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By Adriano Francisco dos Santos

Dentre as diversas atividades executadas na área de Utilidades de uma empresa, o processo de clarificação e potabilização da água é de suma importância para a manutenção dos processos e das pessoas que ali trabalham. O presente trabalho visa mostrar a preocupação da Área de Energia com os funcionários, colaboradores e comunidade, no que se diz respeito aos riscos a saúde e segurança na utilização do cloro gasoso no processo de clarificação e potabilização da água e as atitudes tomadas para eliminação desse risco, durante o processo de substituição do cloro gasoso pela tecnologia Oxamine®.

Jul 31, 2018

By Eustáquio Vieira Júniorr, Dalton Martins Neto, Filipe da Costa Oiveira

O Alto-Forno 2 da Ternium Brasil, no Rio de Janeiro, iniciou sua primeira campanha em 16 de dezembro de 2010. No decorrer de sua campanha, verificaram-se problemas de deslocamento de staves de ferro fundido e deformação dos staves de cobre chamado “efeito banana”, causando a perda da capacidade de refrigeração destes componentes do sistema de arrefecimento. Após a análise dos eventos foram executadas diversas ações para recuperação e preservação do Alto-Forno 2, sendo estendidas também ao Alto-Forno 1. Dentre as ações de preservação para o Alto-Forno 2 foi estabelecido que deveriam ser substituídos os staves danificados e alguns setores da carcaça que apresentavam trincas e deformações, e consequentemente a perda de suas propriedades mecânicas, visando eliminar as interrupções na operação do Alto-Forno 2 para reparos localizados e redução das instabilidades operacionais causadas pela não uniformidade das superfícies dos staves. O trabalho apresenta o detalhamento da técnica utilizada para substituição dos staves, a seleção dos materiais assim como os preparativos operacionais que garantiram o bom desempenho do Alto-Forno 2 nos momentos que antecederam a parada e após seu retorno à operação, mostrando a viabilidade técnica e econômica da atividade.

Oct 1, 2019

By J. O. Mack, J. B. Russell

IN recent years, solders containing 20 per cent tin with no bismuth or cadmium have been developed by a few companies, and personnel have been properly instructed in their use. In addition, since the tin shortage, a number of solders containing less than 10 per cent Sn, and some with no tin, are being used in special applications; however, a solder of this type has yet to be developed that is satisfactory for general use. [ ] The purpose of this investigation was to develop an alloy containing a maximum of 15 per cent tin, with no cadmium or bismuth, having solder properties equivalent to or better than those of substitute solders now specified containing i8 to 20 per cent tin (Table I), or even approaching the properties of the standard 40 to 60 tin-lead solder. The wartime restriction of bismuth and cadmium, elements that have beneficial effects on fluidity, solidification range and strength, makes it increasingly difficult to develop a general-purpose solder containing a maximum of 15 per cent tin. In the course of this investigation, 11 elements were used in various combinations with the basic 15-85 tin-lead alloy. These elements were antimony, silver, copper, indium, thallium, lithium, calcium, barium, potassium, sodium and arsenic. In all, 116 low-tin solders were investigated, with the idea of developing a solder that will give satisfactory working properties, specifically in regard to "wetting" of copper, brass and iron, solidification range, capillarity and shear strength of a soldered joint. The relative importance of these various properties plays an important role in the search for substitute solders, since it is almost impossible to retain all of the desired qualities of a high-tin solder and still make drastic changes in the alloy composition. Because of the expected uses of a general-purpose solder, it is necessary that it have properties, especially in regard to wettability, that will enable it to be used on the metals in common use. BASIC CONSIDERATIONS The maximum liquidus temperature of a solder is determined by the particular application involved and the temperature that can be obtained by the source of heat.

Jan 1, 1944

By C. A. Garcia

The solvent extraction of gold cyanide from alkaline cyanide solutions with monosubstituted guanidines, bis disubstituted guanidines and a tetrasubstituted guanidine was investigated. The guanidine functional group is protonated in alkaline solution and the guanidinium cation is stabilized so that the aurocyanide anion can be extracted even at -pH 12 if an appropriate carrier is used. Typical aprotic carriers including both aliphatic and aromatic solvents limit gold extraction by guanidines to pH 10; whereas the presence of an alcohol extends gold extraction to pH 12. UV spectroscopy suggests that the alcohol facilitates protonation of the guanidines, stabilizes the guanidinium cation, and facilitates gold extraction at high pH.

Jan 1, 1993

By C. S. Chang

PEARL starch, a corn starch prepared with a minimum of alteration, is a good selective depressant for iron oxide minerals.1 From what is known of the complex chemistry of corn starch, there is evidence that it consists of a mixture of saturated giant polymeric molecules, both straight and branch- chained, the constituents consisting of glucose units with hydroxyl radicals as active or polar groups. To add to the existing knowledge of the chemistry of the flotation process, it is desirable to ascertain the effects on the corn starch as an iron oxide depressant when some of the hydroxyl radicals are replaced by other active groups that are common to flotation reagents. The ideal way to carry out this investigation would be to test reagents containing different active groups derived from corn starch. The preparation should be such that the reagents possess the same degree and location of substitution and are ac- companied by little or no degradation of the starch molecules. This, of course, is almost impossible to realize, as it is difficult to control the degree and location of substitution as well as to prevent degradation of the starch molecule during preparation.

Jan 9, 1954

By James A. Clum

The shift to lower grade iron ores, e.g., magnetic taconites, resulted in a shift towards agglomeration practices which could effectively deal with the fine particle sizes generated in the liberation and concentration processes. If the iron bearing particles are not extremely fine, e.g., -1/2 in + 100 mesh, sintering is an adequate means of agglomeration.(1) For the more dispersed ores which result in fine concentrates (more than 80%,-325 mesh), the fine particles must be agglomerated by mechanical means before final hardening, e.g., pelletizing.(1) In the pelletizing process, the essentially mechanical step of balling is extremely critical since the strength of the pre-fired pellet determines the firing conditions. The ability of the proper amount of moisture to hold together a ball of the very fine ore concentrate particles has long been recognized. It is a charac¬teristic of the reaction at the interface between the ionic solid of the ore concentrate and the polar water phase which overlays the solids. The strength in such moisture laden balls, the green strength, is a strong function of the water content (Figure 1) and thus deteriorates rapidly for either a small excess or a small deficiency of moisture. For purposes of commercial practice, the control of green ball handling properties by accurate control of ball moisture is too demanding. Moreover, as the ball is heated towards its hardening tempera¬ture, e.g., 1300'C, there is a substantial drying reaction which would lead to such a low dry strength of the ball that it would not support its own weight much less the weight of other balls in a firing furnace.

Jan 1, 1976

By R. A. Hevia

Florida Power and Light is the fifth largest investor-owned electric utility in the country. It has a service territory that covers 35 counties, or 28,000 square miles, 2.5 million customers, and serves 5.6 million people. The total installed capacity is 13,470 MW, generated by four nuclear units, 36 oil and/or gas fired units, and 48 gas turbine units. Traditionally, FPL has been an oil-based utility. In 1979, this dependency on oil became obvious when 42 million barrels of oil were burned during the year. At that time, it was also projected that, based on the current estimates of customer growth and available generation capacity through 1990, FPL's residual fuel oil consumption would increase from the 1979 level of 42 million barrels (6.7 million m3) per year to approximately 55 million barrels (8.7 million m3) per year by the mid-1990's. Concern over this was further aggravated by the fact that it was difficult to estimate both the price and quantity of fuel oil that would be available over the next decade since changes in the world market, decisions by oil producers and refiners, and international political developments would all affect the availability of oil. Also, at that time, the price of residual fuel oil had increased drastically, and there was no reason to think that these prices would soon stabilize. Thus, oil back-out became a primary objective of FPL and since then, FPL has been actively investigating ways to decrease fuel oil consumption.

Jan 1, 1985

By P. Munjal

"Usage of Supercritical CO2 in place of high pressure freshwater has proven to be a potential breakthrough in the technique of fracturing. Tapping of carbon footprints from feasible sources like industries can be used to manufacture Supercritical CO2 required for fracking. Supercritical CO2, being less viscous than water, creates complex and coherent micro-fractures which can connect many more natural fractures greatly, increasing maximally the fractures’ conductivity leading to an increment in production. The better clean-up property of Supercritical CO2 provides auxiliary benefits of immediate evaluation of fracture zones, usage of an optimized quantity of mesh proppant and elimination of the need of swabbing. Also, Coal has a stronger affinity for CO2 than for CH4. When CO2 is present, CH4 on coal is replaced by CO2. This also ensures rigorous recovery of gas from the coal beds. Use of Supercritical CO2 will obliterate many problems as the CO2 used for fracturing is either sequestered beneath the crust or is recovered at the surface and reused. Therefore, injecting CO2 into coalbeds achieves not only enhanced CBM recovery, but also greenhouse sequestration underground. INTRODUCTION Coalbed Methane At various times in the geologic past, earth had dense forests in low-lying wetland areas. Due to natural processes such as flooding, these forests were buried underneath the soil. As more and more soil deposited over them, these dead plant remains were compressed. As the process continued the plant matter was protected from biodegradation and oxidation, usually by mud or acidic water. Under high pressure and high temperature, dead vegetation was slowly converted to coal. The omnibus process of formation of coal, thus, comprises of conversion of dead plant matter into peat, followed by its conversion to lignite, then sub-bituminous coal, after that bituminous coal, and lastly anthracite. This process of enrichment of coal as it is progressively forced deeper into an ambience with higher temperature and pressure involves biological and geological processes that take place over a long period and is called coalification. During coalification, large amounts of methane-rich gas are generated and stored within the coal on internal surfaces; hence comes coalbed methane. Coalbed methane (CBM), a gas formed as part of the geological processes that are responsible for the generation of coal, is adsorbed into the solid matrix of the coal during its formation process. Coalbed methane is distinct from a typical sandstone or other conventional gas reservoirs, as the methane is adsorbed and not absorbed. The methane is in a near-liquid state, lining the inside of pores within the coal. The open fractures in the coal that result from the liberation of volatile materials (and subsequent contraction due to the liberation) from the coal due to the high temperature and pressure conditions encountered, called cleats, may also contain free gas or can be saturated with water."

Jan 1, 2015

By B. K. Mishra, Avijit Biswal, B. C. Tripathy, Abhijeet Singh, K. Sanjay, T. Subbaiah

We studied theeffect of anode substrates such as pure lead (Pb), lead antimony (Pb-Sb), and lead-silver (Pb-Ag) on the structural and electrochemical properties of electrolytic manganese dioxide (EMD). X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and chemical analyses were used to determine the structural and chemical characteristics of the EMD samples. The charge-discharge profile was studied in 9 M KOH using a galvanostatic charge-discharge unit. In all the substrates the current efficiencies were more than 99% except with Pb-Sb where it was 90%. Results revealed the nature of the substrate strongly affected the morphology of the deposited material which in turn affected the electrochemical properties of the EMD samples. XRD analyses revealed that the nature of the anode did not affect the crystal structure of the deposited EMD and all the samples were predominantly ?-MnO2, which is electrochemically active for energy storage applications. The EMD deposited on lead substrate showed superior discharge capacity of 245 mAhg-1 when compared with other substrates.

Jan 1, 2014

By D Craw, C Smith, C Martin

The Wangaloa coal mine closed in 1989, and an attempt to grow Pinus radiata on quartz-rich overburden dumps was not successful. The site is currently being rehabilitated with re-profiling and native plant establishment. Plants are being established in a range of substrates that consist of variably disaggregated Tertiary coal measure sediments derived from the mine sequence. This material has low organic matter content (typically <10 %), originating from coal fines or carbonaceous sediment. Substrate samples were collected during December 2003 from a range of sites varying in age, slope, and parent material. Nutrient analysis includes nitrate, ammonia, total N, total P, available P and readily exchangeable base cations. Total nitrogen and phosphorus are low on areas of recently disturbed, quartz-rich overburden, with total N =1200 mg/kg, and total P =200 mg/kg. Background forested areas have total N ranging between 2800 - 3300 mg/kg and total P of 420 - 500 mg/kg. Quartz-rich overburden sites contain available nitrogen levels of less than 6 mg/kg, while background forested areas are generally >20 mg/kg. The soils and water runoff are generally acid, with pH down to three. Water samples have been collected from both ground and surface resources on a monthly basis since December 2003. The main lake on the site had pH of 4.6 in 1999, and this remained relatively unchanged when 850 tonnes of lime were added in 2002. However, the lake pH changed to 6.4 within a one month period in 2004, and has fluctuated since that time.

Jan 1, 2004

By David L. Moffatt

Considerable current interest is evident[l,2] in the use of transient electromagnetic methods for subsurface remote sensing. A transient method is discussed which uses a periodic video-type pulse containing a wide frequency range. A video pulse is used as an interrogating signal both for "target" identification and detection for relatively short depth (c 20 meters) applications in soil and soft rock media. If the medium is favorable, e.g., hard rock, greater depth applications appear to be feasible. The same procedures would be applicable for deep geological exploration but would require a substantial reduction in frequency and increase in target size. It should be noted that video pulse generators with 35 kv peak voltage and nanoseconds base widths are now within the state-of-the-art, thus significant power over broad spectral ranges is possible. In the design of a video pulse sounding system, 5 main problem areas can be identified; 1 ) selection of the pulse shape or spectral content of the video pulse, 2) design of a radiating structure which effectively couples such a pulse into the medium, 3) isolation of the radiating and receiving mechanisms, 4) realistically accounting for the dispersion and attentuation of the medium and the air-medium interface, and 5) interpretation or processing of the received signal waveform. Each of these problem areas will be discussed and illustrated with experimental and/or theoretical results. The Video Pulse Selection of the proper video pulse signal is dictated by 3 considerations, the maximum desired depth of penetration, the attenuation of the medium and the required resolution and size of the target. For a lossy medium, penetration and resolution are clearly at cross purposes and a compromise is necessary. The exact nature of the compromise is dictated by the application, but the spectrum of the video pulse should not contain any frequencies higher than the predicted cut-off, i.e., that frequency which is attenuated to the threshold level of the receiver. As a practical matter, it may be necessary to select 1 or 2 video pulses reasonably suited

Jan 1, 1973

By Kirk Ellison, Eric S. Lindquist, Peter Faust, Stephen M. McLandrich

"The 181 Fremont Tower will be an 800-foot high-rise with a 60-foot deep basement located in a dense urban part of downtown San Francisco. The design and construction methods of the subsurface elements navigated a variety of site constraints such as loose fill and soft estuarine soils, shallow groundwater, contaminants, historic obstructions, small work area, proximity of adjacent buildings, and the on-going excavation and build-out of the adjacent Transbay Transit Center (TTC) train box. Design of the approximately 260-foot-deep drilled shafts (some of the deepest foundations ever constructed in San Francisco) was proven by a full-scale load test that provided unique data on the frictional capacity of the deep soil and Franciscan Complex bedrock in the region. Design and construction of the shoring system for the 5-story basement excavation was exceptionally challenging because of the on-going construction for the TTC. To allow for flexibility during construction, hydraulic rams were placed in a transfer waler along the shared TTC shoring wall that could adjust the forces transferred through to the TTC excavation if required. Open and steady communication between the shoring engineer, the geotechnical engineer, and the shoring/foundation contractor was crucial in order to satisfy the complex constraints of this site.INTRODUCTIONThe 181 Fremont Tower is a new build mixed-use tower, currently under construction in the dense urban core of the South of Market District of San Francisco, California. This high-rise will consist of 54 above ground floors with the roof level 700 feet high. Atop the roof will be some architectural features including a spire that will top out at just over 800 feet, which will make it the second tallest building in San Francisco upon completion.The tower is being developed by Jay Paul Company and the architectural design is by Heller Manus. The structural engineer and geotechnical engineer for the project is Arup North America Ltd (Arup). The shoring designer is Brierley Associates (Brierley). The general contractor is Level 10 Construction (Level 10) and the specialty foundation contractor and excavation contractor is Malcolm Drilling Co., Inc (Malcolm)."

Jan 1, 2017

By Kenneth Cottingham

THE area described herein is situated on what is known as the Arches Fork anticline in Roane and Calhoun Counties, W. Va. When the area was first mapped, it was felt that well records would give a more intimate idea of conditions, both structural and lithologic, than could be expected from surface horizons. The surface formations are chiefly members of the Monongahela series, though northward the hilltop outcrops are those of the Dunkard. Neither series offers a key horizon sufficiently definite to be satisfactory, although the structure as determined from well records was later checked against two of the more persistent surface sandstones. In mapping the subsurface structure, the top of the Big Lime (Greenbrier) was employed as the key horizon. The average depth to the top of the Big Lime varies from 1600 to 2000 ft. (487 to 609 m.), while the average thickness as indicated by well records is 113 ft. (34 m.). The oil-producing formation is the Big Injun, lying just below the Big Lime. In two instances, well records show the Lime and Injun separated by a few feet of "break." The Big Injun is recorded as having a variable thickness. Seven logs report it as missing and one gives it the maximum thickness of 105 ft. (32 m.), while the entire average for thickness is 19 ft. (6 m.).

Jan 1, 1922

Asian countries are now facing very crucial aspects of urban living under the recession of the economy. The current situation is such that those hard aspects may make the living standards worse and worse in the next century, unless proper measures are taken on the infrastructure for urban lives. More than half of the population in Asian countries are now living in cities. Nowadays, the socio-economic development of the Asian countries has been closely linked to the development of world economy because of the border-less economy system. The population inflow to big cities is inevitable as the Asian countries step into an industrialised economy. Such a tendency will be further accelerated when Asia becomes a centre of financial business in the 21st century. The government of any country has realised the situation very well. The United Nations has established a specific agency to solve the problems caused by the rapid urbanisation. This global agency for urbanisation is named United Nations Center for Human Settlement and it is so called Habitat. There are three Habitat offices in the world, Nairobi in Kenya, Santiago in Chile and Fukuoka in Japan. The activities of Habitat offices cover a wide field of issues such as housing, urban development, infrastructure and environment, etc. Habitat Fukuoka Office is serving Asia and Pacific in co-operation with the government offices concerned.

Jan 1, 1999

The history of civilisation continues to register a steady tide towards the urban life as the basis of its social organisation. The manifestation of this movement is a continuous growth and increasing density of population in our towns and cities, as the favourite space for the development of humanity. Naturally, this trend raises a certain number of problems which grow proportionally with the size of the city. The use of the underground space has an important role to play in solving such urban problems. But various issues must be taken into account when developing urban underground space.

Jan 1, 1999

By E. Ray Webb

A interest to geologists and to mining and petroleum engineers is a laboratory method for determining the dip and strike of sub- surface structures, as well as the direction of fault planes traversing them. The information is derived by making use of the magnetic properties of borehole cores which must show visible representations of bedding or fault planes. Complete knowledge of these factors aids greatly in the successful exploitation of both ore and petroleum deposits.

Jan 1, 1940

By J. A. Vonhof, R. O. van Everdingen

Since 1949, a total of 59 disposal wells have been installed in Canada to inject liquid wastes from refineries, mining operations and chemical plants into subsurface formations at an ever-increasing rate. Well depths range from around 600 feet to almost 5,500 feet; injection rates range from 0.5 (U.S.) gpm to more than 1,000 gpm for individual wells; wellhead injection pressures range from a slight vacuum to over 500 psi. Apart from strictly technical considerations of well design, the geological, hydrodynamic and hydrochemical conditions at the disposal site have a strong bearing on the safety and success of such operations. Prevailing hydrogeological conditions in large portions of the country do not allow safe subsurface disposal.

Jan 1, 1973

By Robert Stefanko

The concept of disposing of liquid industrial wastes by deep-well injection is not a new one. Brines associated with crude oil long have been disposed of in this manner, with the additional benefit of aiding secondary oil recovery. More recently, with the expansion of nuclear energy, the lethal, highly radioactive wastes which are by-products of the fission process have created severe disposal problems. During the past ten years, a variety of industries have resorted to subsurface disposal, some of the details of which are given elsewhere (1,2). The list reveals wide variations in injection rate, pumping pressure, cost, and waste disposition. Included are successful installations in Western Pennsylvania.

Jan 1, 1969

Perhaps the only thing certain about an address that purports to look into the future of any human endeavour is that time will prove it :.o be inaccurate. In undertaking the dubious, but oft-times necessary business of prediction, thr, historian will base his/her forecasts on tr-ands of the past, the speculator on current events, and the politician on what he/she would dearly like to see happen. The thoughts expressed in this address seem to have arisen through exercising a combination of all three of those philosophies but, hopefully, with a smat- tering of pragmatism.

Jan 1, 1988

By Whittaker B. N, Reddish D. J

This paper presents the physical modelling results of subsurface fracture development associated with Iongwall mining operations and an application of image processing techniques to interpretion of the results. Physical modelling results haióbeen obtained by employing a large sand and plaster model loaded purely by gravity as a means of fracturing the subsurface strata above the longwall excavation. The results have shown fracture development and crack propagation as a longwall face advances and demonstrated that the strength of stratified rocks, the presence and position of a weak band-, and the extraction thickness, have significant effects upon the overall fracture patterns above the excavation. Binary images of fracture patterns were scanned from the black and white photographs of the tested models using an image analyser coupled to a video camels. These images were manipulated by a custom written C program which allows the images to be processed in both vertical and horizontal direction. The images were filtered to quantitatively differentiate between vertical and horizontal fracture intensities. The vertical fracture intensity is particularly important as vertical fractures are considered to provide the main avenues for surface and subsurface water inflow into the excavation. The use of the image analysis techniques has shown a promising improvement in image enhancement and in model results interpretation in a quantitative manner. The numerical nature of the image analysis results will allow further statistical comparison with other modelling techniques to be undertaken and significantly increase the scope for use of the modelling technique results.

Jan 1, 1992