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By George M. Bouton, Lawrence Ferguson

The experiments described in this publication were inspired by the Bell System's large interest in lead-alloy sheathed cables and by the wide range of fatigue and corroding conditions to which they are sometimes subjected in service. The first experiments consisted of operating specimens of lead + I per cent antimony telephone cable sheath alloy in a fatigue test while they were immersed in water taken from a manhole. Because of many published reports concerning corrosion-fatigue phenomena of various metals and alloys, a reduction in fatigue life was expected(1)2 Instead, however, the fatigue test ran on for many times the normal number of cycles an4 was finally stopped without failure. Because of this, the experiments were broadened to include the effect of many media on the fatigue properties of four lead alloys over a wide range of testing speeds and strains. One material, a viscous tacky polymerized isobutylene3 used in

Jan 1, 1945

By I. K. Choi

In a recent paper by Smith and Wen(1) the adsorption of sodium dodecylsulfate and trimethyldodecylammonium chloride on kaolinite was studied. As would be expected considering the general negative character of kaolinite, except perhaps at quite' acid pH values (2,3,4), it was found that trimethyldodecylammonium chloride adsorbed strongly on kaolinite at basic pH values. Furthermore, it was found that sodium dodecylsulfate adsorbed strongly on kaolinite at acid pH values, particularly at initial 1H values below pH 3 (final pH values near pH 4). It is interesting to note that adsorption of the anionic surfactant was strong under conditions where the kaolinite was apparently slightly negatively charged (2). The present paper reports on an extension of the work by Smith and Wen. In this paper the effects of the presence of dodecyl alcohol and sodium hexametaphosphate on adsorption of sodium dodecylsulfate and trimethyldodecylammonium chloride on kaolinite are considered.

Jan 1, 1967

By J. D. R. Neilsen

The objective of the research conducted and presented herein was to determine the effect of pre-established free gas saturation on the sweep efficiency of an isolated inverted five-spot well pattern. The investigation concluded that the ultimate recovery of an isolated inverted five-spot may be slightly increased by establishing a free gas saturation prior to water flooding; however, of more significance is the extreme deviation of the pattern's performance after water break-through from that commonly obtained from developed well patterns. The rapid "water-out" characteristic common to both linear floods and floods conducted in developed well patterns was not evidenced in the isolated inverted five-spot. Instead, the wells continued to produce oil long after breakthrough until ultimate areal sweep efficiencies of four, five, and six hundred percent were obtained prior to the water-oil ratio becoming excessive.

Jan 1, 1962

By A. Singh, M. Ntlhane, V. Ross, M. Dlame

"Fine valuable particles are often lost to flotation tailings streams due to inefficient collection by air bubbles as well as passivation of surfaces by oxidation and slimes. The application of high-shear hydrodynamic cavitation devices (HCDs) to overcome this problem has already proven to be a considerable success in the industry. This paper details the results of further investigations that were undertaken at Mintek to better understand the mechanisms involved when preconditioning feed slurries in an HCD. By promoting inter-particle attrition and conditions of high shear within the reactor, cleaning of particle surfaces is enhanced as well as the formation of superfine (nano) bubbles which are believed to aid their agglomeration and subsequent collection by normal sized bubbles. In order to broaden the envelope of understanding with regard to application of the technology, rather than tailings material as investigated earlier, a Platinum Group Mineral (PGM) UG2 ore from the Bushveld Complex in South Africa was used in this study. The results of a series of batch flotation tests in a 10L Denver cell are presented, being conducted after the feed has been subjected to different methods of preconditioning. It was demonstrated that the preconditioning significantly improved the flotation kinetics of the PGMs, the optimum being obtained after around 20 passes through the reactor. This was accompanied by a much enhanced recovery-mass pull relationship and a significant improvement in the grade-recovery response. Significantly, the selectivity between the PGM and the deleterious chromite (expressed as Cr2O3) gangue more than doubled under these conditions. Modelling of the PGM data by means of the modified Kelsall model indicated that both the fast and slow floating rate constants were improved.INTRODUCTIONIt is well known that the flotation recovery of fine and ultrafine particles, typically less than 10 micron in size, is a challenge (Yoon et al., 1989; Miettenin et al., 2010). Although these particles are typically well liberated, due to their very low mass and inertia, the collision efficiency with air bubbles is low as a result of the inability of particles to penetrate the liquid streamlines around bubbles. Hence the probability of contact is often regarded as the ratedetermining step in flotation of ultrafine particles. Introducing more power into conventional flotation machines is likely to solve only part of the problem, as conventional mechanisms are effective only to a point in terms of shear and micro-turbulence. Further challenges are posed by the treatment of low-grade or oxidised tailings dump material, where valuables are passivated due to prolonged exposure to the atmosphere or slimes. Over the years, various mitigating strategies have been investigated, including the use of dissolved air flotation (Martinez-Gomez et al., 2013; Calgaroto et al., 2015), shear flocculation (Subrahmanyam and Forssberg, 1990), seed or carrier flotation (Tabosa and Rubio, 2010), sonication to clean particle surfaces (Aldrich and Feng, 1999; Newell et al., 2006), high intensity conditioning (Bulatovic and Salter, 1989; Chen et al., 1999; Tabosa and Rubio, 2010), and various electrochemical approaches such as changing Eh in order to promote formation of dixanthogen, dissolution of oxidation products by lowering the pH, activation by sulphidisation (Newell et al., 2006; Becker et al., 2014), and the use of alternative collectors."

Jan 1, 2018

By James A. Doolittle

In the underground type of mining operation, the finer portion of the waste material commonly is pumped as a hydraulic slurry to a tailings disposal pond. (1)* The tailings slurry is deposited via a pipe manifold system located around the perimeter of the pond. This method of deposition produces zoning because the coarser material tends to settle out immediately while the finer particles tend to remain in suspension and are deposited progressively nearer the center of the pond. The manifold system must be raised periodically as the pond fills with the tailings material. Over a period of time, this procedure will produce a zoned embankment known as a tailings dam. A typical pond and dam are shown in Figure 1. In plan view, the dimensions of tailings dams can be on the order of miles, with the height of the dam reaching 100 to 200 feet. Due to such factors as inadequate compaction, inherently low strength of the tailings material, and the possibility of high phreatic surface, many dams at some point become unstable, i.e., the factor of safety against a slope failure approaches 1.0. Remedial measures are required to improve the safety factor in order to prevent massive failure of the dam. In most cases, stability can be improved by effectively flattening the slope of the dam as shown in Figure 2, but this is not possible in every case. Occasionally, a tailings dam is constructed adjacent to a natural or legal boundary so that it is not possible to construct a conventional berm or to reduce the slope angle with earth moving equipment. Even a terracing process would require removal of the material and this may not be practical. In such a situation, an alternate scheme to improve stability must be found.

Jan 1, 1974

By Jalal Vakili

In designing very large excavated slopes which are becoming increasingly common in both mining and civil engineering projects, the most important decision of the engineer is the selection of a slope angle. The purpose of the geotechnical study of the slope is to ensure reasonable stability of the slope in the most economical way. Because the rock mass composing each slope is unique, there are no standard solutions for slope stability analysis. A practical solution is formulated from the basic geologic data, engineering properties of the rock, geometry of the slope, and ground water observations. Stability analysis consists of analyzing the forces causing and resisting slope failure. There are several methods of slope stability analysis. The limit equilibrium method evaluates the overall stability of the sliding mass just on the verge of slip, using some or all of the three equations of static equilibrium of a plane problem. The stress-strain relationships of the rock mass are not considered. Method of analysis include the assumption of the shape of the slip surface. Peterson (10) introduced the Swedish method of analysis in 1916, which is based on cylindrical sliding surfaces. Fellenius (4) in 1926 extended this method and introduced the method of slices. This method was refined by Bishop (I) in 1955 and later used by Morgenstern and Price (8) in 1965. In many cases layers of extremely soft strata or strata weakened by neutral stress cause failure to take place by translation along plane of weakness instead of by rotation on a circular surface. In this paper, a slope with a horizontal layer of weak meterial is selected for analysis. This is a usual case for open pit lignite mines where lignite seam may be non-cohesive and 'weaker than the overburden rock or a soft clay layer underlies the seam. It is also a common case of rock fill dams supported on a foundation stratum of clay where the strength of the clay layer is less than that of the rock fill. It is shown that utilizing this method, the location of potential failure surface and the value of the minimum factor of safety can be calculated directly and the trial computations of factors of safety for a number of assumed failure surfaces are not necessary.

Jan 1, 1982

By D. H. Rubisov, V. G. Papangelakis

Sulphuric acid pressure leaching is the process of choice to recover nickel and cobalt from laterites with variable iron and magnesium contents. The latter influences the acidity levels required for effective leaching of nickel and cobalt, and during leaching, iron is rejected in-situ as hematite. Classical solid/liquid separation is performed via a CCD circuit, the performance of which depends upon the size and shape of precipitated particles. In this paper, precipitates obtained by acid-leaching of various lateritic feeds at 270°C are characterized using SEM/EDX and laser particle size analysis. It is shown that as acidity increases, the shape of the precipitates gradually changes from platelets to spheres, thus improving the S/L separation properties of the residue. The use of hydrogen ion concentration “at temperature,” calculated from a speciation analysis, allows the explanation of this change of morphology independently of the type of the ore feed. The possibility of precipitating magnesium sulphate “at temperature” is also discussed. In order to take advantage of this precipitation for scale reduction (as has been proposed in the past) without compromising the residue quality, [H+] “at temperature” must be controlled within an optimum range.

Jan 1, 2000

By S. McCarthy, K. E. Waters, A. Jordens

The beneficiation of rare earth (RE) element bearing minerals has become an active area of research as applications for these elements grow while the supply to non-Chinese consumers is restricted by export quotas. One of the most interesting beneficiation techniques for RE minerals is froth flotation as their unique chemistry suggests that collectors with a specific affinity for RE cations should be able to selectively recover these minerals. Existing literature, focusing mainly on bastnäsite flotation, identifies hydroxamic acids as excellent collectors for RE minerals. The high stability of hydroxamate-RE cation complexes is the explanation most often offered for the observed selectivity of these reagents in bastnäsite flotation however some research has also suggested that mineral solubility plays a crucial role in the success of hydroxamic acid flotation of RE minerals. This work investigates the interaction of allanite, a relatively insoluble RE-silicate mineral, with benzohydroxamic acid using zeta potential measurements and microflotation. The effects of Fe(III) and Fe(II) ions as potential activating ions (cations that form stable hydroxamate complexes) on benzohydroxamic adsorption to the allanite surface are investigated as a potential solution to promote hydroxamic acid adsorption. The results indicate that the optimum conditions for separation of allanite from quartz occur at pH 4 using FeCl2 as an activator for benzohydroxamic acid adsorption.

Jan 1, 2014

By R. Du Plessis, J. D. Miller, D. G. Kotlyar

The low potential hydrophobic state of pyrite in amyl xanthate flotation with nitrogen is of particular interest with regard to the N2TEC flotation technology currently being used for the recovery of auriferous pyrite at Newmont’s Lone Tree Plant in Nevada. The N2TEC system had been found to operate satisfactorily, but cyanide in the flotation mill water appeared to be responsible for a loss in pyrite recovery. This supposition was confirmed with laboratory experiments and a program was initiated to study flotation chemistry variables by electrochemically controlled contact angle measurements. Experimental results show that activation of pyrite in such cyanide solutions can be achieved more effectively with lead than with copper. Subsequently, based on these fundamental studies, significant improvement at the Lone Tree Plant was achieved by lead activation, in which case the recovery increased to expected levels. The effect of activator is particularly significant not only with respect to pyrite depression by residual cyanide, but also with respect to collector (PAX) consumption and the initial state of the pyrite surface. Each of these issues is being studied in detail and research progress is discussed herein.

Jan 1, 2002

By Z. Yu

The effect of particle size on coal dewatering has been well recognized However, there are no systematic studies on ultrafine coal dewatering. The results discussed last year revealed the effect of flocculant type and coal wettability on the filtration of ultrafine coal In this paper, the differences in dewatering between -25 µ m ultrafine and -500 µ m fine coal with addition of flocculants, surfactants and oil-emulsions in vacuum filtration are further investigated Significant differences were observed in the reduction of the cake moisture. The utilized emulsions were found to be very powerful and promising filtration aids for both ultrafine and fine fractions of hydrophobic and hydrophilic coal

Jan 1, 1995

The effects of additives, sodium hydroxide, sodium carbonate, sodium oleate, oleic acid and polyacrylic acid, on stirred media milling of limestone have been investigated. The results are evaluated in terms of specific surface area, specific energy and energy efficiency as a function of additive dosage, polymer molecular weight, solids concentration and relevant operating variables. Use of additives generally results in changes in specific surface area and energy efficiency, while under certain conditions a more than 100% increase in these parameters can occur. Relevant interfacial properties have been measured and milling mechanisms involved are explored particularly in terms of the effect of additives on the flow patterns at higher solids concentration.

Jan 1, 1996

By J. R. Campbell

IN order to discuss the subject intelligently, it will be necessary to touch briefly on the forms in which sulphur is supposed to exist in coking coal to be carbonized in beehive or byproduct ovens. Sulphur is known to exist in coal as sulphides and sulphates, as can be determined experimentally. Then there is the so-called organic sulphur, i.e., sulphur in combination with the carbon, hydrogen, and oxygen of the coal, about which much has been written, but nothing definitely proven in an experimental way. In fact, so far as we know, there never has been developed a satisfactory and conclusive method in the laboratory for the direct determination of organic sulphur. For most coking coals, it can be safely assumed that the preponderance of sulphur is in the form of pyrite (FeS2). When exposed to comparatively low temperatures during the coking process, it loses its sulphur according to the following chemical reaction: 7FeS2 = Fe7S8 + 6S. It will be seen, therefore, that six out of the 14 atoms of sulphur (or 42.8 per cent.) are expelled, or volatilized. Fe7S8 remains in the coke as pyrrhotite, or magnetic sulphide of iron; this accounts for the highly magnetic properties of the powdered coke. A more commonly accepted reaction is FeS2 = FeS + S, in which the straight sulphide of iron is produced with 50 per cent. volatilization of sulphur. In the beehive methods of coke making, air is introduced in sufficient amounts to carry on the distilling and the coking processes, and the sulphur is oxidized along with the other volatile products: First, into sulphur dioxide (SO2), known by the pungent and suffocating odoremitted from the trunnel head; second, into sulphuric anhydride (SO3); and, finally, into sulphuric acid, as it comes into contact with the air and moisture. In a properly regulated draft on a beehive oven, there is never complete combustion of the gases. In other words, the coking process should be carried on in a reducing atmosphere, and a low-grade producer gas kept issuing from the trunnel head. For coals of about 30 per cent. volatile matter, the ratio of air to gas is 3 ½ to 1. In complete combustion, the ratio is 6 to 1, producing an extremely high temperature

Jan 1, 1916

By Wenying Liu

The effect of aeration on chalcocite heap leaching was studied by analyzing the historical data from two chalcocite heap leach pads located in Chile, one with aeration and the other without aeration. The data showed that the copper leaching kinetics of the aerated heap was greater than that of the unaerated heap within a certain leaching period, after which there was no effect of aeration on the copper leaching kinetics. The total acid consumption per ton of ore processed was higher in the case of aeration, which was supported by the higher pH of the PLS. But the net acid consumption per ton of copper produced was the same in the two cases. Approximately 5% of the total iron added to the unaerated heap was precipitated inside the heap. In contrast, there was no net iron precipitation or generation inside the aerated heap. Bacteria activities were thought to occur even in the unaerated heap, but the extent was much less than in the aerated heap. Given the importance of forced aeration in chalcocite heap bioleaching, mathematical modelling will be applied in the future work to assist the optimization of the aeration system design.

By Y S. Zhang

Natural phenomena and human engineering construction activities had great influence on the geosciences space. Natural disasters, particularly mine disaster and other geological disasters happened frequently, which brought great losses both in people’s lives and economics, therefore, to explore the essential causes and mechanisms of disaster by some useful approaches is the most important step in mine disaster prevention. In a variety of methods, building an aground-underground seamlessly integrated model, and then analysing the formation and development mechanism of mining disaster based on this model is a useful way. In this paper, we studied an aground-underground seamlessly Integrated modelling method, and correspondingly given an aground-underground seamlessly integrated 3D spatial model, CSG+CD-TIN+GTP-TTS, by which we can carry out analysis of surface subsidence and underground laneway distortion efficiently, finally preliminary applications verified the effectiveness of this method.

Nov 22, 2011

By Ulrich Leiste, David M. Fox

This paper presents the results from small scale testing aimed at measuring the loads on a rigid target due to the detonation of a buried mine. The aim of this research is to find how the impulse delivered to the target varies as the air filled void volume fraction within the soil changes.

Jan 1, 2013

By Vincent Carlsson

A comprehensive investigation has been undertaken to clarify how pellets are affected by alkali circulating in the blast furnace. The investigation has been performed with acid and basic pellets in a special furnace. Experiments were carried out to ascertain the influence of potassium on swelling and reducibility when added at different stages of reduction. After that, the significance of the quantity of potassium added in the hematite stage was studied. A parallel experiment with sodium as the alkali component was also con- ducted. Besides these vaporization experiments the effect of alkali on softening and reduction characteristics at high temperatures was investigated. The results showed that alkali always increases swelling, especially when added in the hematite stage. The addition of alkali increases reducibility of acid pellets during reduction from wustite to 70 % reduction. The softening temperature is significantly lowered by the addition of alkali and is, in any case, lower for acid pellets than for basic pellets. The microscopic studies showed that alkali ferrites can be formed irrespective of the influence of alkali on the slag phase.

Jan 1, 1977

By Frame Ritzert, Dennis Keller, Vijay Vasudevan, David Arenas

"An investigation was conducted to describe topologically close packed (TCP) phase instability as' a function of composition in the advanced ·Ni-base superalloy Rene N6. TCP phases are detrimental to overfill high-temperature performance of Ni-base superalloys because of their brittle nature and because they deplete the Ni-rich matrix of potent solid solution strengthening elements. Thirty-four variations of polycrystalline .Rene N6 determined from a design-of-experiments approach were cast and homogenized at 13 l5°C for 80 hours followed by exposure at 1093°C for 400 hours to promote TCP formation. The alloys had the following composition ranges in atomic percent: cobalt 10.61 to 16.73, Mo 0.32 to 1.34%, W 1.85 to 2.52%, Re 1.80 to 2.11%, Ta 2.36 to 3.02%, Al 11.90 to 14.75%, and Cr 3.57 to 6.23%. Physical and chemical characteristics of all microstructures obtained were described using various analytical techniques. From these observations, a mathematical description of TCP occurrence (s and P phase) was generated for polycrystalline Rene N6.IntroductionNi-base superalloy single crystals represent the state-of-the-art for turbine engine airfoil application as they offer the best balance of properties to allow for the high operating temperatures required: for efficient engine operation.1 Current trends in alloy design take advantage of improved creep rupture strength with the addition .of higher levels of refractory elements. 2 In .particular, the addition of significantly higher levels of Re in third generation superalloys is key for both microstructural stability and creep rupture strength. 3 While the presence of the refractories is thought to provide strength benefits from solid solution hardening, a tendency for alloy instability in the form of topologically-close-packed (TCP) phases or secondary reaction· zone (SRZ) ·phenomena accompanies the high refractory content. 3 The formation of these phases in sufficient amount is detrimental to the overall high temperature performance of Ni-base superalloys because of their brittle nature and because they deplete the Ni-rich matrix of potent solid solution strengthening elements.4 The tendency for a particular composition to form TCP may not be immediately known since the precipitation of TCP phases in Ni-base superalloys is nucleation controlled, thereby requiring long times at elevated temperatures to precipitate. 5 They preferentially nucleate along the octahedral planes of the Ni-base superalloys, usually in areas of refractory metal enrichment at grain boundaries or inside dendrites.5-6 In Rene N6, two closely related TCP phases, a and P, have been observed.2"

Jan 1, 1998

By J. E. Johnson

(Cleveland Meeting, October, 11,1912.) THE subject of blast-furnace slag is one which has had much consideration, particularly from the scientific standpoint, and several years ago technical literature contained many learned discussions on the oxygen-ratio of the acids and the bases, all on the assumption that acids and bases must be present in a ratio depending on molecular weight and chemical valency. Much work has also been done, sometimes in conjunction with the former, on the total heat and the temperature of initial fusion or softening of various slags. A wider knowledge of the blast-furnace now enables us to say that for practical purposes this work has been of almost no value. It is now generally admitted that on the physical side the important point of a given slag is neither its total heat of fusion nor its softening-point, but its free-running temperature, since this is the critical temperature of the furnace. This temperature bears no definite relation to the softening-temperature, as determined by Seger cones, for instance, because some slags melt relatively like ice, with a very short viscous-range, while others melt relatively like tar, with a very long viscous-range. In one the difference between the softening- and the free-running temperature may be very small, as little as 100° F., while in another this difference may easily be 200° or 300°. The importance of this difference is so great in practice as to destroy completely the value of exhaustive investigations, even such as those of 0. Boudouard, published a few years ago.1 * Presented also at the Joint Meeting of the Institute with Section IIIa, Metallurgy and Mining, of the Eighth International Congress of Applied Chemistry, New York, September, 1912. 1 It may not be amiss at this point to call attention to the excellent suggestion of Woolsey McA. Johnson, made several years ago, for determining the temperature at which different slags have the same practical fusibility. This suggestion

Oct 1, 1912

By Sverre Olsen, Kai Tang

The composition of ferromanganese slag is very important as it determines the slag/metal equilibrium relations including MnO content of final slag, melting relations and slag viscosity. The slag composition is further expected to influence the process temperature. The properties of ferromanganese slags are suitably described by its basicity and A/S mass ratios. The influence of slag basicity has been discussed in the previous papers. The present paper will discuss the effect of Al2O3 on melting relations, viscosity and MnO-content of final slag. This discussion will be based on assessed thermochemical databases and a recently developed viscosity model.

Jan 1, 2007

The mineralogy of ten trihydrate bauxites and their leached residues from bomb digestion tests at 140, 180 and 2400C was investigated and the resultsòcorrelated with analytical data. It is shown that increased recovery of alumina at high temperatures is due to. the dehydroxylation of goethiteòrather than the presence of alumina monohydrates. The effects of aluminous goethite -on the interpretation of "available alumina". results-and normative analysis are discussed and it is concluded that,'cautionòmust be exercised in interpreting the results of bomb digestion tests in terms of alumina hvdrates.

Jan 1, 1973