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By S. Siddiqua

Diffusion is known to be the main transport mechanism of contaminants in fine-gained soils. To date, it is still common practice to estimate contaminant migration in the Bangkok Clay by means of pure advection models. A series of experiments with various chemical species was performed to determine transport parameters such as the diffusion coefficients and the distribution coefficients. The soil used was saturated undisturbed Soft Bangkok Clay. Column experiments were utilized in a number of laboratory tests involving advective-diffusive migration. Effective diffusion coefficients of different ions were back calculated from the test results. The distribution coefficients were determined from the results of the column tests and batch test. The results indicate that the evaluated parameters are in the range of values obtained from other researchers on similar kinds of soil. Based on this results contaminant migration by diffusion in the Soft Bangkok Clay can now be performed.

Jan 1, 2005

By Xu Weihong

After being pre-treated, composite electro-deposits of semi-bright nickel/nano-SiO2 with bright nickel or with amorphous Ni-P alloy, and Composite electro-deposits of Zinc were prepared on Nd-Fe-B magnetic material. The effect of cathodic current density, nano-SiO2 concentration, stirring strength and surfactants on the corrosion resistance of electro-deposits were studied. In addition surface appearance and structure of the composite coatings were analyzed by SEM. The present investigation shows that the corrosion resistance of composite electro-deposits of semi-bright nickel/nano-SiO2 with amorphous Ni-P alloy was the best, the solution system of semi-bright nickel/nano-SiO2 with bright nickel was stable and its electro-deposits also had an excellent corrosion resistance, composite electro-deposits of Zinc not only had good corrosion resistance, but also low cost, thus making it an excellent electro-deposit for medium or low-class Nd-Fe-B magnetic material.

Jan 1, 2006

By Qingxia Liu, Chen Tingzhong, Chen Jin, Yang Xiaosheng

It is common problem (Huan Xinsheng, etc.,l992)for most iron ore concentrators in China that the concentration of thickened tailings is lower than the need for economical transportation. To solve the problem, two methods of improving the properties of the existing thickeners and using separate thickening technique have been applied in three iron ore concentrators. However, in the case of the Daye iron concentrator a new technique of cyclone-flocculated sedimentation was developed by present authors and verified by experiments. The new technique employs efficient hydrocydone designed by authors in conjunction with a low cost flocculant named KLP.

Jan 1, 1995

By Emma Arakelova

?2?2 (98 %) vapour passed through a reactor at 25Pa where a Zn? target was placed at 273K- 373?. Experiments were carried out on a flow- type vacuum device. ?2?2 decomposition on Zn? surface accompanied by formation of a Zn-containing volatile complex which transferred to the gas phase, and Zn? deposited on a substrate at condensation. As the substrate, five sequentially located quartz cylinders were used at 293K- 423 K (?n). Decomposition of the Zn-containing complex on quartz substrates carried out as a first- order reaction. ?The complex decomposition constant (??) increased with the substrate temperature (?n=293 K, ??=7.05 sec-1;?n = 373 K, ?? = 87 sec-1;?n = 423 K, ?? =158 sec-1). ?The complex decomposition constant did not practically vary when the target temperature increased; the complex formation rate increased slightly.

Jan 1, 2006

By P. C. A. Maia, J Alexandre, F. A. J. Saboya, A. R. G. Azevedo, G. C. Xavier

"This work shows the characterization of clay and the granite waste by-product from the sawing process of the granitic blocks, used as raw material for brick ceramic. Besides, shows the degradation of the ceramic material obtained with different by-product contents in the waste after lab test degradation, is investigated. The clay is obtained from mine use areas of ceramic industry in Campos-RI and the waste is originating from of the area of Cachoeiro-ES, an important center of decorative stone in Brazil. The mixes were made by the addition of 0% up to 10% of the waste in the raw material. After drying and firing up to 900°C, obtained prismatic pieces were considered intact. Physico-mechanical properties were obtained from wet and drying tests in laboratory considering 50 and 150 cycles. The results showed that the use of powder byproduct has a considerably influence on the weathering and strength of the material.IntroductionThe ornamental rocks and coating defines the most promising areas of business in the mineral sector [l]. In this context, the Espirito Santo appears as the main Brazilian state in production and export of ornamental rocks, representing 47% of national production [2] which in tum is one of the economic sectors most representative of this State, due of its transport logistics and port vocation that facilitates the export of such products.It is estimated that the state of Espirito Santo there are approximately 1,200 companies dedicated to the activities of ornamental rock by providing 20,000 direct jobs [ 1]. These mobilize support activities, such as companies that provide machinery, equipment and supplies for industries, including service providers for maintenance.However, the production of rocks produces about 15,000 tons of granite waste/month [3] only in the municipality of Cachoeiro ltapemirim-ES. This is justified by the presence of more than 500 extraction industries, cutting and processing of stone, with about 900 looms, waste generators.According to [4], there is great potential for the use of granite waste in red ceramics introduced for the manufacture of bricks, blocks structural ceramics. and other ceramic products, especially when evaluated on exposure to weathering."

Jan 1, 2014

By Gregory E. Tieman

Hydrologic impacts of longwall mining were studied in 1986 after mining had occurred at mine "Z" in northern West Virginia. This mine is 700 to 1,300 ft deep, with a surface topographic relief of 300 to 500 ft. Five springs and one dug well were reportedly dewatered by mining. All such supplies are above nearby streams in elevation, and at least 800 ft above the subsided mine. Three of these six supplies showed partial recovery within one year. Only supplies within 50 ft in elevation of a nearby stream showed apparent partial recovery. Measured perennial streams showed notable depletion in streamflow over mined longwall panels that were less than two years old. Normal stream discharge was measured over panels more than two years old. Most apparent hydrologic dewatering impacts appear to be temporary, and the most vulnerable areas for these impacts are hill sides.

Jan 1, 1986

By Xiaojie Gao, Shufeng Yang, Jingshe Li, Chengsong Liu

In the blast furnace process, the dust entrained in the blast furnace gas enters into the down-comer, flows through the gravity dust separator (to eliminate coarse particles) and then is collected in a bag-house. The powder collected by the baghouse is called bag dust, while both fractions are called blast furnace dust whose main components are C and Fe. The dust also contains small amounts of nonferrous metals such as Zn and Pb, which have some value. Also, due to the small particle size and low density the dust is easily suspended in air and so can endanger human health. Therefore it is necessary to develop a process to both treat the dust to recover the metal values and to dispose of the residue – preferably by recycling to the blast furnace itself via the sinter strand. These objectives will result in good economic, environmental and social benefits [1].

Jan 1, 2014

By Juliana Augusto Molari, Deborah Dibbern Brunelli, Leonardo G. de Andrade e Silva, Patricia N. S. Poveda

There are several additives aimed on improving the processing characteristics as well as mechanical properties of the plastic materials. Being polypropylene is one of the main polymers used in the plastic processing industry due to its easy processability and application versatility, was chosen as the base resin for this study. Additives can aid the processing of polypropylene, either by promoting a better slip between the chains (lubricants), or by contributing to nucleation and crystallinity (nucleating). In this study, the raw materials copolymer polypropylene, lubricant (internal and external action), organic nucleating agent (metallic salt) and inorganic nucleating agent (metallic oxide) were considered. Mechanical tensile tests, Charpy impact and spiral flow to verify melt index were performed to characterize the samples with additives and standard (copolymer polypropylene). The interference of these additives with polymeric matrix was observed.

Mar 1, 2018

By S. N. Monteiro, N. A. Cerqueira, E. B. Zanelato, J. Alexandre, M. T. Marvila, B. C. Mendes, A. R. G. Azevedo, G. C. Xavier

Mortar is a widely used building material and has its application in buildings in extremely vulnerable environments and susceptible to degradation, such as facades. The objective of this work was to evaluate the loss of mechanical resistance to compression and flexure and the loss of mass of the mortars with effluent sludge from paper industry, when exposed to saline environments. The specimens were done with 0, 5, 10 and 15% of incorporation in lime paste and subjected to saline mist equipment that sprays salt solution in cycles simulating natural degradation conditions using literature data. It can be concluded that mortars with a15%incorporation obtained a significant loss of mass and a decrease in their mechanical resistance, which impairs their use in civil construction and influence in other properties of the material, with a level of incorporation of 10% the results within Brazilian standards.

Mar 1, 2018

By In-Ho Chi

In copper metallization, resistivity of copper seed layer is very important since the thickness of seed layer is less than 200iun. Conventionally MOCVD has been used for this purpose however electroless copper plating is simple process and the resistivity of copper deposit is less than that of copper prepared by MOCVD. In this study eIectroless depositions of copper were conducted on different substrate to find optimum conditions of electroless copper plating for electronic applications. To find optimum conditions, the effects and selectivity of activation method on several substrates were investigated. The effects of copper bath composition on morphology were investigated. The effects of pH and stabilizer on deposition rate was investigated. The resistivity of copper with thickness was also measured.

Jan 1, 2001

By Namavari. H., M. Ashouri, M. R. Sarhadi, S. H. Mansouri, A. Sarrafi

The splash phenomenon and its effective parameters in metallurgical converters have been studied thoroughly for decades. The detailed studies of processes such as tuyere blockage, wave formation during air injection, entrapped phases, and also processes which control the formation of bubbles in viscous fluids are not feasible yet. In this research, we have used a converter-shaped vessel made of flexi-glass. Water and oil have been used as matte and slag phases respectively. The effective operational factors responsible for creation of splashing have been studied such as air flow rate, tuyere angles, depth of tuyere submergence, tuyere blockage, density and viscosity of liquids, liquids heights, etc. The results have been found as follows: the amount of splashing increases slowly as air flow rate increases. However, as the air flow rate reaches a critical value (depending on the physical specification of converter) the amount of splashing rises sharply, because the flow of air inside the liquid changes from bubbling into a jet stream; and most of the splashed materials are in the form of filaments instead of droplets. Changing tuyere angle from horizontal towards vertical position will increase the turbulence level on the fluid surface and causes an increase in the amount of splashing. The effect of tuyere submergence is related to the converter opening angle. As the converter opening angle is shifted towards the hood position, the amount of tuyere submergence and splashing will increase. As density of the liquid increases, the number of droplets splashing increases with a decrease in drop size. Therefore, the total amount of splashing decreases. However, as viscosity of the liquid increases, the splashing material increases due to the changes in the splashed material from droplet shape into filament form. The height of liquid inside the converter, depending on the relative height of heavy phase and light phase, is an important parameter regarding splashing. As the relative height of heavy phase to light phase increases the splashing will decrease. The tuyere blockage will cause the pressure in the inlet manifold to increase; and in real cases will increase the splashing. Finally, we have development a model based on dimensional analysis to relate the above parameters in order to calculate the amount of splashed material.

Jan 1, 2007

By M. Z. Mubarok

Effect of single addition of a lignin-based biopolymer additive, DP 2782, at various dosages as well as in combination with thiourea on cathode polarization during copper deposition was investigated by performing potentiodynamic and galvanostatic measurements using a potentiostat. The result of electrochemical measurements was compared with the behaviour of cathode deposition with glue and thiourea additives. Surface micro-appearance of the copper deposit after 1 h galvanostatic scan under current density of 330 A/m2 and various additive type and dosage was evaluated by scanning electron microscopy (SEM) examination. It was found that the addition of 2.5 mg/l biopolymer gave sufficiently polarizing effect of copper deposition. SEM examination of the cathode surface after galvanostatic scan revealed that the combination of the biopolymer with thiourea (2.5 and 3.5 mg/l) resulted in a compact deposit which is comparable with that resulted from the test with glue and thiourea.

By Daniel Kim, Justin McAllister, Shijie Wang

"At the Kennecott Utah Copper Refinery, impurities in the electrolyte are being precipitated in the circulation system and form a hard scale in the piping. This scale must be removed periodically for proper electrolyte flow. Distinct layers of differing composition form as the operating conditions of the tank house change. Scale samples from the inlet and outlet pipes were analyzed to discover the nature of the precipitates. Each sample was sectioned and examined under optical microscopy and SEM. The composition of the scale was analyzed using ICP, XRD, and SEM/EDX mapping. The rate of deposition was determined by measuring the amount deposited on new pipes after elapsed time intervals. In order to determine how to minimize the formation of the scale, the mechanism was studied and the results are presented in this paper.IntroductionIn copper electrorefining, impure copper anodes are refined into pure copper cathodes. The impurities from the anodes are either insoluble and report to the slimes or soluble and dissolve concentrating in the electrolyte. These impurities are controlled by bleeding electrolyte from the system. Over time, the impurities combine to precipitate a hard scale on the surfaces contacted by the electrolyte. The scale causes problems with tank house circulation systems. In order for the refinery to operate properly, the scale must be removed periodically from the walls of the pipes. The first step to control the buildup of scale on the pipes is to understand the composition and the phases that are present in the scale."

Jan 1, 2012

By Ji-He Wei

The ESR of Cu-Cr-Zr alloy has been experimentally investigated. The remelting experiments have been carried out with different slag fluxes in the Cal, + Nal, CaF2 + ZrO2 and CaF2 + NaF + ZrO2 systems on an ESR furnace of 25kg capacity; using a water-cooled copper mould of 96.5 mm diameter, with the forged square bar electrodes of 50x50 mm2. The slag amount was taken to be 1.5 kg. The remelting current and voltage used were 1600-1800A and !5-25K, respectively. The influence of the slag composition on the stability of the remelting process and the losses of alloying elements (2r and Cr) has been considered and examined. The technologies of hot working and heat treatment of the ES ingot have been described and discussed. Some physical properties of the slag in a CuF2 + NaF + ZrO2 system and the remelted Cu-Cr-Zr alloy have been determined. The results indicated that with the slag flux of CaF2 + NaF + l0 mass % ZrO2 and the other operation parameters employed, a high quality ingot of Cu-Cr-Zr alloy may be obtained at the considerably high yields of Zr and Cr by means of ESR. For the remelted Cu-Cr-Zr alloy with a specified composition of 0.5 mass % Cr and 0.1 mass % Zr, the appropriate electrical conductivity, hardness and softening temperature are as high as 45-46S/m, HRB 82-84 and 550°C. respectively. The properties of the Cu-Cr-Zr alloy products are in accordance with and superior to the requirements and specifications of ISO5l82-l99l(E).

Jan 1, 2000

By J. Lui

Inco Copper Cliff Smelter commissioned two new Inco flash furnaces in 1991/1993 as part of its S02 abatement program. Each flash furnace is equipped with a fluid bed dryer. The ~ 12 wt% water content in the concentrate filter cake, flux, reverts and sludge is removed in the fluid bed dryer. The dry solids are discharged from the dryer together with exhaust gases into the baghouses where they are separated. The dry solids are transferred to four storage bins. In September 2003, for the first time since startup in 1991/1993, a large amount of elemental sulfur accumulation was discovered on the walls, roofs and floors of the outlet side of the baghouse chambers. Several baghouse fires were experienced during cleaning and conducting maintenance work in the elemental sulfur contaminated baghouses. Laboratory scale test work at the Inco research lab was conducted to understand the mechanism. A plant solution to minimize elemental sulfur formation was implemented with success. This paper summarizes the efforts to understand and minimize elemental sulfur formation in the baghouse chambers.

Jan 1, 2007

By Chengguo Zhang, Bruce Hebblewhite, Faham Tahmasebinia, lsmet Canbulat

"Coal burst is a dynamic release of energy within the rock (or coal) mass leading to high velocity expulsion of the broken/ failed material into mine openings. This phenomenon has been recognised as one of the most catastrophic failures associated with the coal mining industry, which can often lead to injuries and fatalities of miners as well as significant production losses. This paper aims to examine the mechanisms contributing to coal burst occurrence, with an emphasis on the energy release concept. In this study, a numerical modelling study has been conducted to evaluate the roles and contributions of difference energy components. The energy analysis presented in this paper can help to improve the understanding of energy release mechanisms especially under Australian conditions.INTRODUCTIONCoal burst is one of the most hazardous problems encountered in underground coal mines, which occurs at different locations in a variety of mining systems and operations. This phenomenon always involves a violent and dynamic energy release with large rock mass/coal deformation and ejection that can cause severe damage to openings, equipments and may result in fatalities and injuries.The first coal burst occurrence was reported in Britain in 1738 (Dou 2001). Since then, international experiences are available in Canada, South Africa, USA, former Soviet Union, China, India, France, Germany, Poland and Czechoslovakia. Rice (1935) classified coal bursts as two general types, namely excessive pressure bumps and shock bumps and he further mentioned that pressure bumps are caused when pillar stress exceeds bearing strength. Shock bumps are induced by the breaking of thick, massive strata at a considerable distance above the coal-bed, causing the immediate roof to transmit a shock wave to the coal."

Jan 1, 2016

By Yushuai Xian, Youjun Tao, Fangyuan Ma

This study compared particle size distribution and density distribution of crushed products for waste printed circuit boards (WPCBs) before and after heat treatment. The crushing process for heat-treated WPCBs is a selective crushing process; more metal is concentrated in the coarse particle range of 1.0–0.5 mm and high density range of 2.8–2.96 g/cm3. WPCBs were separated using the Falcon separator to recycle useful metals. The Box-Behnken module of Design-Expert was used to obtain optimal separation parameters, namely, rotational frequency of 25 Hz, recoil water pressure of 0.025 Mpa and feed speed of 34 ml/s. On this basis, the separation indexes for WPCBs with and without heat treatment were compared. Experimental results show that the recovery effect is better for heat-treatedWPCBs than for thosewithout heat treatment. Comparedwith the non-heattreatedWPCBs, the product grade of heat-treated WPCBs is 1.95% higher, and its recovery is improved by about 14%. Finally, characteristics ofWPCBs before and after heat treatment were analyzed on the basis of stress experiments and scanning electron microscopy (SEM), respectively. Results of mechanical characterization indicate that the stress experiment for non-heat-treated WPCBs has a maximumpressure load of 212 N and displacement of 20mm, but heat-treatedWPCBs only need 140 N stress and 14 mm displacement. SEM shows that copper foil and fiberglass cloth are deformed in different directions and sizes after heat treatment to form gaps, which promote liberation of copper foil and fiberglass cloth.

Sep 10, 2020

By Jiu-ju Cai, Wen-caho Liu, Fei Liu

"With the northern cities of China as study objects, and to confirm Ground-source heat pump system of the environmental benefit and the developing direction. In this paper LCA was applied to the environmental benefit Ground-source heat pump System from raw materials acquisition to system production, utilization and disposal. The conclusion shows that Ground-source heat pump system of the environmental benefit in the northern cities of China. The result showed that Ground-source heat pump system had remarkable environmental benefit. 1. Introduction Life cycle assessment Originate in the sixties of last century, what it paid close attention to is to obtain processing from products raw materials, the processing of products produces, products transportation, products use and maintain to the influence to environment of course. It is a products -oriented environmental management style, it is the environmental management mode of meeting the needs of sustainable development strategy [1]. The research object was in the city and lie in the North of China, would undertake Beijing Olympic Games some football matches in the second half of 08, in order to improve the local environment, adjust the energy structure, reduce the heating consumption of urban coal in the centre, eliminate the coal-burning boiler under 10 tons, since 2005, the local government promotes and utilizes actively the heat pump technology in the source substitute the heating of coal-burning boiler. At present, this area is adopted the technological heating area of heat pump of source reach 20 million square meters, account for this area heat 11.2% of area always, it is estimated, by 2010, adopt the technological heating area of heat pump of source will reach 65 million square meters, the proportion of the area rises to about 30% to account for this area and always heat [2 ]. Study to the whole lifespan of heating system of heat pump of ground source of this area on the basis of LCA method, obtain the products impact on environment of different stages and environmental benefit, find out and reduce or dispel the measure of the influence, improve the environmental benefit of the ground source heat pump heating system.2. MethodologyThe research approach used in this research is the Life cycle assessment, the frame of the research approach is goal and scope definition, the inventory analysis, impact assessment, interpretation.[3][4][5]"

Jan 1, 2008

By L. B. Tsymbulov, N. A. Fedorova

The equilibrium of exchange reaction (Cu20)+[Ni]=(Ni0)+2[Cu] taking place in the course of interaction of metallic nickel-containing copper melts with different oxide melts (Cu20-NiO, Cu20-NiO-Si02, Cu20-NiO-FeO(Fe203)) in the area of their homogeneity has been studied. The studies, based on the known value of equilibrium constants and defined copper and nickel activity indices in metallic melts and equilibrium concentrations of Cu, Ni, Cu20 and NiO, determined the YNio/ycu2o ratios in the oxide melts of the above systems. For the equilibrium between nickel-containing copper and binary oxide melt Cu20-NiO, values of YNiO and Ycu2o were determined both by calculation and experimentally. Based of the data conclusions regarding oxide melts construction are presented.

Jan 1, 2007

By Shulin Nie, Mats Olsson

The mechanism of rock fracture by explosive is a fundamental in rock blasting. It is generally believed that the shock waves from the detonation initiate the fractures. Then the detonation gases penetrate into the fractures and elongate them. However, our previous researches indicated that the detonation gases do not contribute significantly to the fracture propagation. In our latest experiment, blasts have been carried out in 8 large granite blocks. The main goal was to study the fracture mechanism, namely to determine whether the shock waves or the detonation gases fracture the rock.

Jan 1, 2001