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By Jia Ma, Zhi-Chao Liu, Kang Liu, Chun-Feng Li, Bao-Bin Tang

"The geological environment of the certain uranium-molybdenum deposit is very complicated. While the study of process mineralogy is relatively few, which restricting the processing and leaching effect of ores. According to reaserch on process mineralogy of this mine, the basis of ore processing can be provided. The main contents of research are the uranium occurrence state and the influence of H2O2 in acid leaching. By various methods and experiments, the process of uranium mineralogical characteristics in this deposit are systematically studied. The results show that the uranium is mainly in the form of independent uranium minerals. The structures of these uranium minerals are venous and disseminated in mineral fissures, or microgranular inclusions in quartz and feldspar. It is not appropriate to concentrate the uranium minerals by flotation beneficiation because that the loss rate of target metals via water leaching process is very high. The ores are suitable for being acid leaching directly with 6% – 8% of H2O2, and the maximum leaching rate of uranium can be 96.88%. INTRODUCTION The uranium ores with associated elements have a large proportion in uranium resources (Lei, et al., 2014, Xing, et al., 2006; Ritchy and Wong, 1985). The uranium and molybdenum are easy to be paragenesis in nature enviroment because of their similar chemical properties. Therefor the uranium-molybdenum associated deposits are widely existing, such as the sedimentary sandstone uranium deposit in American with vanadium and molybdenum, the sedimentary sandstone uranium deposits in French with vanadium (Chen, et al., 2014; Lounis, 1997). A certain epithermal porphyry uranium-molybdenum deposit in China is mainly controlled by the subrhyolite- porphyry and the fault zone (Lv, 2012; Rui, 2010; Liu, et al., 2010). The ore properties of this deposit are complex, which include the high alteration degree, and the fine grain size of the target minerals (Ma, et al., 2013). The ore properties and occurrence state are quite different during each mining stage. As a consequence, the consumption of reagent increased and the leaching rate declined as long as the continuously mining. The author explored the best leaching rate of target elements According to the basic research on process mineralogy of present ores, experimental study of water leaching and oxidizing acid leaching on different particle sizes."

Jan 1, 2018

By Shilai Yuan, Huimin Lu, Panpan Wang

A big andalusite ore bed was found in Dingxi District, Gansu, China. In this paper, the feasibility of producing solar grade silicon from aluminum-silicon alloys by carbothermal reduction of andalusite ore was studied. First, the carbothermal reduction experiments were conducted in a 100 kVA DC submerged arc furnace with reducing temperature 2000–2200 °C and reducing time 4 h, the hypereutectic aluminum-silicon alloys containing 50–55 mass% aluminum and 35–45 mass% silicon were obtained; then the investigation on solidification of the hypereutectic Al-Si melts under the temperature gradient as an intensified separation silicon way was carried out. According to previous investigation, the optimized technical process for solar grade silicon and eutectic Al-Si alloy from andalusite ore was proposed.

Mar 1, 2017

Study on Pure Mineral Flotation Tests of Low-Grade Phosphate Ore in Zhijin, Guizhou Province, China

Sep 13, 2010

The paper studies the flotation process of native Rare Earth minerals such as: bastnasite, monazite, mixed minerals of bastnasite and monazite, respectively, using the new effective collector - H205 which has been developed by Baotou Research Institute of Rare Earth, and describes their flotation properties. The test results of different ore samples show that at moderate pulp pH values, Rare Earth minerals can be effectively separated from barium and calcium bearing intergrowth minerals (barite and calcite) and high quality Rare Earth concentrates can be successfully obtained by H205 as collector with water glass as depressant. In order to determine optimum technical conditions, the effect of pulp pH, pulp temperature, pulp density and reagent dosage on the flotation were investigated in the test. Simultaneously, the paper explores the mechanism of the flotation separation of Rare Earth minerals from intergrowth minerals. The infrared spectra for H205 and RE cations by theorical analysis shows that H205 formed chelate complex with RE cations and adsorbed on the surfaces of RE minerals. The mechanism of the intergrowth minerals depressed by water glass can be explained as: H2Si03, HSi03 and gummy SiO2 hydrolised from water glass are selectively adsorbed on the gangue minerals, making them hydrophilic and depressed, under pulp pH value 8.5 to 9.5.

Jan 1, 1993

Study on Rational Process Flow Sheet for Beneficiating Low-Grade Cu, Mo, Bi, S, W Polymetallic Ore

Sep 13, 2010

By Z. G. Guan

The tungsten ore in Xingluokeng belongs to a symbiotic deposit containing granite and fine vein-type wolframite and scheelite. The tungsten (WO3wolframite) accounts for only 0.233% of the raw ore, 49.60% of the , 49.60% of the scheelite and 0.8% of the tungstite. The dissemination size of the tungsten ore is extremely uneven, with 0.02~1.28 mm for scheelite and 0.01~1.28 mm for wolframite. The dissemination size of scheelite is coarser than that of wolframite. The size of 83% of scheelite and 60% of wolframite is greater than 0.04 mm. The composition of minerals in the ore is quite complex. The major metallic minerals include wolframite, scheelite and pyrite, which are followed by molybdenite, chalcopyrite, arsenopyrite, limonite, magnetite, hematite and siderite. The major gangue minerals include quartz, feldspar, muscovite, biotite and sericite, which are followed by chlorite, fluorite, apatite, dolomite, etc. According to the dissemination features and liberation degree of the tungsten minerals, the technology flowsheet of gravity concentration for coarse particles and flotation for fine particles to re-cover the low-grade and fine vein-type tungsten minerals is adopted, and -0.7 mm is selected as the processing size. The closed-circuit grinding procedure, with the combination of the rod mill and high-frequency vibration screen, is adopted. The grinding product is classified into three products of -0.7 +0.2 mm, -0.2 +0.04 mm and -0.04 mm. The gravity separation is adopted for the former two to recover tungsten minerals and the flotation is adopted for the last one. Under the condition that the raw ore contains 0.23% WO3, some technology indexes of beneficiation have been achieved. The gravity tungsten concentrate contains 63.54% WO3 with the recovery 70.11%. The slime flotation tungsten concentrate contains 35.22% WO3 with the recovery 10.48%. The composite tungsten concentrate contains 57.53% WO3 with the recovery 80.59%. Thus, the tungsten minerals are re-covered effectively.

Jan 1, 2014

Study on Reasonable Mineral Processing Flow Sheet of Yunfu Low-Grade Pyrite Ores Low-grade ores in Yunfu Pyrite Mining Area were investigated, in order to find an economical, reasonable and environment-friendly mineral processing technology, which is of low consumption and high efficiency in pyrite recovering, which can ensure that the quality of pyrite concentrate product is eligible for sale and the sulfur content of the discharged tailings meets the national emission standards. A flow sheet with a classification, a jigging for coarse-grain minerals and a spiral chute separation for fine-grained minerals was adopted, and the sulfur grade and recovery of the pyrite concentrate is 35.50 per cent and 86.70 per cent respectively, while the grade of tailings is only 6.70 per cent.

Sep 13, 2010

By Yufeng Guo

Mineralogy and physico-chemical characteristics of a nickel hydrometallurgical residue and recovery of iron-bearing minerals by flocculation-magnetic separation were studied. The results show that the nickel residue is super-fine and fraction less than 0.045mm reaches 85.4%. Ferrous minerals are chiefly magnetite and ferruginous glass. Magnetite accounts for 31.7% and exists as free magnetite. Ferruginous glass is of multicomponent amorphous substances with low-iron grade but strong magnetism, and accounts for 39.9% of total iron minerals. Addition of flocculants increases granularity and magnetic force of fine iron-bearing particles and improves iron grade and recovery. The tests with flocculation separation show that a concentrate assaying 56.68% Fe with 81.72% recovery was obtained in a magnetic tube. A concentrate with 56.92% iron grade and 67.96% recovery was obtained by flocculation-magnetic separation with a magnetic cylinder.

Jan 1, 2006

By Y. Nakamura, T. H. Okabe, S. A. Sunkar, K. Nose

Ruthenium (Ru) is known as a platinum group element with a very small production volume. In fact, the worldwide annual production of primary Ru metal is only about 20-30 tons, and it depends on the amount of Pt produced, since Ru is a byproduct from Pt smelting. The primary uses of Ru are as a material for resistors, as a catalyst for electrode materials, and as a sputtering target for hard disk memory storage. In order to recover Ru from the spent sand-blasting abrasive media generated during the cleaning of the apparatus used for Ru sputtering, a hydrometallurgical recovery process using hypochlorite solution has been investigated. In this study, various types of recycling processes that are presently under development are also introduced, and their features and differences are discussed. The advantages and disadvantages of the new recycling processes are evaluated, and the possibility of establishing new recycling processes in the future is discussed from a multilateral perspective.

Jan 1, 2014

By Ming-Feng Ye, Jun Wang, Guang-liang Wu

In order to reduce the Al2O3 inclusions in 50Cr5MoV roller steel produced by EBT-LF-VD-VC process in a steelmaking plant, the LF refining slag was optimized and the influence of optimized slags with different w(CaO)/w(Al2O3) ratios on reducing inclusions were investigated in the laboratory. The results showed that, when w(CaO) = 50–55%, w(Al2O3) = 25–30% and w(CaO)/w(Al2O3) = 1.5–2.0, this optimized slag can not only reduce massive Al2O3 come from aluminium deoxidation, but also change the remain into plastic CaO-MgO-Al2O3 spherical compound inclusions with 1–5 lm diameter, the harm on the performance of the steel was minimized.

Mar 1, 2018

By Yuanbo Zhang, Zhixiong You, FENG ZHOU, Guanghui Li, Zhengwei Yu, Zhiwei Peng

Reduction disintegration of sinter significantly affects the coke consumption and productivity of blast furnace smelting. As we know, the reduction disintegration index (RDI+3.15) of sinter obtained from titanomagnetite concentrate is relatively worse than those from ordinary iron ores. In this study, the effect of sintering parameters, mainly involving coke breeze dosage and basicity on sintering indexes was investigated using titanomagnetite concentrate as raw material in an experimental-scale pot. Subsequently, RDI+3.15 of the sinter was detected according to the Chinese standard of GB/T13242-91. The results show that RDI+3.15 rises with the increase of coke breeze dosage, while it decreases with increasing basicity from 0.5 to 2.0 and then increases in the basicity range of 2.0-3.0. Finally, the microstructure of sinter before and after reduction was studied. And the mechanism of reduction disintegration was preliminary revealed by analyzing the morphologies and distributions of minerals in the sinter.

Jan 1, 2015

By Zhiyuan Shen, Dan Zhao

The abstract discusses the importance of reliable mine monitoring systems for preventing accidents. It focuses on diagnosing ventilation system failures caused by roadway faults that alter airflow resistance. The paper proposes using an improved Support Vector Machine (SVM) method to identify the fault location based on changes in air volume detected by wind speed sensors. The approach involves building a sensitivity 0-1 matrix and establishing a roadway fault scope library. The improved SVM method is tested on the Daming coal mine, demonstrating its effectiveness in diagnosing fault locations, reducing training time, and improving accuracy compared to traditional SVM.

Apr 5, 2022

By Fengyu Ren, Kunpeng Yu, Gideon Chitomb, Qiangqiang Gao, Liqiang Ma, Jiangtao Zhai, Ichhuy Ngo

The penetration of rock fragments of overlying strata causes advanced ore dilution during drawing. The results of numerical and physical experiments showed that the proposed numerical simulation was applicable and the microscopic parameters of the model were reliable. The penetration under the variables of particle diameter ratio, density ratio, overlying strata thickness, and particle morphology was clarified. The penetration was quantitatively characterized by the discharge amount and the dilution rate. The experimental results showed that the diameter ratio and density ratio had a significant influence on the penetration. On the irregular shape of particles, the penetration is weakened. The overlying strata thickness had little effect on the penetration. This study could provide a theoretical basis for the full section uniform drawing, avoiding advanced ore dilution and further optimization of recovery rate.

Nov 13, 2023

By Qi Shifu, Guo Tao, Liu Haoquan, Yao Chaogui, Zheng Li

Abstract: To excavate oil-gas pipeline ditches in a rocky region or area the explosive method is needed. When a parallel ditch is to be dug by blasting near or in the vicinity of an existing pipeline, a safe criterion must be determined to ensure safety for the latter. In this investigation, with the construction of the second phase of the West-East Gas Pipeline Project, we carried out real blasting tests and numerical simulations to explore the safety criteria for the existing pipeline. Through this investigation, we obtained the safe strain elasticity threshold es2000µe, blast vibration velocity calculation formula, and the maximum vibration velocity Vmax=14cm/s(5.51in./s) for the pipe under blast shock loading, and worked out how to determine the charge size in the follow-up blasting excavation. These results can be used to determine the maximum explosive weight per delay and decide delays for the initiation circuit network in blasting a parallel pipeline ditch, and to make safety assessments for the existing pipeline in service. Having successfully been applied in the second and third phases of the West-East Gas Pipeline Project, China-Russia Oil Pipeline Project and China-Myanmar Gas Pipeline Project, these findings are very significant for other similar pipeline construction.

Jan 1, 2014

By C. Y. Jia

Adsorption of Thiooxidans ferrooxidans and Mycobacterium Phlei on the surface of pyrite and galena was studied. From the experimental results, it was observed that Mycobacterium Phlei adsorbed preferentially on pyrite than on galena at neutral and alkaline pH values, while Thiooxidans ferrooxidans is not at all pH range, and the scanning electron microscopy photograph also indicated that. FTIR and XPS of two strains of bacteria indicated that there are much functional groups on surface of them, such as O?H, N?H, C-O, C?N, C?O etc, but S-O group occurred on Thioox-idans ferrooxidans cell surface and the P-O group appeared on Mycobacterium Phlei cell surface, and the content of C?O?H and C?O?C groups on Mycobacterium Phlei cell surface is higher than that on Thiooxidans ferrooxidans cell surface, this also been known from UVS investigation. The affinity of these groups to metal ions on sulfide minerals is able to explain the selective adsorption.

Jan 1, 2014

Pyrite and Chalcocite have different crystal lattice, with different dissolution rate in the same ac-id solution, the dissolution rate of which is accelerated with increasing redox potential, they are leached simultaneously at high redox. In present work, some methods are adopted to inhibition the bioleaching of the pyrite by controlling the redox potential. Shake flask experiment shows that the dissolution of pyrite and chalcocite is slow as redox potential <700mV(Eh), but the dissolution in-creases exponentially as redox potential>800mV(Eh), they have good selectivity at redox potential between 700mV and 760mV(Eh).

Jan 1, 2014

By Xin Tan, Changgen Li

"The floatabiliby of chelate CF-collector for zinc and lead oxide minerals was described. It found that CF-collector possesses a strong collection power for zinc and lead oxide minerals as well as excellent selectivity for the gangue minerals. A new technology of zinc and lead oxide flotation with CF reagent as a collector, lead nitrite as a activator and water glass as modifier was presented. The mechanism of interaction between reagents and minerals was discussed by means of adsorption, zeta potential, nephelometric titration, XPS and infrared spectra was investigated.CF-collector, newly developed by Beijing General Research Institute of Mining and Metallurgy (BGRIMM), is a kind of chelate collector for the flotation of oxide minerals. CF-collector mainly consists of N-nitroso-N-phenylhydroxylamine ammonium salt. The CF-collector was used for the selective flotation of scheelite in the Chinese plants.In this paper, the effects of the dosages of activator Pb(NO3)2 and depressants (sodium hexametaphosphate, polyphosphate, water glass and salified water glass) on the floatabilities of several minerals (cerussite, smithsonite, calcite, dolomite, limonite and quartz) as well as their mixtures were investigated in the presence of the CF-collector. The results show that the CF-collector is the excellent collector for selective flotation of cerussite and smithsonite. Pb(NO3)2 can selectively activate the oxides of lead and zinc resulting in a decrease of the CF-collector dosage. The sodium hexametaphosphate plus the salified water glass are the effective depressants for gangue minerals. Based on the above facts, the “CF process”, namely, used CF reagent as a collector, Pb (NO3) 2 as a activator, and sodium hexametaphosphate plus salified water glass as depressant, has been used for the flotation separation of the lead oxide mixtures or zinc oxide mixtures without disliking and heating. For the feed lead assaying 19.07%, the lead concentrate assaying 49.81% Pb at the recovery 80.69% was obtained after one step flotation. For the feed zinc assaying 12.85%, a zinc concentrate of assaying 29.56% Zn at recovery 83.87% was obtained."

Jan 1, 2003

Study on Selective Reduction and Magnetic Separation of Low-Grade Nickel Laterite Ore to Produce High Nickel Concentrate

Sep 13, 2010

By Li Qihou, Liu Zhihong, Liu Zhiyong, Yao Wei

Black copper sludge, which mainly contains copper, arsenic and a little antimony, bismuth, selenium, tellurium, is an important recyclable secondary resource. In this paper, selective removal of arsenic from black copper sludge by alkaline oxidative pressure leaching was studied. The influences of alkali concentration, leaching time, leaching temperature, oxygen pressure, liquid-solid ratio and other variables on the leaching rate of arsenic, copper and tellurium were investigated. The results were as follows: when the leaching process was conducted at initial alkali concentration of 1mol/L, liquid-solid ratio of 10, stirring rate of 500r/min, leaching temperature of 140°C for 5 h and oxygen pressure of 2.5MPa, the leaching rates of arsenic and tellurium were 85.43% and 59.7% respectively, and copper, antimony, bismuth were not leached. Hence, arsenic has been removed effectively from black copper sludge, while the valuable metals such as copper, antimony and bismuth remained in the residue that can be further recovered easily. INTRODUCTION Black copper sludge is a byproduct in the purification process of copper electrolyte. Arsenic, antimony and bismuth are major harmful impurities in copper electrolytic refining system. The accumulation of these impurities will cause adverse effects, such as the increase of electrolyte resistance and power consumption and deterioration of cathode copper quality (Wang, Liu, & Zhang, 2001). Hence, electrolyte purification is an essential part of the electrolysis process (Liang, Chen, & Guo, 2009). Electrolyte purification methods include electrowinning (Davenport, King, Schlesinger, & Biswas, 2002), solvent extraction (Navarro, Simpson, & Alguacil, 1999), ion exchange (Arroyo et al., 2017), coprecipitation (Wang et al., 2003, 2018; Xiao et al., 2007; Xiao, Cao, Mao, Shen, & Ren, 2014), activated carbon adsorption (Navarro & Alguacil, 2002), electrodialysis (Cifuentes et al., 2015), redox process (Zhou, Peng, Zheng, Ma, & Cui, 2011; Peng, Zheng, Zhou, & Chen, 2012; Zheng, Peng, Ke, & Chen, 2013), among which the electrowinning method is simple in operation and effective in impurities removal, making it the main process for current electrolyte purification. Some copper ions can react with harmful impurities to form complex black copper sludge by controlling the operation conditions of electrowinning process. Based on the estimated data provide by Davenport et al. (2002), an annual output of 400,000 tons cathode copper could produce 432-2168 tons of black copper sludge by electrowinning method. Black copper sludge contains 30~50% copper, 15~30% arsenic and a small amount of rare elements such as selenium and tellurium. Thus, recovery of valuable metals can bring huge economic interests. Moreover, arsenic in these sludges could cause significant environmental pollution. Therefore, effective removal of arsenic from these sludges is urgent and significant.

Jan 1, 2019

By Hongyang Cao

The iron constituents selectively separated from the modified copper slags by magnetic separation and flotation.were studied. The results of magnetic separation for modified copper smelting slags show that the grinding size, current intensity and dispersant agent had great influence on grade, and recovery ratio of TFe in preparation concentrate; The results of flotation for magnetic concentrate show that the positive flotation of sodium oleate negatively upgrade the grade of magnetic concentrate, but the reverse flotation of lauryl amine and soluble starch are effective. The grade of TFe can reach 54% and the recovery ratio can reach about 90% in magnetic concentrate, when the grinding size is 45.8µm and the current intensity is 2.5A. The optimal effect is obtained by using lauryl amine as collector and soluble starch as depressant to reverse flotate magnetic concentrate, and the grade of TFe is upgraded 2.37%.

Jan 1, 2009