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By S. Yuan

Oxygen ion conducting yttria-stabilized zirconia (YSZ) tube was used to remove oxygen from molten Cu at 1373K. Outer surface of the tube was in contact with the melt and the inner surface containing a thin layer of porous Ni-ZrO2 cermet electrode was in contact with a reducing gas. The migration of oxygen species (O2-) from the Cu melt through the YSZ tube is accompanied by an equal and opposite flux of electrons maintaining electroneutrality. Without applying an external EMF, the fluxes are maximized by short circuiting the melt with the cermet electrode. For efficient oxygen removal, the YSZ tube must be thin, contact resistances should be negligible, and the electrodes must be porous and cover the entire electrolyte surface for charge transfer. This refining process is environmentally sound, can use reducing gases such as H2, CH4 and CO without running the risk of increasing H or C content of the melt.

Jan 1, 1993

By Ranklin W. J, Swinbourne D. R

Lead blast furnace slags contain typically 10 - 20 mass per cent Zn. The zinc can be recovered by slag fuming, in which a powdered coal/air mixture is injected into a molten slag bath. Volatilised zinc is recovered as zinc oxide from the gas and processed hydrometallurgically to produce zinc metal. The ISASMELT continuous lead smelting process in operation at Mt Isa produces a slag containing about 12 per cent Zn which is currently granulated and stockpiled. This slag could flow to a further bath-smelting reactor for continuous zinc fuming. Rather than collecting the zinc as fume from such a process, one option would be to recover it using a lead splash condenser. The success of this operation would depend on the composition of the gas produced, in particular the concentrations of gases capable of reoxidising zinc vapour, viz, carbon dioxide and water vapour. The aim of this investigation was to determine the smelting conditions for a bath-smelting process such as ISASMELT or SIROSMELT which would produce a gas similar in composition to that from an Imperial Smelting Furnace by thermodynamic modelling of the process using the CSIRO Thermochemistry System. It was found that such a gas could be produced if coal injection and oxygen enrichment of the combustion air to at least 40 per cent 02 were used. However, the off-take gases must be conditioned by addition of methane to reduce the water vapour content to acceptable levels. An addition rate of ten per cent of the off-gas flowrate was found to be adequate. Addition of methane to the off-gas had the added advantage of cooling the gas from the bath temperature to a temperature suitable for normal lead splash condenser operation.

Jan 1, 1993

By R. E. Gertsch

A mobile-modular carbon adsorption mill design and operation for small to medium sized heap leach precious metal mines is presented. In the mobile-modular strategy, charcoal columns with adsorbed metal move from small strategically located carbon adsorption loading stations to a central stripping facility and back. The design has many advantages: 1) It scales-up from pilot plant to full production. 2) It has low capital requirements. 3) Operational costs are competitive with other systems. 4) Mill production can react quickly to changes in ore grade or property area. 5) The solution circuits are simple and easy to maintain. 6) Charcoal damage is reduced.

Jan 1, 1993

By Raja V. Ramani

The importance of adequate mine ventilation for good health and safety conditions has been recognized since miners first ventured underground. All over the world, governmental actions on mine health and safety are directly connected with mine atmospheric environments, their assessment and control. These governmental actions have been, and continue to be, motivated by the repeated experience that potential threats from inadequate control can evolve, either suddenly or in the long-term, into unpleasant reality, with catastrophic health and safety consequences. These governmental actions are also an indication of the remarkable professional progress being made in the field of mine ventilation. Surely, no developed country allows underground mines to operate without strong measures for the control of ventilation under legislation specific to the mining industry. In the United States, the federal government's responsibility for mine safety has evolved over the years through a series of legislative actions beginning in 1865 and continuing through 1910, 1941, 1947 and 1952. The passage of the Federal Metal and Nonmetallic Mine Safety Act of 1966 (the 1966 Metal Act), the Federal Coal Mine Health and Safety Act of 1969 (the 1969 Coal Act) and the Federal Mine Safety and Health Amendments Act of 1977 (the 1977 Mine Act) are the most important milestones in this long legislative history. The 1977 Mine Act adopted many of the stronger features of the Occupational Health and Safety Act of 1970, perhaps the most significant piece of legislation on workers' occupational health and safety in US history. It is worthwhile to ask, "How far has the United States come in mine ventilation since the enactment of the 1969 Coal Mine Health and Safety Act?" This Act and its associated regulations defined in great specificity many standards for healthful and safe operation of a mine and, in some cases, what constitutes good ventilation practice. Since 1969, the frequency and severity of disaster-type events in US coal mines has decreased markedly. A primary reason for this achievement is the strength of the Coal Mine Health and Safety Act's regulatory features in such areas as methane concentration control, dust control, intrinsic safety and explosion-proof enclosures, minimum air quantity and quality standards and air distribution and escapeway provisions. These requirements greatly influenced mine ventilation planning, engineering and practice, leading to increasingly safe working conditions.

Jan 1, 1993

By Animesh Jha

Univariant diagrams are constructed for the reduction of nickel and cobalt oxide and sulphide minerals. The results from the carbothermic and hydrogen reduction of sulphide minerals are compared. The importance role of lime and calcium sulphate in controlling the emission of sulphurous- gases during reduction reaction is also explained. The mechanism of carbothermic reduction of nickel sulphide is explained by examining the sulphur exchange and reduction reactions. The phase equilibrium relationships that determine the formation of multicomponent liquid are characterised. Also the governing equilibria for inert atmosphere calcination- roasting of nickel and cobalt sulphide minerals are also described for the metallization of nickel and cobalt.

Jan 1, 1993

By H. Peter Knudsen

In most open pit gold mines, ore-waste selection is based on estimates made from blasthole samples. These estimates frequently are biased. This paper focuses on the source of the conditional bias. While it is true that high grades and "outliers" can induce a bias, they may not be the only reason for the persistent bias seen at many mines. In this paper, it is shown that the poor blasthole sampling can cause a conditional bias in the estimates.

Jan 1, 1993

By Steven A. Whittle, Robert E. Cook

Years ago, personal computers (PC) were pricey devices destined for who knows where in the process industry. Now their use runs the gamut from low end data acquisition systems to high performance windows into the process area. Their applications range from CAD, CAM, CIM, and CAE to factory floor scheduling, process planning QC, facility management, cell control, and publishing. This discussion traces the evolution of a zinc plant's control automation program beginning with a PC as an operator interface and migrating to higher level work stations. Included in this paper will be a discussion of an Open Industrial System and the role PCs have played in this facility.

Jan 1, 1993

By Stavros A. Argyropoulos

Exothermic mass transfer takes place in various areas involving metallic systems, ranging from liquid metal processing operations to the growth of thin films in microelectronics. The formation of intermetallic compounds plays an important role in the exothermic mass transfer of metallic systems. Two types of exothermicity are identified , namely , Microexothermicity and Macroexothermicity. The former is encountered when small amounts of metals are mixed, while the latter is exhibited when a solid metal in a lump form is added into liquid metal. In this paper two types of exothermic mass transfer in metallic systems will be presented and reviewed. Mathematical modelling work for these types of exothermic mass transfer will be analyzed.

Jan 1, 1993

By Ian Misich

A research programme has been undertaken to evaluate and predict the effect of total extraction of coal by underground methods on the superimposed strata, aquifer systems and ground surface in the Collie Basin. Western Australia. The research work has integrated comprehensive field monitoring of surface and subsurface subsidence with empirical, analytical and physical modelling in an effort to develop an effective predictive tool which can be used in all mining scenarios. Early results indicate that although each method has certain limitations, this approach has enabled the researchers to develop a very good understanding of the subsidence mechanisms from the mine panel through to the surface in the weak, water saturated sediments in the Collie Basin. Given that both subsurface and surface subsidence characteristics have tied in well, greater confidence can be held for predictions made by representative models.

Jan 1, 1993

By James S. E

Financial risk of environmental problems is the key to many important business decisions within the mining industry. Massive uncertainty makes it difficult to choose a strategy for managing environmental problems to reduce corporate financial exposure to environmental impairment. A correct and practical method exists to clarify the risks and help make decisions. A case study on an insurance problem illustrates the method.The approach used is to translate existing data on environmental problems into probabilistic expressions of financial risk, and organise the expressions to reveal alternative solution strategies for the insurance problem.

Jan 1, 1993

By L. M. Petrie, D. C. Marozas, S. E. Paulson

The US Bureau of Mines (Bureau) is conducting research to evaluate the potential for developing an in situ leach mining process that will selectively extract manganese from oxide ores, leaving gangue relatively undisturbed. To accomplish this, a geochemical approach based on deposit-specific information, such as mineralogy and geology, is used to constrain the operating parameters of the system. Among the studies being conducted are: • leaching experiments to define reaction mechanisms and kinetics, • detailed petrologic characterization at the microscopic scale to assess manganese distribution and leaching efficiencies, • deposit characterization and evaluation, and • development of potential manganese recovery schemes. Data from these studies are being used to develop engineering design information for an in situ mining process. Specific details of the Bureau's research project are discussed, including results obtained to date.

Jan 1, 1993

By Francis O. Otuonye

The results of an ongoing study to determine the response of full contact rock bolts to shock waves due to blasting are presented. A time domain systems modeling and analysis technique was used to identify the axial and bending response of the bolt when explosives charges are detonated at close-in distances.

Jan 1, 1993

By Douglas Brittsan

This paper presents pile tension and compression load test results for the Southern Freeway Viaduct (North) pile load test site. The testing program represents a collaboration between California Department of Transportation (Caltrans), Federal Highways Administration (FHWA), and a group of pile manufacturers and construction firms. The participating manufacturers included Fundex, Halliburton, Monotube, and Nicholson, with each firm supplying proprietary pile systems. The field test program measured and will allow the direct comparison of the tensile and compressive capacity of nine common and proprietary pile systems installed in nearly identical soil conditions. Data reported here-in details pile compression and tensile load-deformation measured at the pile head. Cursory data regarding pile installation details are included to aid in data interpretation.

Jan 1, 1993

By K. V. K. Prasad

Stochastic simulation has been routinely used for performing risk and sensitivity analyses in a variety of fields. The commonly used means of generating the simulations has been the Monte Carlo approach which usually employs a Simple Random Sampling (SRS) scheme of the variable distributions. This method is prone to sample clustering and requires a large number of samples to represent the distribution faith-fully. This can become problematic for simulating complex processes where it is impossible to run an arbitrarily large number of replicate simulations. The Latin Hypercube Sampling (LHS) method uses a stratified sampling approach which assures representation of the input distributions for any given number of samples. In this paper the LHS and SRS approaches are compared using a petroleum resource estimation example.

Jan 1, 1993

By Hinkley JT, Smitham JB, Nicol SK

Historical investigations of mineral flotation have highlighted the many factors which affect flotation. Some of these are related to the mineral, its degree of liberation (however defined), solution chemistry and flotation reagents. The complexity of the interactions between these factors often leads to uncertainty over whether the final grade/recovery results obtained in either laboratory or pilot scale tests are in fact the maximum recovery at a specific grade. The reason for this is that there has not previously been a general technique for establishing the floatability of an ore. This study describes the further development of the 'tree' flotation technique for minerals other than coal, and in particular its application to iron ores. Oxides have been chosen as a system of intermediate complexity between the simple coal system and sulphide minerals to illustrate the principles and develop the concepts. The 'tree' flotation procedure consists of the progressive flotation to completion of successive froth products, followed by reflotation to remove entrained material. It therefore represents an 'equilibrium' approach to floatability rather than a kinetic approach. By ordering the various products and tails in order of increasing grade, a cumulative curve of grade and recovery can be constructed against which an isolated batch or plant result on the same ore can be compared. In this investigation, a Jaspilitic iron ore was tested at various grind sizes to determine the 'best' flotation grade-recovery that could be obtained with a given set of reagent conditions. The separation characteristics of a process are best measured on a system which contains particles which behave as 'middlings' with respect to the process in question. For this reason a natural ore was chosen in preference to model systems in order to relate more readily to plant situations.

Jan 1, 1993

Experimental Mine, Val d'Or, Quebec, Experiments on the ignition of sulphide dust clouds by explosives have been conducted in a 1 m3 explosion chamber. The explosives tested are ANFO, emulsion, aluminized emulsion and Detasheet. By controlling the composition of the ANFO and the emulsion explosive the oxygen balance could be changed in order to identify the dominant factors in the ignition of sulphide dust clouds by explosives. Experimental results, combined with theoretical calculations, show that the temperature of the detonation products is the most important parameter in the ignition of the dust cloud while the combustible detonation products are of secondary importance in the case of non-aluminized mining explosives. In the case of aluminized explosives and explosives having very negative oxygen balance the ignition of the dust cloud is assisted by the large amount of combustible detonation products.

Jan 1, 1993

By J. S. Freer

Integrated Environmental Management (IEM) involves the integration of environmental factors Into project planning, execution, and operation from inception to final closure and after-care. The objective IS to develop the most cost effective, environmentally acceptable manner in which the project can proceed, and to gain the approval of the authorities and the support of the interested and affected parties (I & APs) for the benefit of the developer, the economy, the people of South Africa and the environment on which they depend.

Jan 1, 1993

By Tom W. Gonzales

Magma Metals Company commissioned a 3000 tpd Outokumpu flash smelting furnace in July 1988. Through September 1992 the PSP has smelted a first campaign record 4.1 million tons of concentrate. This paper discusses modifications made to the original process equipment to overcome design flaws as well as future design changes currently under consideration.

Jan 1, 1993

By Clyde DeRossett

Surface fractures, sometimes of significant size, are observed in eastern Kentucky over high extraction areas. Field observations were correlated with mine maps and a regional subsidence prediction computer model. The opening of large fractures is attributed to the presence of a pre-mining joint system, which exists near outcrop in the eroded Appalachian plateau. Lithological composition of the overburden influences the process of fracture opening. No correlation was found between the areas of the predicted maximum horizontal extensions and the actual location of fractures. In this paper a mechanism of fracture formation as a result of the high extraction mining is presented, with recommendations for mine planning to minimize surface damage.

Jan 1, 1993

By Merwin Bernstein

Peru has been an important source of metals since Aug. 29, 1533. On that day Francisco Pizarro took charge of the 24 t (772,000 oz) of gold and silver that constituted Atahualpa’s ransom. At today’s prices, the value of that booty ranges between $100 and $150 million, depending on the proportion of gold to silver. Since then, Peru’s silver and gold production has been legendary. Current mine production Most of Peru’s metals are mined from the Andes Mountains and its foot-hills. The Andes run the length of the country parallel to the Pacific coastline from Ecuador to Chile, a distance of nearly 3000 km (I 875 miles). They are about 300 km (187 miles) wide and much of the range is more than 3000 m (9900 ft) in elevation. High plateaus (altiplanos) occupy a large part of the range. Both flanks are rutted by large valleys and canyons. Many of these peaks are prodigious. which make road building expensive and adds to the cost of mining.

Jan 1, 1993