Search Documents

Develop an easy-to-use, reliable, resin-grouted cable support system capable of being installed as primary and secondary roof support in coal mines.

Jan 1, 1994

By Gretchen K. Hoffman, George S. Austin

Soil amendments or soil conditioners generally carry the con- notation of being useful for problem soils or soils needing special treatments to produce maximum yields. Many different materials have been utilized, both inorganic and organic. Only the most commonly used and those that appear to have potential to become commonly used will be discussed. Soil productivity depends on many factors. Soil amendments mainly modify physical characteristics and microbial action, and/or change the pH of a soil, rather than directly supplying plant nutrients. They give soil the needed physical properties to allow plant growth, fight erosion, or save water. Some soil amendments provide nutrients in addition to altering the physical, biological, or chemical characteristics of soil. The term "soil amendment," as it is used by Soil Science Society of America, allows soil amendments to be materials other than those used primarily as fertilizers (Anon.,1987). Soil amendments as fertilizers of any type will not be considered here because this aspect is more relevant to the previous chapter entitled "Agricultural Materials: Fertilizers" in this volume. Several inorganic soil amendments have been used since the early 20th century to alter the character of soil: limestone, lime, and similar calcium-rich carbonates and oxides for acid soils, and calcium sulfate (gypsum) and native or uncombined sulfur for alkaline soils. The use of these amendments (limestone, lime, gypsum, and sulfur) or their equivalents has been studied and documented in many basic soils tests (McCaslin and Boyle, 1980). Perlite and vermiculite are considered in separate chapters and only a brief statement of their use as soil conditioners will be made in this chapter. Peat is the principal natural organic soil amendment, but manure, both as a fertilizer and soil conditioner, is used in every part of the world. In less-developed countries, manure is the primary soil fertilizerlconditioner. An organic-rich material designated as "humate" has been marketed as a soil amendment for many years and will be addressed in this paper. Other materials are discussed by the Soil Science Society of America in its Special Publication 7, "Soil Conditioners" (Stewart, 1975). They include bitumen emulsion, polyacrylamide, polyvinyl acetate, polyvinyl alcohol, bentonite, nonionic surfactants, and natural mulches. Zeolites can be added to the list of miscellaneous soil amendments (McCaslin and Boyle, 1980), as can calcium chloride (Pressler and Pelham, 1985), sulfuric acid, ferric and ferrous sulfate, aluminum sulfate, ammonium polysulfide, calcium polysulfide, and ammonium bisulfite (Stromberg and Tisdale, 1979). Sludge will not be considered as a soil amendment because it has properties more consistent with fertilizers. All these "other materials" account for a very small amount of the volume and value of soil amendments used and will be only briefly discussed.

Jan 1, 1994

By J. L. Yordan, T. Hilderbrand, R-H Yoon

High brightness clays are produced from Georgia kaolin by flotation. Fatty acids are used commonly as collectors for anatase, which represents the major colored impurity in the crude. This process requires activation of the minerals with divalent cations such as Ca2+, in which case proper control of the activation step is crucial to the success of the flotation process. In the present work, laboratory tests have been conducted using alkyl hydroxamates as the collector for anatase. A major advantage of using hydroxamate is that this new collector requires no activator. The laboratory tests show also that the hydroxamate collectors produce consistently better products with higher yields from a variety of kaolin clays.

Jan 1, 1994

The Ramu chromite deposit occurs in the Marum Ophiolite complex and is the most economically attractive chrom-ite deposit in Papua New Guinea. Its lateritic nickel, chromite and cobalt potential has attracted several compan-ies to prospect the deposit.In the present work, the compositions of chromite in the Ramu lateritic deposit and coexisting olivine-chromite pairs in Marum Ophiolite dunite were analysed with the electron microprobe for Fe, Mg, Cr and Al. The results were used to determine the relationship between the cations in the tetrahedral and octahedral structures of the chromite. In addition, the Fe, Mg, Cr and Al cations of the coexisting olivine-chromite pairs were used to calculate the equilibrated temperatures of crystallisation of the chromite. The variation of Fe", Mg and Cr cation values of the chromite in relation to the calculated temperatures was studied by regression analysis.

Jan 1, 1994

By H. Suharyono

The results of an experimental study of polymer-induced flocculation of clay suspensions in continuous, stirred-tank reactors are presented. The effects of polymer dosage, mixing time and mixing intensity are shown to be generally similar to those observed for equivalent batch systems, but flocculation appears to be generally less effective in the continuous process. Settling rates are lower and supernatant turbidities are higher for the continuous system. It is postulated that non-equilibrium effects due to simultaneous polymer adsorption and floc growth can be exploited so as to enhance flocculation in batch systems. The nature of the continuous process, however, offers less opportunity for taking advantage of such effects. Conditions in a continuous flocculation system inherently lead to a closer approach to equilibrium.

Jan 1, 1994

By M. H. Lin, S. Kou

"Czochralski pulling has been a very widely used process for growing single crystals for electronic and optical applications. Dopant segregation can significantly degrade the quality and yield of single crystals. We have used the floating-crucible technique for segregation control in Czochralski pulling, our floating crucibles being unique in that the melt passageway is very long. As such, dopant back diffusion is suppressed, even when the cross-section of the melt passageway has to be relatively large to help the melt go through or when the pulling rate is very low. Single crystals of model materials K-doped NaN03 and Pb-doped Sn have been grown with very uniform dopant concentrations. IntroductionSingle crystals of electronic and optical materials are often doped with a small amount of impurities to develop required physical properties, e.g., P and B in Si for n-type and p-type semiconductors, respectively, and Nd in YAG lasers. Dopant segregation can result in nonuniform physical properties, thus degrading the quality and yield of the resultant crystals.Figure 1 is an illustration of the conventional Czochralski process for crystal growth. Several techniques have been developed to control dopant segregation in Czochralski pulling, including the push-pull technique (1,2), the drop-pull technique (3-7) and the floating-crucible technique (8-13). The first two techniques require precise sensing devices and feedback control systems to keep the feeding rate equal to the pulling rate. The last technique is simple since the feeding rate is automatically equal to the pulling rate."

Jan 1, 1994

By H. Kamarudin

The behaviour of cassiterite-sulphosuccinamate flotation system was examined in the light of zeta potentials measured by micro-electrophoresis method. It was observed that sulphosuccinamate substantially affects the zeta potentials of cassiterite, lowering its i.e.p. to pH 2.5 and indicating a specific adsorption and/or chemical interaction. The optimum concentration for flotation, as seen in micro-flotation tests, was found to be associated with the most effective lowering of the zeta potentials, the optimum pH being 3.0. The effect of cations in the pulp was examined for the presence of ferrous, ferric, aluminium and lead ions. The ions ferric and aluminium were observed to create an intense effect of increasing the potentials to positive side, possibly due to adsorption of cation hydroxy complexes, as indicated by their respective species distribution diagrams.

Jan 1, 1994

By Kazuyoshi Kawami, Fumihiko Sumiya, Kunihisa Katsuyama, Yuji Ogata, Koichi Kurokawa, Yuji Wada

When explosives are detonated in the borehole where there is an air gap between the explosive charge and the borehole of inner wall, the shock cave in an air gap travelling ahead of the detonation front sill be generated. This shock wave is called the precursor air shock wave (PAS). The explosive is precompressed by the PAS, and as a result of that the detonation failure occur on occasion. This phenomenon is well known as channel effect.

Jan 1, 1994

By Hjalmar Thiel

Since industry is progressing into the deep sea, marine scientists have expressed their concern about environmental disturbances which will be introduced by using the deep seafloor for mining metalliferous resources or as a repository for wastes. Environmental studies have been conducted on national levels and in bilateral or multilateral cooperation in the development of manganese nodule mining, as this is generally achieved in marine research. These investigations were partly large-scale and experimental approaches aiming at the assessment of the impacts expected to occur in commercial mining. The results elaborated till today and expected to be acquired in the foreseeable future may remain limited. Reliable impact evaluation will result from monitoring a Pilot Mining Operation (PMO). The lecture will present the broad outlines of a possible program and a preliminary calculation of approximate costs for such a combined industrial test and environmental monitoring event. Although the extent of necessary efforts for the environmental risks evaluation can only be estimated rather vaguely, it will become evident that the required human, technical, logistical, and financial resources to be mobilized will exceed industrial capacities and go beyond national funds. Therefore, such assessment of environmental risks is calling for broad international cooperation. While industrial developments for mining the deep sea will be ruled by competition or probably by restricted joint ventures, environmental care ranges outside competition and falls within the interest of all parties involved. Environmental studies, unlike technologies for the same function, do not primarily need duplication. International cooperation in PMO monitoring would equally well support all mining companies or consortia, it would minimize the efforts for all engaged in this challenging venture of deep-sea mining and it would maximize the precautionary discussion on and the care for the deep-sea environment.

Jan 1, 1994

By A. M. Copeland, A. J. Barrett

The use of hydraulically placed backfill in the deep gold mines of South Africa has increased rapidly over the past decade. The backfill that is delivered to the placement areas has a relatively high moisture content, and it is therefore pumped into geotextile containment bags that allow excess water to drain out but retain solid particles. The specific problems associated with this process that are addressed in this paper include the loss of solid particles entrained in the excess water, the rate of strength gain of the backfill, and the post-placement shrinkage of the backfill. The results of laboratory, surface stope, and underground tests are described. The parameters that were varied included the slurry density, the particle-size distribution, and the feed rate of the slurry the concentration of added flocculant; and the type of geotextile used as containment. Suggestions are given for the optimization of the placement properties of backfill.

Jan 1, 1994

A significant amount of information regarding the crushed stone and sand and gravel industries in each State is available from State agencies and State trade associations. These organizations continuously monitor the State mineral industries and are therefore an important source of detailed information at the local level. This third edition of the directory was prepared to provide a listing of government agencies and trade associations that can assist the users interested in obtaining detailed listings of crushed stone and sand and gravel producers, in addition to the information published by the U.S. Bureau of Mines.

Jan 1, 1994

By C. Flores

It is well known that manganiferous silver ores containing manganese intimately associated with silver are not amenable to conventional extraction methods. The segregation process has been applied primarily for recovering copper from oxidized and oxide-sulfide ores. A new alternative process combining segregation roasting followed by flotation to recover silver from refractory manganiferous silver ores, was studied using a 23 factorial experimental design. Laboratory investigations have been conducted on a manganiferous silver ore analyzing 0.02% copper, 0.09% lead, 0.33% zinc, 12.55% manganese and 187 g/ton silver to study the effects of additives salt, coke and copper oxide on silver recovery. Results indicate that 79.3% silver recovery can be attained in the absence of copper oxide and 88.4% when the copper oxide content is 1.5% at '750°C, 2% salt and 1% coke and 30 minutes of roasting time. It was concluded that doping with copper oxide improves silver recovery.

Jan 1, 1994

By G. Ahuja

Tests were conducted to investigate the effects of cyclone geometry, operating conditions, and particle size on magnetite classification. The effects of these parameters on the partition curve for narrow size fractions were studied using a 25mm diameter cyclone cleaning -150 µ m coal. Additional tests were run to investigate the effects of geometry and operating conditions on the slurry, solid, and water splits. The relationship between the relative density of the underflow stream and the relative density of separation was also investigated. This paper presents the results from this study.

Jan 1, 1994

By I. Martinez-Dominguez

In September 1992, mining in Mexico was opened again to foreign investment by President Salinas-de Gortari, after thirty years of "Mexicanization" of mining industry which limited foreign participation up to a 49 % (or 34 % in case of national reserves) on a Mexican mining corporation. During said period mining in Mexico was controlled by four or five big mining companies and besides mining production was focused mainly on silver, lead, zinc, copper and fluorspar. Suddenly in middle of a big crisis on Mexican mining industry due to low prices of minerals in the world and also in a period on which it seems that mining industry in the United States and Canada has been condemned to die for environmental reasons, it appears a new Mexican Mining Law to permit foreigners to participate in mining in Mexico' trough Mexican mining corporations that they may control up to 100 %

Jan 1, 1994

By G. D. Naugle, L. C. Atkinson

Introduction Deep open-pit mines invariably affect the local and regional hydrologic systems. Pit dewatering, occurring during mining operations, puts an obvious hydrologic stress on these hydrologic systems. However, post-mining hydrologic impacts resulting from the pit refilling with groundwater following the cessation of mining activity can also be significant. The prediction of the rate at which the post-mining pit will fill with groundwater is a critical aspect of assessing the long-term hydrologic impacts. Numerical groundwater flow modeling provides a method for predicting the groundwater refilling rate of the pit. The rate at which pit "lakes" fill depends on several factors: •the rate and duration of pit dewatering; •the depth and size of the ultimate pit and •the pre-mining hydrologic regime. These factors can be incorporated into a detailed numerical groundwater flow model that can then be used to assess the effects of dewatering and post-mining recovery on the local and regional hydrologic systems. A sufficiently detailed, numerical groundwater model provides the oportunity to: •account for complex geology near the pit; •assess the impact of active pit dewatering and •predict the long-term impacts of post-mining groundwater flow into the pit. A detailed groundwater model incorporating these items has been developed and applied at an operating open-pit mine. Developed by Durbin and O'Brien (1987), the three-dimensional, finite-element, groundwater flow model was used to represent the hydrologic system of an approximately 253-km2 (98-sq mile) area surrounding the pit. Historical groundwater elevation data, stream flows and meteorologic, geologic and geophysical data were used to establish the dimensions and initial conditions for the model. Steady-state conditions, representing the pre-mining local and regional hydrologic systems, were simulated using the initial conditions incorporated into the groundwater model. The groundwater model was then utilized to simulate various dewatering programs, to predict the filling rate and the groundwater depth in the ultimate pit once mining activities are complete and to assess the long-term impacts on the regional groundwater flow system. Development of pit lake model Groundwater modeling efforts were completed in two phases. The first focused on pit dewatering activities, while the second phase concentrated on the post-mining effects on the hydrologic system. The final estimates of groundwater elevations calculated during the pit dewatering simulations were used in predicting the post-mining recovery of the hydrologic system. The groundwater model was also modified prior to the second phase to account for the volume of rock removed during mining activities. To account for the actual volume of rock mined, the geometry of the post-dewatering model grid was modified to approximate the final pit geometry. The depth and width of the ultimate pit were divided into eight idealized stages that represented significant changes in the bench geometries. These eight stages were then introduced sequentially into the model according to the predicted water elevations within the pit. In this way, changes in the volume and depth of water within the pit were accounted for through time. Once the ultimate pit geometry was accounted for in the model, it was necessary to assign new hydraulic characteristics to those parts of the model grid (elements) that represented excavated rock. The solution of the numerical model requires that finite hydraulic conductivity values be assigned to the portion of the groundwater model that represents excavated rock. Therefore, the calculated groundwater elevations differ, somewhat, between the edges and the center of the open pit. These model-calculated water elevations at the edge and in the middle of the open pit represent the elevation of water that would occur in the pit lake. To minimize the error in the estimated level of water within the pit lake, the hydraulic conductivity was increased to a value that would: •minimize the predicted difference between the groundwater elevations across the open pit and •produce a numerically stable solution. Specific storage is the hydrologic parameter that accounts for the water produced by compaction of the aquifer matrix. To predict the groundwater volume that would flow into the ultimate pit, this parameter was assigned a value equivalent to the compressibility of water. This value of specific storage reflects the post-mining groundwater storage occurring as an open body of water. Additionally, a specific yield of 1.0 was assigned to the pit elements to represent the 100% porosity of the open pit. In

Jan 1, 1994

By Marvin A. Ph. D. Friedman

The following paper describes an overview of evaluations for assessing the potential hazards associated with handling newly developed reagents used in the mining industry. Important factors in determining the risk and hazard associated with handling a particular chemical include hazard identification, dose-response assessment, exposure assessment, and risk characterization. The hazard evaluation step involves collecting and evaluating appropriate toxicology information on a chemical. This can include a comparison of the structure of a developmental chemical with that of a material with known toxicology information. Acute toxicology data, including oral, inhalation, and dermal LD50 values, eye and skin irritation data and sensitization or allergic potential information are typically generated for new chemicals. Environmental and in-vitro genetic toxicology data (e.g. Ames test) are also used to evaluate new mining reagents.

Jan 1, 1994

By George J. Karabin

The Roof Control Division of the Pittsburgh Safety and Health Technology Center, MS HA, is routinely involved in the evaluation of ground conditions in underground coal mines. Assessing the stability of mined areas and the compatibility of mining plans with existing conditions are essential elements in assuring a safe working environment at a given site. Since 1985, the Roof Control Division has successfully used the Boundary Element Method of Numerical Modeling as a tool to aid in the resolution of complex ground control problems. This paper will present an overview of the modeling methodology established and details of techniques currently used to generate coal seam, rock mass, and gob backfill input data. A summary of coal and rock properties used in numerous successful evaluations throughout the country will be included and a set of Deterioration Indices that can aid in the quantification of in-mine ground conditions and verification of model accuracy will be introduced. Finally, a case study will be detailed that typifies the complexity of mining situations analyzed and illustrates various techniques that can be used to evaluate prospective design alternatives.

Jan 1, 1994

By Euler M. De Souza

"This paper presents a study developed to assess the potential use of salt tailings as backfill to control surface subsidence and as a mine bulkhead used to isolate areas of potential brine inflows. A series of index tests, centrifuge model tests and quasi-static creep consolidation tests were performed to evaluate the creep and consolidation properties of salt backfl1l and to evaluate the effect of brine inflow and brine infiltration on backfill behaviour. The centrifuge models were specifically designed to study the mechanical behaviour of salt backfill under the influence of brine inflow and long-term creep. Test results indicated that salt tailings could be applied underground as a bulkhead to seal off areas of potential inflow with the additional advantage of controlling room closure and local back instability. It is hoped that this study will assist mine planners to develop contingency plans to control brine inflow occurrences. IntroductionThe use of salt tailings as backfill is a technique that would assist in the control of potential brine inflows and surface subsidence, and would have a very positive impact on the long term adverse environmental effects associated with surface salt tailings disposal. A centrifuge testing program was designed to evaluate the behaviour of salt tailings as backfill; the effectiveness of salt backfill as a bulkhead used to isolate areas of potential brine inflow and the potential use of salt backfill to control surface subsidence. The testing program was also used to evaluate the creep-consolidation properties of salt backfill and to evaluate the effect of brine inflow and brine infiltration on backfill behaviour. This paper presents the results of the experimental centrifuge testing program and a comparison of results with models tested under I g using an electrohydraulic servo-controlled loading frame (MTS) and a creep consolidation cell. Applicability of the results to practical underground soft rock mining is also discussed.The centrifuge model tests indicated that salt tailings could be applied underground as bulkheads to seal off areas of potential inflow with the additional advantage of controlling room closure and local back instability. Because the applied stresses (1.2 MPa) and fill consolidation were relatively low, the centrifuge simulated bulkhead did not retain all of the inflow brine. At typical field stresses it is expected that the fill would be able to seal off panels with brine inflows. Further testing at higher stresses are suggested to determine the consolidation and stress levels at which the fill would completely retain any potential brine inflow head and positively act as mine bulkhead."

Jan 1, 1994

By D. R. Spears

The U.S. Bureau of Mines has had an ongoing interest in developing new reagent schemes for floating Stillwater, MT, chromite ore. Previous reagent schemes have been unsuccessful in achieving complete separation, primarily because little is known about the surface chemistry of the minerals in this ore. In order to design a rational reagent scheme, a study of the binding of various functional groups (R = -H, -OH, -CO2H, -NH2) on the two components (chromite and forsterite) of the Stillwater chromite was undertaken. Electron Paramagnetic Resonance (EPR) Spectroscopy was used to determine the adsorption isotherm, from a cyclohexane solution, of spin-probes which contained the functional group of interest. This was complemented by studies of the saturation surface coverage of the spin probe on the two minerals. In each case, more sites existed on chromite than forsterite; however, the forsterite sites were more strongly binding for each functional group. The results are discussed in terms of their implications for flotation.

Jan 1, 1994

By Patrick R. Taylor

Sub-micron sized boron carbide powders have been synthesized in a non-transferred arc thermal plasma reactor. Precursors for this synthesis are boric acid or boron oxide powders and methane. The powders produced were characterized in terms of size, shape and purity. Methods to increase the purity of the product were evaluated and included hot water leaching to remove unreacted oxides and controlled temperature, air roasting to remove excess carbon. Theoretical results are also presented on the thermodynamics and mechanisms of the synthesis reactions.

Jan 1, 1994