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By Allen Garrison

THE chemistry of clays and shales has been assuming increasing importance in the petroleum industry, and two factors have greatly influenced this trend. The first has been the growing evidence that the marine shales are source beds, and that the petroleum compounds have migrated to the sand reservoirs overlying or underlying these shales: the second has been the demand for drilling, fluids better adapted to penetrate these marine shales without difficulty and expense. ORIGIN AND GENERAL COMPOSITION OF CLAYS AND SHALES Clays, shales and surface soils are all closely related materials. They are mixtures of finely divided compounds formed during the weathering of the solid crust of the earth. Their nature is essentially colloidal; that is, their behavior is determined by the state of division of the materials and the surface reactions of the smallest grains. Many of their chemical changes affect only the exposed areas and do not involve the interior of the grains of matter. The extent of these reactions is more nearly proportional to the area of the substances than to their mass, therefore it is possible for a small. amount of a material in an extremely fine state of division to completely dominate the character of the mixture. More than 83 per cent of the crust of the earth is composed of three elements-oxygen, silicon and aluminum. Consequently, the corrosion products of the crust are predominantly aluminosilicates, or compounds of aluminum, silicon and oxygen. If we add the compounds of six elements-iron, calcium, sodium, potassium, magnesium and hydrogen-more than 98 per cent of the crust has been accounted for. These six elements, together with the first three, also appear in soils, clays and shales. But direct chemical analysis is of little value in describing the nature of such materials. Many chemical individuals may be present in variable amounts,. and the extreme subdivision of any one of the individuals may contribute qualities that dominate the mixture.

Jan 1, 1939

By Allen Garrison

THE chemistry of clays and shales has been assuming increasing importance in the petroleum industry, and two factors have greatly influenced this trend. The first has been the growing evidence that the marine shales are source beds, and that the petroleum compounds have migrated to the sand reservoirs overlying or underlying these shales: the second has been the demand for drilling fluids better adapted to penetrate these marine shales without difficulty and expense. ORIGIN AND. GENERAL COMPOSITION OF CLAYS AND SHALES Clays, shales and- surface soils are all closely related materials. They are mixtures of finely divided compounds formed during the weathering of the solid crust of the earth. Their nature is essentially colloidal; that is, their behavior is determined by the state of division of the materials and the surface reactions of the smallest grains. Many of their chemical changes affect only the exposed areas and do not involve the interior of the grains of matter. The extent of these reactions is more nearly proportional to the area of the substances than to their mass, therefore it is possible for a small amount of a material in an extremely fine state of division to completely dominate the character of the mixture. More than 83 per cent of the crust of the earth is composed of three elements-oxygen, silicon and aluminum. Consequently, the corrosion products of the crust are predominantly aluminosilicates, or compounds of aluminum, silicon and oxygen. If we add the compounds of six elements-iron, calcium, sodium, potassium, magnesium and hydrogen-more than 98 per cent of the crust, has been accounted for. These six elements, together with the first three, also appear in soils, clays and shales.

Jan 1, 1939

By Allen D. Garrison

THE chemistry of clays and shales has been assuming increasing importance in the petroleum industry, and two factors have greatly influenced this trend. The first has been the growing evidence that the marine shales are source beds, and that the petroleum compounds have migrated to the sand reservoirs overlying or underlying these shales: the second has been the demand for drilling fluids better adapted to penetrate these marine shales without difficulty and expense. ORIGIN AND GENERAL COMPOSITON OF CLAYS AND SHALES Clays, shales and surface soils are all closely related materials. They are mixtures of finely divided compounds formed during the weathering of the solid crust of the earth. Their nature is essentially colloidal; that is, their behavior is determined by the state of division of the materials and the surface reactions of the smallest grains. Many of their chemical changes affect only the exposed areas and do not involve the interior of the grains of matter. The extent of these reactions is more nearly proportional to the area of the substances than to their mass, therefore it is possible for a small amount of a material in an extremely fine state of division to completely dominate the character of the mixture. More than 83 per cent of the crust of the earth is composed of three elements-oxygen, silicon and aluminum. Consequently, the corrosion products of the crust are predominantly aluminosilicates, or compounds of aluminum, silicon and oxygen. If we add the compounds of six elements-iron, calcium, sodium, potassium, magnesium and hydrogen-more than 98 per cent of the crust has been accounted for. These six elements, together with the first three, also appear in soils, clays and shales. But direct chemical analysis is of little value in describing the nature of such materials. Many chemical individuals may be present in variable amounts, and the extreme subdivision of any one of the individuals may contribute qualities that dominate the mixture.

Jan 1, 1939

It was shown previously that chalcopyrite could be floated without using a collector when the ore samples were treated with small amounts of sodium sulfide (Na2S). The role of this reducing agent was considered to be one of a cleaning agent to remove the hydrophilic surface oxidation products. It was later found, however, that the collectorless flotation could be obtained only under slightly oxidizing conditions. This might suggest that collectorless flotation is not due to the clean surface but to the elemental sulfur which may be present as an incipient oxidation product. Therefore, a search for the presence of elemental sulfur has been made by means of ESCA, mass spectrometry, and solvent extraction followed by W spectrophotometric analysis. On the basis of these results, the mechanisms of collectorless flotation are discussed.

Jan 1, 1983

By G. E. Agar, P. L. De Bruyn

Flotation is an important example of a chemical process by which one solid may be separated from other solids in a mixture. In contrast to other chemical processes such as leaching and smelting, separation of solids by flotation is characterized by the establishment of contact among three phases. In froth flotation these three phases are the solid to be floated, an aqueous electrolyte solution, and a gas, usually air. The gaseous phase may be re- placed by an organic liquid phase or this organic liquid phase may be added deliberately as a fourth phase. To gain an understanding of the flotation sys- tem, it is therefore necessary to study the chemical and physical properties of surfaces and to establish the effect of changes in composition of the bulk phases on the nature of the three interfaces, solid-gas, solid-liquid and liquid- gas. With very few exceptions inorganic solids are completely wetted by the aqueous phase so that the first step in flotation is to replace partially the solid-liquid interface by a solid-gas interface. This displacement process is accomplished by the addition of suitable reagents to the aqueous phase. The resultant surface reaction leaves the solid surface with a hydrophobic film. Although the primary objective of these reagent additions is to alter the solid surface, chemical reactions between the added chemical species and those species derived from the dissolution of the solids are unavoidable. For a quantitative description of such reactions and for the determination of the feasibility of a proposed reaction, we rely on available thermodynamic data. The application of thermodynamic principles to flotation systems has contributed much to our understanding of flotation. The changes in thermodynamic properties such as free energy and chemical potential are accessible to experimental determination, and a knowledge of their magnitude allows us to develop and predict a chemical mechanism oy which a solid becomes floatable. In this chapter it will be assumed that the reader has a working knowledge of the general principles of thermodynamics and solution chemistry. A complete discussion of the physical chemistry of flotation must include a treatment of solubility relations, complex ionic equilibria, reaction potential, and the elements of electrochemistry, especially those dealing with reversible electrical cells. The principles related to all of these features of the flotation system will not be discussed in this chapter. The discussion will be concerned with the thermodynamics and electrochemistry of surfaces and the electrical double layer model of the interface.

Jan 1, 1962

Surface Chemistry of Iron Ore Throughout a Processing Plant

Sep 13, 2010

Industry and regulatory agencies have requested guidance on safe blasting near transmission pipelines. The U.S. Bureau of Mines and AMAX Coal Company have studied surface coal mine overburden blasting near four steel and one PVC pipe-line of 15 to 5l-cm diameter, monitoring vibration, strain, and pressure. Unlike tests simulating construction blasting, these were up to 1000 kg per delay in 3l-cm blastholes. Worst case comparisons showed that 12.7 cm/s blasting vibrations produced strains about 1/4 that of pressurization and 10-18 pct of the ultimate tensile strength. No failures occurred from blasting as close as 15 m which produced vibrations over 60 cm/s.

Jan 1, 1994

By Maria I. De Rosa

Table 19 and figure 7 show the number of fires and fire injuries for surface coal mines by state during 1990-1999. Table 19 also shows by state the risk rates, employees' working hours, lost workdays, and coal production. For surface coal mines, 215 fires occurred in 21 states during 1990-1999. Ninety-four of those fires caused 93 injuries and I fatality (the yearly average was 21.5 fires and 9.3 fire injuries). Fourteen fires and seven injuries involved contractors. The Ewhr value was 729 x 10° hr (In = 0.026), the CP value was 6,355 x 10° st (Fn = 0.034), and the LWD value was 8,141. Kentucky had the most fires and fire injuries (45 fires and 23 injuries), followed by Pennsylvania (33 fires and 14 injuries), West Virginia (25 fires and 14 injuries), and Indiana (20 fires and 8 injuries). Among these states, Pennsylvania had the highest fire risk rate value (Frr=0.145), while Kentucky had the highest injury risk rate value (In 0.041).

Jan 1, 2004

By M. E. Kuchta

Surface coal mine design can be facilitated with the use of an interactive graphics personal computer program. This mineral inventory and planning program (POLY CALC) is described and its use is illustrated with a case study. The case study deals with investigating a stripping sequence and associated dragline stripping requirements.

Jan 1, 1986

By M. A. Weaver

This paper will investigate the historic and present state of the bituminous coal industry within the Commonwealth of Pennsylvania, with special emphasis on surface mining operations. It will address pertinent parameters such as production, markets, quality, number and size of operations, price, and productivity from a statistical viewpoint. In addition, relevant statistical parameters of select areas of the Appalachian Coal Region will also be presented and discussed.

Jan 1, 1989

By S. T. Sorrell

To obtain a negative determination for prime farmlands in its approved lignite surface mine permit application, Phillips Coal Co. conducted a soils mapping effort and a historic land use survey. In addressing the justification for topsoil substitute materials, the company relied on results of a geochemical evaluation to demonstrate improved drainage, trafficability, and fertility. It also relied on results of field test plots. Post-mining land use was determined through the use of overlay maps considering existing land use, vegetation, and historic prime farmland. The reclamation plan incorporated these elements plus indicator species, existing vegetation, and wildlife needs.

Jan 1, 1985

By Shawn T. Sorrell

Phillips Coal Company (PCC) submitted the first surface mine permit application under the Office of Surface &lining approved regulatory program of the State of Louisiana. This application for the Oxbow Lignite Surface Mine which is located approximately 64 kilometers (40 miles) southeast of Shreveport, Louisiana was submitted in March 1981. The State of Louisiana Office of Conservation, Surface Mining Division, assigned this application number LSM-1, indicating it is the first one submitted in Louisiana history. The permit area for the Oxbow Mine encompasses 6,251 hectares (15,627 acres). Of this total permit area, 5,862 hectares (14,656 acres) were classified by soil type as prime farmland by the U.S. Soil Conservation Service (SCS). Prime farmland acreage in the permit area became a major central issue in our early planning stages and throughout the permitting process of the Oxbow Mine, due to the magnitude of acreage involved.

Jan 1, 1982

By C. P. Boddy

One of the most difficult tasks a project manager will have in pre-mine planning is dealing with the mine site's hydrologic regime. Numerous federal statutes passed by Congress in the last decade have made the coal mining industry more responsive to the environmental impact during all phases of the mining process. Permitting these mines has dictated a cradle to grave approach in dealing with water related issues. This paper will attempt to explore the application of these technology- based laws and their direct application to the unique environment found in Alaska's interior regions.

Jan 1, 1985

By Nichols. R. S.

"Surface coal mining production from Elk Valley and area in southeastern British Columbia began in 1913. Since 1970, five open-pit mines have been put into production: Westar Mining&apos;s Hanner and Greenhills Operations; Fording Coal&apos;s Fording River Operation; Byron Creek Collieries&apos; Coal Mountain Mine and Crows Nest Resources&apos; Line Creek Operation.ln 1983 these mines produced 14.9 million tonnes of raw coal at an average strip ratio of 4.9 bank cubic metres of waste to 1.0 tonne of raw coal. This is 70% of the estimated 21.1 M tonnes annual capacity .Multiple seams are recovered with truck/shovel and dragline equipment. There is a wide range of equipment types in use with a recent trend toward larger and more mobile equipment.Coal mining in Elk Valley involves advancing along strike in four steps: hangingwall waste removal; seam cleaning; coal recovery; and foot wall waste removal. Each mine is unique in its approach to these four steps but the truck/shovel methods can be categorized into three main groups: seam dips < 35 degrees as at Harmer, Fording and Greenhills; seam dips 35 to 50 degrees as at Line Creek; and seam dips >50 degrees as at Byron Creek. Dragline mining at Fording involves bath waste and coal removal by draglines."

Jan 1, 1984

By Taisuke Sakakibara, Shinya Suzuki, Tatsuya Kato, Chiharu Tokoro, Kenichi Muto

Surface complexation using a diffuse layer model were constructed for arsenic (As(V)), zinc (Zn(II)) and silicate (Si(IV)) for aluminum hydroxide in the co-precipitation process. From experimental investigations using isotherms, zeta potential measurement and XRD analysis, it was confirmed that co-precipitation involved not only surface complexation but also surface precipitation. However, surface complexation was major mechanism for As(V), Zn(II) and Si(IV) removal under the target removal level of the Japanese effluent standard. In surface complexation modeling, exchange capacity of aluminum hydroxide was determined from specific surface area obtained from experimental measurement and site density obtained from reference. Surface complexation coefficients were determined by fitting the removal property and sorption isotherm obtained from co-precipitation experiments. These parameters were in agreement with the numerical parameters found by Karamalidis and Dzombak (2010) who reported a database of adsorption equilibrium constants for gibbsite. The surface complexation models constructed in this study were applied to neutralization process of an actual AMD treatment. Our model could successfully represent the pH edges for As(V), Zn(II) and Si(IV) in the neutralization of AMD.

Jan 1, 2015

By Liuming Wu, Willis Forsling

The complexation of Alizarin Red S (ARS) at the surface of hydrous fluorapatite particles has been investigated at 25.0 C by means of potentiometric titrations, adsorption experiments in 0.1 M NaCI ionic medium, and Diffuse Reflectance Infrared Fourier Transform spectroscopy (DRIFT) studies. A chemical model describing the reaction at the aqueous mineral surface has been established under equilibrium conditions according to the reaction [== -CaOH2 + HA2 - « _ =PO CaA2 - z + H30&apos;; to (int.) = -5.61 ± 0.02 3 a =PO- logBs-1110(int.) ( ) within the range 8.40 <_ -log[H ] <_ 9.80.] Experimental data were evaluated using the computer program FITEQL on the basis of a constant capacitance model for the electric double layer. The surface complex structure, has been proposed to involve the quinoid and alpha phenolic oxygens of ARS coordinated to the calcium sites on the fluorapatite surface.

Jan 1, 1993

By Hiroshi Maeta, Takao Kino, Hirota Osono, Kikuo Matsusaka, Azusa Shida

"Prior to refine an ultra-high purity material, it is necessary to estimate the surface cleanness of a base material. In this report, the cleaning method of a surface for refining of an ultra-high purity aluminum has been studied. Aluminum sample of 99.999% purity was p9lished mechanically and electrically and washed with various solvents. Surface composition and a depth profile near the surface were examined. Based on the experimental results, surface structure of an ultra-high purity aluminum was discussed.IntroductionRecently, studies on high purity metals have become of interest, and we have reported .various properties of an ultra- high purity aluminum1- 2)In order to purify a metal, it is necessary to clean a work area and to make vacuous as possible. So, we are studying the purification of aluminum by an ultra-high vacuum refining system and a zone refining system set up in a clean room with cleanliness class of 1000.Now, in order to avoid a mixing of impurities into the refining metal, a surface cleanness of a base metal is very important factor. The purity of the base aluminum used our work is 99.999%, but the surface state of the base aluminum is not clear. Aims in this work .are to investigate the surface state and to obtain the cleaning method of the base aluminum.Experimental procedureSamples used in this work were 99.9% (3N), 99.99%(4N) and 99.999% (SN) aluminum produced industrially and 99.9999% (6N) aluminum purified by us."

Jan 1, 2000

By Marcela C. Santini, Luiz A. Teixeira

"Surface conditioning (also referred as etching) of plastics prior to metallization is generally conducted with sulfuric I chromic acid solutions. Although these baths perform well technically, the presence of Cr (VI) imposes serious operating problems of an environmental nature. The present work reports ·the results of a study of surface conditioning o(ABS using solutions based. on sulfuric acid, with hydrogen peroxide and/or nitric acid, replacing chromic acid, as oxidants. Process performance was evaluated by SEM and by the uniformity and adherence of electroless nickel coatings applied on selected conditioned samples. The results showed that the evaluated types of solutions could be optimized to perform as well as the chromic-based baths, with a much superior environmental quality.IntroductionMetallization of plastics is normally undertaken for either decorative or functional purposes. Through metallization, the specific properties of plastics such as light weight, design flexibility, and low-cost of manufacturing are enhanced by the addition of properties usually associated with metals. These include reflectiveness, abrasion resistance, electrical conductivity, and a variety of decorative effects (1).The available processes that can be used for metallization of plastics are vacuum metallization or vapoµr deposition; indirect metallization and plating (1). Plating can be sub-divided into electroless plating and electroplating. In electroless plating, metal ions in aqueous solution are deposited on the .activated plastic surface by oxi-reduction reactions without the aid of an external electric potential, forming a thin metallic layer. This electroless deposited film has two functions: (a) it provides an electrically conductive substrate that allows further coating by electroplating; and (b) provides a secure bond between the plastic substrate and the electroplated layer (1,2). In case the electroless metallic part requires an additional layer for finishing purposes, or just an increase in thickness, the part can be additionally electroplated with a· variety of metals - in most cases those are copper, nickel or chromium (3)."

Jan 1, 2000

By Lyda W. Hersloff

As decommissioning of various radioactively contaminated facilities begins, the question of appropriate residual surface contamination becomes an issue. Surface contamination can result in exposure to people via inhalation, ingestion, and external radiation exposure, There is therefore the potential of exposure to workers involved in the dismantling of a facility as well as members of the general public acquiring salvageable equipment, tools, and building materials. The levels established as acceptable for unrestricted use by national and international organizations vary by as much as an order of magnitude for certain radioactive materials. The calculated doses associated with some acceptable contamination levels can be significant. The principle of ALARA, as low as reasonably achievable, is therefore a necessary element in establishing surface contamination levels for a specific site. Some components in evaluating site specific surface contamination levels for unrestricted use, especially removable contamination, include evaluations of the historical use of a facility, the mixtures of radioactive materials a&sociated with surface contamination, and resuspension factors for various materials.

Jan 1, 1991

By K Hortin

Kidd Creek mine in north western Ontario is developing phase 1 of the deep mine project for mining between 2100 m and 3100 m below surface. Heat problems were experienced during the 2003 summer in working places about 2300 m below surface. At the time the mine had a æcold stopeÆ for cooling the air supplied to the mine below 1500 m from surface. The æcold stopeÆ is where during winter, ice is created in both the open pit and its connecting airways to the mine and used to cool air in summer. The operation and limitations of the existing cold stope were evaluated and led to the requirement for additional mechanical cooling to be available for the summer of 2004. The first stage of a surface refrigeration plant providing 7.5 MWR of cooling was approved, the compressor set was ordered in early January 2004 and the plant commissioned six months later in early July 2004. Based on the current modifications to the mining plan, further plant expansions are required in 2006 and 2009 leading to a total of 19 MWR of mechanical refrigeration and 8.5 MWR equivalent from the extended cold stope. The refrigeration system is described with emphasis on the specific adaptations necessary to suit Canadian conditions. Additional investigations were; using the refrigeration compressors in winter for heating and, extending the performance of either cold stopes or alternative ice storage systems. The winter use of refrigeration involve removing heat from the mine exhaust air to provide a cooling load and to use the hot water in the condensing circuit to heat the intake air and reduce reliance on mine air heating with natural gas. This paper follows on from an earlier one presented at the Seventh International Mine Ventilation Congress where the background and planning of the mine ventilation and cooling requirements were described for extending the mine at depth to 3100 m.

Jan 1, 2005