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By M. B. Cortie

An account is given of the development of ferritic stainless steels since their discovery in the early years of this century. The alloys became very widely used in the 1950s, the market during that decade being driven strongly by a demand for automobile trim made of ferritic stainless steel. The production of ferritic stainless steel declined as a proportion of the total at the end of the 1950s as consumer preferences changed. However, the market is now growing strongly again, this time driven by a demand for oxidation-resistant alloys for motor-vehicle exhaust systems. The tonnages produced, applications, and market shares of the various alloys are discussed and compared. Trends in world stainless-steel production, product forms, technological development, and usage are examined.

Jan 1, 1993

By Charles L. Kimbell

For 1991, the aggregate value of world international export trade in mineral commodities was roughly estimated at $685 billion in current 1991 dollars. The estimated level was about 6 % higher than that for 1990, but still more than 3 % below the record high set in 1980, and the year was the fifth in a row in which the value of exported minerals advanced. Table 8 provides a data series for the estimated value of world export trade in all mineral commodities from 1979 through 1991, as well as a breakdown of this total into fuel and non fuel commodities. The data shown are based on the historically more traditional and realistic (from the viewpoint of data availability) practice of reporting trade values for the year before the year of review. Despite the considerable increase in the dollar value of mineral commodity exports, their share of total export merchandise trade declined to 19.1 % in 1990 from 19.7% in 1989. At 19.1 %, this share was very near the recent year record low of 19.0% reached in 1988. Comparable 1991 figures were not available in time for inclusion here, but it is expected that the mineral commodity share of the total will be little altered from that of 1990.

Jan 1, 1993

Traditionally, the Lead Lode at Broken Hill has been represented on presentation plans, cross sections and diagrams in scientific papers as a solid black mass, around which the more 'interesting' and 'structurally useful', wall rocks appear to wrap. Structural analysis of the Broken Hill orebodies has usually turned to these wall rocks to determine the structural history of the mineralisation.This tendency to represent the orebody as a massive single entity is incorrect and the aim of this paper is to illustrate that sulphide orebodies (in this case Lead Lode), are a dynamic part of the mine stratigraphy. They can preserve a great deal of useful structural information that can be recorded with detailed internal mapping.Three main categories of ore type are recognised in Lead Lode; Stratiform ores, Mobilised ores and Metasomatically altered ore. The ore types in these categories occupy or have formed in distinct structural and stratigraphic positions and have clearly recognisable inter-relationships.

Jan 1, 1993

By M Surtees

The Limpopo region in southern Africa is considered to be a favourable target for the discovery of base and precious metal mineral deposits. The integration of gravity, geomagnetic, LANDSAT data and geotectonic history is used to formulate an ore deposit model which can be used in the implementation of mineral exploration programmes. Field work was carried out to test and refine the model.

Jan 1, 1993

By Park. D. W., Y. M. Jiang, L. A. Morley, W. Keeton

Underground room-and-pillar mining operations in the Warrior Coal Field in Alabama frequently suffer instability due to soft floors and thinly-laminated immediate roofs. This investigation concerns a mine that was experiencing ground-control problems with weak floor conditions. Several roof falls occurred locally, and as much as 0.6 m (2 ft) of floor heaves have been experienced. The paper presents the results of comprehensive analyses conducted on floor heave, roof sagging, pillar- penetration and floor bearing capacity using instrumentation and numerical modeling.

Jan 1, 1993

By Ronald O. Harma

Iron ore pellets made from concentrates produced from low grade iron ores are the primary iron bearing feedstock for iron making in North American blast furnaces. Steelmakers are demanding increasingly higher quality to provide for improved blast furnace productivity, efficiency, product quality and environmental compliance. Unfortunately, this higher quality iron ore product must be produced from the vast deposits of low grade iron ores that are becoming increasingly poorer in quality with regard to mineral liberation and ease of concentration. Since some of these low grade iron ores require grinding to as fine as 90% -500 mesh (25 microns) for liberation and since more of the silicious gangue and other minor undesirable constituents must be removed to provide the higher quality, we have come to depend on flotation to do the added work. Flotation technology and other preflotation unit operations must improve to meet these increasing demands. In many cases, flotation equipment, reagents and circuit operating performance have improved little during the last two to three decades. Mechanical flotation cells have grown from 14 cubic meters (500 cubic feet) to over 84 cubic meters (3000 cubic feet) to help reduce capital and operating costs; however, flotation metallurgical performance has not improved, Column flotation has only recently shown promise in improving metallurgical performance for iron ore rougher flotation. Previous column flotation success was mainly in scavenger and cleaner flotation steps for treating minerals other than iron ore. Although some new flotation chemicals have been developed for removal of silica and other minor constituents under widely varying mineralogical scenarios, recovery of iron mineral has not improved. The operation and control of flotation circuits have become more challenging because of the increasing workload on flotation. Better sensing, process control and operation of flotation circuits are essential as we go forward. Iron ore upgrading by flotation can be classified into either anionic or cationic methods. Anionic flotation of either iron oxide or silicious gangue is accomplished by collector type, pH control and selective chemical activation . Similarly, cationic flotation of silica or iron oxides is accomplished by collector type, activation and/or pH control. Removal of other minor constituents is achieved by using specialty chemicals under controlled conditions for preflotation, co-flotation or post flotation steps. Generally, anionic flotation is used for floating cleanly liberating crystalline oxidized iron ores such as hematite, specularite and martite. Earthy and hydrated oxides such as hematite and geothite can be upgraded with either anionic or cationic collectors after controlled dispersion of slimes or prior removal of slimes. Anionic flotation of silicious waste can be achieved by calcium activation of silica. For magnetic iron ores small amounts of locked silica particles (middlings) can be removed by cationic silica flotation, which is the only method in commercial use in North America today. Historically the efficiency of these iron ore flotation processes has been restricted by the loss of fine iron particles (minus 500 mesh) to the tailings product. New technology is required to overcome this loss and improve overall flotation performance. Development of technology for more selective separation of silica and other minor undesirable constituents from iron ore will provide both quality and cost benefits to the iron and steel producers. Development of future iron ore production in North America will face stiffer technical challenges. These new and undeveloped iron ore deposits are largely oxidized (non-magnetic) and by nature contain more slimes and other undesirable constituents. Unless other new technology evolves, flotation will be the major treatment process required to upgrade these difficult low grade iron ores.

Jan 1, 1993

By W. K. Collins

Engineered Scavenger Compounds (ESCs), developed by the U.S. Bureau of Mines, are a novel class of compounds that can selectively recover a desired element from a solid or molten alloy. Lithium titanate (Li2Ti3O7 or L'20-3T'02) is being used as an ESC to recover lithium (Li) from Aluminum-Lithium (Al-Li) alloys. X-ray diffraction measurements have shown that lithium titanate undergoes a phase change from an orthorhombic structure to a hexagonal structure. This change is due to the incorporation of Li in the matrix of the material and the effect of temperature. Although both are metastable, the hexagonal phase that forms during the scavenging of Li from Al-Li alloys appears to be the more stable phase. Recovering Li from the ESC by electrodeposition does not cause the structure to revert to the orthorhombic phase. Both the orthorhombic and the hexagonal structures of Li2Ti3O7 have similar scavenging capacities for Li. This paper proposes a new mechanism for the phase transformation.

Jan 1, 1993

By Peter Florian

At 5:50 am on October 1, 1992, the new $800 million Pittsburgh International Airport Midfield Terminal opened its gates to the world after five years of construction and more than 24 years of planning. Despite numerous design changes, this massive project was completed on time and substantially within budget. The importance of this airport to Allegheny County and the Pittsburgh region was recognized 24 years earlier by Allegheny County Commissioners Tom Foerster and the late Leonard Staisey. Staisey and Foerster established a program to acquire land for the "Airport of the Future".

Jan 1, 1993

As part of the U.S. Bureau of Mines (USBM) program to characterize subsidence this combination of software and hardware has been used to remotely monitor overburden response to longwall mining. Background The principle of time domain reflectometry (TDR) is being used by the USBM to monitor strata displacements induced by mining. This capability has been enhanced by the availability of cable testers with serial communication modules that allow users to get TDR records in digital form. Actual field installations involve coaxial cables that arc hundreds of meters long, and the many records obtained when monitoring such long cables on a daily basis motivated development of software to view interactively and compare waveforms and to analyze signature changes. Time domain reflectometry (TDR) was developed in the 1960's as a method to locate discontinuities in coaxial transmission cables. The concept has been extended to measurement of properties of materials into which probes are embedded, such as water content of soil, and evaluation of coaxial cable dielectric behavior. This technique was adapted by the USBM in 1975 for use in checking the movement of rock during underground mining. Coaxial cables are grouted into a rock mass that is expected to cave, and progressive rock movement causes the cable to deform. Consequently, there is a progressive change in cable electrical properties that produces changes in TDR pulse reflection signatures. TDR technology has been advanced by Northwestern University to the point where it is now possible to distinguish shear deformation from tensile deformation, and to quantify rock mass displacements, by analyzing these changes in TDR signatures.

Jan 1, 1993

This paper addresses the role of mine geology in mining geotechnics. The role is assessed and discussed in terms of five main elements; geotechnical complexity, geological complexity, mine scale, percentage sampling and geological uncertainty. Lastly, the overall objectives and mine geology requirements are listed in terms of the various mine development stages; exploration, feasibility-design and operating.

Jan 1, 1993

By Wencai X

The conversion relationship between the Bond Work Index W1, specific output of mill and the energy efficiency of grinding were developed using dimensional analysis. These relationships were validated and the value of the conversion coefficient ~ was also obtained using a new installed device for measuring grindability of ores. With the new simulating algorithm the mill specifications, output and size distribution of grinding products of industrial mills can be calculated based on laboratory measured results. This algorithm is more accurate and simpler than any of the other empirical relationships. KEYWORDS: Conversion coefficient method, grindability, grinding Constant.

Jan 1, 1993

By Chen B

In recent years great efforts have been made in the optimisation of ball mill operation. This paper describes a methodology developed for modelling and optimising the steady-state grinding process. Thirteen basic similarity numbers of the process are derived. Based on these similarity numbers, we build a group of mathematical models which give a full description of the relation between dependent and independent variables. The parameter estimation and multi-objective optimisation of the grinding process have been done using these models, and validated with experiments in a continuous laboratory-scale ball mill.

Jan 1, 1993

By E. Ozberk, J. B. Hiskey, M. J. Collins, B. J. Scheiner, M. E. Chalkley, I. M. Masters

Conventional zinc concentrates generally contain 5 to 10% Fe, while bulk concentrates can contain up to 20% Fe. As a result, the disposal of iron bearing residues is an integral part of zinc refining operations. The quality of iron residues must comply with ever changing and increasingly stringent environmental legislation. Zinc has been recovered from sulphide concentrates by a hydrometallurgical route for almost one hundred years. The disposal of iron was a major difficulty for the industry for many decades and was directly responsible for low overall zinc recoveries. The introduction of the jarosite process in the mid 1960's allowed for the treatment of neutral leach residues and the precipitation of iron in an easily filterable form. Subsequently, three additional iron precipitation processes have found commercial application in the zinc industry: the goethite process; the paragoethite process; and the hematite process. The Sherritt Zinc Pressure Leach Process has been developed for integration with existing roast leach electrowin zinc plants, or as a stand alone facility for the treatment of a wide variety of zinc bearing feed materials. It is essential that these processes allow for the disposal of iron residues in an environmentally acceptable form. This paper describes the integration of the Sherritt Zinc Pressure Leach Process with commercially proven iron precipitation processes. The results of laboratory testwork and data from operating plants are presented.

Jan 1, 1993

By Michael D. Duffy, Martin W. Chenoweth

"Tenn Luttrell Company (TLC) is a major lime and limestone producer in the eastTennessee area. The property, which isreferred to as the Chesney Mine, has been mined from the surface and underground overthe past 20 years. The ore body consists of three major zones of chemical grade limestonewhich lay at a dip of 30 _ 65 degrees. In July of 1989, Tenn Luttrell Company made thedecision to reopen the underground operations which had been suspended during a time ofincreased surface mining."

Jan 1, 1993

By R. T. Richins

Coeur d'Alene Mines Corporation (CDE) is a precious metals mining company. The company's three mining operations are located In Nevada and Idaho. Collectively, these mines (Rochester in Nevada, and the Galena and Coeur In Idaho) produced about 61,000 ounces of gold and more than 7.5 million ounces of silver in 1991. The company is currently planning the development of two major properties; the Fachinal gold-silver project in Chile and the Kensington gold project near Juneau, Alaska. Fachinal and Kensington hold encouraging potential to significantly expand CDE's gold production during this decade. The permitting process for these two distinctly contrasting environmental settings, project design requirements and regulatory/political circumstances provide the basis for a comparative analysis of licensing and permitting requirements, timeliness of the permitting process and costs in the U.S. and Chile.

Jan 1, 1993

By G. Chung, W. Petruk, D. Doyle

"A series of tests was conducted on Carol Lake iron ore, which contains about 38 wt % hematite and 19 wt % magnetite, to establish a flowsheet for high weight yield by spirals. A pilot plant was run in parallel with the IOC concentrator to simultaneously test two flowsheets on the same feed material. The IOC concentrator processes the ore by treating it directly in a spiral circuit, whereas the pilot plant used a laconite flowsheet which had a low intensity magnetic separator (LIMS) at the front of the circuit. The LIMS produced a non-magnetic (hematite-rich) product and a magnetic (magnetite-rich) product prior to treating the ore in two separate spiral circuits. The results from about 150 tests were evaluated by chemical assays and materials balancing techniques, and a selected test was evaluated by the image analysis and materials balancing technique.The image analysis and materials balancing evaluation showed that a higher hematite recovery was obtained by the hematite spiral circuit than by the IOC concentrator spiral circuit, and a slightly lower magnetite recovery by the magnetite spiral circuit than by the IOC concentrator spiral circuit. Furthermore the hematite recovery by hematite spirals was higher than the magnetite recovery by magnetite spirals. The better hematite recovery was achieved because a higher liberation is obtained for hematite than for magnetite, and the hematite in the Carol Lake ore has a narrower grain size range than magnetite. Consequently, better spiral control can be maintained when processing a hematite-rich spiral feed, than when processing a magnetite-rich spiral feed. Since the feed to the IOC concentrator spiral is a mixture of hematite and magnetite, an intermediate hematite recovery is obtained by the IOC concentrator. INTRODUCTIONA study of characteristics that affect recoveries of hematite and magnetite from the Carol Lake ores of the Iron Ore Company of Canada (IOC), was carried out in connection with a project on designing a flowsheet for maximum weight yields. A pilot plant using a taconite flowsheet was run in parallel with the existing IOC concentrator which uses a classical iron ore flowsheet. About 150 tests were run to compare iron recoveries and weight yields by the spirals in the two flowsheets. Better iron recoveries were indicated for the taconite flowsheet, but the results were not consistent and the reasons for the observed differences were not apparent. The material from one test (Test 61), which gave better iron recoveries for the taconite flowsheet, was evaluated by the image analysis and materials balancing technique. A suite of samples was taken from 5 points in the IOC concentrator and from 8 points in a pilot plant (taconite flowsheet). The samples were analyzed to compare the behaviours of the Carol Lake hematite and magnetite in the spirals of the two flowsheets. The results provided a sound basis for further tests in designing a high weight yield flow sheet."

Jan 1, 1993

The disadvantages of the present zinc producing methods, RLE and ISP, are high energy consumption and environmental problems. Therefore, efforts have been directed in Outokumpu Zinc towards the development of alternate routes. One interesting pyrometallurgical process to produce zinc is to inject zinc calcine together with a solid reductant into molten iron, saturated with carbon. This process has been studied by thermodynamic calculations, laboratory tests and mini-pilot test runs at Outokumpu Research Oy, Pori, Finland. The results of these tests are presented and discussed in this paper. The mini-pilot tests demonstrated that over 97 per cent evaporation of the zinc was possible using a reactive coal dust as the reducing agent. The recovery of zinc in the metal phase was at best 88 per cent of input zinc, but only part reported in molten lead in the splash condenser. The final metallic zinc contained at best 98 per cent Zn, the main impurities being dissolved lead and coal carried along with the flue dusts.

Jan 1, 1993

By D. François-Bongareon

"In previous publications by the author, significant advances and generalizations of the theory of sampling of broken ores, prompted and confirmed by experimental results, have been presented. This paper shows how to implement these theoretical results in practice. The models to be used are reviewed, with a description of the various sampling parameters involved. Then the methodology for the experimental assessment of those parameters, including segregation factors, is described in simple and practical terms, along with the use of handy sampling protocol charts. Finally, the particularly important case of processing data from a sample-tree experiment is detailed, and examples of applications covering all situations and types of experiments are provided.IntroductionThe reliability of a sample of crushed material , i.e. the expected (average) deviation between its true grade and the true grade of the lot it comes from, mostly depends upon six factors:• the size (mass) of the sample (and to a minor extent, for small lots, the size of the lot);• the size of the rock particles (degree of comminution)• the nature of the mineralization at microscopic scale (i.e., within even the smallest particles);• the geological nature of the mineralization and mineral of interest;• the grade of the lot in the mineral of interest; and• in some cases, the state of segregation of the lot.In practice, one should first disregard segregation problems, and assess sample variability in the segregation-free case. Once the numerical parameters governing this variability have been assessed, then segregation factors can be assessed in turn. In the case of laboratory standard sample preparation procedures, segregation can usually be disregarded altogether."

Jan 1, 1993

Over the 20 years to 1990 the Australian mining industry, presently worth some $A60 billion, generated a negative real rate of return (McDonald, 1992); not surprisingly under-performing the returns from bonds and industrial equities. Over this same period more than $A70 billion was invested in expanding the Australian mineral industry.

Jan 1, 1993

By Henrie Henson, Dan Burroughs, Shyi-Shyong Jiang

Jan 1, 1993