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By Palmer C. Sweet

Mining-related wastes, which are increasing, are being utilized more and more as valuable resources in Virginia. The Environmental Protection Agency (EPA) divides mining-related wastes into two categories: those generated from mineral extraction and beneficiation and those generated from mineral processing. Materials from both categories are produced in Virginia, where waste (by-product) materials are present at a variety of mining sites and processing plants; some of which have been exploited for various uses in the past and/or present. These materials include: used concrete recycled for roadbase material; pyrite coated with magnetite for use in portland cement; minor amounts of fly ash for use in concrete block, lightweight aggregate, and flowable structural fills; granite and diabase quarry fines for use as agricultural and asphalt filler; lime kiln dust for use in neutralizing and stabilizing coal refuse; soapstone aggregate for use in terrazzo heat retention panels; kaolin for use as a filler product and as an ingredient in white cement; slate quarry fines used as landcover and combined with aggregate for crusher run and as a filler in asphalt; and coal refuse for use as fuel in a lightweight aggregate plant. There are some materials available that have never been utilized, although several ideas were investigated to turn them into usable commodities. One such material is a high-alumina scrap produced as a by-product at a ferrovanadium processing plant. However, large quantities of waste materials from metal mining, industrial mineral, and fossil fuel operations remain to be disposed of in an environmentally safe and economic manner. In 1989, almost one million tons of fly ash were produced from burning of coal at eight coal-fired power plants in Virginia. Present uses for this waste such as an ingredient in concrete block, concrete aggregate, and in structural fills cannot dispose of all the available material; however, increased use of fly ash as a soil/rock substitute for structural fills and embankments may solve the problem of its disposal. Another waste material is calcium carbonate precipitate paste produced at a lithium carbonate processing plant and presently being used for back filling an on-site inactive underground limestone mine. Flue gas desulfurization (FGD) wastes in the form of CaS04 will probably increase threefold. If this material contains a minimum of 95 percent gypsum and negligible chloride, it may have a value to a wallboard manufacturer as we move toward the year 2000. Thought must be given how this increasing waste can be disposed of in an environmentally safe manner.

Jan 1, 1995

By J. W. Dini

Introduction The mission of the Materials Fabrication Division (MFD) is to provide fabrication services and technology in support of all programs at Lawrence Livermore National Laboratory (LLNL). MFD involvement is called for when fabrication activity requires levels of expertise, technology, equipment, process development, hazardous processes, security, or scheduling that is typically not commercially available. Customers are encouraged to utilize private industry for fabrication activity requiring routine processing or for production applications. MFD is .a large diversified service organization including approximately 400 full time employees. The group provides a wide variety of processes including all common machining and fabrications operations, laser and water jet cutting, electrical discharge machining, lapping, electron beam and laser welding, vacuum brazing, heat treating, forming, electroplating and metal finishing, optical polishing and grinding, vacuum coating, vacuum engineering and a variety of plastics operations. These operations occupy more than 1,250,000 square feet of floor space. For more detail on the many fabrication related services available from MFD, see Reference 1.

Jan 1, 1992

By Bradford H. Miller

Separation and Recovery Systems, Inc. (SRS) provides on-site waste minimization and resource recovery using its state-of-the-art MX-1500 centrifuge and MX-2000 thermal desorber. The MX-1500 can process over 450 feed tons of material per day, resulting in centrifuged cake containing 20% to 60% by weight. The MX-2000 is a hollow-flite thermal processor indirectly heated by either steam or hot oil. SRS has dewatered and/or deoiled over 1,000,000 feed tons of material in the refining, chemical, and energy industries using the MX-1500. SRS estimates that over 300,000 barrels of reusable oil have been recovered from that material. Additionally, SRS has dried and/or detoxified over 150,000 wet tons of solids or soil to regulatory or customer-specified limits using the MX-2000.

Jan 1, 1994

By E R. Ramanaidou, M A. Wells

Reflectance spectroscopy is now an established technique for mineral exploration and ore characterisation. The efficacy of the technique as a tool to characterise the main iron ore and gangue mineralogy at African Minerals Ltd’s Simbili iron ore deposit in north-central Sierra Leone was tested through reflectance spectroscopic analysis of 13 000 pulped drill reserve samples using CSIRO’s HyLogger-1™ system. Specifically, integration of reflectance spectral data with more traditional methods of analysis, such as geochemical analysis and Satmagan measurements, characterised the mineralogy (ie hematite versus goethite) of the oxidised ore at Simbili, quantified the Al associated with goethite and hematite and evaluated the distribution of the main gangue minerals – kaolinite and gibbsite. Relative changes in the Fe2+/Fe3+-bearing oxide and silicate mineralogy, based on mineral indices derived from reflectance spectroscopic measurements, appeared well-related to changes in the ore profile mineralogy consistent with the main ore types identified at Simbili, as representative of an oxidised banded iron formation sequence. Spectral calibration models, developed from a well-characterised training set of mineral mixtures, representative of the oxidised ore zone mineralogy were used to quantify the distribution of Al associated with kaolinite and gibbsite and the iron oxides, goethite and hematite. Combining these mineral spectral parameters with compositional data enabled the differentiation of Al-substituted goethite and hematite and resulted in the identification of low Al-bearing, or ‘clean’, goethite and hematite from high Al-bearing, or ‘dirty’, goethite and hematite. Spectral quantification of the iron oxide Al composition provides a far more rapid means of quantifying the Al substitution in iron oxides at the deposit scale compared to traditional techniques such as X-ray diffraction analysis. It also enables a level of volumetric characterisation and the potential for large-scale (ie three-dimensional) mapping, which was not previously possible with other techniques. The potential of the technique was also highlighted when mapping the distribution of the main Al-bearing contaminants (gibbsite and kaolinite) identified in the oxidised ore zone at Simbili. Delineation of such zones provides a guide to managing the most appropriate processing options (ie upgrade potential) within a mineralogical framework. Three-dimensional modelling of the gangue phase distribution may also allow the mapping of lithological and/or structural controls that may be prevalent at Simbili. This work highlights the value in the application of HyLogging™ technology for rapid resource characterisation, particularly for volumetric identification and mapping the distribution of both the economic and gangue phases, which otherwise would be difficult to achieve. As such, the technique can provide a fast and inexpensive means to evaluate ore and gangue mineralogy at the deposit scale and provide a first-pass assessment of the mineralogy and compositional attributes, with the potential to better predict ore metallurgical properties.CITATION:Wells, M A and Ramanaidou, E R, 2015. Waste not, want not – delving deeper into the Simbili iron ore deposit using HyLogging™ scanning technology, in Proceedings Iron Ore 2015, pp 337–346 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By S Joyce, Z Agioutantis, D van Zyl, D Shields

Over the past 15 years, the mining industry has begun to incorporate the concepts of sustainable development and sustainable mining practice across the life cycle of mineral operations. This requires addressing economic issues, community impacts and concerns and environmental protection, and is captured in part by the phrase ‘design for sustainability’ (McClellan et al, 2009). Over the same period, the industry has seen a gradual decline in ore grades for many mineral commodities. As a result, large volumes of tailings and mine waste rock are being produced around the world, and it is expected that the annual production volumes of these materials will increase, even if there is not a significant change in the demand for materials.Another related thread of change has been the realisation that societies need to move away from linear economies (raw materials, production, consumption, disposal) towards more circular ones. This will help societies become more resource efficient, which is defined by the United Nations Environment Programme as reducing the total environmental impact of the production and consumption of goods and services, from raw material extraction to final use and disposal. The goal is to create more with less and deliver greater value with less input. Circular economies require thinking in terms of the waste hierarchy (reduce, reuse, repurpose, recycle, recover, landfill).The challenge is that the waste hierarchy was originally designed to address embodied mineral content in products rather than mine waste and tailings generation. It will need to be reconsidered in a mine life cycle context, focusing on a value-based conception of waste (Van Ewijk and Stegemann, in press).In parallel to these changes, it has remained an imperative in the mining industry to dispose of these waste materials as economically as possible while protecting the environment. Single handling of these materials has been the main target, which reduces the life cycle costs of their management but may make reuse of waste and tailings technically more difficult or economically infeasible.This presentation explores a rethinking of the large volume earthen material waste issue at mines. The underlying theme is that some or all of these materials can be valuable resources for the future that can positively contribute to sustainable development. These resources can offer economic gains to firms, communities and societies; contribute to environmental well-being; enhance social interactions with the previously mined landscape if handled properly; and, with proper policies in place, reduce governance commitments. Each of these topics will be briefly explored. This will be followed by a discussion of approaches to manage design and operations to allow future resource recovery.CITATION:Van Zyl, D, Shields, D, Agioutantis, Z and Joyce, S, 2015. Waste not, want not – rethinking the tailings and mine waste issue, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 7–10 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

By Muammer Kaya, Derya Oz

The main objective of this study was to remove printing ink from waste newspaper and improve the de-inked paper brightness as close as the unprinted paper by bleaching agents. This paper summarizes results of laboratory investigation into the de-inkability of newsprint printed with offset printing. Different chemicals and process parameters were varied to assess the effect on the brightness and cleanliness. The operations involved in de-inking process are briefly described and some of the problems being encountered are discussed.

Jan 1, 1995

By Ann M. Hagni

One of the most costly factors in the production of aluminum is the consumption of energy in the form of electricity. Energy consumption is increased as refractories in the Hall-Heroult reduction cells are corroded by penetration of the fluxes cryolite (Na3AlF6) and villiaumite (NaF). To decrease thermal conductivity and refractory waste, protective barrier linings are installed. Dry powder barrier linings form stable reaction products at cell operating temperatures. Four dry powders composed of vermiculite, corundum, wollastonite, and anorthite are characterized mineralogically by X-ray diffraction, reflected light microscopy, scanning electron microscopy, and cathodoluminescence microscopy in this research project.

Jan 1, 1998

By V. I. Lakshmanan

Recycling helps to save energy and is good for the environment. It is also important for preserving the limited natural resources. In addition, recycling creates economic benefits and frees up space at the landfill sites. Process Research Ortech Inc. (PRO) has conducted extensive testwork in the area of waste processing and recycling. A process was developed for the recovery of Zinc from galvanized steel by alkaline leaching followed by solvent extraction and electrowinning. Extensive testwork has been conducted at PRO to obtain a useful by-product from rice husk. Rice husk was combusted in a gas/solid reactor to obtain an environmentally acceptable amorphous silica ash suitable for use in high strength concrete. In another development, vanadium was recovered from fly ash by separating carbon first, followed by alkaline pressure leaching, solvent extraction and precipitation. PRO has also developed an environment friendly process for treatment of industrial wastewater for its reuse to obtain zero or minimal effluent discharge. In this paper, four case studies related to recycling of zinc scrap, controlled combustion of rice husk, processing of fly ash, and reuse of waste water will be discussed.

Jan 1, 2011

By Robbilliard K. R, Floyd J. M

The problems facing the metallurgical industry from the viewpoint of the range of unacceptable residues, flue dusts and slags currently produced from the electrolytic zinc process, electric arc furnace scrap treatment, and blast furnace operation in lead smelting and the Imperial Smelting Process (ISP) are addressed. The application of the Ausmelt technology is discussed and analysed for the pyrometallurgical treatment of zinc plant residues, steel plant flue dusts and lead blast furnace and ISP slags, as well as the more complex issue of smelter modernisation to avoid production of zinc plant residues in the future. Processes developed from pilot work are described and indications of the economics of treatment of electrolytic zinc plant neutral residue and jarosite are given.

Jan 1, 1993

By S. W. White

Plasma arc technology is increasingly being used to process a number of waste materials. In present research, plasma technology is being investigated to treat waste magnesium baghouse dust, which is a waste material from the Magnetherm process. This dust contains mostly MgO, but also contains NazO, CaO, and KzO. Plasma energy is to be used along with a reducing agent to produce pure gaseous magnesium while keeping the other materials in a slag. The magnesium will then be collected by rapid quenching. A non-transferred arc plasma torch is ideal for this reaction because of its high enthalpy and improved energy efficiency over conventional methods. Another advantage of plasma is that it allows for the pre-heating or pre-reacting of fine particles before contact with the melt. Thermodynamic calculations using the Gibb energy minimization method were used to determine the most stable compositions of the materials at various temperatures. Energy balances have also been calculated. These results conclude that we can recover approximately 98% of the magnesium with a proper quenching technique. The calculated results are compared with the experimental data, and good agreement between them was observed.

Jan 1, 1999

By Petr Stehlík

"This paper is aimed at showing and demonstrating progress in technologies and improvements in units for the thermal processing of various types of waste. The following areas are covered: units for the thermal treatment of hazardous industrial waste and common MSW, technologies for the thermal treatment of industrial and sewage sludge, utilizing waste in cement production (material and energy recovery), up-to-date off-gas cleaning systems, original and unique units for the thermal processing of polluted gases, low-NOx burners. The paper represents a review based on industrial applications, papers published in reputable international journals and a monograph under preparation.IntroductionThe present contribution is an overview of the activities and achievements of the Institute of process and environmental engineering (UPEI) of the Brno University of Technology (VUT). The Institute belongs to European leading teams in the field of the thermal processing of various types of waste. The research in the institute currently revolves mainly around a strategic project “Waste and Biomass Utilization focused on Environment Protection and Energy Generation” that is supported by the national government. Due to the limited space this paper is conceived as a review of papers published especially in reputable international journals.Main (strategic) target of the research is development of new, efficient processes (eventually modernized processes with novel original elements) for effective and highly efficient treatment of waste and biomass, including their maximum utilization as renewable energy sources while minimizing harmful emissions. To this purpose, highly advanced know-how for the design and construction of the related technology lines is being developed, supported by mathematical modeling (see e.g. [1]), experimental validation and optimization.Municipal and Industrial Solid Waste – Concept of Waste-to-Energy CentersThermal processing of various types of wastes is not only waste disposal and/or treatment at present. It has to be regarded as waste to energy process wherever and whenever possible and feasible. This observation was at the origin of the concept of new regional Waste-to-Energy Centers (WTEC), outlined in the following paragraphs. The proposal of the centers is based on a combination of experience, know-how and sophisticated approach. The main fact influencing the concept of WTEC is the necessity to treat different types of wastes. Typical types of wastes as well as main products of the processes in a WTEC are shown in Figure 1."

Jan 1, 2008

The work that has formerly been done by the Waste-reclamation Section of the War Industries Board has been tranferred to the Department of Commerce and will be continued as the "Waste-reclamation Service" of this Department. The plan contemplates the establishment of a national waste-reclamation system-comprehensively organized, effective and systematic, and animated by a sympathetic understanding of the purposes and principles of the Service. It is the expectation of the Service that the work will be taken over by the several municipalities or other local governments and made permanent through the creation of a department or bureau for the salvage of waste materials. The local Waste-reclamation Council should be composed of representatives of cooperating national organizations, selected by the mayor; or chief executive officer of the city, town, or village. It will be the duty of the Council to inaugurate an educational campaign to conserve materials so as to make less waste, together with a reclamation movement that shall reclaim the residue of waste in the community, thus conserving the resources of the country both in man power and in materials. The most important materials to reclaim at the present time are: paper, steel, copper, wool, iron, brass, cotton, zinc, aluminum, rubber, babbitt metal, tin-foil, lead, tin and leather.

Jan 8, 1919

By T C. Hughes, R Hughes

Ausmelt has developed and commercialised high temperature reactor technology that has been applied to waste processing in the form of a catalytic waste converter (CWC). Ausmelt Technology uses a top submerged lance system within a versatile converter containing an oxidised molten siliceous slag. Metals and other valuable products can be extracted from wastes for recycle into the community. Non-valuable components such as toxic organochlorinated compounds are destroyed and prevented from reforming. The slag produced is inert and can be safely used in building and concreting. The CWC can be applied to practically all types of wastes and examples from Ni-Cd batteries to toxic wastes are discussed. Additional benefits can be derived from large-scale operations if the surplus heat generated is exploited to produce steam and electricity.

Jan 1, 2000

By P. K. Gbor

Over 2 million tonnes of smelter slags containing Co, Ni and Cu are produced and stockpiled in Canada each year. Smelters also produce SO2 an air pollutant. Recycling these materials will maximize the value of natural resources and minimize possible environmental impacts of industrial operations. The objectives of this research were to understand the characteristics of slag, the reaction of slag with SO2(aq) and to develop a novel method for extracting Co, Ni and Cu from slag using SO2. The properties of slags from different smelters were studied, with emphases on the form of Co, Ni, Cu and Fe. Leaching experiments were carried out in a batch reactor. The parameters investigated included concentration of SO2(aq), stirring speed, particle size, temperature and pH. O2 was introduced into the reactor to study its effect on the system. The amount of each of Co, Ni and Cu in all the slags was less than 1%, while Fe was between 30% and 45%. The form of Co and Fe was primarily oxide, however, significant portions of Ni and Cu were present as sulphides. SO2(aq) alone, was effective in leaching Co and Fe. Cu dissolution was negligible due to precipitation. The presence of O2 improved Cu and Ni extraction. SO2(aq) was found to be more effective in leaching slag than H2SO4 at the same pH. The leaching process was modelled using the shrinking core model. A scheme was proposed for the extraction of Co, Ni and Cu from slag using SO2(aq). The process makes efficient use of SO2, separates Co and Cu at an early stage, and minimizes the consumption of base during Fe separation.

Jan 1, 2003

By Yuta Yamamoto

Seafloor massive sulfides (SMS) which contain Au, Ag, Cu, Zn, and Pb have been interested in as a target of commercial mining these 15 years. Japan has large potential of SMS and a national R&D project for the mining has been active these 5 years. However, the economy of SMS mining is very bad, because the waste tailing disposal cost is very expensive in Japan. A slurry flushing method is experimentally examined in this study for the improvement of the economy. During the flushing, because of density difference between the metal-rich ore and the waste rock, a kind of gravity separation is possible. The results suggest a possibility of the actual application.

Sep 14, 2011

By G W. Wilson, C Panidis

Potentially acid forming (PAF) waste rock contained in dumps formed as a result of open cut mining of metalliferous orebodies are conventionally sealed or covered using a near-saturated, low permeability compacted clay layer, protected with a mulch layer and/or vegetated growth medium. The purpose of the compacted clay layer is to limit oxygen diffusion and the infiltration of rainfall into the dump. Where the aerial extent of the PAF waste rock dump is large, or where suitable clayey material is in short supply, it may be difficult to source sufficient suitable clayey material to form the cover. The paper describes a laboratory-based investigation of combining inert waste rock and tailings to form an alternative seal or cover material. The inert waste rock was sourced from the trafficked surface of a non-acid forming (NAF) waste rock dump, with a maximum particle size of about 100 mm. This was combined with NAF thickener underflow tailings slurry in various mass ratios, and the resulting mixtures tested for their particle size distribution, compaction characteristics, soil water characteristics (relationship between suction and volumetric moisture content), and saturated hydraulic conductivity. The mixtures tested ranged in consistency from those dry enough to be compactable, to those with the consistency of wet concrete that lend themselves to placement without the need for compaction. The laboratory test results showed that the suitability of the mixtures as seal or cover materials is very dependent on the particle size distribution of the mixture, with well-graded mixtures having substantial fines performing best.

Jan 1, 2003

By P Scott

Kaltim Prima Coal, an open cut coal mine located in Sangatta, East Kalimantan, Indonesia, operates two deep pits and two shallow pits with a truck and shovel operation. KPC produced 17 Mt of coal in 2002 by removing 120 Mbcm overburden. Geochemical investigations have indicated 20 per cent of total waste rock is potentially acid forming; ie it has the potential to create acid mine drainage (AMD). In the early years of the KPC operation, the presence of AMD had been observed in the mined out areas and in the waste rock dumps as a result of sulfidic waste rock exposure. A strategy for management of AMD from waste rock was implemented involving: sampling, analysis, modelling, selective handling and validation of final dump covers. Samples of the waste rock lithologies are collected from exploration drill holes for geochemical analysis to determine their acid generating potential. The geochemical database is used to develop the waste rock model for the life of mine pit areas. The acid forming and non-acid forming waste rock is delineated for each mining bench area for selective handling and placement within the waste rock dump during the operational stage. Each mining bench is sampled and assessed to validate the model predictions. The final dump cover is sampled to meet strict Quality Assurance requirements to ensure non-acid forming waste material is used in the outer cover of the dump. The geochemical investigation of the waste rock is integrated with mine planning to design and construct the waste rock dump to minimise the risk of generating acid. This process links the exploration stage, operation stage, and rehabilitation stage for each Pit area. The paper briefly reports the waste rock characterisation, waste modelling and strategies used for management of acid drainage by KPC.

Jan 1, 2003

Waste rock extracted from a mine is typically stored nearby on the surface. Such waste rock piles must be designed to ensure their geotechnical and geochemical stability during the mine operation and after closure. The optimal construction of a pile requires detailed planning. Deposition should involve benches of limited height to control the global slope angle, based on the long term factor of safety. It can also be advantageous to compact the top of each bench and to give the surface an outward inclination to control water flow by limiting infiltration and favoring lateral diversion. When part of the waste rock contains reactive minerals, it is also deemed necessary to use selective placement with the non-reactive portion to prevent direct exposure to natural conditions. The construction must be well documented, and include data from the monitoring program. These and related aspects are presented and discussed in the paper.

Aug 1, 2013

By Michel Noël

This paper presents a partial compilation of adopted measures of waste rock dump closures at mine sites located in Canada and Alaska, where the climate includes cold winters. The paper also presents the selection process that was followed for some of those mine sites. Mining operations usually generate waste rock that can sometimes result in very large quantities. Additionally, the nature of the ore body and the host rock will often introduce environmental impacts. These impacts need to be managed not only during the operations but also in the long term. Mine closure plans consequently have to address the long term issues that sometimes require perpetual treatment. Closure planning often involves the evaluation of risks associated with environmental and financial liabilities. It needs to consider the science, some common definition of objectives, and there will be a need to manage resources and schedules. Closure planning is essentially an exercise in constrained decision making. A performance and risk based ranking matrix is often developed during this selection process to identify the preferred option(s). The case studies presented in this paper provides a few examples. The level of knowledge on acid rock drainage from waste rock dumps has increased considerably over the past decades. It did not necessarily increase the level of complexity of the adopted closure methods, as the selected closure methods are often kept simple. A common approach consists of stabilising the slopes of the waste rock dumps material by resloping and then covering the waste rock with a growth media to support vegetation. Such covers prevent direct contact of animals with the waste rock material, minimise erosion and reduce infiltration to various degrees. The inclusion of water treatment is obviously dependent on the water quality being released.

Nov 1, 2008

The geochemistry of waste rock from mining operations is critical to the development of acidity-related environmental problems during mining operations, and following mine closure. Failure to recognise the potential for waste rock to produce acidic oxidation products may cause mobilisation of heavy metals into ground and surface waters, and create heavy metal levels in soils which are toxic to plants, causing the failure of revegetation programs. Although more usually associated with wet tropical environments, the potential exists for these problems to occur even in and regions such as the Eastern Goldfields region of Western Australia unless appropriate pre-planning is undertaken.Acidity-related mine waste problems can be extremely expensive to rectify, but can be avoided by waste rock characterisation, and pre-planning of waste rock deposition based on this information. Integration of knowledge of waste rock geochemistry with geotechnical engineering, and application to likely problems, is essential for the successful planning and implementation of cost-effective strategies to avoid problems occurring. Pre-planning to avoid problems is likely to be significantly less expensive in most cases than remedial actions to rectify problems after they have occurred, and in fact may involve no additional cost if it requires only rescheduling or redesign of existing or planned Activities.

Jan 1, 1993