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By L. Graydon Carpenter, Donald E. Garrett

Probably the largest single tungsten deposit in the U. S. is one that has yet to produce any tungsten; it is not even listed in tables showing U. S. reserves. This deposit is at Searles Lake, Calif., where the brine contains about 70 ppm WO3. Small though the concentration is, the amount of brine in the lake is so great that it is estimated at 170 million lb of WO3 (8.5 million units), equaling the total of all other known reserves in the U. S. This dry lake is located in the basin formed by the Argus and Slate ranges in the northeastern corner of the Mojave Desert (Fig. 1). It consists of a massive salt body some 35 sq miles in extent, varying in thickness from 0 to 120 ft and containing more than 3 billion tons of salt. A central section of about L. G. CARPENTER and D. E. GARRETT are with the Research Dept., American Potash & Chemical Corp., Trona, Calif. TP 47881. Manuscript, Nov. 4, 1958. AlME Trans., Vol. 214, 1959. 8 sq miles is exposed salt; the remaining area is overlain by mud. Except for the exposed sodium chloride (10 to 15 ft thick) the body consists of a very complex and heterogenous mixture of soluble crystals, containing at least eight major phases. It is only about 53 pct solid, the voids being occupied by a dense brine which is the raw material for two chemical companies operating in the valley.

Jan 3, 1959

By Tingting Li, Guodong Li, Dezhou Wei, Cong Han, Shuling Gao, Yanbai Shen

"The aim of this study is to solve the problem of tungsten leaching from scheelite concentrate using sodium hydroxide in the presence of phosphate by an autoclaving process, which is one of main development techniques for tungsten recovery. To understand the applicability and leaching performance of tungsten leaching from scheelite concentrate, the main work is to investigate the effects of leaching parameters such as initial concentrations of NaOH and Na3PO4, reaction temperature, stirring speed, liquid-to-solid ratio and reaction time on WO3 dissolution rate to obtain the optimal leaching conditions. The chemical composition and phase composition of the samples were evaluated by means of XRF and XRD. The content of WO3 in the leaching residue obtained via washing, filtering and drying was analyzed by thiocyanate spectrometric method. The optimal leaching conditions were found to be NaOH concentration of 6.76 mol·L-1, Na3PO4 concentration of 1.35 mol·L-1, reaction temperature of 180°C, stirring speed of 400 rpm, liquid-to-solid ratio of 2.0 and reaction time of 90 min. The results showed that tungsten leaching rate of 99.20% was reached under the optimal conditions. The technology exhibited superior leaching performance, which not only reduced the consumption of sodium hydroxide but also greatly decreased reaction time in comparison to a conventional autoclaving process. INTRODUCTION Tungsten is an important strategic metal, which is widely utilized in a variety of industries due to its high melting point, superior mechanical properties and heat-resistant performance [1-3]. The chief raw materials for the production of tungsten in nature are wolframite and scheelite [4, 5]. Among them, approximately two-thirds of the tungsten reserves contain scheelite deposits in the world [6, 7]. With the progressive exhaustion of high-quality wolframite resources, scheelite has become a predominant primary resource for the production of tungsten [8, 9]."

Jan 1, 2018

By J. P. BONARDI, William F. Boericke

BOULDER COUNTY, Colorado, ranked during the war years and until the end of 1918 as one of the foremost tungsten-producing districts of the world. In 1919 production fell off drastically, due to heavy importations of foreign ores from China, Burma and South America. So large were the imports that even after the enactment of a protective tariff in 1922 of 45c. per lb. on tungsten metal, equivalent to $7.14 per unit (201b.) of tungstic acid? (WO,), the stocks of metal in this country were extensive enough to supply the demands of industry, and prevent general resumption of mining by domestic producers. Even today there are only two producers in the Boulder district though at one time as many as twenty separate companies were in operation. About the same ratio holds for other tungsten-producing districts in the country, including California and Nevada. Total consumption of tungsten concentrate in terms of 60 per cent WO2 in the United States amounted to approximately 3790 tons in 1928, according to Frank L. Hess.' Of this amount, domestic mines contributed 1290 tons, and the rest, 2500 tons, was imported. Yet in 1917, with tungsten concentrate selling at $20 per unit, the Boulder district alone produced 2707 tons, indicating the effect of enhanced ore price upon production. It is believed by American tungsten miners that, given a sufficiently high tariff, all the demands of industry can be met by domestic production without placing a prohibitive burden on consumers. For instance, in steel manufacturing the percentage of tungsten entering into the manufacture is so small that, ?regardless of cost, it can constitute but a small fraction of the cost of steel to the buyer.

Jan 1, 1929

By Y. Guo, C. Cao

"China is rich in tungsten resource, but they are mainly associated minerals. The similar flotability of scheelite, fluorite, and calcite resulted in the difficult separation by flotation. This work summarized the current situation and the development of flotation reagents, technological process, and mineral processing equipments in China. Fatty acid served as the collector and water glass was the depressant to expand the flotability differences in traditional flotation technology. However the water glass inevitably influenced the flotation of tungsten minerals to a large extend, and the suppressed fluorite was difficult to recover by flotation. Abundant water glass lead to the bad settleability of the tailings and the tail water was difficult to circulate, resulted in serious environmental problems. Recent study proved that the selectivity of benzene armour hydroxyl oxime acid (BAHA) salts was adequate for the separation of tungsten minerals from fluorite, calcite and most silicate minerals without any depressant. By this way, sodium silicate was canceled completely in tungsten flotation, greatly improving the recovery of tungsten and the environmental problems caused by tail water treatment would be solved fundamentally. TUNGSTEN RESOURCES AND DISTRIBUTION IN CHINA China is rich in tungsten resources and the proved reserves accounted for 60% of the world's reserves [1]. However the wolframite has been dried up and the scheelite resources had become the main resource of the tungsten metal. Table 1 showed the most large and superlarge scheelite deposits in China. China has more than 40 large and superlarge scheelite deposits and the total metallic deserves is more than 3 million ton [2]. But most of the deposits were low-grade and the associated relationship was complicated. For example, scheelite was usually associated with wolframite, molybonite, bismuthinite, pyrite, fluorite, and calcite in Shizhuyuan and Yaogangxian mine."

Jan 1, 2016

THERE are three chief production zones of tungsten ore in China. In the Province of Kiangsi mines are located at Kanchow, East River, and West River. Their combined production is understood to amount to 300 to 350 tons of ore per month, and their original exportation is made through the port of Kiukiang, largely to Shanghai. The second zone is in Kwangtung Province, the mines there being at Tayulin. Produc-tion reaches about 200 tons per month and cargo is gen-erally exported through the port of Hong Kong. In the Province of Hunan approximately 25 tons of ore are produced monthly in the mines at Ton-on. Tungsten ore from Kiangsi and Kwangtung Prov-inces is generally about 70 per cent WO, (tungstic acid), while that from Hunan is of lower quality, run-ning about 65 per cent WO3. Kiangsi ore is received from the mines in 100-1b. and Hunan in 224-lb. gunny sacks. No repacking is done except as it is made neces-sary by the condition of the sacks. Kiangsi Province contains the Chinese districts pro-ducing the largest amount of salable wolframite or tungsten. Many districts west and south of Kiangsi have been found to have wolframite deposits.-Com-merce Reports.

Jan 1, 1928

By W. N. Marchant, P. T. Brooks, P. B. Altringer, R. O. Dannenberg

The US Department of the Interior, Bureau of Mines conducted laboratory tests to devise a process for recovering a marketable grade of tungsten from the brine of Searles Lake, Calif. The brine contains only 56 ppm W (70 ppm W03). Using ion exchange resins synthesized by USBM chemists, 98% oft he tungsten was extracted from the brine and 92% of the tungsten was recovered as a marketable iron-tungsten concentrate containing 44% tungsten as tungsten trioxide. Although major technical problems have largely been resolved, research is progressing to escalate testing in a process research unit to provide more reliable data for an economic appraisal.

Jan 8, 1979

By P. B. Altringer

The Bureau of Mines conducted laboratory tests to develop a process for recovering a marketable grade of tungsten from the brine of Searles Lake, Calif. The brine contains only 56 parts per million of tungsten (70 ppm WO3). Using ion exchange resins synthesized by Bureau chemists, 98 percent of the tungsten was extracted from the brine and 92 percent of the tungsten vas recovered as a marketable iron-tungsten concentrate containing 44 percent tungsten as tungsten trioxide. Although major technical problems have largely been resolved, research is progressing to escalate testing in a process investigation unit to provide more reliable data for an economic appraisal.

Jan 1, 1978

By W. N. Marchant, P. T. Brooks, P. B. Altringer, R. O. Dannenberg

The US Department of the Interior, Bureau of Mines conducted laboratory tests to devise a process for recovering a marketable grade of tungsten from the brine of Searles Lake, Calif. The brine contains only 56 ppm W (70ppm WO3). Using ion exchange resins synthesized by USBM chemists, 98% of the tungsten was extracted from the brine and 92% of the tungsten was recovered as a marketable iron-tungsten concentrate containing 44% tungsten as tungsten trioxide. Although major technical problems have largely been resolved, research is progressing to escalate testing in a process research unit to provide more reliable data for an economic appraisal

Jan 1, 1980

Circuit alterations and adoption of more compact items of equipment have made it possible to increase the capacity of the King Island Scheelite concentrator, both with regard to head grade and feed tonnage, while at the same time increasing total recovery and reducing maintenance costs. The present operation is described, with particular emphasis being placed on alterations made during the last two years to achieve capacity Goals.

Jan 1, 1977

By Paul D. Conatore

INTRODUCTION There are important reasons for a discussion of tungsten resources, reserves, and production in the Circum-Pacific area. First, the world's chief tungsten deposits, as well as most of the world's tungsten reserves and production, occur in this region. It is well known that the world's largest tungsten reserves are located in southeastern China and that for many years, the largest individual mine in the world was there. Although China still has the world's greatest tungsten production, the very high-grade scheelite mine of Canada Tungsten Mining Corporation in the Northwest Territories is the largest producer of tungsten today. There is certainly a great quantity of tungsten in Asia, but the strategic importance of this fact is now offset by the wide distribution of mines and production facilities throughout the world, especially in other parts of the Circum-Pacific area such as Australia, Canada, and the United States. In addition, much of the Circum-Pacific area is comprised of Mesozoic-Cenozoic orogenic belts. These global tectonic units are regarded as very favorable for additional tungsten deposits, particularly scheelite-bearing tactites, and consequently, prospecting and exploration will most likely be concentrated in the Circum-Pacific area. Second, tungsten must be regarded as one of the, most important metals of modern industry because of its very special properties. It has the highest melting point, the highest tensile strength at elevated temperatures, and the smallest compressibility of any metal. The metal also possesses a very high density, excellent corrosion resistance, good thermal and electrical conductivity, and a low coefficient of expansion. As a result, tungsten has found increasing importance in a wide range of industries. From the filament in an electric lamp, to cutting tools and drilling bits, to the exotic radiation shields that protect supersonic aircraft and spacecraft, tungsten plays an indispensable role in our daily lives. The primary objective of this paper is to present an overview of important facets of known and suspected tungsten in the Circum-Pacific area. Resources, reserves, current production, planned capacity expansions, and new operations, as well as an assessment of the probability for development of deposits in the Circum-Pacific area, are discussed. RESOURCES The average crustal abundance of tungsten has been estimated at 0.0015 kilograms per tonne. A comparison of the abundance of various metals in crustal rocks to that of tungsten is presented in Table 1, which shows that tungsten abundance is similar to that of its commonly associated metals, tin and molybdenum. Table 1. AVERAGE CRUSTAL ABUNDANCE OF VARIOUS METALS (Grams per Tonne) [ ] With careful thought, it can be realized that tungsten ore deposits result from the concentration of the metal, through normal geologic processes, to levels substantially greater than its average crustal abundance. The minimum technologically and economically workable tungsten concentration, or cutoff grade, is a function of (1) deposit tonnage, (2) mining and milling methods, (3) production tonnage, (4) capital and operating costs, (5) tungsten market conditions, and (6) value of associated recoverable metals. The tungsten cutoff grade that is currently exploitable at a profit varies from 0.09% W03 to 1.55% W03, reflecting concentration factors from 470 to 8200, as shown in Table 2. Table 2. CURRENT TUNGSTEN CUTOFF GRADES [ ]

Jan 1, 1982

By Clarke P. E

At the end of the recent war, reports became available from Europe of the use of tungsten-carbide inserts in percussion rockdrill bits. These bits were used with small size rockdrills, so that the only advantage gained from the use of the harder, abrasion resistant, tungsten-carbide appears to have been the greater life of the bit. Larger machines, such as used in Australia in conventional practice, had to be discarded to protect the relatively brittle tungstencarbide inserts and the vulnerable bonding with the bit body.As it had been found in machine shop practice that some grades of tungsten-carbide had been produced with considerably improved toughness, it was decided by Gold Mines of Australia Ltd. that drilling practice with tungstencarbide bits warranted detailed examination under Australian conditions, and that drilling tests should be undertaken at Morning Star (G.M.A.) Mines N.L., for which it acts as General Manager and Consultant.These investigations progressed through three stages:1. Preliminary Investigations and Tests.When the investigations were initiated no commercial bits were available in Australia, and manufacture was commenced with improvised equipment from virtual scratch. These early tests indicated that the use of 3 in. bore rockdrills in conjunction with tungsten-carbide insert bits was a 'possibility, and that it was unlikely that a small bore...

Jan 1, 1950

By Zay Jeffries

A. G. WORTHING, Nela Park, Cleveland, Ohio (communication to the Secretary*).-The paper by Mr. Jeffries is very interesting. He is to be commended for his pioneer work in the study of equilibrium systems at the very high temperatures which one obtains with tungsten and molybdenum. There is one statement, however, to which I must take exception. On page 1227, a statement is made which would seem to indicate that the Nela Research Laboratory joined Dr. Langmuir in the recommendation of 3,300°C. as the most probable melting point of tungsten. This is not the case. In. the paper referred to by Mr. Jeffries, I have given 3,630°K. or 3,357°C. as the melting-point temperature for tungsten. Confirming observations by other workers in our laboratory justify the belief that this latter value is correct to within a small part of the discrepancy between the two values quoted.

Jan 12, 1916

By Zay Jeffries

IN this paper, it is proposed to outline a method for the determination of melting points of those metals and alloys having high fusion temperatures. The application of the method as used to determine the melting points of alloys of tungsten and molybdenum will be given. It will be seen from these results that tungsten and molybdenum form a completely FIG. 1.-PARTIAL SECTION OF APPARATUS USED TO DETERMINE MELTING POINTS OF TUNGSTEN AND MOLYBDENUM ALLOYS. isomorphous series. This is also verified by the accompanying photomicrographs. Tungsten and molybdenum have been found to crystallize in the salve system, namely, isometric, and the crystal units are cubes. These determinations were made by examining etching pits in the pure metals.

Jan 7, 1916

By Zay Jeffries

J. W. RICHARDS, South Bethlehem, Pa.-I think that the diagrammatic results can be much more clearly set forth if they are plotted as follows: The present diagram, shown on page 1227 of Mr. Jeffries' paper, Logarithm of Per cent of Maximum Wattage Used plots the variation of wattage with temperature in a very inconvenient and uncertain-way. If, however, you plot as abscissas the logarithms of the wattage, you get very nearly a straight line, so that you can interpolate the values with much greater accuracy than you can by using

Jan 4, 1917

By Daniel Hodouin, Claude Bazin

"This paper examines the economic advantages of tuning the operation of a differential Cu-Zn flotation circuit as a function of metal prices. Three operating strategies are considered in the analysis: 1) the operation of the circuit at planned copper and zinc concentrates grade with maximum recovery of both metals; 2) the operation of the Cu circuit at maximum copper smelter return per ton of ore and of the Zn circuit at a maximum zinc smelter return per ton of ore; and 3) the operation of the circuit at maximum copper and zinc smelter return per ton of ore. The second strategy tunes the copper circuit independently from the zinc circuit, while the third strategy tunes both circuits simultaneously IntroductionMetal prices play a very important role in the mineral industry (Malhotra and Dowling, 1991). In many cases, metal prices can be the basis for the GO/NO GO decision of a mining project (Malhotra and Dowling, 1991; Apostolides, 1983; Davis, 1996). This direct impact of metal prices on company revenues is highlighted in many annual reports. The 1995 Noranda Annual Report indicates that a variation of 10% of the copper price impacts its yearly revenues by $25,000,000. Some mine operators claim to mine stopes as a function of metal prices (Liimatainen, 1996; Hartman, 1992). This impact of metal prices is also recognized by mill operators that seek strategies to tune ore processing circuits to maximize revenues from the concentrate they sell to smelters (McKee, 1991; Barker et al., 1989; Hales and Ynchausti, 1994; Cipriano et al., 1995). In many cases the problem of tuning the operation of an ore processing circuit is complicated by the fact that the ore contains two or more valuable metals which have to be recovered into separate products. The Agnico-Eagle (Robitaille and Cousin, 1995) and Barrick East Malartic (Pelletier, 1996) Cu-Au mines are examples, as well as the Cu-Pb-Zn Brunswick mine (Shannon et al., 1993) or the Cu-Zn Louvicourt (Whiteway, 1995) and Selbaie (Wright, 1995) mines."

Jan 1, 2000

By M. Jackman

"Froth stability is critically important for an effective separation of fine and ultrafine particles using column flotation. While a desirable froth stability is required to facilitate the drainage of entrained gangue particles for secondary cleaning, excessively stable froths could create problems in separation efficiency and down-stream processing. In this work, we demonstrate that a stable foam was produced using a poly (N-isopropylacrylamide) (PNIPAM) solution at the temperatures below the critical solution temperature. In contrast, very little foam was produced at the temperature above the critical solution temperature (~32 oC) of PNIPAM. We can also tune the foam stability by changing the temperature of wash water. When warm water of temperature of 50 oC was applied, the foam collapsed and diminished. This is probably attributed to the switching of PNIPAM molecules from coiled to a globule conformation as the temperature is increased. Our results indicate that the foamability and foam stability can be tuned by tempartureresponsive PNIPAM. This is the first time that thermo-responsive PNIPAM has been shown to have potential as a modifier of froth stability in column flotation.INTRODUCTIONIn mineral processing, column flotation has become a more prevalent process in the separation of fine mineral particles (typically < 100µm). Traditional flotation cells are sometimes less efficient in selective separation of ultra-fine particles (Kohmuench et al., 2009). The efficiency of flotation columns is dependent on the froth stability at the top of the cell to drain the unwanted gangue particles entrained in the froth. The greater froth height in flotation columns, compared to mechanical flotation cells, gives a longer froth residence time, allowing more of the drainage process to take place before the froth reports to the launderer. Secondary cleaning, by applying a wash water shower to the froth, enhances drainage of gangue particles entrained in the froth, and improves the recovery of the targeted minerals (Finch et al., 2007).While a stable froth is desirable to facilitate drainage of entrained gangue particles, greater amounts of fine particles have been found to contribute to excessively stable froths which could create problems for down-stream processes (Bethell et al., 2012). Operators have tried spraying additional wash water on the froth, and reducing frother dosage to destabilize the froth and to prevent backup at the launderer. The former is sometimes inefficient, and the latter results in unacceptable recovery loss. Currently, the best practice is often the installation of larger froth launderers, adding expensive defoaming agents, and/or using deaeration tanks (Bethell & Luttrell, 2005)."

Jan 1, 2016

By Katherine (Kate) Bruce

Aurora College ? Yellowknife Campus, in partnership with the Northwest Territories Mine Training Society and industry partners, has developed a 6 ? week program on Underground Mining for delivery in Northern communities. The goal of the program is to inform and connect Northern residents to the career potential at existing and future mining operations throughout the Northwest Territories. The program content includes an introduction to the mine life cycle, basic underground mining methods, the use of technology in training via desktop simulators for underground mining equipment, safety in the workplace, and essential skills training (Ready to Work - North) and assessment. Students completing the short program may then choose to continue into a long (12-week) program to be offered at the Yellowknife Campus. This program expands upon the initial introduction and includes modules on NWT geology, environmental studies, underground mining processes and underground mining equipment operation using the larger enclosed cab simulator for a variety of equipment being used at northern mining operations. Success of both programs will depend upon a variety of factors, many of which are outside of the control of the developers of the training modules. These will be investigated throughout the presentation. Connecting northern employers with northern employees is a major concern. It is hoped that through the development and implementation of a program such as this, that the connection can be made and sustained allowing continued employment for the life of northern mining operations.

May 1, 2008

By Gordon T. Clark, Stephen H. Gleaton

This paper discusses the conceptual design of cut-and-cover tunnels currently being considered as one of the replacement options for the earthquake damaged, elevated double-deck highway and seawall built in downtown Seattle 50 years ago. The 4.8 km (3 mile) long, 6-lane improvement consists of 1.6 km (1 mile) of at-grade roadway with aerial interchanges, 1.6 km (1 mile) of large two-level cut-and-cover tunnels along the Elliott Bay waterfront, and retrofit of the 50-year old, 1.6 km (1 mile)long Battery Street tunnel and north transition to grade. Construction of deep cut-and-cover tunnels, in complex glacial geology overlain by hydraulically placed fill immediately adjacent the existing sea wall, will require extensive use of concrete diaphragm walls, ground improvement and dewatering. The potential liquefaction and lateral spreading of the fill materials in this active seismic region pose significant design challenges and risk.

Jan 1, 2003

By L. A. Garfield

Since the start of mining operations at White Pine in 1953, over 22 miles of drifts have been driven for the purpose of developing the ore body. The drifts, normally driven in multiples of three or five headings, serve as conveyor belt routes, ventilation ducts, equipment and haulage roads, and initial access to mining blocks. Development openings in the flat-lying, bedded ore body are driven in rectangular section from 16 to 32 feet wide and from 8. 5 to 16 feet high. The floor level normally coincides with the bottom limit of the chalcocite values and the roof or back is carried at the most competent stratum adjacent to the top of the ore. A development front consisting of five headings and associated crosscuts is advanced at an average rate of about 100 feet per month using conventional drill and blast techniques and equipment. The cyclic nature of the functions involved in driving the openings and the need to include them in production schedules preclude significant improvements in advance rates using current drill, blast, muck, and haul sequencing.

Jan 1, 1969

By John V. Beall

What progress has been made in rapid excavation of tunnels and shafts? Where do we go from here? To get some answers to these questions was the reason that 500 tunnel men-contractors, geologists, professors, lawyers, mining engineers--came to the University of Minnesota May 15-17. The attendance of 500 astonished conference organizer Professor D. H. Yardley, who had anticipated half that number. They came from Japan, South Africa, Austria, Sweden, and Australia to name a few, and an officer of the Corps of Engineers thought all his people should have been there. The Civil and Mining Engineering Departments of the University combined for the program, which was staged by M. K. Cragun for the General Extension Division. The Saga of the Oso Tunnel The present state of the art of rapid excavation is "good." There is little controversy about where we go from here and what&apos;s more, this reporter finds that the technical know-how to automate excavation in any kind of ground is extant, even if it will take some years to achieve this state. In a nut- shell though, the present status can be seen in its various ramifications in the saga of the Oso Tunnel, as told by V. L. "Vic" Stevens of Boyles Brothers Drilling Co. :

Jan 7, 1968