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By Jung-Joo Kim, Jong-Uk Kim, Turab H. Jafri, Han-Kyu Yoo

"INTRODUCTION Steel sets such as H-type and lattice girders are often installed in the tunnels before the hardening of shotcrete to ensure the stability of conventional tunnels in soft ground conditions. In practice, while designing the tunnels with the help of numerical analysis, steel sets are generally considered only as temporary support elements. Only a few studies propose the direct application of composite support in the tunnel design, based on large-scale experiments and numerical analysis. In order to assess the structural performance of the composite support consisting of shotcrete and steel sets, large-scale experiments were performed on two types of arch-shaped specimens by applying the combined effects of axial forces and bending moments. Based on the experimental results, numerical analysis was performed to assess the application of composite support in tunnel design. The crown settlement, axial forces, bending moments, and load distribution in the composite support were analyzed in the light of different structural patterns. LARGE-SCALE EXPERIMENTS USING COMPOSITE SUPPORT Preparation and Procedure of the Experiments The preparation setup as well as the organized procedure of the large-scale experiments using composite support is shown in Figure 1. An appropriate geometry of the specimens was selected by considering the standard cross-section of a two-lane highway tunnel in South Korea. Under the loading conditions meant to develop the axial forces and bending moments simultaneously, arch-shaped specimens were assembled with the ends of the specimens subtending a 60° arc angle at the center of the arc circle as shown in Figure 2. The fabrication of six specimens was completed in two groups based on the dimensions of steel sets, with the first group of three specimens being reinforced by H100 (No.1, No.2, No.3) and the other three by H125 (No.4, No.5, No.6). In order to reduce the voids on the boundary of the shotcrete and steel sets, concrete was casted over the steel sets instead of using shotcrete. The specimens were designed to incorporate the uniaxial compressive strength of 21 MPa. Shear keys and steel plates were installed at the ends of the specimens, so that shear failure could be avoided at the ends and the specimens could also be protected from detachment at the fixation. Translational and rotational movements at the ends of specimens were fixed."

Jan 1, 2016

By Peter Ay, Vincenz Mehlstaubl, Satyanarayana Narra

"This study gives an insight into non-destructive testing methods suitable for porosity analysis at a small scale, firstly summarizing relevant state-of-the-art technology and pending patents, secondly realizing and documenting the start-up of the VHX-2000 digital microscope by the manufacturer Keyence and thirdly demonstrating practical application with the extended analysis of three fundamentally different agglomerates for which important application-related parameters are determined. Various analysis procedures on the different agglomerates the efficient and timesaving operational features of the digital microscope are outlined. Firstly an analysis of flax fibre agglomerates determines the process conditions best suited to produce agglomerates with specific properties by determining sphericity, cubicity, density and porosity as well as fibre damage and alteration. Secondly the production of iron-hydroxide - hemp-fibre agglomerates serves to obtain information on porosity values as a result of a cauterization of the fibres. The third analysis provides estimations of porosity values for acid-treated lignin agglomerates. Measurements were carried out with compact dry agglomerates and with soaked, expanded agglomerates, determining factors for total water carrying capacity. Practicability of non-destructive testing by digital microscopy is demonstrated and explained concerning the applications in this study by obtaining definite structural findings about the analysed agglomerates. Information on its operation is made available by a practice-oriented manual for the VHX-2000 digital microscope. Further suggestions for more in-detail analysis results with different instruments are given."

Jan 1, 2014

By M. A. H. Shuva, M. A. Rhamdhani, G. A. Brooks, S. H. Masood, M. A. Reuter

Ferrous-calcium-silicate (FCS) based slag has been used in the copper industry over the last two decades. The FCS slag has also been used in a secondary copper processing such as in black copper smelting which has different operation conditions compared to that of typical primary copper processing. In the process, a variety of copper bearing scraps from sources such as industrial waste, consumer waste and electronic waste (e-waste) are used. The valuable metals in these sec- ondary resources are distributed in different phases during the process. Understanding the behaviour of the valuable elements at the relevant conditions is vital for optimizing the process and to maximize the recovery of the elements. In this study, we investigated the structure of Ge-containing FCS-based slag at different conditions (oxygen partial pressure and temperature) using Fourier-Transform Infrared (FTIR) spectroscopy to explore the effect of the polymerization on the behaviour of the valuable element Ge in the slag. It was found that experimental parameters significantly in fluence the slag structure, and therefore, the partitioning of Ge in the slag. A correlation between the distribution ratio of Ge and the slag structure has developed in the current study.

Mar 1, 2018

By D. H. Y. Tang, S. S. Peng

Three-dimensional finite element modeling (3-D FEM) was performed to analyze the safety factors of stump pillars, 5.5 m x 5.5 m, under a cover of 63 m using the Modified Drucker-Prager Theory. The results showed that they were safe. This was substantiated by underground observations. But the safety factors predicted by three commonly used pillar design formulae showed otherwise. This paper discusses the modeling details and analyzes the difference between 3-D FEM method and traditional pillar design formulae.

Jan 1, 1987

By D. H. Y. Tang

3-dimensional finite element modeling was performed to analyze the safety factors of stump pillars, 18 ft. x 18 ft., under a cover of 208 ft. using the Modified Drucker-Prager Theory. The results showed that they are safe. This was substantiated by underground observations. But the safety factors predicted by three commonly used pillar design formulae showed otherwise. This paper discusses the modeling details and anlyze the difference between 3-D FEM method and traditional pillar design formulae.

Jan 1, 1987

By H. Urata, K. Ishii

To determine the effect of F ions in the molten alkali silicate systems on their structures, quenched Na2O-SiO2-NaF systems were investigated by Raman spectroscopy and molecular dynamics simulation. The systematic increase of 1100 cm-1band intensity in the Raman spectra of the silicate melts accompanying the replacement of F for O provides the evidence for concomitant polymerization of melts. From the molecular dynamics simulation, it was confirmed that most of substituted F was mainly coordinated to Na+ ions but not Si4+ions. These results were consistent with the mechanism in which F associated with otherwise network-modifying Na rather than with network-forming Si. Since F was associated to Na+ ions, the replace of O ion by two F ions promote the polymerization of silicate melts. Keywords: fluorine; molten flux; slag structure; molecular dynamics simulation; Raman spectroscopy.

Jan 1, 2004

By George H. Davis

The Caribou sulfide deposit near Bathurst, New Brunswick (Figure 1) is illustrative of one variety of strata-bound sulfide deposits. It consists of numerous near-vertical sulfide lenses which are concordant to the foliation and lithologic layering of low-grade metamorphic host rocks. Pyrite is the chief mineral in these lenses, but appreciable quantities of sphalerite, chalcopyrite, and galena are also present. Rocks in the Caribou mine area belong to the Tetagouche Group of Ordovician age. They consist chiefly of (1) quartz-sericite and quartz- sericite- feldspar schists, (2) greenschists, and (3) slate and phyllite. The trends of these steeply dipping rocks define the trace of a tight, steeply plunging fold structure, the Caribou fold (Figure 2). This fold plunges approximately 750 to the north-northwest; its axial plane strikes N.20°E. and dips steeply westward. Sulfide lenses of the Caribou deposit are associated spatially with the Caribou fold. The deposit is located in the fold along the contact between quartz-sericite and quartz-sericite-feldspar schists on the hanging wall and quartz-chlorite-sericite phyllites and graphitic schist on the footwall (Figure 3). Genesis of the Caribou deposit is ambiguous because its strata-bound form suggests syngenetic sulfide deposition, whereas its location within a fold suggests structurally controlled epigenetic mineralization. Acceptability of a particular genetic model rests on establishing the time of mineralization relative to deposition, deformation, and metamorphism of the associated rocks. To establish the timing for Caribou mineralization, the deformational histories of rock and sulfide, respectively, were compared. Epigenetic and syngenetic models can be tested against this interpreted structural history of the Caribou deposit.

Jan 1, 1971

By Igor Zh. Bunim, Valentine A. Chanturiya, Alexey T. Kovalev, Irina A. Khabarova, Elizaveta V. Koporulina

This paper presents new theoretical and experimental data on possible mechanisms for the formation of micro- and nanophases on the surface of sulfide minerals un der the effect of high-power nanosecond electromagnetic pulses (HPEMP). The gas outflow from nanosecond breakdown channels of sulfide minerals under the effect of HPEMP is considered, with allowance for the condensation of iron vapors. The condensation of matter in an outflowing jet is shown to be an effective mechanism for structureal and chemical transformations of sulfide surfaces. It is established that electrode potential of pyrrhotite is moved together in the negative party owing to formation of iron oxides (hydroxides) and iron sulfates by HPEMP, that provides decrease of xanthate sorption and reduction flotation extraction of this sulfide, whereas electrode potential of pentlandite gets more positive values at the expense of additional formation of element sulfur, that causes increase of xanthate sorption and, as a consequence, increase of nickel sulfide extraction.

Jan 1, 2012

By V. A. Chanturiya

The application of High-Power Nanosecond Electromagnetic Pulses (HPEMP) irradiation in dressing of resistant gold- containing ores appears attractive as this technique provides for a significant increase in precious metal recovery (30-80% for gold and 20-50% for silver), therewith helping reduce both energy consumption and the cost of products. The prospects for applying pulsed power technologies in the mineral processing in order to increase the contrast between the flotation properties of raw minerals dictate the need to perform special studies of the effect of HPEMP on the structural state, phase composition, and physical and chemical properties of surfaces of sulfide minerals as the main carriers of precious metals. This study deals with plausible mechanisms of the micro- and nanophases formation on the surfaces of sulfide minerals under the effect of high-power nanosecond electromagnetic pulses (HPEMP) with high electric field strength ~107 V/m. This paper discusses reasons for the changing of flotation behavior of natural pyrite and arsenopyrite during the pulsed-power treatment. It was concluded that HPEMP treatment may be regarded as a tool to change the surface composition and sorption ability of collector (xanthate) onto mineral surface, and, therefore, it allows to control the hydrophobic-hydrophilic surface balance. Single mineral flotation tests have been shown the significant increasing of the pyrite recovery while the arsenopyrite was depressed. The results of gold containing pyrite (pyrrhotite)-arsenopyrite ore flotation in batch approve the decreasing of arsenic recovery in sulfide concentrate. Keywords: pyrite, arsenopyrite, high power nanosecond pulses, activation, selective flotation

Sep 1, 2012

By C. B. van den Berg

n this study, silver and palladium nanoparticulate inks with different metal-binder ratios were screen-printed onto a paper substrate. The printed layers comprised the metal nanoparticles and an ethylcellulose binder. The layers are not typical metal composites due to the low concentration of binder and high porosity. The electrical sheet resistivity of each particle concentration was measured, and the data fitted using the scaling law of percolation theory and the general effective media (GEM) equation. The percolation parameters, i.e. the percolation threshold and the critical exponent, for each system were determined from the fits and compared. The percolation threshold for the palladium layer (39.8 wt%) was lower than that found for the silver layer (44.9 wt%). The critical exponents determined for the palladium and silver layers were both lower than the universal value for three-dimensional percolation systems. Microscopy observations indicate that the difference in the percolation threshold for the two layers can be attributed to variations in their microstructure.

Jan 1, 2014

By Chen Ya

Layered LiMn0.5Ni0.3Co0.2O2 was prepared from Mn(NO3)2, Ni(NO3)2, Co(NO3)2 and LiOH by co-precipitation and solid state reaction. XRD, C-V and galvanostatic charge-discharge methods were used to examine the structural and electrochemical characteristics. The LiMn0.5Ni0.3Co0.2O2 delivered a high discharge capacity of 167 mAh/g between 2.5 and 4.3 V with excellent cycling stability.

Jan 1, 2006

By Jamil M. Khalifeh, Shadia J. Ikhmayies, Bothina A. Hamad

"The structural and electronic properties of cubic d -NbN are investigated using density functional theory (DFT) and all-electron full potential linearized augmented plane wave method (FPLAPW). The equilibrium structural parameters are determined by fitting the total energy as a function of volume to the Murnaghan's equation of state. We calculated the total and partial densities of states (DOS) and compared them with those computed by different authors. Our DOS at Fermi level is found to be very close to the experimental value. The band structure is computed, discussed and used to find the characteristic energy separations. Valence electron density contours are recorded and discussed. We deduced the partial charge densities of different bands and binding energies of valence core levels and compared them with experimental and theoretical results obtained by different authors.IntroductionNiobium nitride has been intensively investigated over the last decades because of its interesting physical properties and technological applications (superconducting microdevices, microelectronic, catalytic probes, and hard coatings) [l]. While the group IV transition metal nitrides (TMN) mainly crystallize in the cubic NaCl structure (Bl type), those of group V and VI nitrides occur as different phases. Thus for niobium nitride, many phases have been reported in the literature: cubic fcc d -NbN, tetragonal ? -Nb4N3, hexagonal d -NbN, hexagonal e -NbN, and low nitrogen content hexagonal ß -Nb2N [l, 2].Structural and electronic properties of niobium nitride were investigated theoretically and experimentally by many authors. For example, in 1975 Schwarz [3] obtained the partial density of states for NbC and NbN from APW band structure calculations. In 1975 Kallne and Pessa [4] studied the electronic structure of Nb, NbC and NbN by using X-ray emission. In 2003 Amriou et al. [5] studied the electronic structure and bonding mechanism of NbC and NbN compounds using first principle total energy calculations using the full-potential linearized augmented plane wave method. Also in 2006 Sanjines et. al [l] studied the electronic structure of the hexagonal~Nb2N, hexagonal' d -NbN, and cubic d -NbN thin fihns by using X-ray photoemission spectroscopy. They [l] also calculated the densities of states for these phases and used them in the interpretation of the experimental valance band spectra. Most of these studies are old and there is a need for more recent studies. According to our knowledge, there are little comprehensive theoretical studies on this subject by using FP-LAPW method [5], which proved its ability to give accurate results. In this work we used the FP-LAPW method to study the structural and electronic properties of the cubic (fee) o-NbN (space group Fm-3m, prototype NaCl) crystal."

Jan 1, 2013

By Y. Q. Li, X. H. Long

In this work, structural and electronic properties of smithsonite (ZnCO3) and cerussite (PbCO3) as the typical lead-zinc oxide minerals is simulated by means of DFT. The calculated results could be concluded as: (1) The density of states (DOS) of Zn atom in ZnCO3 is nearer to the Fermi level than that of Pb atom in PbCO3, suggesting that the Zn atom of ZnCO3 is more active and easier to interact with water molecules and hydroxyl ions. Smithsonite, therefore, could be more readily depressed in the flotation process. (2) The bond population value of Zn-O (0.23) and C-O (0.92) in ZnCO3 is obviously larger than that of Pb-O (-0.01) and C-O (0.85) in PbCO3, indicating that the covalent characteristic of ZnCO3 is stronger than that of PbCO3. (3) It is shown that the charge of Pb (+1.32e) in PbCO3 is more positive than that of Zn (+1.22e) in ZnCO3, suggesting that cerussite is easier to interacting with HS- compared with smithsonite in the flotation process. In summary, the structural and electronic property of smithsonite is completely different with cerussite, leading to the difference of their flotation behaviour.

Jan 1, 2015

By Mohammad Eslami

The Tabriz-Urmiyeh Highway shortens the distance of north-western cities of Iran by about 130 km, resulting in improved access and efficient transit between Iran and Europe through Turkey. The highway crosses the Urmiyeh Lake, an inland lake surrounded by mountains. Due to the circulation of salt-water in the lake and the necessity to continue shipping between adjacent ports, a waterway should be kept open. Consequently, a bridge was built to provide access of marine traffic. A causeway bridge had a length of 1,260 m, comprising of 19 spans. In construction of the bridge, more than 400 piles having a total length of 32 km have been driven. For design of piles different methods have been used such as static analysis, dynamic testing, and correlations to in situ tests, such as cone penetration test (CPT). This paper presents construction of bridge substructure, full-scale piling tests, and methods of analysis used in the evaluation of the deep foundation capacity. The presentation includes an assessment of four current direct CPT and one CPTu methods to calculate the bearing capacity of the piles. It was found that the CPTu and dynamic testing are two suitable tools for rapid and optimum pile design and verification.

Jan 1, 2010

By Hellsten KJ, Butt CRM

Major Francis Hamilton Buchanan coined the term `laterite' (Latin; brick-rock) in 1807 for the red earths used for building blocks in southern India. Although these earths were actually weathered basalts, the term is now applied to weathering profiles developed upon a wide range of bedrocks. The Ni-laterites are a special class within the broad laterite family.

Jan 1, 1996

By L Xiong, W J Shi, J H. Wei

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Baizhangzi gold deposit is located in the northern North China Craton. The structural and lithological controls on the location and geometry of orebodies were studied through geologic survey, ore spatial configuration analysis and structural analysis. The orebodies of the deposit comprise auriferous quartz-sulfide veins and disseminated gold-bearing sulfides. The auriferous quartz-sulfide veins are dominantly hosted by the NNE- (and NE- and NW-) trending faults, which are subsidiary structures of the regional NNE-trending F2 fault. The subsidiary NNE-trending faults, having sinistral reverse kinematics, are associated with the sinistral reverse kinematics event of the F2 fault, which happened under a regional S–N-oriented compression stress field. The subsidiary NE- and NW-trending faults appear to be compressive and extensional respectively. These NE- (and NW-) trending faults are restricted to the granite intrusion and are associated with a sinistral strike-slip event of the F2 fault, which reactivated under a NW–SE-oriented compression stress field. It makes significant influence on geological evolution and distribution of different ore types that the strike of the F2 fault presents significant transition from NNE- to NE-trending in vertical. The ore-bearing disseminated host rocks, with widespread silicification and pyritisation, distribute in the lower inner contact zone of the granite intrusion, especially in the lower wavelike boundary of granite intrusion.CITATION:Xiong, L, Wei, J H and Shi, W J, 2015. Structural and lithological controls on the location of orebodies in the Baizhangzi lode gold deposit in western Liaoning Province, China, in Proceedings PACRIM 2015 Congress, pp 193–200 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By Dobos SK, Gibson GM, Little TA, Sliwa R

Current studies, and analysis of previouslypublished data, have lead to a re-evaluation of the inclusion of the North D'Aguilar block within the "Gympie Province" in southeast Queensland. The metamorphic rocks are part of a Late Devonian(?)-Early Carboniferous subduction accretionary complex and are unconformably overlain by volcanic and coarse-grained clastic rocks of probable Early or mid-Permian age, as well as by Early to middle Triassic rocks of the Esk Rift. Metamorphic fabrics in the basement rocks include not only those that can be related to convergence, but also younger fabrics that may have developed during Late Carboniferous or Permian uplift and unroofing of the accretionary rocks. A predominance of basic schists, some of which are blue amphibole-bearing, and associated fine-grained pelagic and hemipelagic sediments in the Northern D'Aguilar block contrast with the siliciclastic-dominated sediments of most of the accretionary complexes of the New England Orogen. However the similarity of structural style, and metamorphic and igneous history, with adjacent basement blocks, and with other blocks throughout the New England orogen, suggests that the North D'Aguilar block simply represents deeper, probably underplated, levels of the same subduction complex. Uplift and cooling may have been accomplished by extensional faulting during Permian inception of the Esk rift, which flanks the block on the west.

Jan 1, 1990

By A. L. D. Skury

In the synthesis of diamond, the precursor graphite must present a degree of crystallinity to assure optimum yield and quality for the transformed crystals. X-ray diffraction, SEM and TEM analyses were carried out to investigate the structural and morphologic transformations produced in natural graphite by high pressure-high temperature treatment. The present study had as its objective to characterize the morphological and structural changes suffered by a natural graphite that was subjected to high pressure and high temperature treatments in the region of diamond thermodynamic stability. The results indicate that the material that constitutes the gasket, for the deformable capsule, could act as catalyst in the graphite recrystallization process.

Jan 1, 2006

By Wieslaw Blaschke

The transformation of Polish economy, has contributed to the significant ownership changes and the way of management. Most of non-ferrous metals producers are now joint stock companies or stock companies, which shares are owned mostly by Polish shareholders, the State Treasury, banks or trading companies. However, as compared to the international tendencies, the cost of production of base metals in Poland are still relatively high, and the utilization of secondary sources is still very low. In this sense, the paper point out that some positive results of the current pro-ecological mineral policy in Poland have been already clearly visible in the case of non-ferrous metals smelters, where the emission of dusts and gases was significantly reduced. Therefore, if the current increasing tendency of world production of non-ferrous metals continues, Poland’s role as their primary producer will be reduced.

Sep 13, 2001

By A. R. Kinkel

The Shasta copper-zinc district of northern California lies in the foothills of the Klamath Mountains at the northern end of the Sacramento Valley. It contains two main areas of base-metal ore deposits, the East Shasta and West Shasta districts shown in Fig. 1. The East Shasta includes the area from the Afterthought mine, near the settlement of Ingot on U. S. highway 299 East, to the Bully Hill mine, on the north side of the Pit River, 9 miles to the north- west. The West Shasta, a well-defined northeast- trending district about 8 miles long and 2 miles wide, west of the Sacramento River, Fig. 2, is the western part of the ore-bearing area formerly known as the Shasta copper belt. Referred to in the older writings as a copper arc, this belt was thought to form a crescent extending entirely around the head of the Sacramento Valley, the convex side to the north. Recent studies by the U. S. Geological Survey in cooperation with the California State Division of Mines show that there are two districts, one at each end of the so-called copper arc, which are distinct in geologic structure and ore occurrences, and that there is only sporadic and unconnected copper mineralization between them.

Jan 2, 1955