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By R. H. Walton

"In recent years the recovery of copper from low grade oxide ores has received widespread attention. The cost of treating such ores using conventional technology, such as milling and flotation, is frequently prohibitively high and copper recovery is generally low. The introduction of heap leaching, solvent extraction (SX) and electrowinning (EW) has resulted in high recoveries, good copper cathode quality and low production costs. This technology has now been successfully applied on a worldwide basis.This paper reviews the various process and design options and gives approximate capital and operating costs for a 1.0% copper ore.INTRODUCTIONAs a result of the low copper prices that prevailed for much of the last two decades, aggressive attempts were made by the industry to cut operating costs. Under such circumstances heap leaching, solvent extraction and electrowinning, to recover low cost copper from oxide ores, has received particular attention and ultimately widespread acceptance.Low grade copper ore (typically containing less than 1.0% Cu), which could not be economically treated by other methods, is placed on heaps and leached with dilute solutions of sulphuric acid. The copper rich, pregnant solution, drains from the heap into a collecting pond and is pumped to a solvent extraction plant where it is purified and upgraded. The resulting solution, termed the pregnant electrolyte, passes to the electrowinning section where the copper is recovered as high grade cathodes and sulphuric acid is regenerated, (Figure 1).This paper specifically describes the processing of copper oxides. Other copper minerals such as chalcocite and chrysocolla are also leached by dilute solutions of sulphuric acid. In practice the oxide minerals are frequently associated to varying degrees with less easily leached sulphides, such as chalcopyrite. In some cases, once the oxidized capping of the ore body is removed, the oxides are totally replaced by more refractory sulphides. Under these circumstances the leaching recovery is significantly reduced. However the principles described here for solvent extraction and electrowinning are also applicable to solutions received from heaps containing sulphide minerals, which are leached more slowly and involve bacterially induced reactions."

Jan 1, 1990

By Robert B. Parsons

"It is quite likely that more than a handful of junior exploration companies will receive some startling news from their accountants this spring when 1989s tax returns are being prepared. These companies could find that, for the first time ever, they will have to write a cheque to the federal government on account of a new federal capital tax which became effective July I, 1989IntroductionMany mining companies which have never had to pay a federal income tax are finding that they indeed have a tax liability for 1989. Non-producing companies, such as junior exploration companies, almost automatically assume that they don't have to pay any income tax. But, a new tax imposed under the Income Tax Act catches especially the company that has no income.Effective July 1, 1989, a federal capital tax (some call it a corporation minimum tax) is payable by any corporate carrying on business in Canada where the corporation has ""taxable capital"" exceeding $10 million. As a result of the popular use of flow-through shares in recent years, many junior exploration companies are finding that their balance sheets show capital stock over $10 million, and that they are consequently caught by the new tax. Further, some of these companies are finding, to their chagrin, that the tax for 1989 was due on February 28, 1990, and that non-deductible interest is ticking away on unpaid taxes."

Jan 1, 1990

By R. Reed von Gal

The majority of zinc strip produced in the world today is cast on the Hazelett twiri-belt continuous casting machine. Ten of these machines are currently operating worldwide, and one machine is under construction for the People's Republic of China. The caster, which was first patented in 1947, was originally developed for aluminum and copper alloy casting. In the early 1960s, the design was expanded into zinc casting and within ten years the industry had essentially converted from casting and rolling ingots to twin-belt continuous casting with in-line rolling. The casting process employs two parallel, moving. water-cooled belts as the major mold surfaces. Together with two strings of side dam blocks, the design offers a four-sided moving mold which produces a continuous strip or bar. This paper will cover a bit of, the history, as well as the current technology surrounding this high production process for zinc strip production.

Jan 1, 1990

By R. Benemelis

The existence of resins in some coal deposits in various parts of the world has been known for many years. These resins vary considerably in chemical structure and properties. The resin that is found in Utah coal, however, is rather unique, and has properties particularly attractive for the manufacture of printing ink mastics and adhesives. This resin is a rather dark, very high melting point, low molecular weight hydrocarbon resin. Its typical properties are shown in Table I. Its largest use by far, has been in the printing ink industry. The history of Utah coal resin is interesting, but unfortunately one of disappointment and failure.

Jan 1, 1990

By Paine G. G

The measurement of the fragmentation size distribution of a blast muckpile can be achieved directly by screening the entire muckpile. Screening of muckpiles in a production operation is generally not practical due to the logistics and time involved moving large volumes of rock through a screening plant. An indirect technique to assess blast fragmentation size distributions has been developed. This technique uses photographs of the blast muckpile taken at intervals during the excavation cycle. The images from the photographs are input to desktop computer software via a digitiser tablet. The software compilates the rock fragment sizes and calculates a size distribution. This paper discusses the technique and subsequent data analysis. Examples of the application of this technique for the assessment of comparative blast performance are given.

Jan 1, 1990

By I. Iwasaki, T. Fujuita

The removal of phosphorus from steelmaking slags is essential for recycling such slags to blast furnaces for recovery of their manganese, iron, and lime contents. Phosphorus is mainly concentrated in the dicalcium silicate phase of the slags (Fujita and Iwasaki, 1988, 1989; Suito, et al., 1977). Slow-cooling of steelmaking slags in an air atmosphere increased the grain sizes of constituent minerals; however satisfactory magnetic separation results could not be attained because of the close association of a strongly magnetic ferrite phase with dicalcium silicate (Fujita and Iwasaki, 1988). Curie point of the strongly magnetic ferrite phase in the slow- cooled steelmaking slags was investigated and an attempt was made to separate the phosphorus-bearing dicalcium silicate phase in ground slag pulps heated to a temperature exceeding the Curie point. Materials and methods Slag samples, heated to its fusion temperature of 1370°C and slow-cooled in an air atmosphere, were ground dry to -90 µm (about 170mesh) in a ring grinder. The ground sample was pulped to 1% solids in distilled water using 1 kg/t sodium hexametaphosphate as a dispersant and separated in a Sala high gradient magnetic separator, Laboratory Model 10-15- 20B, using a 100-mesh expanded metal matrix and 300 m/h flow rate.

Jan 1, 1990

By P. E. King

The U.S. Bureau of Mines is conducting an ongoing research project to better understand the phenomena involved within electric arcs utilized in electric furnace steelmaking. With a better understanding of the physical and electrical characteristics involved, dynamic or predictive control of electric arc furnaces may be possible. A mathematical model is presented, but not solved, and the system of coupled equations is analyzed. Characteristic parameters are used to determine relative importance. In this manner, significant quantities are dermed. The parameters found to contribute little to the system of equations of motion are ignored. A resultant simplified system is identified, and directions for further study are indicated toward control of electric arc furnaces.

Jan 1, 1990

By Rudolf E. Greuer, Linneas W. Laage, Xinton Chang

INPUT FORMAT INSTRUCTION FILE FOR PROGRAM MFIRE GENERAL RULES FOR DATA INPUT: $THERE IS NO NEED TO DISTINGUISH INTERGER AND REAL NUMBERS. $ $ SYMBOLS FOR NUMERICAL INPUT INCLUDE THE FOLLOWING $ $ 1234567890 -+BLANK $ $ * FREE FORMAT IS ALLOWED. COMMA AND BLANK SPACE CAN BOTH BE $ $ DELIMITERS. SEQUENTIALLY DISTRIBUTED BLANK SPACES ACT AS ONE $ $ DELIMITER. BLANKS ADJACENT TO A COMMA HAVE NO DELIMITING EFFECT $ $ * A ZERO INPUT CAN BE OMITTED BUT NOT THE DELIMITERS EXCEPT WHEN $ $ THE ZERO INPUTS ARE THE LAST ONES ON A LINE. $ $ * A LINE WHOSE FIRST NON-BLANK SYMBOL IS "$ IS AN INSTRUCTION $ $ LINE WHICH WILL BE IGNORED IN A PROGRAM RUN. $ $ * A LINE WHOSE FIRST NON-BLANK SYMBOL IS NEITHER ONE USED IN THE $ $ ABOVE LIST FOR NUMERICAL INPUT NOR "$, OR WHICH CONTAINS MORE $ $ THAN 3 SYMBOLS OUTSIDE OF THE LIST, IS A COMMENT LINE WHICH WILL $ $ BE SHOWN IN THE OUTPUT FILE. $

Jan 1, 1990

A procedure fm the estimation of pilla1 strength is presented where the design of underground coal pillars is emphasized. An analytical approach has been developed, proposing that the effect of end constraints on the pillar strength and the ductile behavior of coal material should be incorporated in the computation of the stability of coal pillars. Bad on this approach, it has been found that end constraint has a significant influence on the pillar strength. The study indicates that when the end constraint is zero the computed strength of the pillar is the same as the unconfiied compressive strength of the coal mass and will not increase with the increase in the width to height ratio. However. when the end constraint is greater than zero the pillar strength will increase exponentially as the width to height ratio increases.

Jan 1, 1990

By P. Guliov

In the first part of this paper the authors present an overview of industrial minerals produced in the Canadian provinces of British Columbia, Alberta and Saskatchewan, and supplied to the Pacific Rim countries. The second part outlines some of the unique opportunities for industrial minerals that exist in the three western Canadian provinces and those minerals we feel have development potential for overseas markets. Because of time constraints, it is not an exhaustive presentation on industrial minerals, but is focused on a few selected minerals that we believe have high potential.

Jan 1, 1990

A joint research effort by Newmont Gold and Du Pont, working with Kurtis Mooney, of Tri-Combined Resources has developed a new ore-sample bag made of "Tyvek," a spunbonded olefin. "The goal was to find a bag with the best trade-off between efficient draining of moisture, minimal fines loss and compatibility with the conveyor drying process we were developing for our new assay lab," Charles Bucknam, analytical development coordinator for Newmont Metallurgical Services states. None of the available polypropylene, cotton or canvas bags had the needed combination of properties. "Our original tests in 1987 on the plastic bags we had been using showed an average loss of 5.4% of mud sticking to the bags when they were emptied into drying pans. Part of the sample was still in the bag as a residual." Tests on bags of "Tyvek" showed low residuals when the samples were dried in the bags before they were emptied, but about 3% of the fines were lost through the seams. Mooney recommended a new bag design, with fold-over seams.

Jan 1, 1990

The discovery of gold mineralization at the Manhattan mercury mine, Napa and Yolo counties, California in 1978 was the result of applying a new exploration ore deposit model in a region previously unprospected for gold. This discovery, the McLaughlin gold mine, owned and operated by Home-stake Mining Company, is a classic epithermal mercury-hot springs-gold deposit currently producing approximately 7,776,000 grams of gold annually.The exploration program that led to this discovery was based on a mercury-hot springs-gold genetic model. The model was developed using basic knowledge of ore-forming processes plus careful field observations made during examination of many known precious metal districts in. the Western U.S.A. Theoretically, hot spring systems could host gold deposits and, indeed, gold in these environments had been recognized for years. However, at the time of the McLaughlin discovery, it was not known to occur in sufficient quantities to inspire geologists to explore hot spring systems specifically for gold. Field observations recognized the presence of hot spring deposits and mercury mineralization asso-ciated with precious metal districts, (Bodie, California being a type example), and this associ-ation prompted the development of a hypothetical model. Subsequent exploration activities were directed towards the examination of mercury mines and prospects as potential targets for gold deposits. The model envisioned hot spring deposits (sinter) containing mercury mineralization at the surface with anomalous gold values grading downward into significant ore grade gold values.

Jan 1, 1990

By Rudolf E. Greuer, Linneas W. Laage, Xinton Chang

The usual run time errors occur when illegal mathematical operations are attempted by MFIRE For exam¬ple, if the user enters a negative value for the input variable HEAT to model a heat sink or cooling station, a run tame error will occur because an exponential function is employed to better model the changing temperature dis¬tribution in the airways. DATA FILE ERRORS Two types of data file errors can occur. 1 An error may occur because the input data file itself is invalid This may be caused by: The data file cannot be found due to incorrect spelling, drive, or path specification Check the spelling and path at the prompt for location of the data file. The data file contains non-ASCII symbols Check op¬eration of the text processor to insure that only ASCII characters are produced Delete all non-ASCII and/or all out of place characters. 2 Data are accepted by the program, but are incorrect for the data types or ranges or the combination causes a data inconsistency This may be due to. An invalid character is located where a numerical value is required The input data value is outside the reasonable range The input data is insufficient to build the model for simulation. The input data exceeds the capacity of the program. PROGRAM ERROR DETECTION When the program is running, tracing messages are given on the screen indicating the group and lines of data that have been read and the section of the program that is executing Program termination indicates that problems are caused by the subsequent (not read) data file section. For each detected error, descriptive message starting with * ERROR * is issued and the program terminates. When a possibly wrong value and/or its calculated intermediate result is detected, a descriptive message starting with * WARNING * is issued and the program continues. If a modification of input value or calculated intermediate result is automatically made by the program, descrip¬tive message starting with * ATTENTION * is issued and the program continues. LOCATING ERRORS If a message indicates that the error condition occurred due to the data input file, locate and correct the data item. If no error message is issued, but the simulation results are not as expected, carefully check the list of input data shown in the output file WARNING messages and ATTENTION messages may reveal an error in the input data even though the program continues to operate Insure that the default values or modifications adopted by the program run are acceptable. Anomalistic data, though not incorrect or impossible, may lead to an unusual simulation For example, making a fan unusually powerful may prevent a normal strength fire from affecting the airflow distribution in the system Much care must be employed before considering an ex¬treme case. If a message indicates that the accuracy criterion in the temperature section of the program was not satisfied, a table detailing the current parameters of airways which have large fluctuation in the average air temperature from iteration to iteration is produced If the pattern of the parameters is clearly cyclical, while the variation of natural ventilation pressure is stable or cyclical from iteration to iteration, then, most likely there is no single equilibrium stage for the event If the variation of natural ventilation pressure decreases steadily though slowly, increasing the value of data item variables MADJ or ITN (on control line number 1) may allow convergence.

Jan 1, 1990

By N. S. Dalal, N. Leelarasamee, V. Castranova, K. Van Dyke, V. Vallyathan

"INTRODCICTIONSilicosis is the chronic fibrosing disease of the lungs caused by the inhalation of crystalline silica. However, inhalation of crystalline silica, may induce three distinctly different disease patterns; i.e., chrome silicosis, accelerated silicosis, and acute silicosis. These three disease patterns differ in their pathologic characteristics, clinical symptoms, onset of disease, and mortality. Many studies in the past have focused on the elucidation of mechanisms involved in the development of chrome silicosis. We recently reported that freshly fractured silica has surface properties that could make it more reactive with lung tissue than aged silica, and that this unique reactivity of freshly fractured silica may be involved in the pathogenesis of acute silicosis (Dalal et al., 1986; Vallyathan et al., 1988; Shi et II., 1988). Because freshly fractured silica could contain some moieties in an ""excited state,"" due to the breakage of silicon oxygen bonds, we postulated that the de-excitation of these moieties could produce light which could be monitored by a luminescence measurement technique. In addition, if this ""excited state'' of silica could trigger a greater biologic response by phagocytic cells, this activation could be monitored by a chemiluminescence technique in the presence of appropriate enhancers.This investigation describes for the first time the use of luminescence in the study of freshly fractured silica and its properties. Enhanced biologic reactivity of the freshly fractured silica with alveolar macrophages was monitored by the chemiluminescence technique.MATERIALS AND METHODSNative silica was obtained from the dust bank of the GenericRespirable Dust Technology Center, Pennsylvania State University, State College, PA, and ground for 3~ min in an agate ball mill. It was then sieved through a 20 micron mesh filter and used within 1 O min as fresh silica or stored in glass bottles for aging. X-ray energy spectrometry and X-ray powder diffraction studies on representative samples were made to confirm the mineralogic purity. All the silica samples were found to be 99 % pure with minimal detectable conlamination by metal ions."

Jan 1, 1990

By Kent C. Werle

This brief discusses the installation and application of sleeved piles of two different types for two different projects, the W, Seattle to Harbor Island Swing Bridge Project and the Seattle Access Project. A description of these relatively novel piling systems is given, as well as some notes on their installation and application. As implied by the term "sleeved" these are piles which consist of two piles, an inner pile combined with an outer concentric sleeve pile. Background, Swing Bridge The Swing Bridge project is virtually unique in the world in that it is a "lift and turn" swing bridge. It is also a concrete, cast -in-place segmental bridge which is designed to be moveable.

Jan 1, 1990

The outcome of future metallogenic research will be important to everyone because it will. have a profound impact on our ability to find new deposits of non-reservable mineral resources. Failure to replenish our mineral stocks will threaten man's economic and social well-being, and it is vital that future directions of metallogenic research are considered carefully to ensure that research funds are applied wisely to underwrite our future.Today we are witnessing the declining phase of the era of easy exploration. The rate of discovery of shallow orebodies is slowing. This is very evident for base-metal deposits but is becoming increasingly apparent for gold deposits. The easy exploration era was marked by a heavy reliance on exploration techniques capable of directly detecting mineralization. These include simple prospecting methods as well as a host of geochemical and geophysical procedures and tools that enable explorers to pin-point regions' of mineralization within the upper couple of hundred metres of the Earth's crust. The role of

Jan 1, 1990

By H. Pieterse, K. S. Fraser, J. R. Goode

The Goldstrike autoclave plant is designed for the pressure oxidation of 1363 t/d (1500 stpd) of refractory gold ore. The plant was commissioned in early February 1990 over a one week period - an unusually short period for a plant of this complexity. The rapid plant start-up is attributed to certain detailed design and control aspects of the plant. This paper discusses key features of the autoclave plant with emphasis on the design of the splash/flash system of heat recovery and the control systems. Commissioning and plant operations over the first three months are reviewed.

Jan 1, 1990

By Yasuhiro Konishi

Hydrolytic stripping is the process in which metal ions are simultaneously stripped from a loaded cation-exchange solvent extractant and precipitated as oxides or hydroxides. Hydrolytic stripping is usually effected by contacting the loaded organic phase with water at elevated temperatures. The possibility of using hydrolytic stripping to prepare ceramic powders with controlled size and morphology is now being evaluated for different systems, using carboxylic acid extractants. As part of this work, mathematical models were developed to describe the kinetics of nucleation and growth of nickel ferrite particles. This paper describes the development of the models, along with estimation of key parameters appearing in the rate equations from experimental data.

Jan 1, 1990

By Toffeg A. N, Abdul-Hameed I

More than 1000 Ian of seismic reflection data correlated to ten exploration wells along with geological, gravity and magnetic data are used to construct the subsurface structure, in particular the crystalline basement, along a corridor approximately 100 Ian wide that traverses central Iraq in SE-NW direction for a distance of about 500 km from Baghdad in the central part of Iraq to Dohuk near the Turkish border. This transect is one of few such transects that represents the Iraqi contribution to the Global Geoscience Transects (GGT) project. The transect crosses two out of three major tectonic elements of Iraq: the unfolded zone and the folded zone.

Jan 1, 1990

By J. D. Morgan

The US economy grew steadily in 1989, reaching an annual rate of $5.3 trillion in the last quarter (US trillion=1012 ). The value of domestically processed, mineral-based materials rose 5% to $315 billion (US billion=109). The value of metals produced from US ores rose 14% to $11.6 billion, while industrial minerals rose 2% to $20.2 billion. Recycled scrap was valued at $10 billion. Increasing economic activity stimulated metal prices. Yearly lows and highs were $2.31 and $3.56/kg ($1.05 and $1.62 per lb) for copper, $1.58 and $2.57/kg (72 and $1.17 per lb) for aluminum, 77 and 97 cents/kg (35 cents and 44 cents per lb) for lead, and $1.58 and $2.09/kg (72 cents and 95 cents per lb) for zinc. Many mining and metal companies reported reasonable profits. Consumer demand strongly affects mining because the US economy is saturated with long-lived products. Consumer, mortgage, and Federal debt continued to rise. 250 million US citizens already possess 172 million licensed motor vehicles and 100 million dwelling units. New car production fell 4% to 6.8 million units, while truck and bus production fell 1 % to four million units. New housing starts fell 9% to 1.4 million units. Imports supplied a significant proportion of total US consumption of several important mineral materials. Imports of crude and refined petroleum costing $50 billion exceeded domestic crude oil production. President Bush expressed "strong concerns about this country becoming further dependent on foreign oil." And the Department of Energy held a series of hearings around the country to develop ideas for a "national energy strategy."

Jan 1, 1990