituminous coal and lignite deposits of the Dakotas and Wyoming (2,3,4). Most investigators concluded that an epigenetic emplacement of uranium in the coal by means of circulating groundwater and the more extensive concentrations of uranium in coal are apparently related to the permeability of the rocks enclosing the coal beds. Breger (5) and others have shown that uranium is readily adsorbed by coal and is held irreversibly as a disseminated adsorbed constituent. Briefly, lignite beds containing 0.1 to 10% uranium have been discovered in the Dakotas and Wyoming. The distribution of uranium was found to be erratic and was usually concentrated in thin layers, which were characteristically 10 to 14 in. thick and occasionally 30 to 36 in. thick. Lignite beds more than 3 ft. thick generally contain more uranium at the top of the bed than at the bottom. Special strip mining techniques are required to mine these thin

Jan 1, 1983

By Henry G. Petrow, Edward S. Porter

MAJOR occurrences of lignite with significant uranium concentrations have been reported in western parts of the Dakotas, especially in Harding County, S.D., and Billings and Slope counties, N.D. Samples containing as much as 2 pct U3O8 were received at the Winchester Laboratory, but those deposits reportedly of major significance have generally contained 2 to 4 lb of uranium per ton of lignite. Most of the uranium appears to be associated with the carbon in the lignite as a urano-organic complex, although in most instances analysis of inorganic material has shown uranium values. Molybdenum is similarly associated with the carbon, and its concentrations generally parallel the uranium. The noncarboniferous material is mainly composed of gypsum, jarosite, bentonite, sandstone, and miscellaneous carbonates and silicates. The heating value of these lignites has been determined as about 3500 Btu on a dry lignite basis. The ash content of lignite has varied widely, the important samples containing 30 to 60 pct ash on a dry lignite basis. Because of the significant upgrading of uranium values obtained by ashing the lignite, and because recovery of uranium from raw lignite presented formidable processing problems, major emphasis at Winchester has been placed on devising methods to recover uranium from lignite calcines. Proper roasting removes the problem of organic fouling of solutions, reduces the size of the leaching plant for an equivalent uranium throughout, and generally provides equal or better acid leaching efficiency with less acid than can be obtained from the raw lignite.

Jan 9, 1957

Recently, renewed interest in the recovery of uranium from leach solutions has necessitated a re-examination of the hydrometallurgy methods used for uranium in the 1960?s to 1970?s. A synthesizing overview of the lessons learned in those decades together with examination of recent developments in this area is warranted. This paper considers uranium recovery chemistry from acid and alkali leach solutions using solvent extraction and resin ion exchange, and provides information on circuit selection and configuration, equipment selection and design, as well as operational considerations. The unique thermodynamics of uranium solvent extraction are also presented and discussed.

Aug 1, 2010

By M. Streat, R. Y. Qassim

Summary This paper reviews the developments in uranium process technology as a result of modern trends in the design of ion exchange equipment. The operation of the Cloete-Streat fluidised bed contactor is described and pilot-plant development of this contactor for uranium slurry work at Imperial College is outlined. The properties of a suitable ion exchange resin for slurry treatment are discussed, together with a description of relevant rheological properties of ore suspensions. A prediction of ion exchange resin- slurry behaviour is presented in order to establish the feasible operating limits for this type of R-I-P contactor.

Jan 1, 1973

By F. J. Hurst

Phosphate rock, which is a prime source of phosphate used in fertilizer manufacture in the United States, contains uranium. In general, the uranium content of the rock increases with the phosphate content and most high-grade phosphate deposits (>30% P2O5) contain 0.01- 0.02% U3 8. The large tonnages of rock being mined represent a significant potential source of uranium that lends itself to recovery as a by-product of the wet-process phosphate industry. For example, in 1953, the U. S. Geological Survey estimated that recoverable phosphate reserves in the U. S. totaled about 5 billion tons and contained 600,000 tons of uranium. I This estimate did not include any rock from North Carolina which has since been estimated at about 2 billion tons. For the most part, the known, economically mineable U. S. reserves - estimated at about 7 billion tons - are concentrated in a few areas: 43% in the western states of Idaho, Montana, Utah and Wyoming; 28% in each of Florida and North Carolina and less than 1% in Tennessee. In the past, Florida has supplied about 80% of the total U. S. production, practically all of which is land pebble phosphate. All forecasts indicate increased production rates from North Carolina and the western states.

Jan 1, 1976

By F. J. Hurst

The rapid expansion of the phosphate fertilizer industry in conjunction with the projected shortage and spiraling price increase of uranium has greatly renewed interest in wet- process phosphoric acid as a significant source of uranium. Two attractive solvent extraction processes for recovering uranium from the acid have recently been developed and tested through bench-scale at Oak Ridge National Laboratory. One of the processes has been successfully tested on a pilot-plant scale at phosphate plants; the second process, which offers several potential advantages, still needs additional testing. The merits of each process are discussed.

Jan 1, 1978

By Joseph C. Milbourne

Tetra Technologies CCIX? (continuous countercurrent ion exchange) system has been involved in a wide range of uranium concentration, separation and purification applications over the past 40 years. Uranium ion exchange applications have ranged from the treatment of copper heap leach solution containing 5 parts per million of uranium to the treatment of high strength sulfuric acid solutions containing several thousand parts per million of uranium. The flexibility and the countercurrent mode of operation and other unique features of the CCIX? have resulted in successful uranium recovery from these solutions and many others.

Jan 1, 1995

By M. Fan, Z. Long

"This paper presents some studies on recovering valuable elements from Chinese coal by-products, including coal combustion fly ash, stone coal ash, and coal flotation tailings. Both commercialized technologies and economic potential recovery methods are described in this study. Magnetically stabilized air-dense medium fluidized bed separation, tribo-electrostatic separation, froth flotation, and hydrometallurgical methods are discussed in recovering various valuable elements in Chinese coal by-products from different coalfields. These valuable elements include iron, carbon, aluminum, rare earth elements, lithium, gallium, germanium, uranium, titanium, scandium, silicon, vanadium and phosphorus, etc. The ultimate goal is to fully utilize all valuable elements in coal by-product. Each component within coal by-product should be efficiently segregated to its highest value. INTRODUCTION Coal is mainly composed of energy-producing elements carbon and hydrogen. In addition to these elements, coal usually contains many other valuable elements, including iron, aluminum, silicon, rare earth elements, lithium, gallium, germanium, vanadium, uranium, titanium, scandium, and phosphorus, etc. These coal-associated elements are significantly enriched in coal combustion by-product fly ash because of majority of main components, carbon and hydrogen elements, being removed. Table 1 provides the chemical composition range of the main elements oxides in 12 Chinese fly ash samples collected from coal power plants located in Northeast China, Northwest China, Southwest China, and Southeast China. It can be seen from Table 1 that the major mineral components of different ashes are similar, but the bulk chemistry of different fly ashes may vary widely due to the changes of ratios of the mineral components in different coals. The major mineral components in various Chinese coal combustion fly ash are silicates, iron oxides, and unburned carbon."

Jan 1, 2017

By Yuemin Zhao, Wenxuan Liu, Maoming Fan, Zhanyuan Long

"Coal is mainly composed of energy-producing elements carbon and hydrogen. In addition to these elements, coal usually contains many other valuable elements, including iron, aluminum, silicon, rare earth elements, lithium, gallium, germanium, vanadium, uranium, titanium, scandium and phosphorus. These coalassociated elements are significantly enriched in coal combustion byproduct fly ash because the majority of the main components, carbon and hydrogen elements, being removed. Table 1 provides the chemical composition range of the main element oxides in 12 Chinese fly ash samples collected from coal power plants located in Northeast China, Northwest China, Southwest China and Southeast China. It can be seen from Table 1 that the major mineral components of different ashes are similar, but the bulk chemistry of different fly ashes may vary due to the changes of ratios of the mineral components in different coals. The major mineral components in various Chinese coal combustion fly ash are silicates, iron oxides and unburned carbon.Chinese coal fly ash usually contains about 5 to 15 percent of unburned carbon, which are generally chars with irregular shapes and wide particle size distribution. In addition to unburned carbon, XRD analysis of four Chinese fly ash samples from Liaoning, Shanxi, Guizhou and Shandong provinces indicates that the fly ash samples are composed of minerals such as quartz (SiO2), mullite (3Al2O3.2SiO2 or 2Al2O3.SiO2), hematite (Fe2O3), maghemite (gamma form of hematite, ?-Fe2O3) and magnetite (Fe3O4). The mullite and quartz particles are usually present as spherical particles because they are formed by melting clays, feldspars, quartz, calcite and other common minerals in coal during coal combustion. The silicate particles have usually entrapped gas to yield hollow spherical particles because their lower melting point facilitates gas entrapment.The iron oxides are usually spherical also. The magnetite (Fe3O4) is derived from pyrite (FeS2), hematite (Fe2O3), siderite (FeCO3) and limonite (2Fe2O3.3H2O) in the coal. Maghemite (?-Fe2O3) is formed by dehydration of the mineral hydrohematite (?-FeO(OH)) and/or oxidation of magnetite (Fe3O4) during coal combustion. Maghemite (?-Fe2O3) and magnetite (Fe3O4) are strongly magnetic, so they are recovered from Chinese coal fly ash and widely used for coal processing in China (Fan et al., 2005, 2000)."

Jan 3, 2018

By S. K. Pan

The process flow-sheet adopted in treating hematite iron ore in India through wet circuit generates not only 15-25% slime of Run-of-Mine (ROM), but also results in loss of very high quality fine iron ore particles along with it. As the reserves of hematite iron ore is depleting, it is necessary to explore the possibility of upgrading other types of low grade iron ore and slime for recovery of iron minerals; extensive research in this field is being carried out. While beneficiation of low grade ore is yet to be established, slime beneficiation has been quite successful and many installations of slime treatment plant are underway. In SAIL mines, the slime is mainly the discarded particles from Classifiers, which are less than 0.2 mm sizes. R& D initiative has been focussed on the beneficiation of the slimes (49-60% Fe, 3-10% Al2O3 & 4-10% SiO2) of Dalli mines to generate concentrates assaying 62-64% Fe, 2-3% Al2O3, 3-4% SiO2 and a few innovative facilities for the same has been introduced at this mines of Bhilai Steel Plant (BSP). At Dalli mines, the slime is of very poor quality. A typical slime analysis assays 48.54% Fe, 15.1% SiO2, 8.5% Al2O3 and consists nearly 60% (by wt.) particles less than 38 micron. Slime analysis revealed substantial quantity of very high density mineral particles, those causes jamming of Thickener due to faster settling. A novel technique has been implemented to classify the concentrate ore particles from the gangue mineral particles by processing through Fluidized Bed Classifier (FBC) system, which is a gravity concentrator, to treat 50% of the slime generated and the rest is treated through de-sliming hydro-cyclone followed by Medium Intensity Magnetic Separator (MIMS). A special self-vibrating launder has been designed and introduced into the system to recover tiny iron ore particles, which could not get captured by the permanent Neodymium rare earth magnet in MIMS. The classified iron mineral particles from FBC are further treated in a battery of hydro-cyclones followed by modified Slow Speed Spiral Classifier (SSSC) unit. Multiple feed entry system to the SSSC unit is unique and use of particular feed entry point depends on the desired quality of the product and thus converted to a beneficiation equipment rather than mere de-watering unit. By processing slime in FBC system, the valuable iron ore particles with 62.5% Fe, 5.2% SiO2, 2.23% Al2O3 has been recovered from the slime at a material yield of 30%. And very high valued concentrate particles with more than 65% Fe has been sorted out through the magnetic separation route. The overall extra production of beneficiated slime concentrate is 40-45 tph with 63-64% Fe from a slime feed of 120-130 tph solid. This paper outlines few new approaches in iron ore slime beneficiation at Dalli mines for maximum recovery of valuable minerals. Keywords: fluidized bed classifier (fbc), iron ore slime of dalli mines, medium intensity magnetic separator, slow speed spiral classifier (sssc)

Sep 1, 2012

By XUEWEN WANG, Changda Zhang, Huaguang Wang, Mingyu Wang, Bin Hu

The copper smelting process produces plenty of copper slag every year, which is a hazardous solid waste, but a secondary resource. In the present study, the extraction of copper, nickel, and cobalt from copper slag was investigated through the process of sulfation roasting–water leaching and the process of sulfation roasting–sulfate decomposition roasting–water leaching respectively. Compared with the process of sulfation roasting–water leaching, the process of sulfation roasting–sulfate decomposition roasting–water leaching is a better choice, which could not only get almost the same leaching of copper, nickel, and cobalt as the former process, but has a lower leaching of iron and aluminum. For the process of sulfation roasting–sulfate decomposition roasting–water leaching, the leaching of Cu, Ni, and Co reached up to 74.2%, 71.1%, and 69.6% respectively, under the optimal conditions including sulfation roasted with 80 wt% sulfuric acid addition at 200 °C for 60 min and sulfate decomposition roasted at 650 °C for 60 min, followed by water leached at 90 °C for 30min with a liquid–solid ratio of 2 ml/g. The leaching of Fe and Al was only 4.9% and 17.6%.

May 4, 2020

By Dachun Liu, Xuepeng Li

Smelting-acid leaching process is a way to treat high-content arsenic containing copper dust. However, smelting makes a low recovery of valuable metals and acid-leaching produces large amounts of arsenic-iron slag. Arsenic sulphuration volatilization at low temperature was studied, followed by pressure leaching to selectively recover Cu, Zn, and In from copper smelting dust while minimizing arsenic contamination.

Mar 1, 2017

By Yubo Tu, Lianqi Wei, Tianyi Zhao, Peiwei Han, Zhengchen Li, Shufeng Ye

The effect of oxygen partial pressure on the volatilization percentages of valuable metals from iron-rich pyrite cinder by chlorination-volatilization method using CaCl2 as chlorinating agent was investigated in this study. The volatile products were collected directly and analyzed by X-ray diffraction. It was found that there were CuCl2, CuCl, PbCl2, and ZnCl2 existed in the volatile products. Au and Pb volatilization percentages were almost not affected by oxygen partial pressure. Both Cu and Zn volatilization percentages were negatively correlated with oxygen partial pressure when CaCl2 dosage was no more than 4 wt%, and almost uncorrelated with oxygen partial pressure with a CaCl2 dosage of 6 wt%.

Dec 19, 2023

By Chao Li, Lim Hongxu, Yuyue Wang, Xie Yang

"A intergrated process of sulfuric acid leaching, sodium chloride leaching, lead chloride crystallization, lead hydroxide synthesis and roasting was carried out for the recovery of lead, cadmium, copper and zinc from lead smelting dust containing various metals. The results showed that the separation of cadmium, zinc and copper from dust could be obtained after sulfuric acid leaching and corresponding leaching rate were 92.12%, 90.25% and 88.26% respectively. The subsequent sodium chloride leaching carried out for lead with optimized parameters as: sodium chloride concentration 250g/L, leaching temperature 90°C, leaching time 2h, pulp density 33g/L, 0.12mol/L CaCh; The lead compounds crystallization rate reached 86.67%, and then transferred into mPbO·nH2O, the product of 98.66% ß-PbO could be obtained through roasting under 502°C. In the end, a feasible method of ß-PbO preparation from lead containing dust was put forward.IntroductionThe pyro-metallurgy flue dust from smelting lead activities are often stockpiled and pose potential environmental risks due to the heavy toxic elements, such as Pb, Cd, As, Cu, Cl, and Zn which are contained in the dust. With the rapid depletion of rich ore resources in recent years, it has become increasingly more financially attractive to recover valuable metals from previously stockpiled dust, while simultaneously reducing the potential of environmental pollution from toxic elements contained in the dust. Nowadays, pyro-metallurgical and hydrometallurgical routes or both combined methods can be developed to treat secondary materials such as lead ash, leach residues etc. By comparison the hydrometallurgical processes are often considered more eco-friendly.Some chloride leaching processes for recovering lead have been employed using either NaCl, or MgC2 and CaCl2, or FeCl3 [1] The effectiveness of the brine leaching method is based on the formation of complex metal chlorides in concentrated chloride solutions [2] Similarly, Other metals such as zinc, cadmium and copper contained in the flue dust are often treated with sulfuric acid, hydrochloric acid, ammonium solution and sodium hydroxide etc. as lixiviants [3] The metals from leach solutions thus has been obtained by precipitation, ion exchange, solvent extraction or replacement [4]"

Jan 1, 2014

By Shun Myung Shin, Dong Hyo Yang

Cobalt is recovered from square type of spent lithium ion batteries (LIBs) containing 5~20 % Co, 5~7 % Li, 5~10 % Ni, 15% organic chemicals, and 7% plastics together with Cu, Al, Fe, and Mn. The waste LIB was prepared by physical treatment. After screening, the crushed LIBs were separated to +8 mesh, -8/+16 mesh, and -16 mesh powder. Among these, -16 mesh powder was selected for leaching. The leaching test was investigated at 2 M H2SO4, 6 vol.% H2O2, reaction temperature 60 ?, agitation speed 300 rpm, solid/liquid ratio 50 g/ 500 ml, reaction time 1 h. The leaching efficiency of cobalt was more than 99 % and its concentration was 24.9 g/L. For removing of impurities such as copper, iron, and aluminum in the leaching solution before cobalt solvent extraction, the impurities were eliminated by pH control with alkali solution. For selective extraction of cobalt, the aqueous phase removed impurities was equilibrated with different volumes of 0.4 M Cyanex 272 saponified of 50 %. Extraction efficiency of cobalt was about 80 % at first step. Separation coefficient (ßCo/Li) of cobalt and lithium extractions was 206.5. Over 9.0 % of pure cobalt sulfate solution was obtained after stripping with H2SO4 solution.

Jan 1, 2008