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By Cui Wang, Bing Dai, Haibin Zuo, Jianliang Zhang

The damage mechanism of ductile cast iron cooling stave applied to No.4 blast furnace of Guofeng steel was analyzed through damage investigation in details, the damage causes: hightemperature gas flow erosion, wear of burden, high-temperature ablation, carburizing damage, improper operation on blast furnace, etc. were given out both in macroscopic and microscopic views. It can be obtained from metallographic diagrams that the diameter of graphite nodules increases, the number per unit area reduces, and roundness declines, successively, from cold to hot surface, which are not conducive to stave longevity. In summary, the material for staves manufacture should be better in comprehensive mechanical properties to prolong the service life, thus making blast furnace long campaign.

Jan 1, 2015

By Zhang Qin

Dolomite is main impurity mineral in phosphate ores. In practice of phosphate ores production, the grade of concentrates is only containing P2O5 31-32%.In this study, even the increasing of floatation reagent consumption and decreasing of floatation recovery, economic performance is estimated high according to the decreasing of H2SO4 consumption in subsequent production of phosphate fertilizer and the increasing of products value. In floatation stage, influence factor include the synergism impacts of floatation collector, the stages, time, concentration of ore pulp, which were discussed respectively in this paper. Raw material is characterized by mineralogy, chemical analysis, the grain size analysis and milling test . The results show that the grade of concentration can reach to P2O5 36% by deeply de-magnesium oxide from phosphate ores by floatation , which yield a high added value.

Jan 1, 2009

By J. Chai, Y. Qiang, D. D. Zhang

"In order to control Quaternary loose layer settlement in East China, there are monitoring results based on the 3 water level observation holes and 7 sand layer of fiber Bragg grating (FBG) strain sensor. Un-der the conditions of upper group water injecting to lower group of loose layer, the deformation characteristics of upper, middle and lower group of loose sandy soil layer changing with time and relationship with the water level are studied. The constitutive relation of stress-strain is also studied at different sand layers. Research results show that using water injecting from upper group into lower group of loose layer can ease the loose layer compression deformation. With the water level dropped, in East China soil creep deformation occurred, which accord with viscoelasto plastic model. The deformation of lower sand group has clear later effect and no direct relationship with water level. The results provide an important basis for the study East China stratum settlement model and water management. INTRODUCTION Ground-surface subsidence is a common geological disaster, which has the features of continuous, changing slowly, concealment (Y.P. Yin et al. 2005). Today, due to underground mining and constructions in formation compression, surface subsidence is wide-spread in the world, which is the environmental geological problems in the worldwide that cannot be ignored (Y.Q. Xu et al. 2006, D.L Gallo-way et al. 2000, Qiu, B. et al. 2011). The eastern region of China has generally geological disasters in coal mine geological caused by the thick loose layer settlement like as mine shaft failure. Stratum dehydration consolidation is a major cause of loose layer settlement (H.Y .Liu et al. 2007). A method of water injection using ground water to stable water level is proposed, which can effectively control the loose layer caused by compression settlement(J. Chai et al. 2012&.2013). Accurately knowledge the characteristics of strata deformation is the premise of settlement management (Q.C. He et al. 2006). Previous re-search (J.F. Miu et al. 1996, X.Y. Gu et al.1998, Y. Zhang et al. 2006), mainly studies are focused condition of the city pumping irrigation, de-formation characteristics of middle and up loose layers. On a group of aquifer in East China, the loose layer losing water is caused by coal mining, bottom water drainage and overlying strata water flowing fractured zone hydrophobic induced by mining, which the dehydration conditions have great difference from one to another. The Position of water loss is centralized in bottom aquifer, and the formers of ground subsidence geological environment and settlement mechanism are different. According to the study of stratum settlement, usually the de-formation of sand layer is ignored(C.H. Liu et al. 2004), but few studies show that the sand layer have the plastic deformation, and contains the creep deformation, water content of sand soil may become the main settlement layer (Z.X. Wei, 2002, C.H. Liu et al. 2004)."

Jan 1, 2015

By Sun Chuanyao, Cao Fei, Sun Desi, Zhou Dezhi

"The research applies the density functional theory and molecule design technology to design and synthesize the novel flotation collectors for copper-sulphur separation. Density functional theory (DFT) was applied to investigate the electronic properties of O-isopropyl-N-benzyl thionocarbamate (IP-BIAN) and O-isopropyl-N-ethyl thionocarbamate (Z-200). The calculation results show that both the energy of highest occupied molecular orbital (EHOMO) and the lowest unoccupied molecular orbital (ELUMO) of IP-BIAN are smaller than that of Z-200, electronegativity of IP-BIAN is higher than that of Z-200. According to the Klopman’s generalized perturbation theory, the collecting power of the two compounds is predicted to be Z-200 > IP-BIAN, the selectivity of IP-BIAN is better than that of Z-200. Then the thionocarbamate molecular is synthesized, and the compounds are characterized by nuclear magnetic resonance (NMR). It turns out that the test result identifies the prediction after the flotation verified test of pure mineral and actual mineral. The results demonstrate that the EHOMO and ELUMO are smaller in the thionocarbamate after a nitrogen atom is bound to benzyl, the thionocarbamate has strong selectivity and low collecting power. The lower the LUMO energy of thionocarbamate is, the stronger the back donation covalent p-bond between collectors and chalcopyrite is, thus improving flotation power for chalcopyrite and selectivity against pyrite. The result proves the feasibility of design and synthesis of the novel thionocarbamate through the frontier orbital properties of the collectors.1. INTRODUCTION Thiocarbamate is a kind of nonionic polar collector and is now widely used as flotation collector for copper-sulphur separation. The flotation power of thiocarbamate to chalcopyrite is stronger than pyrite, so it has high selectivity against pyrite. The frontier orbital theory and density functional theory (DFT) has been widely applied to study the structure-activity relationship of flotation collectors [1-6]. The flotation test results can be interpreted by using the reaction energy criteria and quantum-chemical parameters, such as the energy of the highest occupied molecular orbital (EHOMO) and the energy of the lowest unoccupied molecular orbital (ELUMO) of collector [7-11]. In turn, there are rarely reports about screening the novel flotation collector, by the frontier orbital properties such as HOMO and LUMO of flotation collectors. In this thesis, we apply the density functional theory and molecule design technology to design and synthesize the novel flotation collectors for copper-sulphur separation. Based on the previous findings of the structure-activity relationship of xanthogen formats [12], it has stronger collecting ability to chalcopyrite while the xanthogen formats after a nitrogen atom is bound to benzyl. Thus, in this study, a novel thionocarbamate molecule O-isopropyl-N-benzyl thionocarbamate (IP-BIAN) will be constructed, when the group structure connected with N atom in the known collector O-isopropyl-N-ethyl thionocarbamate (Z-200) is replaced with ethyl by propyl. The collectors (IP-BIAN and Z-200) have been calculated by DFT methods in quantum chemistry. By analyzing the reaction energy criteria and the frontier orbital properties (HOMO and LUMO), this research predicts flotation performance of novel collectors (IP-BIAN), then the synthetic experiments and flotation verified tests are conducted. The research provides a new theory reference for screening out the high-effective flotation collectors of copper-sulphur separation. This technology adoption will contribute to the sustainable development of mineral resources as it shortens the research cycle of new collector molecules and reduces the investment."

Jan 1, 2018

Study on Desulfurisation and Deashing for Medium-High Sulfur Coal Using Shaking Table As important coal resources, medium- high sulfur accounts for a significant part of the coal reserve in China. The environmental regulations and fuel standard requires sulfur and ash to be removed before it is used, so as to save energy and decrease the emission. Therefore, the effective desulfurisation and deashing technologies are urgent needed. However, due to the local characteristics of the coal, specific technology with optimum operation parameters is required to develop for different local coal. Qinglong is a district of Guizhou Province, which has large medium to high sulfur contained coal reserve. In this paper, medium-high sulfur coal is sampled from Qinglong, Guizhou province. Some basic characteristics such as the mineralogical composition of the coal rock, the monomer existing state and the granulometric composition are determined by X-ray diffraction quantitative analysis and polarisation microscope analysis respectively. Adopting the classified feed method, shaking table tests show that the feed pulp concentration is 20 per cent, the stroke is 13mm, the frequency of the stroke is 380 per min, the cross slope is 3¦ and the volume of wash water is 5.2 L per min. Under such condition, aggregate processed coal yield is 72.87 per cent and sulfur content decrease to 1.31 per cent With shaking table technology of 'First stage rough and intermediate further fine benefication', the yield of concentrate coal increased from 72.87 per cent to 81.21 per cent, while the sulfur content reduced to 1.35 per cent.

Sep 13, 2010

By Wang Jingsong, Ma Tengfei, Feng Fu, She Xuefeng

In this paper the direct reduction melting separation-leaching process is investigated on recovering rare earth from rare earth Bayan Obo complex iron ore (REBOCIO). The REBOCIO was reduced and melting separated to produce iron nugget and rare-earth-rich slag at 1400°C for 12 or 15 min. The RE2O3 is enriched into Ce 4.667(SiO4)O or Ca 3Ce2[(Si,P)3O4]3F, which closely depend on chemical components, especially basic. The optimal acid-leaching parameters of rare earth elements from the rare earth slag are suggested as the hydrochloric acid concentration, the ratio of solid to liquid, leaching temperature, and the leaching time are 1 mol/L, 1:14, 50 °C and 120 min, respectively. The rare earth elements leaching efficiency are more than 95%. Adding of calcium CaCO3 and sodium Na2CO3 in direct reduction process have great in fluence on leaching ef ficiency of thorium.

Mar 1, 2018

By Zhucheng Huang, Zhikai Liang, Ronghai ZHONG, Lingyun Yi

In this work, research of reduction process was studied by means of rotary kiln (u1.5 m /C215 m) process anatomy in order to provide fine guidance to large-scale operation. It was shown that the average reduction degree of 89.96% and metallization ratio of 85.15% were obtained at the highest temperature of 977°C and total residence time of 90 min. The generation amount of metallic iron in section of temperature higher than 900°C and lower than 900°C was 34.15 and 56.38%, respectively. The section of lower temperature of 830–900 °C played an important role in formation of metallic iron, making it possible for mini-pellet to reduce quickly at lower temperature. Two main tasks were completed for mini-pellets in rotary kiln: the reduction of iron oxides in the range of 15.0–4.5 m as well as migration and bene ficiation of metallic iron, facilitating the subsequent separation of iron and gangue minerals.

Mar 1, 2018

By Xi-Shan Li, Qian Li, Yong-bin Yang, Li-na Cui, Tao Jiang, Jie Ge

"With regard to control environment pollution in the roasting pretreatment of sulfur & arsenic-bearing gold concentrate, roasting of double-layered pellet was proposed. In the paper, the characteristics of double-layered pellet roasting were studied. Removal and solidification rates of sulfur and arsenic were investigated as primary factors. The result indicated that the removal and solidification rates of arsenic reached up to 95.91 % and 98.95% while the sulfur was 97.19% and 97.90% respectively on the premise of adopting slaked lime as solidified agent at temperature of 6000, the package proportion of 2.14 and roasting time of 3h. However, pyrite and arsenopyrite were transformed to hematite and magnetite and product of solidification mainly consisted of calcium sulfate, calcium arsenate and calcium sulfite within optimum roasting parameters.IntroductionUtilization of refractory gold resources has been gradually concentrated on with the depletion of the gold resources which are easy to deal with in the world [1]. Sulfur and arsenic-bearing gold ore is a typical refractory gold one, in which ultrafme gold is encapsulated in the structure of metal sulfide minerals [2,3], so it gives poor recovery through direct cyanide leaching. These refractory ores need pretreatment before the process of cyanide leaching to undermine lattice structure of pyrite and arsenopyrite containing gold [4] so that the gold could touch with cyanide solution [5]. Among various methods of pretreatment, conventional roasting method is most effective, but this process generates gases such as S02 and As203 harmful to environment. Therefore solidification roasting was proposed to solve this problem occurring in the conventional roasting at the end of last century."

Jan 1, 2013

By Z. Liang, Z. Q. Liu, X. F. Li, H. L. Zhang

"Dynamic characteristics of frozen soil is important for the safe, effective and rapid construction in cold regions and artificially frozen engineering. In this paper, dynamic characteristics of frozen clay with various low temperature and different strain rate were studied by using Split Hopkinson Pressure Bar (SHPB) test and numerical simulation test. Variation of dynamical parameters and dynamic stress-strain curves of frozen clay were obtained and analyzed. The results of these test show that: Frozen clay exhibits temperature effect and strain rate effect that the failure type tends from plastic failure to brittle failure with the increase of strain rate or decrease of temperature; Under impact loading, frozen clay exhibits three typical dynamic stress-strain curves as strain rate increases, and the maximum strain of frozen clay only linear increases with strain rate.INTRODUCTIONArtificial freezing technology has been widely used in the construction of underground engineering, such as the coal mine shaft, the deep foundation pit, the urban metro and subsea tunnel, etc. Research on dynamic mechanical behavior of artificial frozen soil will provide supports for these artificially frozen engineering (Xu et al. 1998; Ma 2009). However, the dynamic mechanical research on frozen soil is mainly carried out at low frequencies or small amplitudes of the waves, behavior of frozen soil under impact loads or high strain rate loads has not been made clear."

Jan 1, 2015

Study on Dynamic Characteristics of Inertia Cone Crusher and Its Application

Sep 13, 2010

By Y. Q. He

The methodology of active pulsing air separation is a new method for dry material classification. Especially, it is suitable to electronic scraps disposal and re-utilization. By studying the difference of drag coefficients of the particles moving through areas of varying Reynolds numbers, and considering the extra-mass forces acting on the particles in the active pulsing air field, models of the dynamic motion which particles follow were developed. A computer simulation was prepared that showed the traces of particles with different densities and/or diameters, but similar aerodynamic characteristics, as they moved through the turbulent flow, to modify and define the parameters of the models. The simulation was found to predict the observed results with artificial tracing spheres being separated by the laboratory equipment. The separation performance, as being affected by the particles, nature, the air velocity, the pulsing frequency and the air pattern, is discussed. In general, lower density particles are more responsive to variations in airflow velocity. In addition, an industrial scale active pulsing air separator was designed, and it provides a new and efficient method for resource re-utilization in China.

Jan 1, 2014

By Takashi Sasaoka

EGAT Mae Moh Lignite Mine in Thailand produces about 16 million tons of lignite annually from open-cut mining. The coal is used to generate 2,400 MW of electricity. In the near future, however, the coal must be extracted from underground at 400? 500 m (1,312?1,640 ft) deep from the surface. The problem is the thickness of the coal seams. There are two coal seams that are about 25 m (82 ft) thick with 20?25 m (66?82 ft) of interburden between them. Up to now, many mining systems for thick coal seams have been used and improved in the world. However, where the thickness of coal seams is beyond the limitation of the current mining technology and system, an applicable mining system has to be introduced, considering influencing factors such as caving and subsidence. In order to investigate thick seam mining systems and propose a new mining system in ultra-thick coal seams in Thailand, a joint research group was established by Japanese and Thai researchers and mining engineers in early2009. This paper describes underground mining systems for thick coal seams and proposes an innovative underground mining system for thick coal seam, ?eco-friendly underground mining system?, considering geological, geotechnical, and environmental conditions in this mine. This paper discusses its applicability to this mine by means of numerical analysis from the geotechnical point of view.

Jan 1, 2011

By Yongquan Zhu, Zhengguo Zhu, Zhichun Liu, Chao Kong, Xinqiang Gao

"The aim of the study is to have a good understanding of the change in the seepage field during and after the tunnel excavation in weathering alteration rock. Field tests are used to monitor the changes of the water table and the numerical model is used to analysis the influence of the seepage filed with different operation conditions during and after the tunnel excavation. Results indicate that the depth, diameter and pumpage of precipitation well are the main factors that have a great influence on the drainage effect. Results also indicate that different operation conditions had various effects on the decrease in water yield during tunnel construction and the recovery in groundwater level after construction.INTRODUCTIONAs a potential disease during tunnel construction, Gushing water not only affected construction schedule, increased construction cost, as well as affected tunnel stability and safety during operation, but also decreased ground-water level. What’s more, the fall of water table caused by gushing water in tunnel would have influenced surrounding residents’ living water, agricultural water and ecological environment around tunnel. In recent years, enough emphasis has been paid to the influence on environment due to the construction of tunnel as a result of the reinforcement of people’s environmental protection awareness.As a result of water collection and drainage after excavation, groundwater was discharged into the tunnel, which caused a loss of water resources in the adjacent mountain mass. Furthermore, during tunnel operation, it was difficult for groundwater level to resume its original condition, which caused a bad ecological environment, because drainage system during tunnel construction destroyed its original hydrologic dynamic balance.In order to study whether decreased groundwater level resulting from tunnel construction could be restored during operation to its original condition, this paper gave a field monitoring on tunnel displacement during construction and simultaneously, generalized model of regional hydrogeology was created according to field hydrogeology to carry out a calculation of stable seepage flow and draw comparisons between recovery conditions of various water levels."

Jan 1, 2015

By Li Ma, Shaoguo Chen, Gele Qing, Qihang Liu, Keng Wu

Olivine contains higher MgO element, which can be added into blast furnace burden to improve slag stability and fluidity. Effect of calcined olivine and untreated olivine on low silicon pellet production process and quality was studied in this paper. The results shows, calcined olivine has no effect on bursting temperature of green pellet, however the bursting temperature of green pellet will decrease with increase of untreated olivine ratio. Untreated olivine has slight effect on green pellet strength than calcined olivine while the ratio is higher than 2%. The compressive strength of low silicon pellet will increase first and decrease afterwards with increases of calcined olivine ratio under firing temperature of 1250°C, whereas, the changing sequence is reverse fired under 1280°C. The result of untreated olivine pellet compressive strength is same as calcined olivine pellet. However, the compressive strength and metallurgical property of calcined olivine pellet is slightly higher than that of untreated olivine pellet under same condition.

Jan 1, 2015

By Zhiqiang Han, Anil K. Sachdev, Baicheng Liu, Guomin Han, Alan A. Luo

The growth of precipitate phase ,B-Mg11Al12 in Mg-Al alloy is closely related to interface anisotropy and elastic interaction. The aim of this work is to investigate the effects of the interface anisotropy and elastic interaction on the morphology evolution and growth kinetics of the precipitate. In the work, the precipitation of ,B was studied using phase field modeling. In the model, the chemical free energy of the precipitate and the matrix were obtained via thermodynamic calculation. It is demonstrated that the interface anisotropy results in lath-shaped precipitate and the elastic interaction affects the shape of the end of the precipitate. The interface anisotropy causes uneven growth in different directions and the elastic interaction influences its preferential growth orientation. By combining the interface anisotropy and elastic interaction in the phase field modeling, the results showed that the precipitate phase has a lath-shape with lozenge ends, which is in agreement with experimental observations.

Jan 1, 2013

By T. X. Hu

Pyrite ore is one of the main raw materials in the production of sulfuric acid. For a long time, the raw material containing the pyrite, which is used to produce sulfuric acid, generally contains S only 32%~45%. A plenty of residue from the sulfuric acid production contains 40%~50% Fe and 1%~2% S. Some of the residue also contains Cu, Pb, Zn and other harmful elements like As, thus it pollutes environment seriously and is solid waste. The research on comprehensive utilization of the residue has been made by many scholars. Through the study, the residue can only be used to pro-duce iron concentrate and the iron oxide red pigment. But because of the complex techniques, the low recovery, the low grade of iron concentrate , high sulfur in iron concentrate, causing second waste residue and the environmental pollution, the residue is mainly used as an accessory material in the production of cement, and is of a low value. Therefore, the iron resource in pyrite has not been used efficiently until now. In the paper, the flotation condition test, the flotation open circuit test and the flotation closed circuit test to produce high-purity pyrite concentrate with the low-grade pyrite ore in oceanic ore deposit have been carried on. Flotation reagent scheme of sulfuric acid used as activator and butyl xanthate as collector is determined. After four times depth cleaning, high-purity pyrite concentrate containing 52.82% S, 44.29% Fe, and only 2.89% impurities has been obtained. The S recovery is 99.13%, and the Fe recovery is 96.00% in the high-purity pyrite concentrate. The oxidizing roasting depth desulfurization experiment of the high-purity pyrite concentrate has been conducted. The results show that the Fe grade in the residue obtained is 68.58%, the content of S is 0.25%, the content of P is 0.0084%, the content of As is 0.0065%. The residue is a kind of high-quality iron-smelting raw material. Based on the above experiments, the industrial experiments on producing high-purity pyrite concentrate with the low-grade pyrite ore, and producing sulfuric acid and iron concentrate with high-purity pyrite concentrate have been done. The results indicate that the high-purity pyrite concentrate with the S grade of 51.24%, the Fe grade of 44.15% has been obtained. The iron concentrate obtained with 65.73% Fe and 0.23% S is a sort of high-quality iron-smelting raw material applied to the production of steel and iron smelting. Through the experimental study, the sulfur and iron resources in the pyrite ore have been recovered and utilized efficiently.

Jan 1, 2014

By Jong Hyeon Lee, Go-Gi Lee, Chang-Kyu Lee, Hong Youl Ryu, Sung-Koo Jo

This study deals with research on the reduction process of neodymium oxide by molten salt electrowinning. Neodymium fluoride and lithium fluoride electrolyte were used for feed stock of electrolyte and neodymium oxide was added as precursor. Cell current was confirmed that cell potential was applied as constant potential of 4.5V. Argon gas injection into the electrolyte was carried out to confirm convection effect on current efficiency. Applied current was gradually decreased without argon flow, but applied current was kept within a certain range with argon flow in electrolyte.

Jan 1, 2015

By Jing Zhan, Tian-zu Yang, Wei-feng Li, Li-Hua Jiang, Shi-yan Xu, Jian-yang Huang, Chuan-fu Zhang, Yan-qing Fan

The amount and activity of coal, reduction temperature and other parameters of the process of bottom-blown reduction of liquid high lead slag were investigated in laboratory. Methods to strengthen the bottom-blown reduction process were studied by industrial production. The results were in the follows: the reduction temperature was 1150℃; reduction time was 1.5h; the reductant was anthracite; lead content in slag was controlled to 2%; the rate of coal was 7% and gasification loss of coal in high temperature was severe; liquid lead slag reduction rate was faster with coal; prolonging the reaction size had little effect on reducing lead in slag; the size of the reactor can be further reduced.

Jan 1, 2015

By Weijia Guo

With the exploitation of coal resources, a large area of land had been affected by surface subsidence, causing conflicts between man and land to become more conspicuous by the day, affecting the life of general public, and constraining further development of the land. This paper predicts the subsidence areas according to the 10-year mining plan of the Jibei mining district as an example. A plan of environmental management was developed based on sciences and practical economics.

Jan 1, 2006

By Tang Mo-tang

A new process for extracting indium from indium-zinc concentrates was proposed in this paper. The process can directly extract indium from removed copper solution by P204, and cancel the stage of removing iron in the traditional process because of using iron and part of zinc in the In-Zn concentrates for direct preparing high quality Mn-Zn soft magnetic ferrites. The technologies in the processes, such as leaching the neutral leached residues with high concentrated acid at high temperature, reduction ferric and removing copper, and extracting indium, were investigated. The results showed that total recovery ratio of indium has been increased from less than 70% in the traditional process to more than 95%. This process has the advantages of largely simplifying the procedure of indium extraction, zero draining off of iron residue and zero emitting of SO2. So this is a clean production process.

Jan 1, 2006