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By T. T. Chen

Raw anode slimes consisting primarily of PbSO4, AgCuSe, Cu3Se2, Cu2-x Se, Cu2O, CuSO4.5H2O, Sn arsenate and Sb-Bi-As oxide are batch-leached with electrolyte-O2 to dissolve Cu. During this process, Cu2O and CuSO4.5H2O are solubilized and the Cu in the selenides is leached with the formation of Ag2Se and Se. A small amount of Cu remains in the Ag2Se, Sn arsenate and Sb-Bi-As oxide. The decopperized slimes are repulped in Na2CO3 solution to convert most of the PbSO4 to NaPb2(CO3)2(OH). The Sn arsenate and Sb-Bi-As oxide partly react, but the Ag2Se is not significantly affected by the Na2CO3 solution. The NaPb2(CO3)2(OH) intermediate phase is dissolved in acetic acid to leave a final product consisting of Ag2Se, Se, Sn arsenate and Sb-Bi-As oxide, together with small amounts of PbSO4, NaPb2(CO3)2(OH) and various gangue constituents.

Jan 1, 1993

By M. A. Trevits

Methane gas is an ever-present problem facing the underground coal mining industry. Mine operators are mandated by law to maintain safe concentrations of methane gas within the mine environment. Ventilation is used by all mine operators to reduce gas concentrations. When gas emissions are such that ventilation alone cannot control the gas, methane drainage methods must be applied. In the 1970's, there was a concern that unprecedented gas emissions would be experienced as mine operators began new developments in the deep and gassy Blue Creek and Pocahontas No. 3 Coalbeds. Such concern was well founded as significant gas volumes are being emitted as these mining operations mature. In 1971, the O.S. Bureau of Mines began to tabulate and track the change in mine emissions. These data were extracted from the underground coal mine quarterly air quality-quantity inspections performed by the Mine Safety and Health Administration. At that time, approximately 6,560 Mm Id (231.7 MMcfd) of gas were emitted from 430 underground coal mines. It was determined however, that the mines emitting less than 2,832 m Id (100 Mcfd) contributed only 2.1 percent of the total daily gas flow. In 1988, underground coal mines emitted 8350 Mm Id (294.9 MMcfd) from 487 mines. This report evaluates the changing nature of U.S. mine gas emissions over the last 18 years.

Jan 1, 1993

By Jacqueline A. McClaskey

The U.S. Bureau of Mines Information and Analysis Directorate collects worldwide data on virtually every commercially important non fuel mineral commodity. These data form the base for tracking and assessing the health of the minerals sector of the U.S. economy. The Bureau's data collection activity was instituted by the 47th Congress in an appropriations act of August 7, 1882 (22 Stat. 329), which placed the collection of mineral statistics on an annual basis. The most recent authority for the U.S. Bureau of Mines survey activity is the National Materials and Minerals Policy, Research and Development Act of 1980 (Public Law 96-479, 96th Congress). This act strengthens protection for proprietary data provided to the U.S. Department of the Interior by persons or firms engaged in any phase of mineral or mineral-material production or consumption.

Jan 1, 1993

By M. J. Virnig, Marc Le Vier, Rong Yu Wan, Jan D. Miller

Although most gold production from primary resources is achieved by cyanidation, many research activities have focused on alternative processes using noncyanide lixiviants. Such research has been prompted by environmental concerns and problems associated with the processing of refractory gold ores. Numerous research projects have been conducted to search for a noncyanide hydrometallurgical process for gold extraction. In this paper, a technical review of gold recovery from noncyanide solutions is presented, and new results are reported. Gold recovery techniques that are considered include activated carbon adsorption, cementation, solvent extraction, ion exchange, and reduction-precipitation.

Jan 1, 1993

The continuous casting of zinc alloys has been of fundamental importance for many years in the production of a number of products, including sheet for architectural applications, battery cans for dry cells and wire for metallising. The intrinsic benefits of continuous casting, including efficiency and high tonnage capability, uniformity of metallurgical structure and properties, and absence of voids and other defects, have contributed to the success of these products. Less well known, but of growing importance, is the more recent application of continuous casting technology to the production of zinc alloy bar stock products, including bearing stock, machining bar stock, forging stock and cathodic protection anodes. A wide range of zinc alloys are now continuously cast in a variety of cross sectional shapes and sizes to suit the diverse characteristics of these products. Of particular significance are the introduction of hollow zinc-aluminum bearing stock, and the availability of zinc alloy machining bar stock for hydraulic applications and for producing prototypes of zinc alloy pressure die castings. In addition to the traditional benefits, continuous casting provides special properties which are important in the application of these bar stock products. The list of successful applications of continuously cast zinc alloy bar stock is growing rapidly, and the market potential for resultant new zinc applications appears to be significant.

Jan 1, 1993

By Michael H. Leon, John A. Organiscak

Controlling worker dust exposure on longwall mining systems is difficult because the working face area serves as an immediate return during the mining cycle and the amount of airborne dust generated is directly related to production. Since improvements in longwall mining technology have significantly boosted production levels, additional technology is needed to control the airborne respirable dust generated at present and future production levels. One concept to reduce longwall worker's dust exposure is to maintain two splits of air at the face -- a clean intake split in the workers walkway, and a return (dusty) split over the face conveyor. The U. S. Bureau of Mines has recently investigated a concept to overcome the visibility handicap of face partitions by utilizing a permeable polyester mesh. The mesh material was anticipated to provide adequate air-splitting capabilities as long as the pressure differential between the face and worker walkway was minimal. Initial testing of this concept at the Bureau's Lake Lynn Laboratory showed that notable reductions could be achieved with a 1/8 in (3.18 mm) and 1/16 in (1.59 mm) mesh opening size. Dust reductions at 100 ft (30.5 m) and 200 ft (61.0 m) downstream of source were 58 and 36 pct, respectively, for the 1/8 in mesh and 79 and 55 pct, respectively for the 1/16 in mesh. Longwall application of the 1/8 in mesh showed similar results to the Lake Lynn Laboratory tests. A flame retardant mesh was used underground with portable lighting mounted on the shearing machine for face side lighting.

Jan 1, 1993

By C. A. Garcia

The solvent extraction of gold cyanide from alkaline cyanide solutions with monosubstituted guanidines, bis disubstituted guanidines and a tetrasubstituted guanidine was investigated. The guanidine functional group is protonated in alkaline solution and the guanidinium cation is stabilized so that the aurocyanide anion can be extracted even at -pH 12 if an appropriate carrier is used. Typical aprotic carriers including both aliphatic and aromatic solvents limit gold extraction by guanidines to pH 10; whereas the presence of an alcohol extends gold extraction to pH 12. UV spectroscopy suggests that the alcohol facilitates protonation of the guanidines, stabilizes the guanidinium cation, and facilitates gold extraction at high pH.

Jan 1, 1993

Among countries afflicted with insLantaneous outbursts of coal and gas, Australia is noteworthy because of lesser disturbances of the seams and of the occurrence of CO2 in the seam gas from place to place. Research sLarted with the 1954 occurrences at Collinsville and Metropolitan Collieries leading to early publications reviewing the problem, describing occurrences and assessing variations in proneness factors in the two affected coal basins.The basic requirements for proneness include coals of high gas sorptive capacity, high ground stress, use of a mining method which provides higher stress concentrations and limits emission of seam gas, including high rates of advance. With CO2 in the seam gas proneness is greater.The mechanism is complex and not fully understood, but involves the coal, the roof, the floor, the gas, the mine opening, the ventilation, the kind of work and the rate of work. Geological disturbances such as faults and dykes increase proneness and tend to localise occurrences. On-occurrence of outbursts in some mines is difficult to explain.Outbursts are seen as a continuing threat to modem deep Australian mining of high rank coal.The simplest contributory factor to reduce is gassiness - despite the low permeability of outbursting coals - and present practices are showing promise. The greatest challenges for the future are partial degasification to below a known threshold figure and confirmation that this reduction is achieved and identification of anomalous geological structures ahead, the most likely locations for instantaneous outbursts to occur. The advances made to date give promise of a future with reducing experiences of uncontrolled instantaneous outbursts. For the Bulli seam particularly, working to achieve prediction and prevention is most urgent.

Jan 1, 1993

By L. E. Bowman

Efficient filtration of fine kaolin particles plays a crucial role in processing of raw kaolin to a marketable product. Oftentimes, filtration Is the rate controlling step of the whole process. As a consequence, plant production is dependent, to a great extent, on the rates being achieved In filtration. In order to alleviate the bottleneck in production, Nalco Chemical Company initiated a reagent development program to chemically enhance the performance of the filtration units. Filler aids of different classes were synthesized for evaluation. These include reagents whose primary mode of functionality were: coagulation, flocculation, thickening, and combinations of the preceding. All reagents that were synthesized and tested were listed under the appropriate Food and Drug Administration sections of the Code of Federal Regulations. This paper discusses the development and application of a new reagent that Improves the filter production rate with minimal Impact on filter solids. The results of laboratory filter studies along with plant data are presented and discussed. Plant data indicate that this reagent is capable of increasing production rates by as much as 35% on various clays of coarse particles to the finest fractions, as well as clays that are calcined. The reagent's Impact on solids content, re-slurrying characteristics, Brookfield and Hercules viscosity, and drying is within the standards set by plants who have evaluated and now use this product.

Jan 1, 1993

By R. V. Ramani, R. Natarajan, A. Bhattacherjee

Industries in general, and mining in particular, have become safer than ever before. However, there is a need to increase the search for the causes of mining work-related injuries and to contribute to their reduction, as required, through job redesign, work procedures and worker training. Mine accident and hazard control must be practiced in a manner consistent with the overall objectives of the mine management, which include the optimum allocation and effective utilization of the resources. The purposes of this paper are to: • present a set of analytical tools to analyze injury experience data. • apply these tools on a case study example, • discuss the results of the case study, and • identify the application limitations and the future research needs.

Jan 1, 1993

By C. C. Huang

Rare earth compounds, such as samarium-cobalt compounds and neodymium-icon compounds, are being used more often for the manufacture of permanent magnets, because these materials permit the production of permanent magnets with higher magnetic energy potential than the conventional ferrite magnets. Especially, the recent rapid developments in the field of electronics and electro-technology have demanded an increased production of rare earth magnets. Unlike ferrite, which is typically produced by a wet process, rare earths can be ground and classified either in a wet or dry process. In the past, batch ball mills, through-pass ball mills in circuit with air classifiers, and conventional jet mills were primarily employed for the dry processing. These methods, however, have suffered from the problems, for example, wear and contamination, low product quality In particle size distribution, difficult to adopt inert-gas operation, and high specific energy consumption. In this report, dry processing of rare earth powders will be presented, especially ultrafine grinding with fluidized bed jet mill.

Jan 1, 1993

By Bradford F. Townsend, Robin B. Dill, Richard M. Croswell

Innovative geotechnical construction techniques were used to construct three pedestrian tunnels under a building slab-on-grade to allow utilization of basement space for manufacturing. Tunnels were constructed using mining techniques through granular fill soils less than three feet below on-going sensitive manufacturing operations. Project design consisted of jet grout underpinning of exterior foundation walls and an arch of drilled-in grouted horizontal dowels for soil pre-support to limit ground movements during excavation. Permanent tunnel lining consisted of arched steel rib sets and invert struts supported on precast footings encased in cast-in-place concrete slab and side walls and a gunite arch.

Jan 1, 1993

By Bishop D. J

The Imperial Smelting Process for the simultaneous production of zinc and lead is probably regarded by the ecologist as a necessary evil with the benefits of its products marginally outweighing the adverse effects of its operation. The purpose of the paper is to examine the environmental impact of the process and to provide information which will demonstrate that the process has considerable indirect environmental benefits and that success is being achieved in reducing direct pollution of the environment by the process. About 12 per cent of the world's zinc and seven per cent of its lead is produced by the process. This proportion will increase with the construction of a new smelter in China. After a brief description of the process the paper considers one of its principal advantages, its ability to treat bulk concentrates. The production of these at the mine can have a number of environmental benefits. Less comminution may be required to separate the metals from the gangue than is needed to separate them from each other; recoveries can be improved in flotation resulting in cleaner tailings dams, less power demand and reduced consumption of potentially hazardous reagents. Simplification of mining and above ground ore handling may also give significant benefits . The process is a considerable consumer of secondary materials such as galvanisers' ashes, copper smelter dusts and materials containing zinc and lead derived from steel plant dusts. The majority of these materials are fed to the blast furnace after hot briquetting. The consumption of secondary materials is a considerable environmental benefit since otherwise they would require to be dumped in secure land-fill sites. The operation of the process itself continues to be subjected to increasingly stringent environmental standards of which examples are provided. Details are provided of lead emissions at Avonmouth showing considerable success in reducing these while increasing production. The slag from the process continues to find many useful applications.

Jan 1, 1993

By E. Arioglu

Discussion by E. Arioglu Y. Luo and S.S. Peng are to be congratulated for their outstanding paper providing new results from surface subsidence monitoring over longwall panels under different conditions. This writer found the authors' paper very interesting. In reference to this paper, the following contributions are offered: • In the paper, the maximum possible subsidence [(ASmax)] induced by chain pillar convergence has been related to a parameter (h/1- p) by linear regression. (Notations are expressed in this discussion's Fig. 1 (b).) It is a well-known fact that in a goaf the roof lowers onto broken material that gradually compacts. Then the physical behavior of goat may closely follow the compaction characteristics of broken materials. In light of this assumption, a mathematical means (Fig. 1(a)) of defining the expected compaction (i.e. surface subsidence) represents an exponential expression between [ASmax/m vs. h/1-p]. This is based on Luo and Peng's field observations from the Appalachian, Illinois and Alabama coal fields. (The coefficient of regression "r" under consideration was computed to be 0.883). • According to Wardell's (1969) findings for board and pillar mining, the maximum possible subsidence can be expressed in terms of maximum pillar loading (depth, ratio of extraction) and the height-to-width ratio of the pillars left. Using Luo and Peng's 1991 results, this writer discovered a regression equation between the above-mentioned factors. As displayed in Fig. 1(b), the functional expression approximates as closely as possible the observed subsidence data. It may be noted here that Wardell's approach (1969) can be successfully utilized for longwall panels having chain pillars. Reference Wardell, K., 1969, "Ground surface and control," Mining Congress Journal, January, pp. 1-7.

Jan 1, 1993

By P. R. A. Andrews, R. K. Collings

"There are more than 300 occurrences of fluorite in Canada. Deposits of economic significance, however, are confined to Newfoundland and Nova Scotia in eastern Canada, Ontario in central Canada, and British Columbia in western Canada. Fluorite has been mined and processed intermittently in Ontario and Newfoundland until November 1990, when Canada's only producer Minworth Ltd., a U.K. based company, with a mine and concentrator near St. Lawrence on the Burin Peninsula, Newfoundland, closed its operation.CANMET has processed ore samples from each of the major mineralized areas, and thirty-one studies were conducted between 1920and 1970. A summary of the important aspects of the various testwork studies is presented. The production of acid-grade fluorite was possible by flotation, and ceramic-grade, by flotation and gravity concentration methods. Gravity concentration methods included heavy media separation, jigging and tabling. Flotation was by direct and reverse techniques; associated minerals, quartz, calcite, barite, etc. were depressed by a variety of depressants. The function of the major depressants is discussed briefly. The various uses offluorite which include hydrofluoric acid, chlorofluorocarbons, aluminum production, petroleum alkylation, fluxing and ceramic applications etc. are discussed briefly."

Jan 1, 1993

By Gregory M. Molinda

The U.S. Bureau of Mines has developed a rock mass classification system for coal mine roof control. The Coal Mine Roof Rating System (CMRR) evaluates the structural competence of mine roof using simple field tests and observations obtained from underground exposures in roof falls or overcasts. The basis of the WRR is a weighing system which converts descriptive geologic roof rock data to a numerical value, facilitating its use in engineering design. A full suite of data collection and hand calculation sheets accompanies the CHRR A data base is currently being collected from all major coal basins in the United States to validate the CMW. To date, CHRR values are available from 96 roof exposures in 59 coal mines representing these basins. The system can be used to help solve many practical ground control problems, including longwall gate road design, roof support selection, and decisions regarding extended cut length.

Jan 1, 1993

By Fathi Habashi

While it is commonly known that the precious metals and to some extent copper occur in the native state, it is less known that mercury, iron, nickel, and cobalt do occur also in the native state; the last three (Fe, Ni, and Co) usually occur together in form of an alloy. The particle size varies greatly from less than 10 microns (gold and mercury) to about 400 tons boulders (copper).

Jan 1, 1993

By Greg Barfoot, Alex Harrison

Conveyors with multiple drive pulleys of the same diameter and wrap, driven by identical motors through gearboxes of the same ratio, consume different powers. The fundamental issues related to this problem hinge around the drive pulley co- efficient of friction and the intermediate tension. Some basic design concepts will be presented with reference to validity and applicability. The paper will describe some experimental results obtained from multiple drive conveyors in which the drives are spatially separated. The dynamics of tripper drive and linear booster drive systems are overviewed with reference t

Jan 1, 1993

Massive sulfides discovered in 1991 and further explored in 1993 in the eastern Manus back-arc basin, north of Papua New Guinea, represent one of the few modem seafloor occurrences known to he associated solely with highly siliceous volcanic rocks. As such they are very close analogs of ancient volcanogenic massive sulfide (VMS) ore deposits, and hence an excellent natural laboratory for developing new approaches for land-based VMS exploration. The Manus Basin lies between the active New Britain subduction zone and volcanic arc to its south and the opposed inactive Manus subduction trench to its north. It is being extended in a complex pattern of short neovolcanic zones and oblique transform faults. In its western sector, relatively mature back-arc spreading has created predominantly basaltic segments with characteristics and mineralization generally similar to those of mid- ocean ridges. At its far east, however, the basin is distinctly immature. The East Manus Volcanic Zone lies between two members of the Manus transform set, and is an en-echelon series of neovolcanic edifices constructed on extensionally thinned island arc crust formed during the earlier manus subduction episode. Individual edifices range from predominantly basaltic to predominantly dacitic in composition. Two of the edifices are known to be hydrothermally active, and a particulate plume with unknown source occurs in the seawater column above a third.

Jan 1, 1993

By Kim M

Mukuk gold mine in South Korea produces a pyrite concentrate containing gold associated with arsenopyrite as a gangue mineral. The effects of Portland cement as a depressant on the flotability of arsenopyrite were studied to improve the separation of arsenopyrite from pyrite concentrate containing gold. A series of the fundamental flotation tests were performed using Portland cement as a function of pH and concentration of the collector. Flotation recovery of pyrite and arsenopyrite in the fundamental tests with amyl xanthate showed that arsenopyrite was depressed by the addition of a moderate amount of Portland cement, but pyrite was not depressed by it. In the flotation tests of the artificial mixture samples with arsenopyrite and pyrite, following pH were adjusted to be 10.5 by Portland cement, different amount of amyl xanthate was added. The results from these studies showed that flotation recovery of pyrite was 100 per cent under the condition of some addition of amyl xanthate, but arsenopyrite was not floating at all. Portland cement shows remarkable depression of galena, but its effect on the flotability of chalcopyrite is not as clear. In the pulp under Portland cement addition, chalcopyrite can be easily activated by the addition of sodium bisulphite, whereas galena is depressed more effectively. From the batch flotation tests with the pyrite concentrate, the galena concentrate and the Cu-Pb bulk concentrate from the mines, it was confirmed that the results of the batch flotation tests agree with the results of the fundamental flotation tests. The effects of depression by Portland cement on pyrrhotite, marmatite and stibnite are also discussed briefly.

Jan 1, 1993