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By Patricia Negrini Siqueira Poveda, Leonardo G. A. Silva

Thermoplastic materials are sensitive to ultraviolet radiation (UV), which can cause structural changes, causing variation in mechanical properties and appearance. UV range between 250 and 400 nm is considered the most aggressive to polymers, and prolonged exposure to it results in breakage and/or crosslinking chains. Light stabilizer additives, blockers or absorbers are added to the polymers for protection in order to extend the life of the final product. The choice of the adequate light stabilizer additive system depends on factors such as resin final application, thickness, geographic location of exposure, presence of fillers in the composition, contact with chemicals, among others. This study evaluates different additive systems: conventional organic, inorganic nanotechnologyc base and the synergy between them when applied to polyethylene considering carbonyl index and UV/VIS results after aging by QUV chamber.

Mar 1, 2017

By Timothy W. Ellis, John A. Howes

The production of lead-acid batteries is defined by a closed-loop product life-cycle. Active material and grid alloys converge on an adaptable specification that improves both performance and recyclability. This mapping of product requirements for lead-acid batteries has taken over 80 years to develop. But, as the use of batteries made with other chemistries continues to grow, the need for a comparable life-cycle management process becomes increasingly apparent given societal needs to manage raw materials, e.g. the European Union Battery Directive recycling targets. What has taken more than 80 years for lead-acid to evolve in a closed-loop paradigm must now be accomplished in less time for batteries using other chemistries and technologies. End-of-life costs are embedded in the product cost of lead-acid batteries. However, end-of-life costs are not reflected in the product cost of batteries made with other chemistries. Those costs are borne by other constituencies with often inefficient and environmentally damaging results. Lead-acid is a materials technology management model for other products.

Mar 1, 2017

By Shijie Wang

Lifetime achievements of Professor Reddy ’s teaching, research and scholarship in the field of chemical and materials science and engineering are briefly described. He has devoted his entire career in the introduction and application of process engineering principles to the quantitative description of materials processing reactions, and industrial operations. He has formulated quantitative methodologies based on first principles of thermodynamics, phase equilibria and kinetics to: design of slags and fluxes for production and purification of metals and alloys; development of Reddy-Blander model for a priori prediction of impurities capacities of melts; development of novel ionic liquid electrolytes for materials processing; development of new theories for alloys and molten salts; design materials for fuel cells and capacitors; use of thermodynamic approaches to predict physical properties of materials; industrial energy waste separation and remediation; and thermal energy storage. He is a scholar and mentor, and has made numerous scientific and service contributions to the society and metallurgical and materials engineering education.

Mar 1, 2017

By Elizabeth Carvalho L. Cardoso, Ademar B. Lugão, Sandra R. Scagliusi

This research investigated how gamma-radiation affected PP/HMSPP structural foams filled with biodegradable synthetic polyester PLA in terms of thermal properties, biodegradability and infrared spectrum. Polymers are used in various applications providing enormous quantities of wastes in environment and contributing with 20–30% of total volume of solid residues. Besides, shortage of plastics resins obtained from fossil base is addressing research and development toward alternative materials; environmental concerning in litter reduction is being directed to renewable polymers for manufacturing of polymeric foams. Biodegradable polymers, a new generation of polymers produced from various natural resources, environmentally safe and friendly, can contribute for pollution reduction. PLA (poly(lactic) acid)) was chosen to be blended with PP/HMSPP. Blends thereof were subjected to gamma radiation at 50, 100, 150, 200 and 500 kGydoses.Soilburialtestpointedtowardapartialbiodegradationofirradiated PLA-PP/HMSPP foams; other characterizations involved TG/DTG technique and FTIR assessments.

Mar 1, 2017

By M. A. Usman, E. I. Akpan, S. O. Adeosun

Preliminary studies on the extraction and characterisation of biodegradable lignin from palm oil fruitbunch (POFB) for carbon fibre production has been conducted. Centra lComposite Design was used to determine the optimum operating conditions for maximum yield and properties of the extracted lignin. Soda concentration (1–3 wt/vol%), temperature (50–90 °C) and reaction time (20–30 min) were analysed using Rcore software. Experimental results show that using reaction temperature of 90 °C, time of 30 min and 3 wt/vol% soda concentration yields 3.3 g of lignin from 30 g of the POFB. The path of steepest ascent from ridge analysis shows that with temperature of 130 °C, time of 40 min. and soda concentration of 3. wt/vol%, 8.7 g of lignin can be extracted from 30 g of POFB. Analysis of FTIR and SEM show that the lignin has the same structure in all cases with minimal impurities.

Mar 1, 2017

By Muammer Kaya

This paper reviews the existing and state of art knowledge for electronic waste (e-waste) recycling. Electrical/electronic equipments (EEEs) which are unwanted, broken or discarded by their original users are known as e-waste. The main purpose of this study is to provide a review of e-waste problem, give e-waste management strategies and introduce various physical e-waste recycling processes with special attention towards extraction of both metallic values and nonmetallic substances. The hazards arise from the presence of heavy metals (e.g. Hg, Cd, Pb etc.), brominated flame retardants (BFRs) and other potentially harmful substances in e-waste. Due to the presence of these substances, e-waste is generally considered as hazardous waste and may pose significant human and environmental health risks if improperly managed. This review paper describes the potential hazards and economic opportunities of e-waste. First of all, an overview of e-waste/printed circuit board (PCB) components and substances are given. Current status and future perspectives of e-waste and waste PCB recycling techniques are described. E-waste characterization, dismantling, liberation, classification and separation processes, are also covered. Manual selective dismantling after desoldering and metal-nonmetal liberation at −150 μm with two step crushing are seen to be the best techniques. After size reduction, mainly physical separation processes employing gravity, electrostatic, magnetic separators etc., which are commonly used in mineral processing, have been critically reviewed here for separation of metals and nonmetals. The recovery of pure metals from e-waste after physical separation can be performed by pyrometallurgical, hydrometallurgical or biohydro metallurgical routes, which are not covered here. Suitable PCB recycling flowsheets for industrial applications are also given. E-waste recycling will be a very important sector in the near future from economic and environmental perspectives for both developing and developed countries. Recycling technology aims to take today’s waste and turn it into conflict-free, sustainable polymetallic secondary resources (i.e. Urban Mining) for tomorrow. Recycling technology must ensure that e-waste is processed in an environmentally friendly manner, with high metal/nonmetal recovery efficiency a lowered carbon footprint. Taking into consideration our depleting natural resources, this Urban Mining approach offers quite a few benefits; it provides a substantial secondary resource, while also ensuring that the environment is kept free from harmful toxins in e-waste. This results in increased energy efficiency and lowers demand for mining of new raw materials.

Mar 1, 2017

By D. C. Austin, P. J. Hazell, A. A. H. Ameri, J. P. Escobedo-Diaz, D. East, M. A. Bevan, A. D. Brown

Additive Manufacturing (AM) has become increasingly popular due to the ability to produce components with complex geometries and properties. The efficiency of this manufacturing method is investigated in this paper by examining the mechanical performance of AM austenitic stainless steel 316L under different strain rates. Dynamic compression experiments were conducted by using a Split Hopkinson Pressure Bar (SHPB). Microstructural observations were performed by utilizing optical microscopy. The behavior of this material is compared against stainless steel 316L manufactured by conventional methods. The results show that theAM316L used in this study display a considerable difference in the mechanical properties compared with conventional stainless steel alloys.

Mar 1, 2017

By A. P. I. Popoola, D. O. Okanigbe, A. A. Adeleke

In view of the steady depletion of primary sources of copper and the increased global demand for refined copper, it becomes necessary to explore some secondary sources for possible extraction of copper. The waste copper smelter dust (CSD) is a rich secondary resource for copper as shown by the chemical composition of the South African Palabora coppers smelter plant CSD that assayed 18.02, 13.36, and 3.4 wt% copper, iron and sulphur, respectively. Studies on CSD have focused majorly on either dust characterization or treatment, while hydrometallurgical extraction without pretreatment and with pretreatment using techniques such as oxidative roasting are also considered quite attractive. The challenge of iron dissolution during the leaching stage in these processes necessitates adequate purification of the leach liquor before the extraction of the metal as nano-particles. Hence, this review examined the theories relating to the characterization and treatment of CSD for copper recovery as nanoparticles; with factors having a bearing on the treatment process such as kinetics considered with the aim of providing scientific basis for the research.

Mar 1, 2017

By Niander A. Cerqueira, Pâmela Berçot, Afonso G. Azevedo, Victor B. Souza, Victor T. Bartolazzi, Bruno Padilha

In recent years, concern about environmental issues has become a parameter to consider in the projects in engineering. In order to reduce the impact that the tire improper disposal may result for the environment, we sought a solution to this problem. This article proposes the use of rubber scrap tires as fine aggregate in concrete production. The material produced was analyzed by a bending test, resulting in product quality, in particular for application in situations requiring a more ductile material.

Mar 1, 2017

By L. E. K. Holappa

Iron and steel making plays a significant role in global energy consumption and carbon dioxide emissions. The target of limiting the global warming by 2050 is extremely challenging for this energy-intensive branch of industry. In order to be responsible for its own share in cutting CO2 emissions, great advancements must be done. A brief history, present situation and different scenarios are discussed. Possibilities to decrease CO2 emissions in current processes via improved energy efficiency, alternative process routes, energy sources and recycling are examined. On-going and planned efforts and programs of steel producers and institutions, as well as trends of energy generation in the long run are reviewed and evaluated.

Mar 1, 2017

By Paul Laforest, Michael Moats, Daniel Majuste

The interaction of anode and electrolyte chemistry in copper electrorefining is complex. This is especially true with regard to the behavior of Group 15 elements (As, Sb, and Bi). To better understand this system, laboratory electrorefining experiments were conducted using commercial anodes with As/(Sb + Bi) molar ratios of 0.54 and 3.8 and an electrolyte collected from a commercial refinery. The effect of adding thiourea during plating was also examined. Twenty-one hour copper deposits were produced in the laboratory to simulate starter sheet production. The mechanical properties of the electrodeposited copper as measured by an industrially relevant empirical bend test and a one-point bend test developed by UFMG are reported. The crystal structures of the samples were also examined.

Mar 1, 2017

By Michal Stepien, Piotr Palimaka, Stanislaw Pietrzyk

During the steel scrap melting process in an electric arc furnaces, the generated dust may contain a significant amount of zinc. The content of zinc in case of melting galvanized steel scrap is variable and ranges from 15 to 40 wt%. This dust cannot be re-used for the steelmaking process. On the other hand the zinc content is too low to treat the steel dust as a feedstock in pyrometallurgy of zinc. When they are disposed in land fills they have adversely effect the environment. This work presents selected results of research and development of new technology, which was developed in order to utilization steelmaking dust in the sintering process. One of the products (zinc-rich) can be used as a high-quality raw material for production of zinc by pyro- or hydrometallurgical processes. The second one product from the shaft furnace can be used as a feedstock for the steelmaking process.

Mar 1, 2017

By De-qing Zhu, Feng Zhang, Jian Pan

Sintering performance of a series of sinter blends with high ratio of limonite was investigated. The metallurgical performance and mineralogy of product sinter were also examined. The results show that good sintering performance could be obtained when the ratio of limonite was below 43% in the blends of iron ore fines, while good microstructure and metallurgical properties were achieved under optimum sintering conditions. In contrast, sintering performance will rapidly deteriorate when the ratio of limonite is elevated up to 63% in the blends.

Mar 1, 2017

By Chen Tian, Tingfeng Wu, Qinghai Pang, Junhong Zhang, Zhijun He

Microwave technology as new aided tool has been applied on waste water treatment and metallurgical fields. This paper explores the affected factors such as microwave power, microwave irradiation time, polyaluminium chloride (PAC) amount and addition of phosphoric acid on treatment of Blast Furnace gas washing water by utilization of coagulation associated with microwave. Through the orthogonal experiment, the optimum experimental parameters were obtained in the course of treatment of 300 ml Blast Furnace gas washing wastewater: 396 W microwave power, 2 min of microwave irradiation time, 0.12 ml Added PAC and 0.8 ml added phosphoric acid. It indicates the affected factors in descending order on removal of SS in BF gas’s washing water: Added PAC level, added phosphoric acid level, time of microwave irradiation, and microwave power while those parameters that can affect suspended solids(SS)’s hardness reduction in descending order are added phosphoric acid level, added PAC level, time of microwave irradiation, and microwave power. Also, it demonstrates those parameters that can affect washing water’s turbidity in descending order: Added PAC level, time of microwave irradiation, added phosphoric acid level, and microwave power. The results showed that PAC coagulation associated with microwave on treatment of Blast Furnace gas washing wastewater has several benefits: short treatment time, strong sedimentation velocity and other excellent characteristics, it can effectively remove suspended solids in wastewater, the SS hardness and turbidity can be reduced.

Mar 1, 2017

By İbrahim Göksel Hizli, Selim Ertürk, Ayşegül Bilen, Raşit Sezer, Cüneyt Arslan

Turkish celestite ore was roasted in a lab scale rotary kiln furnace with metallurgical coke. Coke and celestite were mixed; the product contained 32% coke which is more than the stoichiometric requirement.100 g of the mixed product was fed to a rotary furnace at 35 g/min. Temperature (1000 and 1100 °C), rotation speed (2.5, 5 and 10 rpm) and the slope of the furnace (2,3 and 5°) were among the investigated parameters. Phase and chemical analyses were carried out by XRD and XRF techniques, respectively. The maximum solubility of the roasted product in water was 48% under the roasting conditions of 1100 °C, 2.5 rpm and 2° slope.

Mar 1, 2017

By S. Chama, K. Nyirenda, J. Machona, P. W. Chishimba, S. Parirenyatwa, G. Kaluba, Y. R. S. Hara, D. M. Musowoya

Our study focuses on upgrading of copper and cobalt from the Democratic Republic of Congo tailings, containing 2 wt% Cu and 0.5 wt% Co. Cobalt is in the complex iron silicate matrix such that its recovery by direct leaching is not possible. Two concentrating methods were employed in order to obtain copper and cobalt concentrates. Copper was concentrated via flotation and, at the optimal conditions its grade in the concentrate was 31.9 wt%. Cobalt was concentrated to 8.6 wt% b ycarbothermically reducing the flotation tailings with coal in a temperature range of 800–1050 °C and followed by magnetic separation. The reaction products were analysed by atomic absorption spectrometer (AAS) and scanning electron microscopy (SEM) techniques. The best carbothermic reduction temperature was found to be 950 °C due to maximum metallisation and less sintering between gangue and metallic/alloy phases.

Mar 1, 2017

By R. E. Vivas, J. A. Villa

"Located in the state of Colima, Peña Colorada is one of the largest iron ore operations in Mexico. The project is owned in equal parts by ArcelorMittal and Ternium. Though boasting a production capacity of 4.1 Mt/a (4.5 million stpy) of concentrate per year, Peña Colorada is faced with declining ore grades. In order to respond to this situation, Peña Colorada had to expand production even further. This expansion created various challenges that were overcome by the adoption and application of new technology. Examples of these technological innovations are discussed in detail in this article and include improvements in geo-modeling, mine planning, and mine operations. The successful implementation of these technologies paid for itself many times over, and has led to significant improvements in production and performance, while lowering the operating costs and reducing the variance between planning and execution.Project overviewPeña Colorada is a mining company that produces about 30 percent of the iron ore in Mexico. This project generates about 1,200 direct jobs and 3,000 indirect jobs, making a significant contribution to the local economy. Similarly, Peña Colorada invests in its local communities through numerous educational programs, scholarships, university agreements, social development, environmental agreements, etc. Peña Colorada’s operations consist of an open pit mine located in Minatitlán and a pellet plant located in the port city of Manzanillo, as shown in Fig. 1. Technological innovationsMost mining projects around the world typically follow the logic of “mining the next best ore.” Consequently, head grades tend to decline over the life of the mine. In the case of Peña Colorada, a decline in head grade combined with a decline in iron ore prices forced the operation to adapt to a new business environment and adopt new technologies to face these challenges. However, the first step along this process was to increase the confidence and reliability of the resource model. This task involved additional drillhole campaigns coupled with more detailed modeling techniques. Once the block model was completed, new optimization studies and production schedules were evaluated with new optimization tools that improved many aspects of the mine plan. The Peña Colorada block model has undergone 3 expansions to reflect additional information not available in the past. The model has expanded to the East and Southwest. The latest model expansion increased the total number of benches to 98 as a result of positive exploration results. Similarly, new geotechnical studies were prepared, which provided new guidelines for pit slope design, and new technology was implemented to monitor ground movement and slope stability. Two sectional block model views in Hexagon Mining’s MineSight 3D, along with the pit designs and geologic solids are shown in Fig. 2."

Feb 1, 2017

By A. Noble

"Froth flotation circuits are widely used throughout the mineral processing industry for the concentration of fine particles. It had been estimated that nearly 2 Gt (2.2 billion st) of ores are treated globally each year using this versatile separation process (Fuerstenau, 1999). Due to the high feed tonnage, a large economic incentive exists for flotation plant operators to optimize the performance of this critical processing circuit. Prior to the 1950s, the optimization of flotation circuits primarily involved the manual adjustment of operating variables based on visual observation and sporadic sampling (Lynch, Harbort and Nelson, 2010). During the next several decades, however, the advent of improved on-line instrumentation coupled with the rapid development of high-speed microprocessors allowed the industry to develop more advanced control systems that could quickly adjust operational parameters in response to disturbances in ore characteristics and plant flows. These early online controls typically involved feedback loops designed to stabilize cell performance through the automatic manipulation of process variables such as pulp levels, gas rates and chemical dosages. The set-points for these controllers were often set by plant operators based on one or more operator objectives, such as maximizing throughput, recovery or grade. More recently, these regulatory controllers have been interfaced with high-level data display and management systems that provide operators with the ability to better optimize flotation plant performance based on mathematical models and rule-based algorithms (Greet, 2010).While tremendous strides have been made during the past several decades, even the most modern flotation plants are still faced with the long-standing question: “What are we trying to optimize?” From an operator perspective, some common responses include “Maximize tonnage of saleable concentrate” or “Maximize metals recovery at a customer-specified market grade.” These replies may or may not reflect those of management, who often focus on economic goals such as “Maximize profits for each operational unit” or “Maximize rate of return for all corporate assets.” Unfortunately, these high-level objective statements do not always translate well into practice due to the disconnect between plant operating protocols and product value. Attempts have been made by industry to overcome this issue using various types of optimization routines such as linear programming or other optimization engines. While this approach does have some merit, these blind routines require considerable input data and interpretational expertise and provide little or no fundamental insight that can be used to drive improvements in concentrator performance."

Feb 1, 2017

By Venancio Astucuri

"El presente texto describe las cuatro competencias que debe poseer un ingenierio de minas para un desarrollo sostenible de la minería. Dichas competencias se dividen en personales, académicas, profesionales y de ingeniería. Este grupo de competencias pueden ser usados también para un proceso de autoevaluación, donde cada uno pueda medir sus competencias con el fin de determinar brechas y superarlas, de forma que las empresas puedan plantear requisitos mínimos para sus diferentes posiciones laborales y, finalmente, para que en las instituciones educativas, estos puedan diseñar de forma adecuada sus respectivos planes de estudio."

Feb 1, 2017

"When boring a tunnel, homogeneous hard rock is the exception rather than the rule. While contractors can set goals such as meters per month and performance incentives, it is also prudent to plan for difficult ground. A properly designed tunnel boring machine (TBM) can tackle fault zones, water inflows, squeezing ground, or whatever the risk may be. The alternative is not a good one: modifying the machine in the tunnel after bad ground is encountered. Not only does this result in increased downtime, but it also needlessly exposes the crew to the tunnel conditions. In the worst case scenario, the entire operation grinds to a halt.However, an accurate GBR cannot always be obtained, particularly for mountainous, high cover tunnels in remote locations. And even with a thorough GBR, unforeseen geological events can occur. What can be done in these situations? Difficult Ground Solutions (DGS) is ground investigation system with a suite of options that can be added to a shielded hard rock machine or dual-mode, Crossover machine to better enable advance when conditions are unknown or difficult conditions are anticipated.DGS consists of a set of integrated features tailored to a specific project’s geology. The main components of the system allow for ground investigation ahead of the TBM, increased monitoring and methods to keep a machine shield from becoming stuck.In fault zones and squeezing groundIf fault zones or squeezing ground are known or suspected, or if there is even a possibility of encountering them, this can greatly affect the TBM operation. Shielded machines protect the crew from the surrounding rock, and they can bore and line a tunnel efficiently, but in fault zones and converging material their shields can be their downfall. Avoiding a stuck machine is paramount to project success. DGS employs several features to avoid the problem of a machine becoming stuck. The first of these is multi-speed cutterhead drives. These drives effectively give the machine multiple modes of operation—high speed, low torque for hard rock, and low speed, high torque for difficult ground. Designing a machine with high-torque, continuous boring capabilities allows that machine’s cutterhead to restart with break-out torque in difficult ground. The net effect is that the machine can keep boring in the event of a face collapse and can bore through fault zones and running ground where the potential for cutterhead jamming exists. Going one step further, multi-speed gearboxes give the machine the ideal earth pressure balance- (EPB-) type torque if larger sections of soft ground are anticipated.Secondly, TBMs can get through squeezing ground and faults using Continuous Shield Advance. This design utilizes a stepped shield configuration — where each successive shield is slightly smaller in diameter — to avoid becoming stuck in converging ground. External shield lubrication is an added insurance against becoming stuck, using a series of radial ports that can pump Bentonite into the annular space to act as a lubricant in squeezing material.As a last effort, if a machine has already become stuck the TBM can utilize augmented, or “super” thrust. Additional thrust jacks can be added to supply an extra boost in a short stroke, generating enough force to break loose a trapped shield."

Jan 12, 2017