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By William Gleason

Despite a global slowdown in most mining sectors, Caterpillar, the world?s largest mining equipment maker continues to forge ahead with new, and improved offerings to the global mining industry. On Nov. 10, as part of its Loading and Hauling Mining Focus Session at its Tinaja Hills proving grounds south of Tucson, AZ, Caterpillar unveiled to customers and media its two latest mining products, the 994K wheel loader and 6020B hydraulic shovel. The Caterpillar 994K wheel loader builds on a nearly 25-year history of the 994 model but with one noticeable difference ? the 994K is bigger ? much bigger. Weighing in at 239,142 kg (527,218 lb) the 994 K is up to 20 percent larger and comes with up to 30 percent increase in payload capacity. This behemoth of a machine is currently being tested at Caterpillar?s Tucson Proving Grounds, Anglo Gold Ashanti?s Cripple Creek and Victor gold mine in Colorado and Taseko?s Gibraltor copper and molybdenum mine in British Columbia, Canada.

Cataclysmic or flood-like release of gas-charged brines, hydrocarbons and slurries accompanied widespread mineralisation of Upper Devonian environments. These are well represented in the Canning and Burdekin Basins of Western Australia and Queensland respectively.The Burdekin Basin provides particularly instructive vein structural sequences. These fall into organic residue to carbonate paragenetic sequences which are known elsewhere to record progressive decarboxylation. Fibrous veins indicate overpressure in fractures with organic residues, acids and gas derivatives driven to overlying groundwater flows. This combination of large flow rates and potent organic mineralisers led to extensive arsenical rare-metal mineralisation which is similar to that concentrated in Upper Devonian extinction horizons of the Canning Basin. Organic-residue mineralisation appears concentrated by certain hvdrostructures and targeted upon particular species. These controls need to be understood to guide modern management stragegies for mineralised organic and nitrogenous wastes.

Jan 1, 1990

By M Rea, E O’Connell

Decarbonising explosives manufacturing and catalysing low-carbon mining supply is a significant global challenge. Low-carbon manufacturing precincts – clusters of geographically close businesses across multiple industries that share a goal of adopting firmed renewable energy and decarbonising process emissions – offer one potential solution. In an Australian first, Orica commissioned tertiary catalyst abatement technology in 2023 to mitigate greenhouse gas (GHG) emissions at its Kooragang Island (KI) facility in New South Wales (NSW), Australia. The EnviNOx® technology (ThyssenKrupp Industrial Solutions AG, Dortmund, Germany) used reduces nitrous oxide (N2O), a potent greenhouse gas arising as a by-product of nitric acid manufacture. As a result, mining customers in NSW are now benefitting from ammonium nitrate (AN) products that are almost 50 per cent less emissions-intensive than those Orica previously offered. The $37 million project is a private-public partnership that has involved partners across Federal and State government, global engineering and technology vendors, local community groups and local carbon advisors to overcome financial barriers.

Sep 1, 2024

By Y. K. Rao

The direct reduction of lead sulfide with carbon in the presence of lime was investigated at several temperatures and under two different inert gas atmospheres. The catalyzed reduction kinetics were determined both with a nitrogen atmosphere and a helium-rich helium-nitrogen atmosphere. The reduction kinetics under the latter were d-ecidedly superior to those under the former. The differences-were interpreted in terms of faster diffusion rates in a helium medium and-synergistic effects.

Jan 1, 1983

By Lene Hansen

Sulphuric acid plants now and then see unexpected increases in SO2 emissions. Our experience is that it is not always easy for the acid plants to pin point the exact reason for the SO2 increase. Sometimes a catalyst bed is sacrificed even though reliable emperature readings and gas analyses could have verified satisfactory activity, hence the leaking heat exchanger is never discovered and after the shutdown the SO2 emissions are still too high. This paper will look into some basic catalyst management tools: Good record keeping is a necessity for collection of representative catalyst samples, reliable operating data is an inevitable starting point for all analysis and trending of operating data is a must for plant optimisation and troubleshooting. In addition these catalyst management tools will give a continuous updated knowledge of the catalyst status in each bed providing the basis for a more effective replacement strategy. The most typical reasons for increasing SO2 emissions will be presented together with easy guidelines for cross-checking of operating data, temperature optimisation and good record keeping.

Jan 1, 2009

By Lene Hansen

Sulphuric acid plants now and then see unexpected increases in SO2 emissions. Our experience is that it is not always easy for the acid plants to pin point the exact reason for the SO2 increase. Sometimes a catalyst bed is sacrificed even though reliable emperature readings and gas analyses could have verified satisfactory activity, hence the leaking heat exchanger is never discovered and after the shutdown the SO2 emissions are still too high. This paper will look into some basic catalyst management tools: Good record keeping is a necessity for collection of representative catalyst samples, reliable operating data is an inevitable starting point for all analysis and trending of operating data is a must for plant optimisation and troubleshooting. In addition these catalyst management tools will give a continuous updated knowledge of the catalyst status in each bed providing the basis for a more effective replacement strategy. The most typical reasons for increasing SO2 emissions will be presented together with easy guidelines for cross-checking of operating data, temperature optimisation and good record keeping.

Jan 1, 2009

By L. Hansen

Sulphuric acid plants now and then see unexpected increases in SO2 emissions. Our experience is that it is not always easy for the acid plants to pinpoint the exact reason for the SO2 increase. Sometimes a catalyst bed is sacrificed even though reliable temperature readings and gas analyses could have verified satisfactory activity. Hence the leaking heat exchanger is never discovered and after the shutdown the SO2 emissions are still too high. This paper will look into some basic catalyst management tools: good record keeping is a necessity for collection of representative catalyst samples; reliable operating data is an inevitable starting point for all analysis; and trending of operating data is a must for plant optimization and troubleshooting. In addition, these catalyst management tools will give continuous updated knowledge of the catalyst status in each bed, providing the basis for a more effective replacement strategy. The most typical reasons for increasing SO2 emissions will be presented together with easy guidelines for cross-checking operating data, temperature optimization and good record keeping.

Jan 1, 2009

By Haydn H. Murray

The three major catalyst markets that utilize industrial minerals as raw materials are petroleum refining, chemical processing, and emission control. Because of economic, competitive, and regulatory pressures, catalyst producers are pushed to develop products with improved performance to meet changing environmental standards. Also, refiners are demanding new families of cracking catalysts that will crack residual fuels. In 1987, worldwide cracking catalyst sales amounted to $457 million (Occelli, 1988a). Recently enacted federal and state laws to improve air quality have prompted strong growth for environmental catalysts, which in 1989 accounted for more than a third of the $1.9 billion catalyst market in the United States (Farrauto, Heck, and Speronello, 1992). A catalyst is a material that promotes or enhances a chemical reaction but does not itself enter into the reaction. One of the more important mineral groups used as catalysts is clays. The first recorded use of clay as a catalyst was its use in the dehydration of alcohol (Bondt et al., 1797). Clay minerals that are used as catalysts are kaolinite, halloysite, smectite, palygorskite, and sepiolite. Minerals used as catalysts, catalyst supports, or as a raw material to make zeolites are kaolinite, halloysite, sodium montmorillonite, calcium montmorillonite, hectorite, palygorskite, sepiolite, talc, calcined kaolinite, gibbsite, chlorite, and titanium dioxide.

Jan 1, 1994

By Jorge M. C. Soares

The CO oxidation reaction has been studied on Au/TiO2 catalysts prepared by incipient wetness (IW) and deposition-precipitation (DP) methods. Additionally the assessment of activity was also conducted on simple gold compounds (Au2O3 and Au(OH)3) and their physical mixtures with TiO2. We have found that there are three types of CO2 production from fresh catalysts, which are only dried, namely: Non-catalytic Type I (low temperature CO2 production); Non-catalytic Type II (higher temperature CO2 production) and Catalytic Type III. The DP catalysts are far more active for Type III reaction, showing activity already at room temperature, whereas the IW catalysts generally do not show steady state conversion until T>673 K. This is due to both large particle size and the presence of residual chlorine for the latter. No truly catalytic activity was found for low temperature CO oxidation on gold precursors on their own, although both Au2O3 and Au(OH)3 react well with CO even at room temperature in an irreversible manner (Type I reaction). Despite that, catalytic activity was obtained by mixing Au(OH)3 or Au2O3 with TiO2 which gives further emphasis on the importance of a good contact gold/support and the absence of chlorine.

Oct 1, 2003

By P. E. Nolan

The disproportionation of carbon monoxide is an important aspect of reduction processes, in the production of carbon filaments for composites, and in the removal of CO from CO,. It can also be a hindrance, causing carbon fouling of equipment and metal dusting. The reaction is thermodynamically favored at lower temperatures, but it occurs slowly. Catalysis of the reaction by transition metals has been examined. A materials science approach to the selection of a catalyst material and of optimum operating conditions is being taken in the present work. Of particular interest is characterization of a catalyst that can be repeatedly regenerated to prevent deactivation in long term use. Experimental data on a less studied catalyst, ruthenium, are reported.

Jan 1, 1992

By M. Kawakami

In the blast furnace, the reduction of iron oxide and gasification of coke occur simultaneously. It is well accepted that the gasification reaction controls the simultaneous reaction. Therefore, it is important to develop highly reactive carbonaceous materials. It is also known that the reaction is accelerated catalytically with the addition of some materials. In the present work, the catalytic effect of iron, nickel and CaO on the gasification of graphite and coke was examined. The catalytic effect of iron, nickel and CaO on the reaction rate of graphite was noticed The effect was larger at lower temperature. At 1373 K, the effect almost vanished. The effect was larger in the order of CaO, iron and nickel. The reaction rate of de-ashed coke increased by the addition of iron and nickel. The effect of iron was larger than that of nickel. The effect was larger at higher temperature, which was contrary to the case of graphite. The reactive surface area increased also by the addition. Therefore, the catalytic effect on reaction rate might be attributable to the increase in the reactive surface area.

Jan 1, 2006

By M. Moinpour, Y. K. Rao

The catalysed direct reduction of copper sulphide with carbon and lime was investigated in the range 850-1000 degrees C using Cu2S-CaO-C and Cu2S-4CaO-4C reaction mixtures. The effects of the catalytic additives K2CO3, Li2CO3, Na2CO3, NaF, Na2SO3 and the ternary eutectic (K,Li,Na)2CO3 were determined. Potassium carbonate, sodium fluoride and the ternary appear to be the most effective catalysts for the direct reduction process. The rate enhancement of the catalysed carbothermic reduction of copper sulphide in the presence of lime was explained in terms of the catalysis of the Boudouard reaction

Jul 1, 1991

By M. Rebolledo, N. Mora, G. Zarate

For decades, the mining industry has been focussed to find an efficient and economically attractive process for the leaching of chalcopyrite. Jetti Resources has developed a novel hydrometallurgical alternative to extract metals of value from mineral ores that the mining industry has struggled to process. Jetti’s catalytic technology, whilst being especially advantaged for extracting copper from low-grade and highly refractory minerals, such as chalcopyrite, seamlessly integrates with existing heap leaching methods and downstream processing operations. The technology uses a catalyst which weakens the metal-sulfide bond in the crystalline structure of the chalcopyrite mineral and alters the structure of the passivation layer allowing the leaching process to continue. Metallurgical test work was conducted to examine the effect of ore variability, in terms of grade and copper deportment. The results presented in this study highlight the amenability of the technology and demonstrate that it is possible to enhance leaching performance of copper primary sulfides over a wide range of copper grades, from 0.1 to 2.2%. Further, it is concluded that despite the copper grade, the tests with increasing chalcopyrite content render copper recoveries up to 4 times higher compared to the tests under non-catalyzed conditions. Jetti’s catalytic technology is currently being evaluated at larger scales, namely a commercial dump leach operation and 50-tonne crib tests. The results obtained thus far are compared to the results from conventional sulfide heap leaching tests. INTRODUCTION For decades, the mining industry has been focussed to find an efficient and economically attractive process for the leaching of chalcopyrite. Chalcopyrite (CuFeS2) is the most abundant and recalcitrant of the copper sulfides (Singer, 2017). Owing to its abundance and economic importance, it is the most demandable natural source for copper worldwide. In fact, the projected demand for copper is further expected to rise much higher beyond the current demand by the year 2020 (Panda et al., 2015). Therefore, it becomes imperative to find low intensity hydrometallurgical technologies for the extraction of copper from chalcopyrite in ores of such low-grades that are un-economic to concentrate and to augment the supply by extracting copper from ores with complex mineralogy that cannot be concentrated (Watling, 2013).

Jan 1, 2019

A strategy is presented for a relatively. "low-tech" means for decontamination of streams . containing .low concentrations of toxic metals. Metal ion solutions were . circulate through fluidized beds of activated carbon which support bio-films ?of bacteria .that naturally excrete exopolysaccharides. The attached 'biomass is shown to significantly enhance nickel, cadmium and silver extraction from dilute solutions (5- l00mg/l). By heat treating (at 300º C) the metal/biomass/carbon particles, bio-sorbed silver was subsequently fixed to the carbon surface. This approach to metal decontamination may therefore also provide a route for dispersing and fixing catalytic metal particles over an activated carbon surface.

Jan 1, 1991

By S. Fuchida, Y. O. Zubair, C. Tokoro

Mining of As-bearing minerals had resulted in the release of arsenic species predominantly As(III), which is known to be more toxic, and undue exposure to it is detrimental to human organ systems. Many materials have been examined for As(III) removal, but it is still challenging to advance sustainable materials for effective removal of As(III). In this paper, a more eco-friendly and superparamagnetic Fe0-Fe3O4 composite was synthesised and evaluated for heterogeneous catalytic oxidation and removal of As(III) with peroxymonosulfate (PMS, KHSO5). The kinetic removal studies showed that removal of As(III) was probably through a chemical process and the Elovich model best represented the experimental data. The removal capacity for As(III) on Fe0-Fe3O4 with PMS (1.76 mmol/g) is superior to that without PMS (0.83 mmol/g). Combined results from XPS and ESR showed that As(III) was fully transformed to As(V) through catalytic oxidation by Fe0-Fe3O4/PMS and afterwards enhanced its removal. The removal mechanism of arsenic was ascribed to the formation of outer-sphere (electrostatic attraction) and inner-sphere complexes. The adsorbent can be separated easily from water due to its excellent magnetisation (64.5 emu/g) and also has good reusability potential as more than 85% of the initial concentration of As(III) was immobilised after five consecutive cycles. Keywords: Arsenite, Fe0-Fe3O4 composite, catalytic oxidation, removal mechanism

Jan 1, 2020

To extract the gold from refractory gold concentrate with high sulfur and arsenic, the gold concentrate was catalytically oxidized to expose the gold for cyanide leaching. The effects of reaction temperature, initial nitric acid concentration, reaction time and initial gold concentrate concentration on the conversion rate were studied. The results show that the appropriate conditions for the catalytical oxidation of this gold concentrate are: reaction temperature of 65 oC; initial nitric acid concentration of 25% (wt.); reaction time of 1.5 hours; initial gold concentrate concentration of 10% (wt.). Under such conditions, the conversion rate of gold concentrate is 92%. The solution can be used to prepare nano-iron oxide red pigment. Gases released in the process can be recycled and reused by oxidation absorption. A chemical background of catalytic oxidation is proposed.

Jan 1, 2014

By Buks Kruger

"After the milling and flotation of the platinum bearing ore, the flotation concentrate is electrically smelted in 6-in-line electric arc furnaces and the resulting furnace matte treated in Peirce Smith converters to remove the iron sulphide. The iron free (less than 1% Fe) converter matte is then granulated and sent to the Base Metals- and Precious Metals Refineries for further processing.During the smelting and converting processes two distinct gas streams are produced.The Peirce Smith converter off gas contains 4% - 9% SO2 which is treated in a conventional Sulphuric Acid Plant to produce sulphuric acid (H2SO4).The electric furnace off gas contains 0.9% SO2 and was (until September 2002) vented through a 91 meter high stack to atmosphere.Off gasses which contain less than 3% SO2 is difficult to handle and quite a few processes had been developed over the years to cope with this gas. A broad spectrum of process suppliers and technology approaches is available and the different technologies can be divided into a few main approaches i.e.Scrubbing of the off gas with an alkaline solution to produce an environmentally friendly and stable waste product which can be discharged onto a tailings dam or permanent landfill site.Physical absorption of the SO2 into a chemical solution to produce high quality chemically pure process chemicals.Catalytic reaction of SO2 with O2 to produce SO3 which is absorbed in water to produce sulphuric acid of less than 90% strength.In October 2002 Impala Platinum commissioned a Sulfacid Plant at its Smelter in Rustenburg which recovers the SO2 from the electric furnace off gasses into a weak sulphuric acid solution.The Sulfacid Plant technology is widely used in the paint pigment industry. This is, however, the first application of the technology on electric furnace off gas.The furnace off gasses contains flue dust which is removed in electrostatic precipitators. The gas exiting the precipitators normally still contains between 40 mg/Nm3 and 60 mg/Nm3 dust and passes through a quench-scrubber before entering the reactors. The quench-scrubber cools the electric furnace offgas down from ± 200 °C to 60 °C and act as a final dust removal stage."

Jan 1, 2003

By W Lu, D Wang

Study of coal oxidation at low temperatures forms the basis of investigating the inherent properties of spontaneous combustion of coal. In general, the process of coal oxidation at low temperatures is very complex, involving many factors. Experiments examining the properties of oxidation and ignition of coal have been carried out. Based upon the results of these experiments, the catastrophe properties in the process of coal oxidation are analysed and the mechanism of catastrophe is proved for the ignition of coal. A folding catastrophe model is also established for the process of coal oxidation. Results obtained show that the process of coal oxidation to ignition is discontinuous, where the coal-environment system yields structure destabilisation. The system can jump from one stable attractor to another. The research results presented in this paper help to show the irregularities of coal oxidation at low temperatures and how to pursue effective control measures.

Jan 1, 2005

By Zhang Zhitie

The limitations in mechanism research of mineral comminution in the past and the basic features of the comminution process have been analyzed. Two kinds of catastrophe model, i.e., cusp model and swallowtail one in the mineral comminution have been put forward. The dissipative structure of the mineral comminution: entropy production rate, extra entropy, extra entropy production and system stability has been discussed. The physical nature of the behavior that an old structure was destroyed and a new one was produced in the mineral comminution process has been brought to light.

Jan 1, 1995

By Karl Zipf

In highwall mining, once a sufficient number of web pillars are developed, they can fail catastrophically in a domino-type failure, posing a safety hazard to highwall miners and sterilizing mineable reserves. Three recent case histories of catastrophic web pillar failure in U.S. and Australian mines are documented and analyzed with two design approaches. The conventional design approach uses only a strength criterion, while the postfailure design approach uses both strength and stability criteria to insure an acceptable failure mode should strength failure occur. Catastrophic highwall web pillar failures can cost money through equipment losses, production losses, coal reserve sterilization and lost opportunity costs. Coal recovery may be higher. but the benefits of higher recovery must balance the potential costs of failure. Application of the conventional or postfailure design approach will decrease coal recovery and revenues, but the risk of potentially costly failure is much less.

Jan 1, 1999