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By Laszlo Valentyik

To separate minerals on a small scale according to their specific gravity, heavy liquids are used, but because of high costs and health hazards they cannot be used in large scale plants. In order to substitute heavy liquids, finely ground solids like magnetite and ferrosilicon mixed with water and clay for the required specific gravity are employed. The clay present in the medium acts as a stabilizing agent since the coarse heavy media solids would sink very fast to the bottom of the container if they were mixed only in water. The optimum amount of clay varies for different processes, but it is generally between 3-6% by weight concentration of solids. As the pseudo-plastic nature of polymer solutions has excellent suspending properties, investigations were conducted at the Institute of Mineral Research to ascertain whether polymers could be used commercially as suspending agents for finely ground heavy media.

Jan 1, 1973

By Laszlo Valentyik

The wide scale acceptance of the heavy media separation is due to its simplicity and efficiency. The two most important variables of the process are specific gravity and consistency of the medium. The latter is a function of the settling rate of the media solids. The almost always present clay in the feed and conse¬quently in the medium acts as a stabilizing agent, and its optimum concentration varied between 3-4%.(1,2) Since polymers essentially perform the same function in oil well drilling muds - i.e. to suspend cuttings during drilling - as the fine clay in heavy media separation, this led to the investigation of whether polymers could be used in heavy media separation as supporting agents. During the first phase of the work, it was found that by the controlled addition of polymers, the stability of the heavy media increased without unduly increasing viscosity of the suspensions, thus yielding conditions for more effective and efficient separation. The results of the experiments were reported in a paper at the AIME Centennial Annual Meeting, March 1971.(3) This paper presents the results of the experiment carried out during the second phase of the work.

Jan 1, 1975

By Laszlo Valentyik, John T. Patton

A conventional heavy-media separation process utilizes a mixture of finely ground solids like magnetite, ferrosilicon, or shale and water. The always-present clay in the medium acts as a stabilizing agent since the coarse heavy-media solids would quickly sink if they were mixed only in water. As the pseudoplastic nature of polymer solutions has excellent suspending properties, laboratory investigations were conducted at the Institute of Mineral Research on whether polymers could be used as suspending agents for finely ground heavy media. The preliminary results (published previously) of the laboratory research studies have shown that sufficient stabilities of heavy media can be obtained at a relatively low polymer concentration. This paper is a continuation of the previous work and it presents some of the results of recent studies where the rheological properties of the heavy-media suspensions were studied in a newly developed settling tube and the already familiar concentric-cylinder-type consistometer. In the investigations bentonites as a stabilizing agent also were included so that comparative results would be available to the plant engineer to assist him in the choice of the most suitable material for stabilizing various heavy media.

Jan 1, 1977

By Omid Lashkari

Keywords: SEED, SSM materials, Microstructural evolution, Rheology, Swirling Speed SEED (Swirled Enthalpy Equilibration Device) is established itself as a new technology amongst the many Semi-Solid Metal (SSM) processes, where swirling of the mush plays an important role in modifying the dendritic structure of as-cast parts. A range of semi solid metal structures, dendritic, rosette and/or globular morphology of primary phase, can be prepared using SEED. The current article reports on the application of rheological tests in characterizing microstructural evolution during SSM processing of 356 Al-Si foundry alloy. A simple parallel plate test machine, designed and constructed at our labs, was used to determine viscosity values for each structure and identify the optimum structure with superior die filling characteristics. Such findings have important technological and economical implications during high pressure die casting of semi- solid metals. The strain-time graphs for 356 Al-Si foundry alloy indicated lower viscosity values for globular microstructure, i.e. improved die filling.

Jan 1, 2005

By V. Pouyafar

In recent years semi-solid processing of steel alloys has gain more attention among researchers. Production of high quality complex steel parts with higher mechanical properties is the final goal for all these researches. A thorough understanding of the flow behavior of the metal under investigation is the key for a successful process design. The material used in this research is M2 tool steel. The experiments were performed using a Searl-type concentric cylindrical rheometer which is specially designed for high temperature rheological measurements up to 1500 ºC. The rheological techniques were consisted of continuous cooling experiments and isothermal holding and also shear rate step change experiments for different solid fractions. Based on the rheological data a single phase thixotropic model has been derived and adopted to the measured data. The state of the microstructure has been applied through a structural parameter. The model fits well with the experiments.

Oct 1, 2011

By C. Camurri

Results from the Metallurgical Department of Universidad de Conception showed that fire-refined copper could be rolled without previous remelting for deoxidation. The goal of this work is to determine the rheology of fire-refined copper from tensile tests at different temperatures and strain rates, and Ford plane compression tests. All that in order to simulate and calculate rolling process variables. For rheology hardness coefficients, n variables between 0.28 at 600°C and 0.46 at ambient temperature are obtained. The sensibility coefficient for strain rate m varies between 0.056 at 600°C and 0.006 at ambient temperature. The activation energy for plastic flow Q in the considered temperature range is 1436 cal/mol.

Jan 1, 1999

By N. Mangadoddy, M. Padhi

The simulation of multi-component classification with modified viscosity model is the key focus in the current study. The classification of the ores using hydrocyclone is a renowned process and has a convoluted flow separation phenomenon. The highly turbulent flow inside hydrocyclone depends on the operating and design parameters apart from the feed mixture. Slurry viscosity also plays a dominant role in the classification of solid particles under the centrifugal settling action. A heterogeneous mixture with different components would result in different settling and rheological behaviour of particles’ suspension in the water medium. The newly proposed multi-component viscosity model (Mandakini et al. 2020) is implemented as a user-defined function to define the material property during the CFD study of the mixture rheology inside hydrocyclone classifier. The multiphase and turbulence model is solved using the modified Algebraic Slip Model and Large Eddy Simulation model. A comparison of the predicted component performance curves is evaluated with and without the corrected viscosity model. The density and size effect on the particle phase distribution inside the classifier are compared, where the misplacements of the finer particles are carefully assessed. Validation of the component classification in hydrocyclone with the laboratory experiments found a close agreement with the rheology based CFD data. Keywords: Dual-component, multi-component viscosity model, double-gap rheometer, computational fluid dynamics, high solids concentration

Jan 1, 2020

By M. Pawlik

The rheological properties of mineral suspensions affect the design and operation of transport, mixing, size classification, grinding, gravity concentration, flotation and de-watering systems. In many cases, the rheological properties can be modified to improve processing through the addition of chemical additives. These additives may be either organic or inorganic and generally affect the state of particle aggregation or dispersion. Inorganic modifiers act primarily by affecting the surface charge of mineral particles and thus control the magnitude of electrostatic attraction/repulsion between particles. The action of organic additives (polymers and surfactants) is a combination of electrostatic and steric forces – the latter being related to the molecular weight of these reagents. While low molecular weight polymers are dispersants (viscosity reducers), high molecular weight polymers are likely to induce flocculation and increase yield stress.

Jan 1, 2004

By Markus Thewes, Mario Galli

"INTRODUCTIONProject-related studies showed that lab tests are a helpful tool for the planning of EPB tunneling and soil conditioning in cohesionless soils. This type of ground commonly represents the extended application range for EPB shields, which demands for a treatment with additives. Considering soil conditioning with foam, so far, approaches exist for the investigation of the foam quality and of the conditioning behavior of soils (e.g. (EFNARC GUIDELINES 2001 2003)), but not any standards for testing procedures related to soil conditioning. State-of-the-art research on the topic is and was conducted for example in Bochum (Germany) cf. (Budach 2012; Maidl 1995), in Lyon (France) cf. (Quebaud et al. 1998), in Oxford and Cambridge (Great Britain) cf. (Borghi 2006; Peña Duarte 2007), in Delft (Netherlands) cf. (Bezuijen and Schaminée 2001), in Turin (Italy) cf. (Borio 2010; Peila et al. 2013; Vinai 2006), and in Aachen (Germany) cf. (Vennekötter 2012). Additionally, applied science is reported by the tunneling practice and suppliers of conditioning agents. Although the research focus in all these and further studies varied, similar test methods and test series were applied. A standardization of essential properties and testing methods (setup and procedures) however did not take place. The results from laboratory testing can only function as index values for practice because in the studies, production and application of the conditioning agents mainly takes place under atmospheric conditions. Nevertheless, the tests enable basic understanding of feasibility as well as processes and interactions going on during soil conditioning. For recommendations for standardized and reproducible testing see (Budach 2012; Budach and Thewes 2015).The most extensive investigations on the flow behavior of soil-foam mixtures have been performed by using the slump test from concrete engineering, cf. (DIN EN 12350-2 2009-08), which originally is applied on evaluating the workability of fresh concrete. Although this test does not describe the actual flow behavior, it rather represents an index on the workability, very much experience exists with this test method. Besides others, the workability – or flow behavior – of the EPB support medium certainly is a major factor of influence on the properties of the material in the excavation chamber and thus, for effective tunneling with EPB shields, cf. (Galli and Thewes 2014). For a summary of various investigations on the workability of conditioned soils using the slump test and resulting recommended slump ranges see (Budach 2012; Vinai 2006). Thereof, slumps between 10 and 20 cm have been reported as suitable workability for EPB applications. However, there is actually not much known about the real flow behavior of soil-foam mixtures related to rheological properties such as the viscosity (?) or potential yield stresses (t0). These physical values are necessary for a realistic determination of face pressure, for the design of required torques, and for an evaluation of the material flow at different locations in the excavation chamber, in the screw conveyor or on the conveyor belt. To generate a linear pressure distribution at the tunnel face, as it is assumed a priori, a low-viscosity fluid is favorable, whereas in the screw conveyor, a high-viscous fluid is needed for a controlled pressure decrease. On the conveyor belt, yield stress plays an important role preventing deliquescence and spilling from the belt. Attempts in characterizing the actual flowing of soil-foam mixtures have so far only been made by few researchers, the application of rheometry is rare."

Jan 1, 2016

By M. B. Daza, B. Lattimer

"Even with modern detection and firefighting techniques, mine fires continue to be a safety concern. However, some underground mine fires can be addressed with the remote application of high expansion foam, reducing firefighter exposure to hazards. The flow of this foam can be numerically or computationally simulated in order to gain a better understanding of its behavior, but rheology parameters are needed as inputs to produce accurate simulations. For this reason, this work studies the rheology of firefighting high expansion foam using a foam generator and Poiseuille –Flow Rheometer. Rheological parameters for foams with expansion ratios between 250-1280 are represented by the consistency index (k) and the power law index (n) due to the results show a strong agreement with the Power Law model for non-Newtonian fluid viscosity. Furthermore, experimental results show that high expansion foam behaves as a shear thinning fluid with a power law index around 0.4 and viscosities in the range of s 0.1 Pa-s and 0.042 Pa-s under shear rates between 44 ??-1 and 187.3 ??-1. INTRODUCTION High expansion foams are called to foams with expansion ratio greater than 200. Expansion ratio (??) is defined as the ratio between the volume of foam produced (i.e. volume of foam solution and volume of gas) and the volume of foam solution used (NFPA 2014). Because of its high expansion ratio, one of the most important application of high expansion foams is to fill or flood large spaces such as hangars, storage facilities and underground mines for fire suppression. The foam can fill large structures using small quantities of foam solution within a short time (Sthamer 2012) (Martin 2012). Although the specific high expansion fire suppression mechanism has not been understood on a quantitative basis, a possible mechanism is fuel isolation when the foam act as a physical barrier between oxygen and the flame. Furthermore, as a consequence of this contact water is evaporated, causing cooling of fuel and surrounding air. Besides, water vapor as product of water evaporation causes a dilution of oxygen concentration available to the fire (Fleming and Sheinson 2012). High expansion foam can be applied remotely by means of conduit pipes or in situ close to the fire. In most of the underground mines scenarios, fires have to be addressed remotely to reduce miner and firefighter exposure to the hazards (Smith et al. 2005). Although high expansion foams should not be blasted and must be deposited directly on the area of application because of their low density (Harding et al. 2016) sometimes it is complicated to apply it directly to the fire due to complex access areas at underground mines. In these cases, foam has to be applied far away from the fire. Despite of this fact there is a lack of knowledge in terms of rheological behavior of high expansion foam under high shear rates (Gardiner, Dlugogorski, and Jameson 1998). Furthermore, there are a few attempts to simulate numerically the high expansion foam flow due to the ignorance of its rheological parameters and its complex behavior. (Weaire 2008)."

Jan 1, 2018

By M. H. Colebrook

Nickel laterites contain about 70% of all continental or terrestrial nickel resources; therefore the recovery of nickel from lateritic ores has large economic significance. The processing of lateritic ores involves the preparation and movement of concentrated aqueous suspensions. However due to complex characteristics and non-Newtonian properties, ranging from shear-thinning to shear-thickening and from thixotropic to rheopectic, a basic understanding of the flow behaviour must be developed. This understanding will assist in the development of new plants and the operation of existing plants. The work in this paper involves the characterization of three ore types from the Vermelho ore deposit to categorize them as rheologically simple to complex. Rheological testing was also conducted on pure mineral samples that represent the main minerals in these samples. The results show that the rheological properties of the ore types can be related to the surface properties and physical characteristics of the main mineral constituents.

Jan 1, 2006

By Michael Li

Paste backfill as a means of supporting underground mining is gaining popularity. Despite this trend, engineering and design of mine paste backfill systems are still largely based on empirical methods rather than established scientific principles. Because of a lack of sound understanding of mineral paste flow, some degree of trial and error is often involved during commissioning and operating of new paste fill systems. New operations often have to be built with flexibilities and contingencies, escalating the overall project costs. This paper reviews the applicability of some scientific and engineering principles to mineral paste flows. Recent experimental data are used to illustrate important points. The phenomenon of mineral paste flow is examined under the context of improving the efficiency and reliability of underground delivery. Gaps in our understanding of mineral paste rheology are pointed out and from those some future research directions naturally emerge. Status and problems of the current engineering and design practice are also briefly discussed.

Nov 1, 2002

By P. Somasundaran, D. R. Nagaraj, Tarun Bhambani, P. Patra

Flotation separation and recovery of value minerals from ores containing fibrous silicate minerals are known to be quite challenging. Earlier studies have established that the metallurgical challenges (poor selectivity and recovery, high energy consumption, etc.) arise from the impact of the fibrous minerals (with high aspect ratio) on pulp rheology, which was found be rather complex. The complex rheological behavior of ore suspensions containing particles with high aspect ratio and its influence on flotation outcome are investigated in this study. Flotation tests and rheological measurements were carried out with both ores (containing fibrous minerals) and a model system comprising nylon fibers (chemically inert) added to a copper ore that had no fibrous mineral. These studies allowed the determination of contributions of physical properties of the fiber to pulp rheological behavior. Optical microscopy images of the fiber pulp indicated that the fibers entangled to form two levels of microstructures: two-dimensional (2D) aggregates under semi-dilute (< 20% solids) conditions and three-dimensional (3D) microstructures at concentrations > 30% solids. The yield stress (σ) values determined for the fiber pulp were logarithmically related to the volume fraction of the 2D/3D structures. The relationships developed here for different ARs showed that the yield stress of a flotation pulp changes with respect to shape, size, and the concentrations of the microstructures. Implications to the effects of such entangle networks on selectivity of flotation separation are discussed.

By Burt Ensley, Viatcheslav Dushenkov, Ilya Raskin, David E. Salt

Roots of many hydroponically grown terrestrial plants, including sunflower (Helianthus annuus L.) effectively remove toxic metals such as Cu+2, Cd+2, Cr+6, Ni+2, Pb+2 and Zn+2 2 from aqueous solutions. It should be possible to scale up this process such that plant roots can be used to treat large volume aqueous waste streams. It can be extrapolated from laboratory results that to reduce the Cd concentration in a waste stream, from 1 ppm to below 4 ppb, with a flow rate of 4000 L/min, would require 3500 sq. m of plant roots with a density 5 kg fresh weight per sq. m. These results suggest that the roots of hydroponically grown terrestrial plants may provide an attractive alternative to the accepted water treatment technologies.

Jan 1, 1995

By J. C. Taylor

The Rhodax inertial cone grinder, designed by France?s FCB Group Fives, is the result of three years, theoretical and mechanical research in the field of compression grinding by the research staff of FCB?s CRM minerals research centre. A number of potential uses have been assessed and will be discussed in the paper. The crusher is an inertial grinder that works on the pressurized bed fragmentation principle. The fragmentation force is caused by the rotation of unbalanced masses rather than by an eccentric mass, as is the case in a conventional crusher. This makes it possible to achieve very high reduction ratios. By controlling the speed of rotation of the unbalanced masses, the grinding force can be modified, thus changing the product size distribution. The paper describes the machine layout, operating principles, control parameters and will briefly describe the results obtained on reef, waste and ROM reject pebbles. Some comparisons are made with conventional crushing.

Jan 1, 1998

By J. Portal

One of the key products produced by the mineral sands industry is the titanium dioxide slag, a process that requires grinding of a coarse product down to a valuable saleable product. Traditional methods have included the vertical roller mill in tandem with dynamic air classifiers and, alternatively, two-stage grinding and crushing through an AG mill in closed circuit with a dynamic classifier and secondary gyradisc crushers. The products produced, commonly known as chloride and sulphate slag, are differentiated by the particle size distribution of the final product. The more valuable chloride slag must, by specification, be a product sized in the range between 850 and 100 microns?the more fines generated in the grinding process, the less higher valuable final chloride slag is produced. This paper will explore a technology that is new to both the mineral sands and to other mineral processing industries. Inter particle communition, or IPC as it is known, has been applied in the cement industry to improve the performance of clinker grinding mills. The principle is to create a process of material on material comminution under high pressure that fractures the material along the grain boundaries rather than breaking it smaller than a gap setting in the crusher. The process is now looked at for the TiO2slag producers because of the potential benefits of energy savings and with a minimal generation of minus 100-micron fines. Discussions will revolve around the design and functionality of the Rhodax® both from a process and maintenance perspective, a typical test regime and results on slag grinding. The development of the flowsheet necessary for the process will be examined, the ancillary equipment required and finally the scale-up from the test to an industrial plant will be investigated. Full-scale results of an operating plant will also be given showing the benefits that can be realized. A promising new flowsheet with fines reintroduction to the Rhodax® crusher will be presented.

Jan 1, 2007

The eastern part of the state of Rhode Island on both sides of Narragansett Bay, including the island of Rhode Island, is underlaid with carboniferous rocks which carry veins of anthracite. This formation extends into the neighboring portion of Massachusetts, including the area from the state line, the towns of Mansfield, Brockton and Bridgewater,: and extending probably ten miles east of the latter two towns, to Middlesboro, and to Fall River. In Massachusetts the coal formation extends over nearly the whole of Bristol, and parts of Plymouth and Norfolk Counties. In Rhode Island and Massachusetts the area covered is about 400 square miles. In both states the exact limits of the coal measures cannot be determined on account of a thick layer of drift which overlays it. Along parts of Narragansett Bay, the coal measures outcrop in the cliffs on the west side of Rhode Island, and the presence of coal here seems to have been noted as early as 1760, and in 1768 a patent was granted to parties who "were about to dig after pit, coal or sea coal" at the back of the town of Providence. In 1807-08 Benjamin Silliman, later a geologist, visited some openings,&apos; and in 1808 a mine was opened near Portsmouth, in the northeast part of Rhode Island. Work was done here until about 1814 when the mine was abandoned. No anthracite had been used in New England at that time, all coal used came from Nova Scotia, Virginia or England, and was high volatile bituminous; neither experience nor the means of firing favored the use of the local fuel? This mine was again working in 1827, was again abandoned and operations were resumed in 1847. In 1837 a note in a magazine mentions, "the immense coal mine in Cumberland-about six miles from the city of Providence" as having a shaft 14 ft. in diameter and 80 ft. deep, that the horses then used for hoisting the coal were to be superseded by a steam engine and another shaft was to be sunk. With these improvements 30,000 to 50,000 tons were to be produced the following year at a cost of $1 per ton and a sales realization of $6.1 Hitchcock&apos;s report refers to a number of localities in both states where definite knowledge of coal existed. These are:

Jan 1, 1942

By Gabriela Pino, Maurício Torem, Lorgio V. Gonzales

It has been long known that many microorganisms are able to interact with mineral particles to obtain a concentrate; thus, one possible technique is flotation and its related process. Biological process have been attracting attention in mineral processing due to lower operating cost and their possible applications to process low-grade and fine ores. The adhesion of microorganism to surface of mineral particles can alter the hydrophobicity of mineral markedly. Such surface modifications modify its hydrophobicity or hydrophilicity will be used to flotation of cassiterite fines. The major difficult to float fine particles is attributed to the low probability of bubble-particle collision, one characteristic of electroflotation process is the ability to create very tiny bubbles, which is known, improve the collision efficiency and flotation performance of fine particles. In this study, the electroflotation of fine particles using Rhodococcus opacus strain as bioreagent was investigated. Electroflotation experiments were carried out using particles of cassiterite around 8µm of mean diameter the adsorption of R. Opacus onto cassiterite particles was confirmed by Fourier transform infrared spectroscopy (FTIR), electrokinetic and contact angle analyses. The measurement of bubble size by laser diffraction showed a mean bubble size of around 26 µm, current density and bacteria concentration appear to be the main parameters affecting the mean diameter of bubbles, electroflotation tests reported recovery around of 64.5 % at pH 5, concentration of 2,87 x10¹² cells/ml (50 mg/L) and current density of 51,4 mA/cm2.

Jan 1, 2014

By P. R. Goad

"Kidd Creek is a large volcanogenic base metal sulphide deposit, located near the west end of the Abitibi greenstone belt, 27 km north of Timmins, Ontario. The rhyolite geology is characterized by a NNE-striking and steeply east-dipping package of rhyolite volcaniclastics upon which has been imposed a strong ESE-striking and north-dipping structural fabric . Massive rhyolite units with grey-black. chloritic cores and yellow, sericitic margins intrude as dykes into the stratigraphic footwall and as sills higher in the stratigraphy. Massive rhyolite units positioned near the top of the felsic pile exhibit an extensive marginal development of hydraulic fracturing and are termed crackle-brecciated rhyolite.The stringer sulphide zone is positioned in a lobate blanket of crackle-brecciated rhyolite at the top of the felsic pile. The stringer sulphide zone is characterized by a mature chemical alteration, being specifically depleted in alkalis and enriched in iron-rich chlorite. with accompanying silica, sericite and carbonate alteration. A suite of trace elements characterizes this mature alteration. The massive rhyolite units, which intrude lower in the rhyolite volcaniclastics, exhibit a core of weak chlorite alteration and strong marginal sericite alteration. Tight or unfractured massive rhyolite units are essentially devoid of sulphide mineralization and exhibit a suite of trace elements characteristic of this immature alteration. It is interpreted that the massive rhyolite units intruded into an already evolving system and ""choked-off"" active conduits carrying hydrothermal fluids and subsequently acquired an immature alteration signature. Rhyolite units positioned higher in the pile developed intense hydraulic fracturing and a mature alteration coincident with the formation of the stringer sulphide zone. In summary, a model, based strictly upon the rhyolite geology, is reviewed to assist in the exploration for volcanogenic base metal sulphide deposits."

Jan 1, 1985

By J. E. Spurr

"Zinc Industry in BelgiumBy March F. Chase, Consulting Metallurgist, Bureau of MinesBelgium for many years was the principal spelter producing country of the world. Gradually its production was surpassed by that of Germany, and Germany in turn lost first place by the production in the 77ti.tad States. For the ten years previous to 1914, 21.6 per cent of the world's spelter was produced in Belgium. Of this production approximately 40 per cent was exported. A large percentage of the balance was rolled and of the shoots thus produced a considerable quantity was also exported.From an economic standpoint even before the war, the Belgian industry was in a unique, if not praoarious, position. Dependent upon foreign countries for ore and foreign markets for sale of products, smeltor was at a distinct disadvantage when compared with some of those of other localities. These disadvantages were partly offset by cheap coal and labor and by whatever there is of value in experience and what we may term for want of a better expression smelting tradition. However intangible this latter may be, it did have and has today an influence on commercial operations.One must not overlook the effect it will have on the revival of the industry. It may not be the determining factor but the fact that for so many years this industry flourished in Belgium, and played such an important role in the industrial life of the country will decide many operators to attempt to re-establish their operations.In 1913 the Belgian spelter plants produced 204,220 long tons of spelter or approximately 20 per cent of the world's production. During this year 500,000 to of ore were treated. The actual value of all of the products derived from treating sine ore amounted to 225 million frames."

May 1, 1919