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By J. B. Vander Sande, I. G. Solórzano, B. S. You, P. M. Jardim, W. W. Park

"Alloys with six different compositions in the system Mg-Ca-Zn were produced by melt spinning. The aging behavior of alloys was investigated by measuring the changes in microhardness after isochronal aging and the microstructure was analyzed by means of transmission electron microscopy (TEM), energy dispersive X-ray spectrometry (EDS), scanning transmission electron microscopy (STEM) and scanning electron microscopy (SEM). All six compositions in the as-solidified condition show a difference in microstructure between the wheel contact side (zone A) and the free surface side (zone B) as a result of the differences in the solidification rate across the ribbons. One of the alloys (Mg-l.5wt%Ca-6wt%Zn) was chosen to be more deeply investigated in this work as it exhibited grain boundary films and an age hardening behavior was produced in that alloy.IntroductionMagnesium is the lightest of all the commonly used metals, and very attractive for applications in transportation. It also has a number of other desirable features, including good ductility, better damping characteristics than aluminum, and excellent castability. However, there are some negative features, such as high reactivity in the molten state, inferior fatigue and creep resistance as compared to aluminum, poor corrosion resistance and high production cost.In recent years there has been a significant increase in magnesium use as a structural material. These structural applications include aerospace, automotive and nuclear industries as well as appliances and sporting goods (1 ). According to reports on Mg-Zn alloys, the addition of Zn (2) in magnesium increased strength. Also, since the maximum solubility of Zn in magnesium is 6.2wt%, a considerable amount of Zn can be retained in solid solution in magnesium alloys by rapid solidification. In addition, Ca is known (3) to be one of the most potent alloying elements for refining the microstructure and precipitates in magnesium alloys, and also to improve mechanical strength and corrosion resistance."

Jan 1, 2000

The past decade has seen a great increase in activity in deep seismic reflection profiling of the continental crust. Some 20 countries have conducted field experiments and the total length of deep seismic profiles surveyed to date is approximately 25,000 km. This total is very large compared to the quantity of such data that existed previously, but very small compared to the total length of seis- mic profiles of the shallow crust carried out for petroleum exploration, which some- times has exceeded 600,000 km on land in one year alone and 1,600,000 km/yr on land and sea. Furthermore, 25,000 km of seismic pro- filing corresponds to exploration of only a tiny fraction of the total volume of the entire continental crust. Thus at this stage of development of the subject, one must be wary of generalizations that are based on these limited data and then ex- tended in scope to include the crust everywhere. The state of the subject is such that virtually every new seismic line reveals totally unexpected seismic fea- tures, a sign that the subject is in its major discovery phase and a warning to the generalizers. Nevertheless, in addition to much new information on deep crustal structure in specific locations, some broad consequences of application of this powerful geophysical technique to a region of the earth not pre- viously explored in this manner are be- coming clear. One is that, as seismic data on the deep continental crust become more abundant and more revealing of complexi- ties, the deep crust can be far better re- lated to rocks at the surface. Conse- quently, the geological style of reason- ing is now being extended from its normal domain of the near-surface to include the deepest crust in a comprehensive story of the evolution of the continents. This change is a subtle but important one and is evident, for example, in some cross sec- tions of the North American Transect Pro- gram, which show surface geology extended in a consistent, though speculative, manner to the top of the mantle. In other words,

Jan 1, 1987

By J. M. Belland

This paper deals with the geology of the Smallwood mine in relation to its influence on mining and milling operations. Structure within the orebody, and variations in ore grade and material types, will be described and associated with the various drilling, blasting and milling operations. The orientation of planes of weakness, either bedding or jointing planes, and contacts between extremes in material types influence the size of the broken material. Generally speaking, variations in grinding rates and recovery can be associated with stratigraphic sequence and metamorphism.

Jan 1, 1966

By Ralph L. Rutherford

Introduction During the past twenty-five years we have seen considerable exploration for oil on the plains of southern and east-central Alberta. This exploration has to some extent gone on in cycles, with periodic starts, stops, and occasionally some reversals. Each major attempt is usually supplemented by the application of some new method of exploration and, following each period of exploration, drilling tests are made. Whereas oil-bearing horizons are the ultimate objective of these explorations, the preliminary investigation frequently aims at a discovery of structure based on the long accepted belief that accumulations of oil and gas are to a marked degree structurally controlled. At the inception of this general exploration for oil, it was natural that attention should be directed to areas where there was surface evidence of deformation of the underlying strata, but, as the programme progressed, it was found that these surface manifestations of structure were often deceptive when attempts were made to project them to depth, to involve the deeper strata. Drilling of test wells was the only satisfactory method of obtaining exact information.

Jan 1, 1946

By G. M. Furnival

A PROGRAMME of structure drilling was commenced in the Southern Alberta Plains in June, 1943, for the purpose of determining the geological structure of the underlying sediments. More than 270 holes have been drilled throughout an area of some 1,800 square miles or 1,000,000 acres (see Figure 1). The Southern Plains of Alberta are covered by a mantle of glacial drift,' at places exceeding 200 feet in thickness. Only where this mantle has been dissected by deep drainage channels is bed-rock exposed to any great extent. Along such channels, surface geological mapping can be conducted to ad- vantage. Accordingly, geological mapping was commenced _in 1942 and continued each season to the present. To supplement this information, a survey of the water wells was carried on in conjunction with the mapping. However, to obtain more positive and evenly distributed structural control throughout the area as a whole and to define more adequately structural trends indicated by the preliminary mapping, it was necessary to resort to the use of drills to penetrate the glacial mantle. Various types of light drills are commonly used for this purpose and provide geological information in the form of drill cuttings, cores, drilling time rates, etc. Correlation of information is generally obtained through comparison of cored sections, drill cuttings, micro-fossils, and drilling time rates. However, in this case the holes were electrologged and correlations were made chiefly by comparison of such logs. The data so obtained is plotted and portrayed in the form of structure contour maps on recognizable stratigraphic horizons and in the form of isopach maps of the recognizable stratigraphic intervals penetrated in the holes. This method had not been widely used in Alberta previously and the technique employed was necessarily developed after the project began.

Jan 1, 1945

By Zhuokun Cao

Manufacture of aluminum foams still suffer from nonuniformity and poor reproductively for there is lack of basic knowledge of foaming process. In this paper, carbon fibers are used as novel stabilizing additive for aluminum foams, and the structure evolution of aluminum foams with different fiber content was studied. A laser rangefinder was used to detect the expansion rate of different al foams. Al foam samples are solidified at different foaming time to determine its relative density and cell size distribution. Results indicate that the cell size of foams linearly increases with the decrease of density, and the slope of the line is influenced by fiber content. The relationship between expansion ratio, density and cell size of the foams is discussed. It is concluded that the density of resulting foam is influenced by the rate of gravity driven drainage, and its cell size is determined by expansion ratio and foaming time.

Jan 1, 2010

By L. Katgerman, H. J. Brinkman, J. Duszczyk

"The phase formation sequence in the in-situ synthesis ofTiB2 in A1 from elemental A1, Ti and B powders is identified with a combination of DSC and XRD. After the melting of A1, A1B2 and A13 Ti are formed at the contact areas between A1-B and A1-Ti. The influence of variations in starting composition on the reaction kinetics is explained in terms of there effect on the different processes in the formation sequence. Parameters in the starting composition that were investigated are; fraction ofTiB2 forming reactants, non stoichiometric Ti:2B ratio's, and addition of alloying element Cu.It was found that a liquid Al phase is necessary for the in-situ TiB2 forming reaction from the intermediate A1B2 and A13 Ti phases. If all Al is consumed by the formation of A1B2 and A13 Ti the TiB2 formation is halted until the decomposition of A1B2 and A13 Ti .Overstoichiometric amounts of B are needed for complete conversion of the Ti, present in A13Ti, into TiB2 This is explained by the fact that some of the stable A1B12 phase is formed after the decomposition of A1B2•The addition of Cu leads to an increasing reaction rate in the A1-Ti reaction. A possible explanation for this is that the A1-Cu liquid penetrates more easily between the Ti and its surface oxide than the unalloyed A1 liquid."

Jan 1, 1998

By Billington WG

A structural study of northwest Fergusson Island, part of the D'Entrecasteaux Group, was undertaken using colour and monochrome aerial photography and Landsat imagery. The resulting interpretation shows an upstanding, in part, dome-like metamorphic core complex, which is bound on three sides by an en echelon series of low-angle, thrust faults. Faceted gneissic layers occur throughout the complex. These facets are triangular in plan view and range in size from a few tens of metres, to massive composite zones which traverse the entire uplifted zone, The lower surface of each of the facets are, in fact, low-angle decollements which, during uplift, slid one upon the other to accommodate the vertical and extensional movements. As a consequence, deep structural valleys developed which widen towards the zone of maximum uplift. In many places, recognisable topographic features are replicated on both sides of these valleys, and under the stereoscope can be visually reconstructed to their original pre break-up positions. The southern margin of the core complex is less dome-like and falls away, via a series of deeply-entrenched structural valleys, towards a volcano-studded lowland. The lowland appears to belong to a rift or arm, stemming from the more southerly located Goodenough Bay Infrabasin.

Jan 1, 1987

By Z. Zhang, R. G. Reddy

Experimental and thermodynamic modelling studies on the structure of alkali borate melts and properties are discussed. A thermodynamic structure model for alkali borate melts is developed to describe the distribution of structural groups in the alkali borate melts as a function of composition. A qualitative interpretation for the boron anomaly in viscosity has been proposed, which regards the boron anomaly as a manifestation of the various antithetical effects caused by the introduction of alkali oxide into boric oxide. It has been found that the viscosity of alkali borate melts increases or decreases according to the changes in rigidity and spatial connectivity of the glass network structure, which is the function of temperature and composition. These concepts with some key examples are discussed in relation to their usefulness and practicality in industrial slags. Keywords: alkali borate melts; structural model; activities; structural groups; viscosity;

Jan 1, 2004

By Xiaodong Jia, Richard A. Williams

"The packing of particles is a fundamental property of a material or system made up of particulates because it underlies many other physical properties of that material or system. Despite being ubiquitous, particle packing has not been an easy subject to study either experimentally or theoretically, except for a few regular shapes.This paper describes the recent developments, arising from research at Leeds, in the computer modelling of packing of complex shaped particles and prediction of physical properties of the structures represented by the packing. The computer model DigiPac, is capable of packing particles of any shapes and sizes in a container of arbitrary geometry. Figure 1 shows a few examples that are relevant to the mining and mineral industry.The ability to predict packing structure of real particle shapes and to compute directly some structuredependent physical properties (such as liquid permeability, mechanical strength/stability, compaction and sintering, dissolution and leaching, etc.) is obviously highly desirable and has significant potential in industrial applications. Examples are presented relating to the packing of granular materials.The mining and mineral engineering industries are well placed to exploit this advance in digital packing and simulation since they deal primarily with asymmetric and complex particulate mixtures. In the future we expect to see a number of developments in this area including:Algorithms that can optimise packing to achieve user-defined propertiesA more rational approach to determining flowability of complex powdersUse of these more realistic packing algorithms linked to blast and crusher design"

Jan 1, 2003

By Xiaodong Jia, Williams. Richard A.

This paper describes the recent developments, arising from research at Leeds, in the computer modelling of packing of complex shaped particles and prediction of physical properties of the structures represented by the packing. The computer model DigiPac, is capable of packing particles of any shapes and sizes in a container of arbitrary geometry. The ability to predict packing structure of real particle shapes and to compute directly some structure-dependent physical properties (such as liquid permeability, mechanical strength/ stability, compaction and sintering, dissolution and leaching, etc.) is obviously highly desirable and has significant potential in industrial applications. Examples are presented relating to the packing of granular materials.

Jan 1, 2003

By Barry C. Roth

A Real Time Automated Remote Reading Electrolytic Tilt Monitoring System was effectively deployed for monitoring an existing five story brick building during underpinning, shoring and excavation operations for a directly adjacent thirty-foot deep excavation. The monitoring system was comprised of four sets of uniaxial electrolytic tilt meters connected to a Campbell datalogger with multiplexer, cellular modem and solar power. The excavation was for the foundation and underground parking as part of a new 55 story tower complex. Challenges to the contractors and to our monitoring personnel which were addressed included a tight urban site contemplating property line to property line new construction with directly adjacent old existing buildings, buried concrete foundations from former site use, cohesionless pervious sandy soils and high groundwater. Highly variable and diurnal ambient temperature regimes due to adjacent building shadows required careful corroboration and application of temperature corrections to the raw data. Earth tides were suspected on a very small scale and investigated by correlation between the data and the local sinusoidal tidal ephemera. Incidental inadvertent contractor interference with the instruments during underpinning due to site constraints was readily detected.

Jan 1, 2007

By John Norton

THE tremendous increase in the use of metals that have been prepared by the various cold-working processes during recent years has greatly stimulated the investigation of problems concerned with the fundamental nature of these processes. It has been observed in practice that different methods of bringing about the same dimension changes in a sample result in a rather wide range of properties. Cold working reduces the ductility of a metal, or what is perhaps more nearly correct, its "working capacity," and naturally the manufacturer wishes to produce an article that has as large a working capacity as possible, and to produce it with the smallest number of operations, It has also been known for some time that cold deformation produces a parallel alignment of the crystal grains of a metal, and that the type of this preferred orientation depends to some extent at least upon particular processes employed in the deformation. The present investigation has for its purpose the study of the relations between the various factors of a cold-working process and the preferred orientation of the metal crystals resulting from this deformation. The work is chiefly confined to a study of cold-drawn seamless tubing.

Jan 1, 1932

By Charles S. Barrett, F. W. Steadman

DEFORMATION bands of surprising regularity are found in large-grained polycrystalline copper after cold-rolling (Fig. I). Individual bands frequently are large enough to permit a determination of their orientation by means of etch pits and an optical goniometer. Measurements have been made on 21 areas in seven different grains, and these, combined with X-ray studies of nine single crystals that had been cold-rolled after mounting in a polycrystal-line block, have contributed to a better understanding of the preferred orientations in rolled copper just as similar studies have for rolled iron' and brass.2.3 Particular attention was given to determining orientations that are stable during rolling and to the manner of fragmentation and rotation of unstable grains. The possible role of twinning was also carefully investigated. The texture of polycrystalline copper after cold-rolling is well established by the pole figures that have been plotted by Schmid and Staffelbach,4 Iweronowa and Schdanow,5 and Brick and Williamson,3 all of which are in substantial agreement. There has been some divergence in the list of individual "ideal" orientations that have been used to describe the texture by these observers and others,6 although the orientation (110) [112]-that is, (110) parallel to the rolling plane and [112] parallel to the rolling direction-is generally recognized as the most prominent orientation and (I12) [111] one of the lesser orientations. Other orientations have been given by some observers as (236) [533], (100) [001], and (I 10) [001]. The texture of copper has also been described as (135) [533].6.1 The sum of these orientations provides a reasonable approximation to the complete pole figure, but it does not follow that these specific orientations are necessarily of fundamental significance, for the choice of indices is arbitrary, within limits. Furthermore, a detailed investigation of the ideal orientations in cold-rolled iron discloses continuous ranges of equally favored positions rather than definite positions of high stability,1 and similarly Brick's observations in a single crystal of a brass2 suggest that all orientations in the range between (110) [113] and (110) [117] are about equally stable. MATERIALS AND METHODS The material used was vacuum-cast electrolytic copper kindly supplied by L. L. Wyman, of the General Electric Co.* Slices 1/2 in. thick and 2 1/2 in. square, cut from the ingot, were rolled with 50 per cent reduction per pass to final thicknesses between 0.02 and 0.04 in., and etched to develop cube-face etch pits suitable for goniometric work.8 The etch was light on some strips and deep in others.

Jan 1, 1942

By B. J. Nelson, F. N. Rhines

STUDIES upon the rates of oxidation of copper alloys containing small quantities of the alloying elements1,2 have shown that steady growth of the scales at predictable rates is limited to a small concentration range and to oxidation at temperatures above 600°C., whereas unpredictable and erratic oxidation behavior is found with alloys containing larger additions and at low temperatures. The latter effect appears to be associated with modifications in the geometric disposition of the oxides. At low concentrations of the baser elements in copper, simple oxidation behavior is typified by the formation of two distinguishable zones of oxidation: (I) a subscale composed of discrete particles of the oxide of the alloying element embedded in substantially pure copper and (2) an external scale composed of cuprous oxide (with a very thin layer of cupric oxide on the outside) containing particles of the alloying element distributed throughout, but most profusely near the metal surface (see Fig. 2, top). Where this type of structure obtains, the process of oxidation is believed to be implemented, and its rate controlled, by the diffusion of the reacting elements through a continuous matrix phase; i.e., through the alpha (metallic) phase of the subscale and alloy and through the cuprous oxide of the external scale. Copper is presumed to diffuse outward through the cuprous oxide layer to the external surface, where it reacts to form more cuprous oxide.3 Oxygen is delivered at the oxide-metal interface in the form of cuprous oxide, which may either react with the alloying element to deposit its oxide at the inner limit of the external scale or dissolve in the pure copper that remains at the surface of the metal after it has become depleted in its oxidizable alloying elements. Both oxygen and the alloying element are pictured as diffusing through the metal, the oxygen inward and the alloying element outward. Where the two diffusion streams meet in sufficient concentration the oxide of the subscale is precipitated. If the oxygen pressure in the surrounding atmosphere is just below the pressure necessary to maintain cuprous oxide undecomposed, no cuprous oxide can be formed; some of the oxide of the alloying element may form upon the external surface, if its decomposition pressure is below that of cuprous oxide, and a normal subscale appears. This condition is achieved experimentally by enclosing the alloy with cuprous oxide together with an excess of copper. At temperatures from 600°C. downward, the precipitated oxides tend to accumulate at the grain boundaries of the alpha phase where a relatively small volume establishes a partial barrier to the diffusion of the reactants. Similarly, large volumes of precipitated oxides tend to deposit in various patterns that may be expected to hinder the diffusion of the reactants in the

Jan 1, 1943

By Jas. E. Thomson

PUBLIC attention was first attracted to the Crow River area of north-western Ontario by the discovery of gold in 1928. The first three discoveries were eventually developed into Central Patricia, Pickle Crow, and Albany River mines. In 1929, preliminary developments were carried out at the Howell vein on N.A.M.E. (later Pickle Crow) claims, and in 1929 and 1930 surface and underground work indicated an ore-body at Central Patricia mine. However, due to the financial depression and the distance of these properties from the railway, it was not until 1934 and 1935 that, benefitted by the revaluation of gold, the real potentialities of these two properties began to be realized. Their immediate success led to a resumption of activity on neighbouring properties throughout the area in 1936 and 1937. Preliminary prospecting in the earlier period had been limited by the scarcity of rock exposures in the country. The procedure in the recent programme of intensive exploration has been along similar lines at most properties and has consisted lf detailed geological mapping accompanied by geophysical surveys and followed by systematic drilling of favourable zones. The present importance of the camp may be judged by the fact that, in 1937, Central Patricia and Pickle Crow mines together produced bullion valued at $3,662,953, and paid $1,450,000 in dividends. In addition, there were pro-mising gold developments at Albany River mine. During the past two seasons, the Geological Branch of the Ontario Department of Mines has been making a fairly detailed study of the geology and mineral deposits in the Crow River area. It is the purpose of this paper to present a brief statement of some of the structural features of these deposits; a summary of other geological information essential for the understanding of the main topic is included. A more detailed report on the area will be published shortly by the Ontario Department of Mines. It is impossible to make full acknowledgment here for all help received, for the writer is in-debted to the management, staff, and consultants of every Company in the camp for generous co-operation in the field and for information, plans, maps, and records placed at his disposal. Reports and articles on properties in the area have been written by Hurst (1), Cormie (2), Reid (3), and the staff of Pickle Crow Gold Mines ( 4).

Jan 1, 1938

By Charles S. Barrett

THE experiments reported in this paper have been fruitful in disclosing the mechanism of the deformation of iron in compression. They have established the nature of "deformation bands," "etch bands," or "X-bands," that have been a recognized but little understood feature in the structure of cold-worked metals since the early days of metallography, and have shown the role of the bands in the development of preferred orientations by cold-working. The work has also shown the relation of the orientation of individual grains to the preferred orientation of the aggregate. Some of the methods previously used in the determination of the indices of slip planes and slip directions are shown to be untrustworthy in the presence of deformation bands. The conclusion is reached that many slip planes and slip directions must operate during each stage in the compression of a single crystal, and that theories failing to take account of this require revision. In conducting the experiments a method of compression has been used by which extreme reductions can easily be reached, even to the limit set by the metal's capacity to deform without fracture. The work is a portion of a research program on the plastic properties of iron and steel. It is being used as a foundation for studies of orientations resulting from recrystallization and is being extended to other metals and other types of deformation. PREVIOUS WORK The previous experiments are few and have given confusing results. Ono1 compressed a polycrystalline alpha-iron specimen between two flat plates of a testing machine and found that severe deformation oriented the crystals into a duplex preferred orientation, one set of crystallites having a cube diagonal of the body-centered cubic lattice parallel to the compression axis, and another set having a cube axis parallel to the compression axis. We shall speak of this structure as a. double fiber texture of the type [111] + [100]. Wever2 also made an X-ray determination of the texture

Jan 1, 1938

By Charles Barrett

THE experiments reported in this paper have been fruitful in disclosing the mechanism of the deformation of iron in compression. They have established the nature of "deformation bands," "etch bands," or "X-bands," that have been a recognized but little understood feature in the structure of cold-worked metals since the early days of metal-lography, and have shown the role of the bands in the development of preferred orientations by cold-working. The work has also shown the relation of the orientation of individual grains to the preferred orientation of the aggregate. Some of the methods previously used in the determination of the indices of slip planes and slip directions are shown to be untrustworthy in the presence of deformation bands. The conclusion is reached that many slip planes and slip directions must operate during each stage in the compression of a single crystal, and that theories failing to take account of this require revision. In conducting the experiments a method f compression has been used by which extreme reductions can easily be reached, even to the limit set by the metal's capacity to deform with-out fracture. The work is a portion of a research program on the plastic properties of iron and steel. It is being used as a foundation for studies of orienta-tions resulting from recrystallization and is being extended to other metals and other types of deformation.

Jan 1, 1938

By Charles Barrett

PLASTIC flow in metal crystals and the changes in orientation resulting from it are generally understood to take place by the following funda-mental mechanisms: (1) slip on crystallographic planes, (2) homogeneous crystal rotation resulting from the slip, (3) bending of the lattice between the planes of slip, and, under certain circumstances, (4) twinning. This paper and a preceding one on iron subjected to uniaxial compression1 concern two additional processes that must now be added to this list: (5) the formation of deformation bands, and (6) the bending and rotation of these bands. The present investigation yields a new understanding and definiteness to the common terms so loosely used when speaking of cold-worked metals -"grain fragmentation," "elongated grains," and "deformation twins," "deformation bands," "etch bands," or "X-bands." Bands have been noted on the polished and etched surfaces of cold-worked metals by vari-ous investigators for more than 25 years, ? yet their nature and their significance have been so little understood that they are not treated in the most comprehensive modern texts on the deformation of crystals. The experiments in this series show that they are one of the fundamental processes in the deformation of metals, of importance in the development of preferred orientations, in work-hardening (since they have the effect of reducing the effective grain size and interfering with slip), and in the recrystallization process. The present experiments were performed on the same stock of mate-rial that was used in the earlier compression experiments1-hydrogen-purified mild steel in which the carbon content had been reduced to the limit detectable under the microscope and in which single crystals could be grown by a strain-anneal treatment.2

Jan 1, 1939

By Stewart A. Ferguson

Location.-The property consists of eight claims (P-12339 to 12343, 12403 to 12405) in Robb township, adjoining Jamieson township on the west. A mocor road extends twenty-two miles northwest from Timmins to the mine. Acknowledgments.- The field work was done in 1940 and 1943, while the writer was employed by the Ontario Department of Mines. The Metals Reserve Company has made available information regarding the property through Messrs. W. R, Dunbar, of Hollinger Consolidated Gold Mines, and W. C. Ringsleben, of the Metals Control Board, Department of Munitions and Supply.

Jan 1, 1945