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By Milton Lissberger

MILTON L. LISSBERGER, ? New York, N. Y.-Solder is a mechanical mixture of tin and lead, a fact which is susceptible of very simple demonstration. A bar of solder of a grade even as low as 30 per cent. tin and 70 per cent. lead, passed through a buffing machine, will show a surface practically identical with that of a bar of second-quality or reclaimed tin. The buffings, on chemical analysis, will prove to be almost pure lead. According to the best practice, solder is made in the following manner. Virgin pig lead is first melted, and when it is thoroughly liquefied, virgin pig tin is added, together with a small amount of flux; the latter is for the purpose of bringing to the surface the so-called "liver," consisting of impurities that may have remained in either the lead or the tin as a result of incomplete refining. The combined material, when completely liquid, is thoroughly stirred for some hours, and is then cast into small pigs. Just before casting, and continuously during this operation, the molten metal yields dross, consisting largely of the oxides of lead and tin; this should be carefully skimmed off. After the pigs have cooled, they are taken to a smaller kettle, remelted, and cast into the desired shape for use; or if wires, ribbons, etc., are to be made, the solder is cast into slugs suitable for extrusion and rolling. During this second operation, the skimming of dross should be even more carefully done than at first. Hand mixing has proved to be the only reliable method for the production of the best quality of solder, irrespective of its percentages of lead and tin. The best quality of solder is not necessarily that which contains the highest percentage of tin, but rather is that composition which performs best on the required piece of work. In order to produce

Jan 12, 1918

By Daniel J. Rider

In 1980 the Niagara Frontier Transportation Authority contracted for three miles of cut and cover box structure and station construction in Main Street, Buffalo, New York. Project depths ranged from 30 feet to 60 feet below street grade. Soils, Figure No. 1, consisted of loose to very compact sands and gravels. Ground water level was generally 20 feet below grade. Specifications required a soldier pile and timber lagging support system with external dewatering. Soldier piles were to be installed in prebored holes with bentonite slurry and lean concrete backfill. Conventional pile driving was not allowed due to concerns over excessive noise and vibrations and its effect on nearby historic structures and the surrounding population

Jan 1, 1987

One of the engineering proposals in the last Congress which was of interest to engineers was the soldiers' land settlement plan proposed by Secretary Lane, under which returned soldiers, sailors and marines would be employed on construction work in the reclamation of swamp and arid lands and would thereafter be given preference in the selection and settlement of those lands. This bill failed in the fillibuster at the end of the session. It is likely that some sort of a plan for soldiers' settlement will come before the next Congress. A new bill has been written up for introduction at the next session which proposes an "infiltration method" of buying improved farms in established communities for' the soldiers' settlement purpose, under the authority and direction of the Farm Loan Board. The contrast of this bill to the one recommended by Secretary Lane is of vital importance to engineers at this time; first, because of the broad engineering improvement program that the latter bill proposes as against no engineering improvement under the infiltration plan; secondly, the community settlement plan of Secretary Lane means improvement of waste lands requiring much engineering work.

Jan 7, 1919

By G. E. Bandelis

In this paper, solid bed erosion processes and the mechanisms involved when a two-phase liquid-solid mixture flows over a bed of solids in a horizontal annulus are analyzed. There are few such studies available with some authors arguing that the flow rate for erosion is always less than the flow rate for the suspension of solid particles thus necessitating further study and analysis of such phenomena. Tests were run to determine the mechanism of erosion and the erosion velocities of the solid bed formed in a concentric annulus for three flu-ids, water, a low concentration water solution of Carboxyl-methyl-cellulose (CMC), which behaved as a Newtonian fluid and a higher concentration CMC water solution which behaved as a power law fluid. Glass spheres of 2 mm nominal diameter were used as solids. The flow rate at which erosion occurred together with the mechanism of bed erosion were determined visually, while the whole process was video recorded. Our tests indicated different erosion mechanisms and different erosion velocities for the three tested liquids, with the liquid viscosity playing a major role. The first mechanism, observed for water flow, gives erosion from the front of the bed while the second mechanism, observed for the flow of the two viscous fluids, gives erosion from the top of the bed. The role of each of the parameters to erosion is investigated, whether it is turbulent flow with the turbulent fluctuations being more capable to remove the solids from the formed bed or whether it is liquid viscosity, which results in the hydrodynamic shearing force. The results demonstrate that liquid viscosity plays a role in the erosion mechanism and yields different erosion velocities of the solid bed hence, it should be taken into account when modeling flow pattern transitions for solid-liquid flows. Prior studies have not identified this and it could be the reason of the disagreement between theoretical models and experimental and field data.

Jan 1, 2006

By James A. Bloom

To operate the Morris Fork Preparation Plant with a closed water circuit has been an elusive goal for Union Carbide. The benefits of a closed circuit have never been questioned. The removal of fine solids from washery water makes possible the recirculation and reuse of the water. Heavy media drag tanks and other separating machines perform better and more consistently with washery essentially free of fine solids. Finally, the production of a clarified effluent makes unnecessary the sludge ponds usually associated with a coal preparation plant. Why then do I say elusive? Because, since plant design was completed in 1970 we have been in hot pursuit of an ever-growing fine solids problem. In four years the minus 28 mesh material in the plant feed has nearly doubled. The replacement of conventional sections with continuous mining machines has led to a lowering in size and quality of product from the mine. In addition, increasing emphasis underground on roadway clean-up has contributed to the fines problem.

Jan 1, 1975

By M Player, R Klug, N Schwarz

There are several technologies available for thickening and dewatering of mining process slurries. The most commonly used are thickeners and filters, but technological developments have made solid bowl decanter centrifuges a viable option and their use, as a modern and alternative technology, is being considered more and more. In terms of tailings, the main goal for all mine operations is to minimize operating costs and the environmental impact of the disposed material. The high potential risk of wet tailings storage in tailings dams is causing this technology to become unpopular, and there is a strong drive in many parts of the world, by governments, communities and environmental agencies to limit any further construction and use of such facilities. For the alternative disposal method of dry disposal of tailings, two aspects of the process have to be evaluated, namely the maximum dryness of the separated solids and the maximum liquid recovery. For most mining operations dry disposal is a new concept. Presenting these companies with examples of operations where this processing option has been successfully applied and proven, will help them to adapt to the changing requirements in the future. Focus has been placed on adapting decanter centrifuges to the mining environment. Modern decanters stand out in terms of their small footprint, low water demand, high availability and their high degree of automation, combined with the excellent cost / performance ratio. Decanter centrifuges have started to play a key role in applications such as tailing dewatering, drilling and tunnelling muds processing, hydrometallurgical processes of gold, nickel or zinc and separating crud in solvent extraction plants. This paper will present advantages of decanter centrifuges compared to the traditional technology and corroborate these advantages by case studies.

Jul 1, 2021

By Richard A. Cubeta

Precast concrete segments have been used in sanitary sewer tunnel design for decades. Federal mandates (reduction in heavy metals and I & I), and system design changes (increased retention times) and other factors have exacerbated corrosion problems. In an effort to combat the ever-growing effect of microbiologically induced corrosion, owners, engineers, and designers have been specifying thin-film lining systems to protect precast concrete segments. These systems have compatibility and installation issues. Chemical additives or calcareous aggregates have been utilized in precast concrete, but have only proven to retard the rate of corrosion and do not eradicate the problem. Solid cast polymer segments are stronger than precast concrete, do not require linings or coatings, are impervious to ground water infiltration, and, above all, are inherently corrosion resistant through and through.

Jan 1, 2008

By D E. Langberg, J S. J va, D R. Swinbourne

Specifications on the types and levels of impurities tolerable in metals are becoming increasingly stringent, and are pushing the limits achievable with conventional refining technologies. Particularly difficult is the removal of electrochemically noble elements with low volatilities, such as copper, from more active host metals such as lead, iron and aluminium. Electrochemical refining, utilising the ability of certain solid electrolytes to selectively transport copper or other impurity cations away from the molten host metal into a separate refining phase, may provide an answer to this problem. Numerous studies on solid electrolytes used in concentration sensors have been reported, as well as a limited number on metal refining. Oxygen anion conducting solid electrolytes have been applied to the deoxidation of copper and steel while cation conductors, eg ¯ -alumina and Nasicon materials, have been used to remove lithium and sodium from aluminium. However, solid electrolytes have yet to be applied to the removal of noble elements. The behaviour of solid electrolytes under the extreme conditions of molten metal refining is not well understood. This paper will examine the potential use of solid electrolytes to remove noble metals such as copper from active host metals such as iron. The suitability, and selection criteria of available solid electrolytes for implementation in the metal refining industry in the future will be discussed. In particular, the stability of Cusicon, a copper superionic conductor potentially suitable for use in metal refining, has been assessed and the results of the experiments are presented.

Jan 1, 2000

During the 1998/99 Asian crisis Solid Energy's export revenues collapsed from over US$70M to under US$40M. Simultaneously, domestic market uncertainty led to decreases in volumes and prices. A major new underground mine was not technically viable, and was closed, and several other mines were marginal. Less than two years later, Solid Energy and its JV partner closed a second new underground mine. The company was in financial crisis, and reported an $86M loss for 1998/99. After refinancing with stringent workout conditions it still had minimal returns due to low prices, unaffordable transportation costs and huge unrealised FX losses as the NZ dollar fell 40 per cent in value. The obvious scenario was to æcash upÆ û complete extraction at remaining mines, sell off any viable parts of the business, pay off debt and wind the company down.In 2002 Solid Energy has completed its recovery. Although margins remain slim and volatile in both export and domestic markets, it is achieving record volumes and revenues. It has paid off its shareholder loan, has minimal remaining FX losses, and cashflow is allowing further mine and infrastructure development. The key to the turnaround has been implementation of rigorous planning, analysis and decision-making in all aspects of the business. The company has a comprehensive, rolling 20-year plan used annually to update rolling five year and annual business plans. Solid Energy augments strong line management operations with rigorous standards and processes for mine planning and development, operational decision-making, and functional support. Detailed, quantitative risk analysis is used in all aspects of the business and allows comprehensive integration of opportunity and risk management across all activities in the company.Coal mining is widely perceived as an æold-economyÆ industry. But, like other successful æold economyÆ companies, the information systems and management processes used by Solid Energy are as leading edge as any in the high-tech sector. They are the key to managing to add and sustain maximum value for a company that has access to coal resources sufficient for hundreds of years.

Jan 1, 2002

By Harold E. Rowen

Sintering is accomplished at a temperature of more than 2000°F. For the purpose of this discussion it will be defined as the art of burning a solid fuel with 90 to 95 pct ash content. Think of the problems of combustion involved in keeping a home furnace burning properly with 12 to 20 pct ash in the fuel and remember that the amount of fuel involved in the 5 to 10 pct combustion loss represented by the definition has to be just about right or nothing is going to happen. Our forefathers discovered that many ores containing metals csscntial to the steadily rising standards of living were associated with other minerals, sulfur and arsenic, for example, which had to be removed before ultimate refining. They did this by utilizing the solid fuels they had available-the sulfur or other readily combustible components- to create roasting heat.

Apr 1, 1956

By H. EI-shall

In this paper, the results of a fundamental study involving zeta potential and turbidity determinations of solid suspensions are discussed. Illustrations of how these results are utilized to design field applications of solid grade polymers to clarify mine drainage water are presented. Other applications in different industries are also reported. The operational and economical advantages are examined.

Jan 1, 1994

By Xue Yongpeng, Zhu Zhenhai, Zhu Ming

The purpose of the Solid Medium Controlled Blasting Technique and Its Applications is to have the inside of the vessel-shaped framework (e.g: oil tank , water pool, gas chamber, chimney, water tower, grain warehouse and etc.) or the one side of the thin wall-shaped structure(e.g: steel bar concrete wall and etc.), both of which are intended to be demolished, inserted with the required solid medium (e.g: soil , sand , coal, salt and etc.) ,in which there is a certain mass density, and then through which the blasting energy is transferred to fulfill the blasting task. For such a technique, it is necessary to bury the explosives into the inserted solid medium and then to start the explosion to blast the intended target into pieces. The filling of the solid medium may be done mechanically or by man. Compared with the water pressure blasting technique, this one has the characteristics of good effect. wide application, simplified construction procedure , safe and reliable operation and small vibration (less vibration than water pressure blasting by 80% to 90%)in particular without any flying stones, thus resulting in better and comprehensive social and economickfficiency.

Jan 1, 2000

By Aline Lima da Silva

The present work is focused on the thermodynamic study of the methane or biogas mixtures conversion on Cu-ceria catalysts. Several experimental studies reported in literature have demonstrated the ability of these materials to operate as SOFC anodes for direct methane oxidation, with the evidence of enhanced tolerance towards sulfur poisoning and carbon deposition. More recently, experimental investigations have shown the feasibility of Cu-ceria anodes to directly operate with simulated biogas feeds at intermediate temperature (1023K). In this way, the effect of the ceria redox properties on the equilibrium composition is investigated, considering methane or biogas mixtures as the fuel. Conditions under which carbon deposition and sulfur poisoning can be prevented are determined. Our study combines results from the classical thermodynamics, obtained with the help of FactSage software, with the new Cu-S and Ni-S diagrams proposed in literature, which were calculated based on the Density Functional Theory (DFT). These diagrams are able to predict a region where sulfur interacts with the metal surface through chemisorption. A comparison between the performances of Ni-YSZ and Cu-CeO2 catalysts is established from a thermodynamic viewpoint. Theoretical results are in agreement with the experimental trends from literature.

Aug 8, 2018

By D. Perednis

Fuel cells with thin samaria-doped ceria (SDC) electrolyte films deposited onto an anode support using spray pyrolysis were fabricated. The SDC films were deposited onto porous NiO-YSZ substrates at deposition temperatures between 400°C and 450°C. The influence of process parameters such as deposition temperature, flow rate, type of salt and salt concentration on the quality of the film was studied. A smooth dense film was successfully deposited using the precursor cerium ammonium nitrate and samarium nitrate dissolved in butyl carbitol (33.3 vol.%), 2-methoxy-l-propanol (33.3 vol.%), and ethanol (33.3 vol.%) solvent mixture. A deposition rate of 125 nm/h was achieved.

Jan 1, 2005

By A. Krishnan

Keywords: Tantalum extraction, SOM Technology, inert anode, membrane stability The Solid Oxide Oxygen Ion conducting Membrane (SOM) technology offers great potential for environment friendly and energy efficient extraction of high-energy content metals. This work was performed to demonstrate the technical and commercial viability of the technology to produce tantalum metal directly from tantalum oxide and ore concentrates using a solid-oxide, oxygen-ion-conducting membrane (SOM). The process can be used to efficiently produce tantalum metal without expensive pre-processing of raw materials and without harmful by products. The work reported in this paper is: the proof that high purity tantalum metal can be produced, study of the electrochemical behavior of the cell and the method to increase membrane stability.

Jan 1, 2005

By Marko Suput

Titanium is a high-strength, low-density metal nearly immune to corrosion, but limited in use by its high price. The high price is due to the cost of smelting and processing the ore. The research on titanium production using the Solid Oxide Membrane (SOM) process aims to consolidate most of the processing steps required for conventional titanium production into a single step making it an energy-efficient and cost-effective method for producing CP billet and ingot and possibly also powders used to make titanium alloys. In the SOM process experiment, a steel crucible contains MgF2-CaF2-TiO2 flux; an inert metal/carbon rod serves as the cathode; an oxygen-ion-conducting yttrium-stabilized-zirconia (YSZ) membrane in the form of a one-end-closed tube contains either a liquid metal that acts as the anode or liquid MgF2-CaF2 ionic flux that connects the YSZ membrane to an anode. During electrolysis, when the voltage between anode and cathode is higher than the reduction potential of titanium oxide, titanium ions are reduced at the cathode and the oxygen ions pass through the YSZ membrane and are oxidized at the anode. The oxygen ions are oxidized at the anode by a reducing agent, hydrogen gas or carbon, forming steam or CO(g), respectively. To date, a suitable MgF2-CaF2-TiO2 flux has been selected and the operating temperature for the SOM process has been determined. Several electrolysis experiments have been performed. As expected, lower valence deposits of titanium oxides have been witnessed at the cathode prior to depositing pure titanium. Continuing work will aim to extend the electrolysis time in order to pass enough charge to produce a significant amount (100 g) of titanium at the cathode.

Jan 1, 2006

By Soobhankar Pati

Solid oxide membrane (SOM) technology has been successfully employed for the production of high energy metals such magnesium, titanium and tantalum by directly reducing their oxides. This paper reports on the recent investigation done for calcium production by SOM process from calcium oxide, dissolved in fluoride and chloride based fluxes. This process employs an inert oxygen-ion-conducting stabilized zirconia membrane to separate the inert cathode in the flux from the anode. When the applied electrical potential between the electrodes exceeds the dissociation potential of calcium oxide, oxygen ions are driven out of the melt and through the zirconia membrane to the anode where they are oxidized. Reduced calcium metal deposits or evolves at the cathode depending on the operating temperature. The SOM cell has been electrochemically characterized, and key concepts related to CaO dissociation, leakage current, solubility of Ca in the flux, and hygroscopic nature of the flux relevant to the SOM process are explained.

Jan 1, 2008

By D. J. Wall, T. D. Johnson, M. T. Parry, G. R. Heath

In coal-fired power stations coal is ground to a fine powder and then transported pneumatically at 25-30 m/s velocity to remote burners. Wear of the conveying pipework is a well recognised problem and traditional lining materials are Nihard and basalt. In many cases these are being replaced by alumina tiles in order to improve life and reduce the frequency of replacement. A programme of laboratory testing of candidate aluminas with AIO, contents between 85% and 99-5% has been undertaken and the results compared with field experience. This gives confidence in the erosion tests, which were designed to replicate most of the field conditions. However, it has not proved possible to draw correlations between the laboratory erosion rates and any of the materials’ bulk properties. SEM, TEM and microanalysis studies have therefore been made in order to look for microstructural aspects that could be influencing erosion rates and it has been shown that intercrystalline cohesion, the matrix phase and porosity appear to have most influence on wear performance. It is necessary to quantify these microstructural parameters if reliable erosion performance is to be obtained. This paper was read at the Institute of Ceramics Annual Convention at the University of Durham, April 1988.

Jun 12, 1905

By K. Lapakko

Several static tests estimate the capacity of mine waste to produce and neutralize acid and are used as tools for predicting metal-mine waste drainage quality. Various methods and their accuracies are addressed. More accurate quantification of these capacities, as well as their availability and reactivity, may be necessary to predict drainage quality from some mine wastes. Chemical analyses, x-ray diffraction, optical microscopy, scanning electron microscopy, and electron beam analyses are among the techniques commercially available to more accurately quantify these capacities and provide insight into their availability and reactivity.

Jan 1, 2003

By N. Lohja

Metallurgical industries are generally big producers of solid residues of various kinds. In contrast with the past where environmental sensibilities were not so elevated and the accumulated mass of these residues were not considerable, these days the solid residues are everywhere scrutinized among others in term of their harmful environmental impact and as possible materials for valuable elements extraction or secondary utilisation. As a case study, the present paper gives an overview of the solid residues discharged by the metallurgical industry in Albania for the last tens of years. The results of two monitoring study on the solid residues of copper, iron and ferrochromium producing industries are also summarized. The first deals with the origin, quantities and chemical composition of these residues and the second one with the impact of harmful ingredients of these residues in the environment. Some methods for the processing of these solid residues are also proposed in order to ensure a clean environment and to make not just possible but also economically viable their secondary utilisation. This work is part of a bigger cooperation project among local institutions and foreign expert companies such as Flogen Technologies Inc and other in various countries that will not only monitor the situation but will also develop appropriate technologies for treatment of these specific residues.

Jan 1, 2006