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By R. L. Nyirenda

An investigation of the reducibility of a cassiterite concentrate with charcoal was made in the temperature range of 1123-1373 K. The course of the reaction was monitored by a combination of sample weight loss measurements, product gas analysis, and chemical analysis of the reaction product. It was found that the cassiterite could be best reduced by a combination? of high temperature, reasonably high charcoal proportions, high charge poroslty, and the addition of a small percentage of lime. Analysis of kinetic data obtained from isothermal experiments using theory from the oxidation of carbon by carbon dioxide gave an activation energy value of 255 lci/mole for the consumption of carbon by reaction with cassiterite.

Jan 1, 1990

By Jin Zuomei

The kinetics of dissolution of nickel matte in the presence of manganese dioxide with silver ions was investigated. The catalytic silver ions enchanced the leaching rate up to a factor of 17. The effects of stirring, temperature, particle size, concentrations of Mn02, silver and ferric ions, and the experimental procedures were studied. Solid residues at various levels of nickel extraction were examined by SEM, TEM, electron micoprobe and X-ray diffraction. These results indicated that the dissolution reaction was topochemical and fits a surface reaction control model. The activation energy was calculated to be 39.15 KJ/mol. The leaching rate of Ni3S2 was independent with stirring rate, but the reaction rate constant was inversely proportional to the initial particle diameter. The order of the reaction rate are 0.41, 0.69, 0.33 with respect to Ag+, Mn4+ and Fe'+ con-centration respectively. Thus a kinetic rate equation was developed. Moreover, we propose a mechanism of silver catalyzed leaching of Ni3S2'

Jan 1, 1990

By D. M. Cruden

"When two discontinuities form a tetrahedral wedge in a rock slope, a factor of safety for the wedge can be simply calculated (if motion is driven only by gravity and resisted only by friction) from plots of the normals to discontinuities on an overlay of a polar, equal-area spherical projection to which the great circles of a similar equatorial projection have been added.IntroductionThe stability of slopes in rock masses is often controlled by the discontinuities that exist in the masses. In particular, the geometry of the discontinuities constrains the ways in which the mass may fail. Displaying the orientation of the discontinuities on a spherical projection has been found to be a useful way of identifying possible failure modes. The most concise display shows the orientation of the normals (or poles) to the discontinuities that compose the fabric of the rock mass. Computer processing of large samples of discontinuity orientations is necessary if the sampling biases identified by Terzaghi (1965) are to be routinely corrected. Fortunately, displays of the poles to discontinuities (or pi diagrams) are relatively easily produced on the line printer of a computer or by a computer plotter (Cruden , 1978; Ramsden and Cruden, 1979). Unfortunately, further analysis of the stability of a rock mass has tended to use traces of typical discontinuities on a spherical projection rather than pi diagrams; examples may be seen in Hoek and Bray's book (1981)."

Jan 1, 1990

The outlook for suppliers of energy to the expanding economies of the Pacific Basin region is essentially positive, but particularly for exporters of high quality steam coal. This paper argues that economic growth in the Pacific Basin region has exceeded world economic growth for some years and that this will continue to be the case for the next decade at least. It looks briefly at the link between economic growth and energy demand and at the relationship between energy demand and the demand for electricity. Changing preferences in fuel mix for electrical generation in the region are noted and tentative forecasts made about variations in this mix. The pros and cons of various forms of fuel used to generate electricity are considered from the point of view of the consumer. Having concluded that steaming coal in particular is likely to become even more important as a generator of base load electricity, the paper looks at the opportunities this presents for exporters such as Australia, and touches on some factors that could prevent development of those opportunities. This paper will concentrate on electrical energy. For the purposes of this paper, the Pacific Basin refers essentially to Australia, New Zealand and the Asian countries bordering the Western Pacific. As a supplier, Siberia is not included because, although it has great potential, it is thought that problems of climate, infrastructure and political restructuring will delay the realisation of that potential until the next century. Although it deals with the Pacific Basin region, where many countries are industrialising rapidly from a predominantly agricultural base, it looks at the experience of mature industrial DECD economies where their experiences seem relevant.

Jan 1, 1990

The kinetics of cyanide loss were found to be first order under any given set of conditions, allowing rate constants to be easily determined. At room temperature and in the absence of activated carbon, some cyanide is lost by hydrolysis to hydrogen cyanide, but this does not occur to any significant extent at pH values higher than about 10. A higher rate of hydrolysis occurs when air agitation is used. When activated carbon is present, an additional carbon-catalysed oxidation reaction is responsible for a fairly high loss of cyanide. The evidence indicates a reaction mechanism that consumes oxygen and produces cyanate ion. Some of the cyanate thus produced decomposes to form a mixture of ammonia, carbonate, and urea, depending on the solution conditions. Additional cyanide is lost as a result of the adsorption of sodium cyanide by the activated carbon. At high temperatures, an additional hydrolysis reaction, which involves the formation of ammonium formate as an intermediate, occurs an/j is responsible for. a high loss of cyanide, leading ultimately to the formation of ammonia, hydrogen, and carbon dioxide. The presence of activated carbon has no effect on the rate of this reaction.

Jan 1, 1990

By D. W. Horsfall

This paper reviews the properties and uses of mixtures of coal with fuel oil, methanol, or water, emphasis being placed on mixtures of coal and water. The material presented is taken from studies conducted overseas, and it is recommended that similar studies should be conducted on mixtures containing South African coals, which differ from the coals of the northern hemisphere

Jan 1, 1990

Mining had a very considerable effect on the country's development. The visual evidence remaining is an integral part of New Zealand history. Early mining for manganese and copper in the 1840s was succeeded by alluvial gold rushes. These gave way to hard rock extraction, hydraulic elevation and dredging. Coal mining dating from the 1850s was fairly widespread. Other minerals were obtained on a small scale. Manufacture of mining' machinery stimulated industrial engineering enterprises. Schools of mines played a significant part in advancing technical skills and several remain as museums. Surviving mine structures and site relics are part of the industrial heritage signifying the technological and economic development of a small isolated nation. Some of these are described. Identification, recording and preservation where practicable is advocated.

Jan 1, 1990

By O A. Cottrill, G A. Oldfield, S B. Nowell

Host-rock û wallrock major and trace element geochemistry associated with epithermal gold mineralisation in the Hauraki Goldfield of New Zealand is poorly documented, even though rock geochemistry is a recognised tool in exploration. Such responses assist in recognition of the regional scale imprint of fossil hydrothermal activity, and indicate targets for detailed evaluation within these alteration zones.   Recent investigation of gold deposits in the Waihi (Gladstone), Golden Cross (Empire), Thames (Waiotahi) and Coromandel (Tokatea) areas indicate enrichments of Au, As and Sb in the andesitic wallrocks hosting mineralisation. Of the other elements examined, Si, K and Rb are enriched, and Na, Ca, and Sr are depleted at all deposits. These trends are best developed in the vicinity of veining. In deposits with clay alteration dominating (Waiotahi and Tokatea) there is also depletion of Mg, Mn, Zn and Cu. Ba and Cr are variably enriched or depleted within different styles of alteration. Base-metal enrichment in the wallrocks is not a feature of Hauraki deposits.

Jan 1, 1990

There is considerable variability in the level of detail incorporated in prefeasibility studies relating to mining developments. Hence, when undertaking a review or audit, it is critical to attempt to ascertain at an early juncture precisely who has compiled the various facets of the study, for what purpose it was intended and the terms of reference given to the authors. Likewise, when commissioned to undertake an audit it is preferable to have proper terms of reference and to be aware of the purpose to which the audit will be put.These factors will influence the degree of detail an auditor would expect to find in the study and consequently, the degree of effort/time required for the audit process. In most instances audits do not imply recalculation of the entire study or modifying it in anyway, but involve an overall assessment of the methodology used, combined with spot checking of detail. One of the most difficult aspects is to determine a realistic order of accuracy for the overall study when the accuracy of the individual components may differ markedly.

Jan 1, 1990

By Kenneth L. Rubow, Virgil A. Marple, Bruce K. Cantrell

"In a cooperative study by the University of Minnesota and the U.S. Bureau of Mines, diesel exhaust and mineral dust concentrations have been measured for aerosols generated in the laboratory and in five underground coal mines. Three mines utilized diesel-powered haulage equipment and two used all-electric equipment. Two source apportionment techniques have been applied to differentiate between the mineral dust and diesel exhaust aerosol concentrations measured. The first technique, using a micro-orifice, uniform deposit impactor (MOUDI) for size selective sampling, is based on modeling aerosol size and the premise that the diesel exhaust portion of the aerosol is predominantly submicron and the mineral dust portion is mostly greater that one micrometer in size. The second technique, Chemical Mass Balance (CMB) modeling, was used to referee the analysis of diesel exhaust and mineral dust aerosol concentrations from the size selective sampling results.The MOUDI size distribution data were modeled to obtain parameters describing the fine and course fractions of the sampled aerosol and to estimate the contributions to each mode from both mineral dust and diesel exhaust aerosol sources. The results showed the size distribution of the mixed aerosols exhibited two definite modes with the minimum between the modes occurring at 0.8 µm. Less than 5 pct of the coal mine diesel aerosol was found in the coarse size fraction. CMB analysis confirms the original premise for using aerosol size to separate diesel exhaust and mineral dust aerosol during sampling.Based on the results from the size selective sampling, a personal diesel aerosol sampler has been developed for measuring diesel aerosol mass concentrations. Th.is sampler uses an inertial impactor to size separate the respirable aerosol at 0.8 µm. All material less than 0.8 µm is collected on an after filter for subsequent gravimetric analysis."

Jan 1, 1990

And it takes more than good organisation. You may read or heard this poignant reflection: We tried hard, but it seemed that every time we were beginning to form up in teams we would be reorganised. I was to learn later in life that we tend to meet any new situation by re-organising, and a wonderful method this is for creating the illusion of progress while producing confusion, inefficiency, and demoralisation This was written by the Roman Gaius Petronius in AD65. How much have things changed in nearly 2,000 years? What then does it take besides the fundamentals and good organisation to build a successful career in a successful organisation? I'm prepared to venture a list of what I'll'call Tips for Young Professionals. If you've got what it takes, and apply these, I think that you'll gain a great deal of satisfaction from your career, even if you don't reach the distant target each of you should have in mind now. So settle back in an advice-receiving mode, and please forgive me if I come across as a master of the bleedin' obvious, as Basil once accused his wife Sybil of being in the unforgettable Fawlty Towers.

Jan 1, 1990

By M. Rieber

The potential for the wide-spread commercialization of superconductivity, the disappearance of all resistance to a direct current (D.C.) electric flow, began in 1986-87 with the development by Bednorz and Muller at IBM's Zurich Laboratory of an yttrium -barium -copper oxide conductor which attained zero resistance at 90t:. Although the status of superconductivity is still pre-bench scale, it is useful to forecast its probable effects on the copper industry. I t should not be forgotten that at their inception, the impacts of transistors, semi-conductors, thin films and fiber optics on the electric/electronics sector of this industry, were largely underestimated. Superconductors are not metals, but a class of ceramics. They represent an efficiency increase of one or more orders of magnitude. If their development is to be a boon to the copper industry, rather than a reduction of metal demand through miniaturization or material substitution, vastly expanded copper containing electrical uses must be in prospect. In this paper the projected uses of high temperature superconductivity are examined, followed by the remaining problems to be overcome. Assuming success, a time horizon for maturation is estimated. The penalties for the non-recognition of new markets and material substitution are shown on the basis of past forecasts. Finally, the application of successful superconductivity to the copper industry over the forecast period is estimated.

Jan 1, 1990

By Robert W. Bruhn

A 125 foot high steel lattice frame tower supporting a 500 kV EHV transmission line and located over the gateroads of a longwall mining operation was subjected to ground movements from the mining of adjacent longwall panels. Under an agreement with the owner of the powerline, the mine operator was required to minimize mining impacts on the transmission line. In view of this requirement, the mine operator prepared a forecast of the expected subsidence ground movements prior to the onset of mining. These forecasts, in conjunction with finite element analyses of the tower superstructure under the imposed ground movements and wind loadings. suggested that the structural capacity of the tower would probably be diminished little, if at all, by mining. Ground movements determined by survey during mining of the two longwall panels were found to be in close agreement with predictions. Strains measured in selected tower members during mining generally agreed with values calculated by the finite element analyses. The study confirmed a methodology to predict subsidence and to assess its effects on steel lattice transmission towers.

Jan 1, 1990

By Johnson RW, Rogerson R

New perceptions of the nature of volcanic hazards on Bougainville Island have resulted from a recent remapping of the geology of the island. Ignimbrites and calderas have been identified at six Quaternary centres (Emperor Range, Tore, Kunua, Billy Mitchell, Loloru, and Laluai), and large-scale explosive activity now must be identified as a significant volcanic hazard on the island. Billy Mitchell and Loloru volcanoes are identified as the most likely sites of future, major, explosive activity. Billy Mitchell was recognised formerly as an extinct volcano, but is now known to have produced major eruptions 370 and 918 years BP. Five ignimbrite units recognised at Loloru range in age from about 12 700 to 3200 years BP. Bagana is an active volcano in central Bougainville, but its explosive activity is relatively minor and does not significantly affect areas beyond the uninhabited area of the volcano itself. Balbi is the largest volcano on Bougainville and has an extensive geothermal area at its summit. It was thought to have been in eruption last in the early nineteenth century. However, 370 and 940 year BP plinian ashfalls from Billy Mitchell cover the central area of Balbi, so the latest significant activity from Balbi may have been at least 1000 years ago.

Jan 1, 1990

By Butler RD

The Singhbhum Copper Belt is an arcuate zone of verthrusting which extends over a strike length of about 180 kilometres, located in Eastern India, 150-300 kilometres west of Calcutta. The Belt is noted for its mineralisation, and both copper and uranium are currently being mined within it.

Jan 1, 1990

By Grouhel P

Blasting performance is directly related to the characteristics and efficiency of the explosives used. The selection of the correct explosive for particular blast conditions and objectives depends on the ability to characterise the performance of individual explosive products. Techniques have been developed by the JKMRC to measure explosive performance and assess the impact of explosive performance on blast results. Studies conducted at a number of mine sites have shown that different types of explosives perform quite differently and that the performance of any particular explosive can vary significantly. The principal causes of these variations have been identified and detailed blast monitoring techniques, including the analysis of muckpile fragmentation and shape, have been used to quantify the effects of explosive performance on blast Results.

Jan 1, 1990

By G. A. Dawe, E. G. Kelly

Because of the nature of the breakage in the Barmac vertical spindle impactor, the 80% reduction ratio is very small, so that when an energy efficiency is calculated from Bond's method, it appears to be very low. However, the product size distribution contains a high proportion of fines. It is argued that the production of these fines accounts for the high energy consumption, and Bond's method is modified to account for this, by considering the crusher to be, effectively, a number of smaller crushers in parallel, each having a different reduction ratio.

Jan 1, 1990

By D. Corrigan, A. Ahmad, R. Sood, J. Bratt, R. Holt

Zinc oxide based electronic ceramics are being used increasingly to protect electric and electronic circuits against transient voltage surges. Varistors are produced by sintering and annealing ZnO based powder compacts through long sintering and annealing cycles. Because of the length of these cycles, a manufacturing plant is saddled with expensive high temperature equipment with low throughput. Ceramics Kingston Inc. has developed a new technology that uses 2.45 GHz microwave energy for sintering and annealing. The new technology has the potential for increasing equipment and labour productivity very considerably. Additionally, the new technology will result in appreciable energy savings and add flexibility to the manufacturing process. Microstructural examination of varistors sintered conventionally and by microwave technology showed considerably smaller grain size in the microwave sintered materials. The electrical properties of the microwave sintered ceramics compare very favorably with those of the ones sintered conventionally.

Jan 1, 1990

LITHOPROBE is a national, collaborative research grogram with the general objective of understanding the teotectonic evolution of the North American continent through multidisciplinary lithospheric studies in carefully selected areas of Canada. Six transect areas are investigating Precambrian evolution, although only in two of these is the research well evolved. The Archean Kapuskasing Structural Zone in Ontario is confirmed as an upthrust slice of upper to mid crust exposed at the surface. The Late Proterozoic Keweenawan mid-continent rift is shown to be the deepest known rift on Earth and the Grenville collisional zone of Ontario and Quebec involves crustal scale imbrication and ramping of deeply buried rocks to the surface. Two transect areas are investigating Phanerozoic evolution. In the Newfoundland Appalachians the geologically defined tectonostratigraphic domains do not coincide with lower crustal blocks defined by seismic reflection data. The Southern Cordillera Transect in western Canada is examining the nature, timing and dynamics of the assembly of the Cordillera, and particularly the role of accreted terranes. Work in the eastern and central segments has extended the known western limit of the North American craton at least IOO km westward and crustal-scale ramps associated with metamorphic core complexes have been identified.

Jan 1, 1990

This paper provides an overview of current and future mine developments in the major island nations Indonesia, Papua New Guinea (PNG), New Zealand, and Fiji, and the French territory of New Caledonia. Many of the other 11 small island nations in the region, such as Vanuatu, Pulau and the Solomons have been the subject of considerable exploration orientated towards gold in the past few years but without any deposit found with confirmed economic viability.

Jan 1, 1990