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By Thomas Pichler

In the past marine mining technology has focused on bulk mining of base metals from polymetallic massive sulfides. This has not been very successful because of the relatively low unit value of these metals and other reasons such as water depth, etc.. The process of gold enrichment in hydrothermal deposits is controlled through five different factors: (1) nature and source of the solution, (2) source of the gold, (3) a mechanism for mobilizing and transporting, (4) a mechanism for deposition, and (5) a mechanism to preserve the deposit. Gold has been identified in marine polymetallic massive sulfides from various locations on the ocean floor (e.g., spreading centers, seamounts) with contents ranging up to 5 ppm Au. This is within the current range of 1.0 to 7.0 ppm gold content which classifies gold ores. The gold appears to have been derived during hydrothermal alteration of the oceanic crust. Until the present there has been little attention to the possibility of mining gold or other precious metals in the marine environment. However, the magnitude of hydrothermal alteration (seawater can penetrates to a depth of 5 km into the oceanic crust) and primary gold contents of the rocks in the pathway of the fluid indicates that major gold deposits must have formed on or in the ocean floor, but they have not been found. To find a big deposit might only take an exploration model exclusively designed for gold exploration on the ocean floor.

Jan 1, 1993

By Collins M. J, Ozberk E

A major advantage of the Sherritt Zinc Pressure Leach Process is the conversion of sulphide sulphur in zinc concentrate to elemental sulphur during pressure leaching. Elemental sulphur can be recovered as a marketable byproduct by flotation of the leach residue, and melting and filtration of the sulphur flotation concentrate. The behaviour and deportment of sulphur during pressure leaching, flotation, and melting and filtration are discussed in this paper using data obtained from the treatment of a wide variety of zinc concentrates in the laboratory miniplant at the Sherritt Research Centre. The quality of the elemental sulphur byproduct and a process for purifying the sulphur are also Presented.

Jan 1, 1993

By Kubo H, Kubita K, Morinara M

A quantitative method for predicting the mechanical properties of zinc alloys is proposed on the basis of the molecular orbital calculation of electronic structures. A new parameter which is the s-orbital energy level, Mk , of alloying elements in zinc was introduced into this method. This Mk parameter correlates with the electronegativity and the atomic radius of elements. The compositional average of this parameter varied linearly with the tensile strength and the hardness of commercial alloys and some alloys developed by Mitsui. This electronic method was very convenient in designing high performance zinc alloys efficiently.

Jan 1, 1993

By M R. Stevens

The Kauri Block (Hauraki Hill) andMatawai Valley epithermal vein systems, near Coromandel township, are hosted by hydrothermally altered Miocene andesites and Mesozoic greywackes of the Coromandel VolcanicZone. The hydrological setting of both geothermal systems was probably that of an andesitic volcanic arc. Two types of veins are recognised: 1. Simple veins composed of fine comb quartz, and 2. Complex (breccia) veins composed of vein fragments of sulphide-bearing, chalcedonic silica cemented by saccharoidal and fine comb quartz.   Pyrite, arsenopyrite, marcasite, and gold form the ore minerals. Both deposits historically exploited hypogene and supergene bonanza gold.   At Hauraki Hill, breccia veins up to 7m wide contain abundant fragments of recrystallised colloform banded-crustiform textured quartz veins ('Golden Cross' style) and were probably major channels for ascending deep mineralising fluids. Alteration assemblages are zoned with the higher elevations of Hauraki Hill-Bunkers Hill characterised by strong kaolinite alteration whereas deeper levels are dominated by illitic clays.   At Matawai, complex veins and hydrothermal breccias pinch and swell, and inflect, within a total width of veining and alteration that exceeds 50 m. The greywacke host rocks are altered to an assemblage of illitesmectite, quartz, chlorite and pyrite although there are pockets of kaolinite.   The proposed genesis of veins and ores in both deposits invokes episodic rapid mixing (quenching) of hot mineralising reservoir fluids with cool acid condensate waters, whilst acidification and increased fO2 triggered gold deposition. These hydrothermal systems heated up during their later stages and at Matawai visible gold was deposited from a late mesothermal stage. The main conclusion is that the northwest CVZ has excellent potential for large gold deposits (= 30 tonnes contained gold).

Jan 1, 1993

By Robert B. Parsons

"The Canadian mining industry is not off to a good start in the 1993/94 budget season. Of the five provinces and territories to table budgets as of March 31, 1993, the industry's scorecard shows: one win, one tie, and three losses.IntroductionBy the end of March, five of Canada's twelve provincial and territorial governments had tabled their 1993/94 budgets. The mining industry is off to a bad start. The industry's scorecard shows one win, one tie, and three losses. Only Newfoundland appears to be paying any attention to the industry's concerns about the impact of taxation on competitiveness. It is particularly disconcerting to see that non-profit based taxes continue to increase, at a time when these taxes are the focus of a united attack by the entire industry.NewfoundlandFirst, the good news. On March 18, 1993, Finance Minister Winston Baker announced the following changes to the province's mining tax regime:"

Jan 1, 1993

By I. H. Gundiler

Although cyanidation has been universally applied in the processing of gold and silver ores, the search for less toxic alternatives continues. Difficulties encountered in processing ores containing oxidized copper minerals and the inherently slow kinetics of cyanidation have generated a renewed interest in thiosulfate leaching. This process, as well as the catalytic effects of copper ion, were well recognized and widely applied towards the end of the past century. In this study, the effects of copper, ammonia, and thiosulfate concentrations on gold dissolution were investigated using the rotating disk technique. Extraction of gold and silver from an oxidized copper-bearing ore was also studied utilizing a statistical experimental design, and these results were displayed in the form of contour plots.

Jan 1, 1993

By Liu Chunpeng

Under an inert atmosphere, the temperature enhancement of nickel bearing pyrrhotite irradiated by microwave was measured with a special metal-sheathed thermocouple and the non-isothermal rate equations were obtained. Under the controlled oxygen potential of the reacting gas in the microwave field, over 90% sulfur contained in the pyrrhotite is converted into elemental sulfur directly, the iron and the nickel are transformed into FeO,, NiO, NiFe,O, and FeSiO,. According to the experimental data the rate of the elemental sulfur produced is in diffusional control and the non-isothermal equation derived is

Jan 1, 1993

By Thomas J. Keefe, O&apos

Results of metal electrodeposition experiments conducted at the University of Brussels and University of Missouri-Rolla over the past few years are reviewed in terms of the relationship and impact on industrial processes. Examples are cited from common electrowinning, electrorefining, or electroplating operations for copper, zinc, nickel, cobalt and silver. The following topics are considered : metallographic structure, crystallographic texture, surface morphology, nucleation and growth, additive monitoring and effects, high current density, substrate related properties including adhesion. The studies were conducted on a variety of scales from laboratory beaker tests to full sized pilot and industrial operating plants.

Jan 1, 1993

By A. Koursaris, Y. N. Turan

This paper reports the results of a literature review carried out on nitrogen-alloyed austenitic stainless steels and their properties. It was found that a large volume of work has been carried out on the subject, particularly with regard to the more common stainless steels such as types 304 and 316. No work appears to have been conducted on the highly alloyed steels such as type 310S. Nitrogen has been found to increase the stability of the austenite in stainless steels and to impart significant improvements in the mechanical and corrosion properties of these alloys. Importantly, nitrogen appears to increase both the ductility and the strength of austenitic stainless steels over a wide range of temperatures.

Jan 1, 1993

By Andrews S. J

Century is a shale hosted zinc, lead, silver deposit developed within gently folded, Proterozoic Lawn Hill Formation shales and siltstones, approximately 250 kilometres north-northwest of Mount Isa, comprising 118 million tonnes of stratiform mineralisation, averaging 10.2 per cent ,,inc, 1.5 per cent lead and 36 grams per tonne silver. The deposit is largely overlain by Cambrian limestone and younger Proterozoic sedimentary rocks, outcropping at only two places. Small discordant lode lead-silver deposits formed the basis of relatively small scale mining activity in the area for almost 100 years, exploration tenement covering the deposit being granted to CRAE exactly 100 years after the first mining leases were pegged in the area in 1887.Stratiform mineralisation occurs within three distinct blocks, bounded by normal faults and the unconformity between Lawn Hill Formation and overlying Cambrian limestones. The Termite Range Fault, a major northwest trending, regional scale fault system occurs adjacent to the northeast deposit boundary, while the Magazine Hill Fault, possibly a component of the east trending Little Range Fault system, forms the southern boundary of the deposit.

Jan 1, 1993

By M. P. Oommen

This paper provides a brief look at a proposed short-longwall for coal, development. The proposed method is an attempt to realize the advantages of longwall mining in deposits that, historically, would only be minable by continuous mining methods. An overview of the proposed layout, development requirements, production rate, ventilation scheme and other associated features is provided. This mining method could help operators in above-drainage seams where minable areas are smaller. It may also have application in areas that are peppered with gas wells and in environmentally sensitive areas which preclude the use of conventional longwalls.

Jan 1, 1993

By Dr. -Ing. Rainer Alles

Introduction Belt conveyors usually run in a straight line. The correct alignment is a major criterion for reliable functioning and optimum running properties. Any misalignment of the conveyor, especially mistracking of the belt, can have many negative effects. As a consequence of this, damage can occur on the belt and conveyor, some material can he thrown off at the edges and serious running problems can arise. In the worst case the belt can come off its supporting structure so that operations are brought to a halt. The absolutely straight alignment of a belt conveyor is actually impossible so that on closer observation every belt conveyor contains more or less sharp curves. Whereas on non-movable conveyors the deviations from the straight can he kept within the range of practical measuring accuracy by careful installation, movable conveyors in surface mining or belt systems in difficult terrain often contain curves that are easy to see with the naked eye. Below ground, too, alignment cannot always achieved to a desirable extent or is changed by geological faults over the years. Despite these unwanted curves, most belt conveyors perform their function reliably. In view of the belt tension, the belt tends to take the easiest path. This in general is the shortest distance between the pulleys on which the belt is tensioned and bent. This means for example that for a curve radius of 10,000 m over a flight of 100 m the greatest deviation from the ideal line is as much as 12 cm. And a figure of this magnitude cannot normally he accepted. In such cases, use is made of guide devices to properly train the belt if it doesn't center itself anyway. If it's possible to control the belt position over such unwanted curves. it can also he expected that the belt tends to follow the desired curved path within certain limits. I'd now like to cite a few examples to illustrate the ways and means of guiding a belt conveyor in curves. Cost-effectiveness The advantages of belt conveyors, in particular for longer conveying distances and mass flows have been known and undisputed for some time. However, there are often obstacles standing in the way of the concept of straight routing. If a belt conveyor is to bypass elevations or existing buildings or to follow the seam of underground deposits or a predetermined path, then substantially tighter radii and longer curves are desirable or necessary.

Jan 1, 1993

By S. M. Khandrika

It is shown that dewatering of fine coal particles (D50 : 21 microns) is enhanced near the point of zero charge. The coal surface is modified by the addition of copper ions and adjusting pH to precipitate surface active metal hydroxy species which promote agglomeration and produce low moisture cakes. Filtration kinetics data are used in calculating filter cake parameters from an integrated form of Darcy's law. The influence of copper ions and pH on filter cake parameters and correlations among them are presented.

Jan 1, 1993

By G. H. Harris

The flotation behavior of two high sulfur coals using a non-ionic surfactant as collector from two series of compounds containing oxygenated functional groups was studied in detail using a 2-liter Denver flotation cell. The performance of these reagents was compared with that of an oily collector, namely dodecane. The results showed that at the same coal recovery, a much lower dosage of these non-ionic surfactants was required as compared with that of dodecane. More import was the performance of these compounds as promoters for oxidized as well as un oxidized coal. Mechanisms of interaction of these compounds with the coal are suggested.

Jan 1, 1993

When a major mineral find has been announced the general perception is that a battle between Aborigines and the mining company involved will inevitably occur.It is a fact that many miners in the past have not had a good relationship with Aborigines because of their indifferent attitudes towards them. They saw no common future and went their particular way. However, attitudes have changed significantly since Noonkanbah and both miners and Aborigines are seeking common ground in order to achieve mutual benefits from the establishment of a mine on or near Aboriginal land. There are many obstacles that both miners and Aborigines need to overcome inordertofindthiscommongroundtoachieveawin/win situation. The obstacles can be found in entrenched ideas and practices which need overhauling, not the least of which emanate from government policy and requirements.Without going into specifics, the Noonkanbah incident during the 1970's where Aborigines and their supporters confronted miners who were ordered by the Western Australian governmentto drill on Aboriginal land, polarized Aborigines and miners. Since this incident, many Aborigines, particularly those in the cities, have had the attitude that mining and Aboriginal culture are in direct conflict. Aboriginal opinion is generally shaped in the larger cities through mass media coverage of the opinions of urban Aborigines and their supporters. Through no fault of their own, these Aborigines were removedfromthe land of their ancestors and have notlived atraditional Aboriginal life-style for a number of generations and most have little knowledge of, nor have had involvement in, traditional Aboriginal lore and culture. For the most part these people live in awestern life-style and few still know their language. They generally have high profiles, often giving viewpoints that are wrongly considered "Aboriginal" and supposedly representing all Aborigines. This group is very different with their thought processes and values from those Aborigines who live on their own traditional lands with a traditional life-style, and practise their age old ceremonies. Their tribal values are based in their relationship with the land, expressed through complex religious ceremonial rites of song, dance and legend. Today this group is very much diminished in numbers but nevertheless in the region of the Gulf of Carpentaria there is a high proportion ofpeople who practise their lore, speak their own languages and pass on traditions to their children. It is well documented in the history of Australia that Aborigines have been decimated in numbers and whole tribes have been wiped out. Certainly in this region the experience has been no different.

Jan 1, 1993

By D. R. Hembree

This paper discusses the mineralogy and metallurgy of the Kuroko-style volcanogenic massive sulfide ores mined at Formosa Exploration Inc. I s Silver Butte Mine located in southwest Oregon. The principle ore type is pyrite + chalcopyrite + sphalerite, while subsidiary pyrite + bornite + sphalerite ore is also mined. The two styles of mineralization have distinctly different metallurgical behaviors and must be treated separately. Selective flotation methods are used to produce copper and zinc concentrates from the first ore type, while bulk concentrates are produced from the bornite ore. Careful mine planning and coordination between the mine and mill are utilized to achieve optimal recoveries.

Jan 1, 1993

A great part of the research on froth flotation of gold ores deals with ores containing gold associated mainly with sulphides, resulting in a largely accepted view that what takes place with sulphides (eg pyrite) in a flotation cell also happens to gold particles. This paper is concerned with the influence of some inorganics (CuSO4, CaO and NaCN) on gold particles flotation, using ethyl or amyl xanthates as collectors. The bench-scale tests were carried out with ground quartz and gold particles mixtures. Some findings stemmed from this study: flotation of the gold particles of size 0.16 mm was efficient adding only frother; larger gold grains were better recovered by the use of stronger collector CuSO4 did not seem to be an activator for gold; the addition of NaCN up to 200 g/t or CaO up to 2000 g/t did not depress the gold grains when amyl xanthate was used as collector although with ethyl xanthate the gold depression was verified.

Jan 1, 1993

By Robert B. Parsons

"Ontario and Quebec taxpayers will have to dig deeper into their pockets to pay more tax, according to budget papers tabled in these provinces in May 1993. Individuals will be hardest hit, but corporations will also have to ante up in the face of higher rates, reduced deductions, and new taxes.Up, up, and away...Somewhere in the bleak picture of the 1993 Quebec and Ontario budgets, there is a bit of good news for the mining industry.Careful scrutiny reveals:• Ontario will correct a capital tax provision which inadvertently penalizes flow through share issuers;• Quebec's flow-through incentives will be extended to December 31, 1995; and • both Quebec and Ontario will allow deductions for mine site reclamation payments.The industry may also find some comfort in the fact that Ontario's new corporate minimum tax will be profit-based (unlike the federal minimum tax), so that non-producers should not face a liability for this tax. There is some concern though, about Quebec's announcement that the refundable credit mechanism in the Mining Duties Act will be reviewed."

Jan 1, 1993

By William J. Gray

The Roof Control Division of MSHA's Pittsburgh Safety and Health Technology Center has been conducting a program to evaluate methods employed by the U.S. coal mining industry during recovery of longwall faces. The objective of this effort is to provide information on safe and efficient roof control methods currently being used to recover longwall faces. In addition to a literature review and extensive contacts with MSHA and industry personnel, 14 mines were visited to observe firsthand various aspects of longwall recovery. It is hoped that the dissemination of this information will aid in the prevention of accidents and a reduction in costly downtime during recovery.

Jan 1, 1993

By A. Henchiri, G. A. Gruber

INTRODUCTION Phosphatic resources may be quantified in terms of ore tons and phosphate analyses; however, to quantify phosphate reserves it is necessary to estimate the tons and quality of phosphate rock that can be extracted from the ore. The yield and grade of phosphate rock that can recovered from sedimentary phosphate deposits are usually difficult to estimate because of variations in stratigraphy and/or mineralogy. Prospecting phosphorite ores for purposes of estimating reserves and preparing mine plans requires considerably more effort than defining ore thickness and P205 content. In Florida, for example, it is standard practice to prospect by core drilling and to subject each strata (split) to beneficiation testing, and to perform detailed chemical analyses on the beneficiated products from each strata. For a completed drilling pattern the area of influence of each hole is 2.5 acres. The number of strata per drill hole typically varies from two to five, and thus complete prospecting of a 40acre tract requires drilling 16 core holes and beneficiation testing of about 48 ore samples. Florida practice is not appropriate for all phosphorite deposits. Functional drill rigs and trained drillers may not be readily available. Water for core drilling may be unavailable and the characteristics of either the overburden or ore may require careful attention and excessive cost to obtain representative core samples. Alternate ore sampling methods include auger drilling, rotary drilling to obtain cuttings, and the excavation of trenches, pits, and shafts. Drill cuttings samples are generally the least expensive to obtain, but they are usually unsuitable for beneficiation testing because of particle size reduction during drilling. Ore samples from surface trenches and pits are expensive and may not be representative of deeper ore. Ore samples from shafts are the most expensive to obtain, but if taken properly they are reliable for use in laboratory and pilot plant testing. Regardless of the prospecting technique used, reliable estimates of the yield and grade of phosphate rock that can be extracted from an ore deposit are required: • to justify capital expenditures for a new mine • for mine design and mine planning • for beneficiation plant design • for production forecasts, quality control, and marketing. This paper describes models that predict the beneficiation response of ores from three phosphate ore deposits. The purpose of these models is to obtain maximum utilization of available prospect data with the least cost. ORE DEPOSITS Simple beneficiation models have been developed for ores from three sedimentary phosphate deposits around the Mediterranean area. The first deposit, herein described as "A" ore, is located north of the Mediterranean Sea. The second deposit, designated as "B" ore, is located east of the Mediterranean Sea, while the third deposit, "C" ore, is located south of the Mediterranean Sea. Ore "C" is from the Sra Ouertane deposit in northwestern Tunisia.

Jan 1, 1993