Search Documents

By Sang Han Son

The vapor pressures of FeCL2 and ZnCL2 in the FeCL2?ZnCL2 system were measured by the transpiration method at 873K and 9I7K, The vapor pressure data were interpreted to indicate the formation of complex ions in the FeCL2?ZnCL2 melts, It is presumed that the complex molecule FeZnCl4 as well as FeCL2 and ZnCL2 exists in the vapors in equilibrium with molten FeCL2-ZnCL2 mixtures, The activities in the FeCL2-ZnCL2 system are shown a negative deviation from Raoult's law. These results suggest the formation of complex ions such as ZnCL14 in molten FeCI2?ZnCL2 mixtures.

Jan 1, 2003

By Thomas R. Wildeman

Experimental methods for studying vapors over solid minerals are reviewed and an especially developed method using atomic absorption is described. The method is used to study vapor pressures over Te. Ag, Au, Ag2Te, and AuTe2 from 250°C through 10S0oe. Vapor pressures observed and, concurrently. sintering properties are significantly altered by the form of the solid. The vapor pressures of the tellurium compounds reveal complex processes occurring on the surfaces of the solids. The data given also point out a method of recovering precious metals from their telluride minerals w

Jan 1, 1987

By Yu-ki Taninouchi, Toru H. Okabe

Among platinum group metals (PGMs), Pt, Pd, and Rh are the essential constituents of automotive catalysts. Recovery of PGMs from catalyst scrap is important, but it is difficult because PGMs are chemically stable and are present as minor components in the scrap. A vapor treatment method using FeCl2 vapor to alloy PGMs with iron, enabling subsequent magnetic separation, is developed and tested on Pt, Pd, and Rh wires.

Mar 1, 2017

By Caisa Samuelsson

Experimental studies in laboratory-scale equipment have been carried out to study the vaporisation from dust generated during the copper converting process. In the present work the vaporisation of Zn, Pb, As, Sb, and Bi from a dust collected in the electrostatic precipitator after the copper converter were studied. The results show that Pb, Bi and As were vaporised to a high degree from the dust at a temperature above 900°C in a gas containing N2, SO2 and a small amount of H2. The vaporisation was high for these elements also in a gas containing N2, SO2 and 02 at temperatures above 1120°C. In an earlier study, thermodynamic calculations showed that it is possible to selectively condense metals at high temperature' in a gas atmosphere generated during a copper converting process. The present study was carried out to verify the thermodynamic model. The results indicate that it should be possible for a selective condensation of Zn at high temperature. The temperature required for a selective condensation of Zn is dependent upon the gas atmosphere, e.g., the oxygen potential.

Jan 1, 1998

By Dhanesh Chandra

Metal carbonyls are of great importance in chemical vapor deposition (CVD), composite materials fabrication, and other near-net shape technologies. Carbonyl CVD application applies to deposition of high-purity metallic/alloy coatings. Vapor pressures of solid Os3(CO)12,Rh6(CO)16, Ru3(CO)12, Ir4(CO)12, Re2(CO)10, Co2(CO)8, Cr(CO)12,, and W(CO)6carbonyls have been measured using gravimetric-torsion effusion system. The vapor pressure data is used for many low and high temperature CVD applications. Interesting decomposition/disproportionation vaporization behavior has been notedfor Rh6(CO)16, Ru3(CO)12 and Co2(CO)8. The vaporization studies of Rh6(CO)16 showed virtually complete decomposition to Rh metal and the measured molecular weight of the effusing gas from the solid Rh6(CO)16 was 27.75 g/mol, close to that of carbon monoxide as compared to 1065.56 g/mol for the value of solid Rh6(CO)16. Electron microscopic characterization, X-ray line broadening results for Rh carbonyl has been performed on the vaporization product. However, Ru3(CO)12, Co2(CO)8 showed very complex behavior. The molecular weights of the vaporizing species have been estimated and the numbers of vaporizing species are proposed. For example, there was partial decomposition of Ru3(CO)12to(approx. 52%) metallic Ru and CO gas during vaporization, as suggested by the difference in the molecular weight of the vaporizing species of 107.58 g/mol compared to the actual value of 639.33 g/mol. The dimer Co2(CO)8 partially disproportionates to tetramer Co4(CO)12, monomer Co(CO)4, and CO gas. Whereas, the Os3(CO)12, Cr(CO)12,, and W(CO)6have shown virtually no disproportionation. The total vapor pressures of all the above-motioned carbonyls, partial pressures of various species, average molecular weights of the effusing gases, equilibrium constants for the vaporization reactions, their enthalpies, entropies, and Gibbs energies will be presented.

Jan 1, 2006

A laminar-flow furnace technique was used to study the combustion of 37-53 µm size fraction of Woodlawn copper concentrate containing 7.4 per cent zinc, 5.0 per cent lead and 22.5 per cent copper. Factors studied included the effect of time, temperature and the distribution of volatile elements between the panicles and the fume. Air was used for most of the work but a few tests were carried out using 1 per cent oxygen in nitrogen. Chemical analysis, X-ray diffraction, and scanning electron and optical microscopy of polished sections were used to characterize the reaction products.When the concentrate was combusted at low temperatures (800-900°C), the fume was rich in lead. At higher temperatures, this was diluled by increasing amounts of zinc and copper. 70 per cent of the zinc, 60 per cent of the lead and 40 per cent of the copper were found in the fume after oxidation at 1400°C. Lead, zinc and copper were present in the fume as anglesite (PbSO4), zincite (ZnO) and cuprite (Cu2O) respectively. The major phases present in the panicles were magnetite (Fe3O4) and/or cuprospinel (CuFe2O4), with some zincite and cuprite.Elemental copper was found in the particles oxidized in 1 per cent oxygen. Possible vapour species responsible for the vaporization are discussed.

Jan 1, 1985

By John P. Hager

One possible approach for the recovery of mercury from acid plant blow-down sludge in smelters is the use of a vacuum retort reactor for the vaporization of the mercury with subsequent collection of metallic mercury in an attached condenser. An experimental study was undertaken to investigate the vaporization of mercury when present as a compound in the Hg-S-O and Hg-Se systems. A transpiration reactor was modified to operate under reduced pressure and with a continuous flow of inert sweep gas. A water-cooled cold finger was inserted into the exit end of the reactor to provide for the rapid quenching of the exit gases and the collection of the mercury. Rates of vaporization were measured at several temperatures for each compound and were generally found to be constant at a given temperature and reactor pressure. The results were used to determine the minimum operating temperature for 100% vaporization of the compound in 60 minutes. For Hg2SO4, HgSO4, and HgSO/2HgO the required temperatures. for a reactor pressure of 50 Torr. were determined to be 634°, 622°. and 603°C. respectively. For HgO, HgSe, and HgS the required temperatures were 557°. 451°. And 382°C. respectively. For HgS the rate of vaporization was also measured at a reactor pressure of 1 00 Torr. The rate of vaporization was found to be slower resulting in an increased vaporization temperature of 423°C. It was also determined that the mercury vapor present in the exit gas stream can back-react with the other gas species to a significant extent and can result in very little condensed metallic mercury. For the vaporization of both HgS and HgSe. the mercury vapor was found to have back-reacted to the extent that virtually none of the vaporized mercury was collected in metallic form. For the vaporization of Hg2S04? HgS04, and HgSO4*2HgO the amount of metallic mercury recovered varied from approximately 50% for HgS04*2HgO to approximately 10% for Hg2S04 and HgS04. Only for HgO was the recovered mercury in primarily elemental form. The application of the results to the operation of a vacuum retort and condenser system is discussed.

Jan 1, 2001

By T. Tamagawa

Vaporization of zinc and mixing of zinc vapor with CO-CO2 mixtures were studied experimentally to prepare Zn(g)-CO-CO2-Ar mixtures with desired composition for investigating the condensation behavior and efficiency of zinc vapor. The vaporization rate of zinc was generally constant under given conditions, and could be increased by raising the flow rate of the carrier gas, temperature and vaporization area. The Zn(g)-CO-CO,,-Ar mixtures were quenched by a water-cooling sampling tube for measuring the actual composition of the mixtures in the reactor. The oxidation extent of the zinc vapor in the CO-CO2 mixtures had relation to the CO2/CO ratios and the temperatures. Under current conditions, it was necessary to employ the CO2/CO ratio below 0.125 for mixing the zinc vapor with CO-CO2 mixtures without oxidation. In addition, the appearances and zinc contents of the condensed zinc on the sampling tube were also examined.

Jan 1, 2001

By Anupam Madhukar

The essence of an atomistic unified kinetic model of strained thin film growth and defect initiation is presented along with a comparison of its consequences obtained from computer simulations with experiments. Within the competing kinetics of a strain dependent activated incorporation of atoms and an asymmetry between upwards and downwards inter-layer migration, the model provides a consistent description of 2D versus 3D morphology evolution accompanied by the appearance of surface vacancies and steps at no energy cost. The correlated migration of these precursor defects offers an atomistic mechanism for the emergence of surface half-loops from the growth front (thus accounting for configurational and thermal entropy) governed by activation energies closer to their correlated motion under the evolving strain fields and thus substantially less than those calculated with respect to the perfect crystal as the reference state. The essential mechano-chemical nature of the problem is compared and contrasted with the historical literature of such phenomenon as precipitation hardening and sintering in metallic and ceramic composites.

Jan 1, 1994

By D. G. Tisdale, W. Curlook, J. M. Toguri

"In this study, the vapour phase reduction of titanium tetrachloride conforms to the traditional Kroll chemistry, but employs argon as an inert carrier gas and requires a higher reaction temperature of 1150°C to 1250°C. A vapour phase reaction is advantageous because titanium is the only condensed phase present, and the metal can be collected free of magnesium or magnesium chloride, in marked contrast to the titanium sponge produced by the conventional Kroll process. The yield of metallic titanium from the reaction was determined as magnesium additions ranged from 36% to 168% of the stoichiometric requirement. Yields of over 99% were obtained when an excess of magnesium was present. Although the collection efficiency was low, metallic titanium was collected at the reaction site, where all other species were present as vapours. Magnesium and chlorine concentrations in the collected titanium were less than 0.3%.IntroductionA proposed method (Curlook, 1987) for titanium production has been investigated as an alternative to the conventional Kroll process (Kroll, 1940). The advantages of the new process include a simplified means of recovering the product metal, and a potential for lower overall energy consumption and greater product purity. A higher reaction temperature for the reduction of titanium tetrachloride results in a vapour phase reaction, rather than the conventional liquid phase reaction. This is the major conceptual difference between the proposed and the established (Kroll) processes.This study focussed on optimization of the process chemistry and briefly examined the issue of product deposition and collection. The reduction of titanium tetrachloride with magnesium, to produce metallic titanium and gaseous magnesium chloride:"

Jan 1, 1997

By E. H. Baker

Vapour pressures of sulphur have been measured over the temperature range 340-1039°C by means of boiling-point measurements, an internally heated pressure vessel being employed with argon as the pressure medium. The results are expressed satisfactorily by a four-term pressure-temperature relation. At the cited critical temperature of 1040°C the calculated critical pressure is 204 atm. From the pressure-temperature relation and available thermal data for the vapour, the approximate composition of the saturated vapour in terms of the various molecular species has been derived for the critical point

Dec 1, 1971

In September 2003, a test was conducted to see if a115-mm- (4.5-in.-) diam Mocap Vari-Stem blasthole plug could improve the pattern of explosives using different top stemming material. The test took place at the J.S. Faulkroad and Sonsstone quarry in McCalisterville, PA. The test consisted of a production stone blast. Half of the holes were stemmed with standard crushed stone. Two-thirds of the remaining half were stemmed with Vari-Stem plugs and crushed stone. And the remaining one-third of the second 50 percent was stemmed with Vari-Stem plugs and only drill cuttings.

Jan 1, 2004

By José Luis Vitteri

Dado que se generan largas colas de los camiones mineros en los puntos de carga, es necesario revisar las causas principales que la originan. Entre estas tenemos: el desconocimiento de la variabilidad y sus efectos nocivos y la aceptación de que el mínimo costo de operación se obtiene con la mayor utilización de la excavadora. En este sentido, el presente texto describe el manejo de la variabilidad en los procesos de carguío y transporte con equipos pesados a través del estudio de sus causas, de forma que la única manera correcta de reducir el perjuicio de la variabilidad en el transporte, es manipulando la frecuencia inicial de los camiones.

Oct 1, 2013

By C. L. Van Dover

Organisms living at hydrothermal vents are adapted to catastrophic disturbances in their environment caused by processes such as tectonic activity and mineralization that shift the locus of fluid flux and volcanic eruptions that pave over active systems and reset the hydrothermal cycle. The scientific community appreciates this risk of natural, local loss of species, genetic, and habitat diversity. The risks of more profound loss of diversity and ecosystem function and health as a consequence of additive commercial activities in hydrothermal systems are unknown, and are not the same across all deep-sea hydrothermal systems. Vent communities differ from one ocean basin to another, as do the geological settings and geochemical dynamics of vent systems. Communities on the East Pacific Rise represent one end-member in the catalog of hydrothermal vent communities. In these systems, the life cycle of a hydrothermal field is on approximately the same time scale as the lifespan of the species that live there. From studies of the 1991 and subsequent eruptions at 9N on the East Pacific Rise, we understand the rapidity with which new vents are colonized when nearby brood stocks are available to repopulate the system. Almost instantaneously, microbial biofilms and mats form, followed quickly by invasion of mobile opportunistic organisms (especially crabs, copepods). In a matter of a few months, a predictable succession of sessile organisms recruits, grows, and reproduces. Within two to three years, the system returns to levels of species diversity that begin to match those of the pre-eruption condition. Vents on the Mid-Atlantic Ridge (MAR) represent a different end-member, with catastrophic disturbance rare relative to the life span of the organisms that make up the bulk of the biomass. We have no experience with an eruptive event or other major transformation of venting activity on the MAR and thus have no knowledge or insight regarding the time it would take for the biological diversity to return to pre-cataclysmic levels.

Jan 1, 2008

By T Baumgartl, D R. Mulligan, D Doley, A Schneider

In arid and semi-arid areas evapotranspiration (ET) cover systems are often used to mitigate contaminated seepage from hazardous mine waste into the adjacent environment. The theory of ET covers is based on the water balance equation with the aim of minimising seepage. While cover systems are commonly trialled, the influences of variability in climate and cover structure on water balance equation parameters are seldom investigated.Water balance equation parameters and their variability were analysed for two ET cover trials constructed from benign waste rock in semi-arid Australia. Seasonal and inter-annual variations in rainfall critically influence cover performance. For successful cover system operation, the average return periods for higher than average rainfall should be taken into account. In addition, failure of ET covers has a higher probability in areas with marked rainfall seasonality. Water holding capacity and plant available water content are low in covers constructed from waste rock. Changes in water holding capacity due to variation in particle size distribution are likely and critically influence cover performance. The application of topsoil can be beneficial for water ingress control through run-off, but a balance has to be struck between run-off, erosion and plant available water. Changes in vegetation composition only influence evapotranspiration water losses at plant coverage exceeding 50 per cent, which is unrealistic in semi-arid areas. This study showed that the capacity of ET cover systems to hold and dispose of received rainfall is often lower than assumed by industry practitioners. Furthermore, in order to improve reliability of long term cover performance, the variability of rainfall and water holding capacity of the cover has to be included in water balance models.CITATION:Schneider, A, Baumgartl, T, Doley, D and Mulligan, D R, 2012. Variability in parameters of the water balance equation and their influence on evapotranspiration cover performance, in Proceedings Life-of-Mine 2012 , pp 293-300 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 10, 2012

By Shahzad Moosa, John M. Pitt

Statistical variability in rock strength can be evaluated by rapid, inexpensive ultrasonic pulse velocity measurements, an important consideration since rational probabilistic design in rock is often hampered by the cost of obtaining sufficient strength data. Experimental ultrasonic pulse velocity measurements on a set of 96 limestone specimens showed two distinct statistical populations. Both populations followed Weibull distributions, with flexural strength distributions paralleling pulse velocity distributions. Thus, experimental results suggest that strength variability may be predicted from a few rationally selected strength measurements and several ultrasonic tests. The correspondence between strength and velocity may then be used to develop an experimental transformation function, allowing the development of a statistical distribution function for strength based on the known statistics of velocity. Comparison of experimental groups with full sets of corresponding strength1 velocity data showed the technique offers a fairly accurate description of the statistics of strength.

Jan 1, 1986

By D. G. Krige

Recent publications have demonstrated the important role that can be played by a priori information of the grade levels, variability, and spatial patterns in adjacent or nearby areas in improving the quality of grade estimates for virgin or sparsely drilled areas. A research project was therefore conducted involving the collection and analysis of extensive sampling and borehole data from 7 reefs on some 30 Witwatersrand mines. This paper shows that the 'equivalent' log variance for the two-parameter lognormal model provides a good basis for the study and comparison of the levels and behaviour of relative variances. The trends of these against the corresponding log areas were found to form distinctive patterns, which are useful for these purposes. The patterns for the Basal, Vaal, Carbon Leader, and Main Reef Series form a reasonably close group, whereas those for the V.C.R.(particularly where the facies are mixed), B Reef, and Kimberley-Elsburg Reefs (particularly for narrow channel widths) do not always conform. The patterns shown by underground chip samples are also compared with those obtained from borehole cores. It is shown how this information can be used to improve the borehole valuation of new mines and of virgin areas in existing mines.

Jan 1, 1993

Differences in the assay results of replicate samples engender doubts on the reliability of ore sampling and of assaying procedures. An analysis of variance is a technique to estimate the variability at each level of the procedures. In an example, the variability of one-metre core samples was far greater than that of the assaying technique.

Jan 1, 1976

By S C. Dominy

The gravity recoverable gold (GRG) parameter reflects liberated gold or gold-dominated composite particles that can be recovered by gravity separation. Recoveries depend upon mineralogy, in situ particle size and the comminution and extraction method used. Any ore bearing >15 per cent of gold greater than 50 ¦m in size is likely to have a GRG component. The principal characterisation methodology applied is the three-stage GRG (3GRG) test, based on a 40 kg to 100 kg sample. An alternative is the single-stage GRG test (SGRG), which is generally based on a 20 kg sample. Experience has shown that GRG values can vary throughout an orebody, particularly within different grade and/or mineralogical domains. Test programs must consider sample frequency and mass. This study demonstrates the variability of GRG results based on different sample masses. Consecutive underground faces on a coarse-gold dominated quartz vein were sampled taking five different masses from each. Each sample was processed using a SGRG approach. Subsequently, each development round was batched through a small gravity production plant. The results show that the small samples understate the plant GRG and show inter-sample variability. Large samples show less variability and a SGRG closer to the plant GRG. A high SGRG broadly correlates to higher gold grades, more coarse gold and larger gold particles. These results are intuitively correct, but indicate the likely challenges of sampling for gold recovery in heterogeneous systems.CITATION:Dominy, S C, 2013. Variability of gravity recoverable gold values in relation to test sample size, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 293-302 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By J. P. Harrison, K. Gao

It is well known that in situ stress measurements at a given site will generally display significant variability. However, it appears that a robust analysis of such measurements – i.e., one that is faithful to the tensorial nature of the data – is not available. Despite the fact that stress is a tensor, stress magnitude and orientation have long been analyzed separately using classical statistics. In earlier work we demonstrated the applicability of tensor statistics to the analysis of stress variability. Here, we investigate further the difference between tensor and classical statistics with respect to the stress tensor correlation matrix. Our analysis commences with the selection of a series of valid correlation matrices. Then, assuming that standardized tensor components follow the multivariate standard normal distribution, these correlation matrices are used to generate marginal probability distributions of the eigen-parameters (i.e., principal stress magnitude and rotation angle). From these, random stress tensors are generated, their eigenparameters determined, and the probability density distributions of these obtained using both classical and tensor statistics. Our results indicate that, for all correlation matrices, both methods give practically identical distributions for principal stress magnitude. However, the discrepancy between the two methods with regard to probability density distribution of rotation angle is highly dependent on stress component correlation. This discrepancy is usefully quantified in terms of the integral, with respect to orientation, of the difference between the two probability density distributions. This parameter, which we term Area Difference, is closely linked to the magnitude of the correlation matrix determinant, which itself is related to the normal stress correlation coefficient (i.e., ?x ,?y ??). Assuming that Area Difference should not exceed 0.1, we identify the critical determinant for any particular value of normal stress component correlation coefficient. Thus, using published in situ stress data and the obtained critical determinants, we show that for a specific normal stress component coefficient, when the correlation matrix determinant is less than its critical determinant, the more precise tensor statistics should be used to calculate the distribution of rotation angle. These results demonstrate that the customary analysis of stress measurement data may lead to erroneous results, and that tensor statistics appears to be preferred approach.

Jan 1, 2015