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By Ahmad Ghahreman, James McNeice

"Cerium is the most abundant rare earth metal and is often found in deposits along with small amounts of more valuable metals such as neodymium and gadolinium1. As a result, the production of cerium oxide often exceeds market demands, thus in some cases it would make more sense to remove the cerium from the process solutions before further purification. A common method of cerium removal is to precipitate CeO2 from the acidic leach liquors by raising the pH to oxidize cerium(III) to cerium(IV). This study investigates the oxidation kinetics using three oxidants; hydrogen peroxide, sodium hypochlorite, and potassium permanganate. The effect of oxidant, pH, cerium concentration and temperature on the oxidation kinetics will be discussed. Cerium oxidation in solutions with pH ranging from 1.0 to 4.0 was investigated at cerium concentrations ranging from 2.0 g/L to 16.0 g/L. A cerium recovery of 40% can be achieved at different conditions with each oxidant at room temperature, with higher recovery at 60°C.INTRODUCTION Over the last 70 years, the rare earth elements (REE) have become crucial components of modern technology. These metals are categorized as light rare earths (LREE) or heavy rare earths (HREE) by governments and miners based on weight, abundance, and therefore value. The minerals bastnaesite, monazite, and xenotime compose the majority of the world?s exploitable sources of these metals (Binnemans, 2013; Parker and Baroch, 1971). Geologists classify the LREE ores as „cerium group? minerals, approximately 50% cerium oxide by weight. The cerium group minerals monazite and bastnaesite compose the majority of world production, leading to an overproduction of cerium relative to world demand. This ratio of light to heavy REE in deposits has led to a phenomenon referred to as the balance problem (Binnemans et al., 2013). As an example, to produce 1 tonne of europium oxide from a bastnaesite deposit 450 tonnes of cerium oxide must be processed. This means that any push to increase production and access the value of the HREE metals will drive down the value of the LREE metals leading to diminishing returns (Zepf, 2016). These ores also contain measurable levels of thorium, subjecting them to complex radioactive waste regulations. During the 20th century, the USA was the largest producer of rare earth metals (REMs), primarily sourced from the Mountain Pass mine in California. However, due to a combination of market dynamics and regulations, China has dominated the market for the last two decades. The largest Chinese REE mine, Bayan Obo, produces rare earth (RE) concentrate as a byproduct of iron mining, decreasing their relative production costs (Gupta and Krishnamurthy, 2005). This mine alone represents about half of world bastnaesite production (Zhi and Yang, 2014). Rising demand for high-tech products has forced Chinese producers to commission other large mines, climbing to 90% of world production in the early years of the new millennium (Mancheri, 2016). This presents the west with a looming supply risk of these critical metals in the future."

Jan 1, 2017

By Mohamed Mekkawy, William W. Wheaton, Ira Brotman

"The Virginia Port Authority and the U.S. Army Corps of Engineers are partnering to construct the Craney Island Eastward Expansion (CIEE) to meet the dual purpose of extending the life of Craney Island as a dredged material management area and providing land for a state-of-the-art marine terminal. The over 500-acre (200-hectare) expansion provides additional upland dredged material capacity for the Hampton Roads Harbor by constructing perimeter dikes, that once filled, will provide land for the development of a container terminal. In the winter of 2010/2011 the first stage of sand fill was placed, followed by the installation of approximately 12 million linear feet (MLF) (3.6 million linear meters, MLM) of marine PVDs. With over 36 MLF (10.9 MLM) of PVD required to complete dike construction the project will be one of the largest PVD installation project in the U.S.This paper details the challenges associated with the construction of the cross dikes, in particular the design, testing, installation and monitoring of prefabricated vertical drains (PVDs) installed overwater to depths of over 130 feet (40 meters) for foundation improvement in the insitu very soft Norfolk Clay. With expected settlements of 20–30 ft (7-10 m) and 30 percent average strains, the discharge capacity of the PVDs was of particular concern. Laboratory data is presented showing the magnitudes and variability of discharge capacity under different confining pressures in both a straight and buckled condition.The method of installation and monitoring of the marine PVDs in open water included developing a specialized barge and sophisticated positioning and data collection system to verify installation location, depth of penetration and track quantities. An observational method, including material testing, detailed surveys, periodic in-situ testing, and instrumentation, was utilized by the project team to assess the project’s progress and allow for validation of consolidation and strength gain rates and magnitudes."

Jan 1, 2017

By N. Sahin, M. Can, Z. Ekmekçi, Y. Öztürk, Ö. Biçak, I. B. Çelik, B. Kocabiyik

"In this paper, a case study from Çayeli Bakir Isletmeleri A.S. (Rize, Turkey) about the selective flotation of copper minerals from sphalerite is discussed. Çayeli Cu-Zn Sulfide Ore contains different ore types, such as yellow ore, clastic ore, bornite-clastic ore, bornite-yellow ore, and black ore. For some of these ore types, selective flotation of copper and zinc is very difficult presumably due to presence of secondary copper minerals such as bornite, chalcocite and covellite, and also surface oxidation. These factors affect Cu-Zn selectivity due to activation of sphalerite particles in the ore during the process. The main objective of this work was to improve Cu-Zn selectivity by optimization of the pulp chemistry for different ore types of Çayeli ore. After preliminary flotation tests investigating effects of different chemical conditions, a plant survey was performed to determine the plant performance and sources of the problems when problematic bornite-clastic ore is treated in the plant. Various chemical conditions are tested in the laboratory scale test for better depression of sphalerite in copper flotation circuit. Combination of Na2S+ZnSO4+MBS was found to be the most effective depressant scheme. INTRODUCTION Ore variability is one of the most important factors affecting performance of a process plant both in short and long term planning. The geometallurgical modelling becomes a common tool to determine ore variability problems and develop the most efficient solution during life of mine (1, 2). Flowsheet design and equipment selection and sizing are usually done based on the results of ore variability test works. However, in some cases ore variability may not be foreseen during the design stage and therefore the solutions should be developed based on the existing flowsheet and equipment in the plant. In this situation, ore characterisation, problem statement and diagnostic testing should be applied step by step. The problem could be due to changing feed grade, mineralogical characteristics, grindability and surface characteristics when flotation is involved. The variability in feed grade with fixed mineralogy can be handled with relatively simple modifications (i.e. adjusting throughput or equipment capacity) in the plant. Variability in ore mineralogy is the most complex and difficult problem to tackle. Because, mineralogical variations could bring variations in mineral composition, texture and liberation. These variations can potentially lead to the variations in grindability of the ore and flotation behaviour. Variations in grindability are usually managed by optimization of operational parameters in grinding circuit, as it would be costly to replace the existing equipment in the circuit (3). The variations in flotation behaviour are mainly due to variations in mineral types and distribution, texture and surface oxidation. One or all of these factors could be observed in a flotation operation. Therefore, a comprehensive investigation both in plant and lab scale should be conducted for definition of source of the problem. The testwork to solve the problem and retrieve the performance is planned and conducted depending on the source of the problem (4, 5)."

Jan 1, 2017

By Michael Karmis, Emily A. Sarver, Ellen S. Gilliland, Leigh-Anne H. Krometis

"Public engagement is increasingly important in ensuring the success of projects related to energy development, particularly with regard to issues of environmental protection, public health, and socio-economic impacts. This is due to concurrent trends in public behavior, including a rise in public interest in these projects that is not matched by a rise in science literacy, and increasing organization and participation of the public through social media, citizen science, and grassroots initiatives. In recent years, several high-profile incidents have demonstrated that when public concern is ignored or met with a passive response from industry, it can rapidly grow into organized opposition that negatively impacts or wholly derails a project. Engaging, listening to, and educating stakeholders during early planning and development phases are therefore essential to earning credibility and trust. Moreover, maintaining two-way lines of communication throughout the lifespan of a project demonstrates social responsibility and facilitates cooperation, acceptance, and even support from communities and others. Positive experiences with specific projects at a local, community level can influence the larger public opinion of an entire industry sector. This paper presents cases studies of public engagement related to shale gas development (including hydraulic fracturing and pipeline construction), mountaintop removal mining, and management of mixed-use watersheds near surface mining operations. The experiences highlighted in these case studies are used to draw best practices of public engagement for sustainable energy development.Introduction Within the scientific research community, the importance of public engagement has gained increasing recognition. In a 2007 article in Nature, medical researcher, Patrick Taylor, stated that public engagement has both “gone viral” and “gone global” and has the ability to make real impacts to research (Taylor 2007). Nancy Baron, the science outreach director for COMPASS, an organization providing communications training for scientists, provides further evidence for the increasing focus on engagement, including shifting attitudes observed during her own experience as a communications coach and documented in surveys, the recent inclusion of communication and engagement activities in academic tenure review, and the surge of workshops, materials, and other resources available on the subject (Baron 2016). In addition to COMPASS, a number of organizations and institutes have been developed to train scientists for communication and engagement with the public, perhaps most notably the Alan Alda Center for Communicating Science at Stony Brook University, and academic fellowship programs, such as the Leopold Leadership Program at Stanford University and the Wilburforce Fellowship Program, have been established for the same purpose."

Jan 1, 2017

By Ray Nivens, Umit Turunc, Caroline Sui, Nick Morrison, Douglas Steiner

"In most copper mines and concentrators, mill water is continuously recovered and reused, with fresh water added to make up for losses. When mixed, these water chemistries can lead to severe scaling, especially in pipes, tanks and pumps on the mill water supply side, reducing flows and causing significant production losses.At KGHM Robinson Nevada Mining Company, increases in the fresh water addition ratios resulted in severe scaling problems and premature pump failures thereby jeopardizing plant production. What initially appeared to be a few isolated scaling events eventually unfolded into a recurring pattern of water supply-related production losses with increasing severity. Through completion of detailed root cause analysis, chemistry modeling, laboratory work, in-plant testing and system engineering, the mechanisms of scaling were identified and addressed.Advancements in fresh water addition practices and antiscalant application methods resulted in a stepwise reduction of the mill water scaling. Cost savings and production benefits were significant to the plant’s financial metrics.IntroductionThe production of mineral and metal concentrates using the flotation process requires large quantities of water. Flotation is utilized as the primary means for beneficiation with sulfide ores. Mined ores are crushed and ground into a slurry of 20-55% solids. For each ton of ore, 400-900 gallons of water1 are needed to supply the grinding mill. Additional water is needed in the flotation circuit as well. With many modern mills operating at2 11,000-165,000 tons/day, water supply volumes can be upwards of 3,000 gpm to 100,000 gpm of flow.For plants operating at or above capacity, disruptions and restrictions in water supply flow can have a direct impact on the production and recovery of the metal. Water supply flow can be limited for a wide variety of reasons but of interest are those limitations that are due to mineral scaling. Mineral scaling is the selective point precipitation of inorganic species above saturation concentrations. Precipitated species form flow-restricting deposits in the mill water system (tanks, pumps, pipe and valves), that will eventually impact water supply to the concentrator."

Jan 1, 2017

By Michael Laing

Blasting regulation and restrictions are tougher today than ever before. When blasting in population centers, strict limitations are often placed on the environmental effects caused by blasting, more specifically vibration and overpressure. Blast-induced vibration can be a tricky thing to manage at times, but there are a variety of options at our disposal to help optimize and manage vibration. This paper focuses on the application of rudimentary signature hole analysis to optimize blasting vibration in localized areas surrounding a mine.

Jan 1, 2017

By Stephen C. Tadolini, Minova USA Inc., Peter S. Mills, David R. Burkhard

"Fiber-reinforced spayed concrete has been used for several years in civil and tunneling operations. Research conducted to reduce cure times and increase compressive and flexural strengths resulted in the development of Tekcrete Fast®, a cementitious product capable of obtaining 41 MPa (6,000 psi) compressive strength and 8 MPa (1,200 psi) flexural strength in only 3 hours and reaching 7 day strengths of 62 MPa and 11.7 MPa (9,000 and 1,700 psi), respectively. A single bag product that uses conventional shotcrete and gunite application systems make it a natural crossover product for mining applications. The discovery of incredible adhesion properties and high resistance to chloride permeability helps ensure long-term stability and increases the ease of application. Project results from Disaster City® in Texas and the application for rehabilitating a coal mine belt entry are presented. The case study illustrates the effectiveness of the product in stabilizing a coal mine beltway and adjacent cross-cuts that were subjected to progressive sloughage due to humidity and cyclical loading. INTRODUCTION Original research produced a shotcrete formulation that extends beyond stabilization and can be used to restore the structural integrity of damaged infrastructure. The primary challenge was to develop a shotcrete or gunite that had structural strength within a few minutes to prevent parasitic loading, allowing ingress into damaged structures minutes after applying the mix formulation. This also applies to mining conditions where rapid support of progressive failures can minimize failure. An additional benefit was discovering that the product had extremely high adhesion properties in addition to high flexural strengths. The approach to product design was the development of “single bag” dry mixes that are entirely self-contained, can be rapidly transported anywhere in the field or underground, and can be deployed using simple equipment. Dry mix eliminates issues relevant to high shear water mixing because water is added in the form of a mist at the point of delivery; thus a low water-to-cement ratio can be achieved. However, since there is no onsite powder mixing, the product must have a high degree of inherent homogeneity. Minova offers a commercial version of this material, Tekcrete Fast®, a product that has been successfully deployed in the mining industry and is currently being used in civil, construction, and tunneling operations. The material can rapidly stabilize lose ground in metal, nonmetal, and coal mines. This paper described the technology development, product testing results, and applications and describes a case study to stabilize a coal mine beltway."

Jan 1, 2017

By Farzad Khodabakhshi, Adrian P. Gerlich

"Multi-pass friction stir processing (FSP) was performed to fabricate a new Al-Mg-Graphene nanocomposite. Microstructural developments and distribution of graphene were studied by using electron backscattering diffraction (EBSD) and transmission electron microscopy (TEM) analysis. In the stirred zone (SZ), grain structure was refined down to about 2 µm attributing to the operative dynamic restoration mechanisms and the locking effect of graphene phase. As a result, the yield strength of Al-Mg alloy was improved more than two times due to incorporation of graphene nano-sheets. Also, the indentation hardness resistance of nanocomposite was increased up to ~60%.INTRODUCTION Aluminum-matrix nanocomposites have garnered significant in recent years due to their superior performance and potential advantages for several industrial applications including the automotive and aerospace sectors. Among various reinforcing nano-materials, carbon-based structures featuring sp2 or sp3 hybridization bonds have been found to offer considerably improved physical and mechanical properties. Such carbon allotropes form at micro- and nano-scales including; graphite, carbon nano-tube (CNT), nano-fiber, and graphene. The potential of two-dimensional (2D) carbon materials was introduced in 2004, with the development of graphene as an alternate 2D allotropic form of the carbon structure with a honey-comb lattice at the atomic-scale. It has been shown that it is currently among the strongest materials ever tested with an intrinsic tensile strength of 130 GPa and Young’s modulus of 1000 GPa, and also offers unique thermal and electrical properties.To fabricate metal-matrix nanocomposites reinforced by graphene nano-sheets with typical metallurgical processing techniques, some attempts have been reported in the literature for various solid-state techniques including; hot rolling, mechanical alloying, and friction stir processing (FSP) of pre-cast plates or surface dispersed graphene oxides. The main challenge in those methods was to facilitate the considerable high temperature and pressure for attaining a uniform dispersion of the nano-sheets during the consolidation process. In most cases, significant difficulties have been reported in obtaining a uniform dispersion of graphene within the metal matrix. Among various techniques for production of metal-matrix nanocomposites, FSP has attracted significant attention as a method of surface modification since it was first reported by Mishra et al. In this process, a non-consumable rotating tool is plunged into the surface of material for the aim of microstructure modification. Extreme material plasticity is induced without melting as a result of friction between the tool and workpiece. Frictional heating and severe plastic deformation induced by the FSP process enables metal matrix nanocomposite fabrication by softening the base material and mechanical stirring to disperse the reinforcing nano-materials into the matrix."

Jan 1, 2017

By D. C. R. Espinosa, P. Aliprandini, J. A. S. Tenório, M. M. Jiménez Correa

"Nickel and cobalt are the main value metals in nickel laterite ore. Cyanex 272 is an extractant used to separate nickel from cobalt present in leach solutions. Previous studies demonstrated the extraction of cobalt, magnesium and manganese at pH 5 using Cyanex 272 as extractant, while nickel remained in aqueous solution. However, it is difficult to separate cobalt from a solution containing magnesium and manganese. One possibility to change the metals’ behavior during the solvent extraction process is to change the mixture of extractants used. In order to study the solvent extraction of cobalt from a solution containing manganese, magnesium and nickel, a mixture of two extractants was investigated. Cyanex 272 (CY) and Versatic 10 (VC) were selected as extractants in the organic phase. The extractant concentrations used were: 20% CY; 15% CY, 5% VC; 10% CY, 10% VC; 5% CY, 15% VC; and 20% VC. In all cases, kerosene was used as a diluent, at 80 vol%. The synthetic leach solution used in this study was prepared according to the composition of a typical nickel laterite leach solution. The pH value of the solution used was 5, and the aqueous/organic ratio used in solvent extraction testwork was 1/1. The study has shown that the composition of the organic extractant mixture did not increase cobalt separation.INTRODUCTION Sulfide and laterite deposits are the main sources of nickel. However, production from nickel sulfide ores has been decreasing over the years, relatively speaking, increasing the focus on the exploitation of laterite nickel ores (McDonald & Whittington, 2008). Laterite ore deposits are found in tropical and subtropical regions. A characteristic of laterite ores is the presence of a complex and heterogeneous mixture of metals (Crundwell, Moats, Ramachandran, Robinson, & Davenport, 2011; Georgiou & Papangelakis, 1998; Gupta, 2003; Kesler & Simon, 2015; Moskalyk & Alfantazi, 2002; Oliveira, 1990). Nickel concentrations in laterite ores are typically 1–2% (Dalvi, Bacon, & Osborne, 2004)."

Jan 1, 2017

"Cast blasting is the primary means of overburden displacement in a surface coal mine. It serves two purposes; fragmenting the rock and throwing it directly to its spoil pile using explosive energy. Increased throw minimizes costs by reducing the amount of material that needs to be re-handled. Prior studies have shown that by only changing blast hole timing with the same blast design, fragmentation and throw alters. It is necessary in cast blasting to optimize both fragmentation and throw, since larger fragments will require more wasted energy to throw the same distance. In an operating mine in Georgia, an optimum inter-hole delay for fragmentation has been found by studying timings from 0ms to 45ms. Instantaneous timing between holes increased the throw by over 100 ft, but fragmentation was poor. Shock and detonation wave collision is a potential reason for this increased throw. This paper investigates this optimized inter-hole timing while altering top and bottom column primer time to potentially improve throw while maintaining optimum fragmentation. Timings studied are top initiation, bottom initiation, and top and bottom simultaneously. INTRODUCTION Explosives are utilized extensively by the mining industry in order to break rock, as either ore or overburden, for hauling, loading, and crushing. An effective production blast strives to achieve optimum rock fragmentation in order to increase the efficiency and reduce the costs of those downstream operations, while simultaneously meeting environmental regulations. The goal of blasting with respect to fragmentation is, according to Hettinger (2015), “to decrease the average particle size of the fragmented rock without overly increasing fines or, in other words, improve fragmentation.” Additionally, the distance the rock is transported by the explosive energy from the blast, also known as throw, can increase efficiency by reducing the amount of material that is re-handled by mine equipment. The primary situation in which this is desirable is the cast blasting of overburden across the narrow pit of a surface coal mine. A key variable in a blast design pattern that can be manipulated to optimize both fragmentation and throw is delay timing between detonations. The invention and increased utilization of electronic detonators has allowed for precise delay timings to be used between rows, holes, and even multiple primers within the same hole. These recent developments in the blasting community have also provided an opportunity to investigate whether or not the mechanism of shock or detonation wave collisions caused by short timing delays are responsible for any increased fragmentation or throw. This experiment attempts to demonstrate if an increase in throw can be achieved while maintaining optimum fragmentation. This study consisted of 3 full scale bench blasts at a granite quarry in Talbotton, GA. Each blast was characterized by the timing delay between the top and bottom primer in the blast column of each hole; one simultaneous blast with a 0 ms delay, a bottom-initiated blast with a 1 ms delay, and a top-initiated blast with a 1 ms delay. Fragmentation analysis of the resultant muckpiles was performed using a combination of the PortaMetrics handheld point-and-shoot rugged tablet from Motion Metrics and the software WipFrag from WipWare. Throw was measured by placing strategic distance markers on the floor of the bench and then taking overhead photographs of the muckpiles after each blast. High-speed video footage was captured of each blast using an MREL Blaster’s Ranger II camera."

Jan 1, 2017

By J. Herbst, J. Groppo, A. Noble, R. Q. Honaker

"Coal and coal byproducts produced annually contain a sufficient amount of rare earth elements (REEs) to meet current U.S. demand. The REEs exist in the form of minerals, ion-adsorbed elements associated with clays, and chemically bonded elements within the organic coal matrix or host mineral. Researchers at three universities collaborated to evaluate the effectiveness of existing physical and chemical concentration processes for the recovery of the REEs. The efforts found that physical separation processes can increase the total REE content in the thickener underflow material collected from a Central Appalachian coal cleaning facility from around 300 ppm to values greater than 17,500 ppm on an ash basis. Leaching followed by solvent extraction was found to be the most effective to recover the REEs from coarse middlings materials collected from multiple coal basins, as indicated by recovery values exceeding 80 percent. Based on material characterization data and process evaluations conducted for several potential feed coal sources, economic recovery of the REEs will require byproduct production of both clean coal and REE concentrate using a process flowsheet that is unique for each source. IntroductionRecent studies initiated by the National Energy Technology Laboratory showed that U.S. coals contain significant amounts of rare earth elements (REEs), suggesting that rare earth minerals (REMs) and/or REEs can be produced as byproducts (Ekmann, 2012). According to the report, the richest source of REEs is the Central Appalachian coal. At present, there are 208 coal preparation plants located in the region consisting of areas within the states of West Virginia, Kentucky, Pennsylvania, Virginia, Alabama and Tennessee, with a total capacity of 166,495 t/h, or more than 1 Gt/y (Fiscor, 2014). If only a portion of these plants are retrofitted with advanced separation processes, the U.S. coal industry would become a significant producer of REE concentrates as byproducts. An inherent advantage of becoming a byproduct producer of REEs is that no mining cost needs to be part of the production cost."

Jan 1, 2017

"Real-time, on-stream analysis of the metal content of process slurries is an essential prerequisite for process monitoring and advanced control of mineral processing circuits. On-stream X-Ray Fluorescence (XRF) sensors for base metal applications are available commercially and form the basis of many plant monitoring circuits. To date, these commercial technologies have been insufficiently sensitive to measure precious metals such as gold and platinum group elements, typically present at part-per-million (ppm) and sub ppm levels. CSIRO has developed a novel X-ray based technology, called UltraGold, which enables detection of gold in slurries on a real-time basis with a precision below 100 parts-per-billion. This technology is based on the use of advanced X-ray optics, extensive Monte Carlo computer modelling for analyser design, high accuracy X-ray spectrum fitting where the X-ray intensities are matrix corrected. In this paper, we will introduce this technology and discuss the results of a proof of principle study performed in the laboratory with plant slurries (tailings and concentrate) from an Australian beneficiation plant. Finally, we will discuss further planned improvements. As projected grades in (gold) mining around the world fall and several large-scale mines approach the limits of their economic reserves, this method can enable significantly reduced operating costs by rapid analysis to improve circuit efficiency and hence improve recovery significantly.INTRODUCTION This paper describes a study undertaken to explore the feasibility of applying CSIRO?s UltraGold XRF technology to the on-stream measurement of gold in process slurries. The provision of rapid, accurate information of gold grade in feed, tailings and concentrate streams would facilitate significantly improved process control and early detection of plant upsets, resulting in substantial cost-savings. CSIRO have patented X-ray fluorescence (XRF) techniques for the analysis of key elements in slurries present at part-per-million (ppm) and sub-ppm levels. Conventional, commercially available on-stream XRF instruments generally have detection limits in the tens of ppm range, precluding their use for analysis of elements like gold that are mined and processed at much lower concentrations."

Jan 1, 2017

By Ekin Güngor, Berkant Ozdemir, Erkan Bayrak, Serdar Ergün, Sedat Esen

"This paper presents the final wall blasting practices at Eldorado Kisladag Gold Mine in Turkey. Benchmark and improved wall control designs were explained in detail. Kisladag Mine has been implementing a high quality slope stability program on-site. The quality of pit walls is generally considered excellent, with very few wall failures being evident and with presplit hole barrels prominent in most areas of the pit. However, a minor scale slope failure occurred recently at the north-east section the pit. A project was initiated to diagnose the cause of the crest loss and evaluate ways to limit its effect on final walls. Final wall blasting practices and geotechnical designs were evaluated. The work presented in this paper showed that changes to the blasting and geotechnical parameters are required atthe north-east section of the pit. Geotechnical design changes were 10 m bench heights with 70 ° slope face angle at that specific area. Having implemented several geotechnical and blast design changes (elimination of the subdrill for the catch bench, appropriate primer location, more favorable blast tie-up and delays), the crest loss was minimized significantly (<1.5 m) (<5 ft)."

Jan 1, 2017

By G. R. Waters

"The technology behind industrial applications such as Hydrometallurgy continues to evolve, as do the corresponding regulations and specifications that ensure the safety of workers and the environment. Valves make up key aspects of this technology, and often represent the single point of failure for entire operations. More often than not, the valves being used in Hydrometallurgy applications are known as Severe Service Valves (SSVs) due to their ability to withstand the extreme conditions. Most experts agree that SSVs are identified by applications, and that these applications are challenging to the valve’s ability to provide a minimum acceptable level of performance over a minimum acceptable duration. The Manufacturers Standardization Society (MSS) of the Valve and Fittings Industry has designated Ross Waters, President of CGIS, as Lead to the Task Force put in place to determine the minimum requirements a valve needs to be able to perform to when faced with extreme conditions, whether from pressure, temperature, toxicity, solids, or usage. This paper serves to determine what the minimum requirements are for SSVs in Hydrometallurgy applications. It will draw on five decades of industry experience from one of Canada’s leading valve experts.INTRODUCTION Severe Service Valves Severe Service Valves (SSVs) mean different things to different people. Until today, defining SSVs had little if any global agreement or recognition. That is about to change as the Manufacturers Standardization Society (MSS) has accepted an application to produce a Standard Practice so defining them. This paper provides information about the selection of SSVs in all industries but focusses on metallurgical processes and applications and offers examples to illustrate the successful and unsuccessful use of these valves. All of this with the purpose of raising the awareness of the industry on all sides, from the suppliers and manufacturers, specifiers and to the users and owners of them. It also supplies tools to understand where and why to separate SSVs from general purpose or commodity valves (GPVs). SSVs are often identified by applications, and these applications are challenging to the valve’s ability to survive. Within these applications the elements that make the service severe are being analyzed, quantified and qualified. From this, we expect to offer objective and repeatable definitions and guidance to improve the experience of SSVs, reduce unnecessary costs, provide longer service life and process runs, improve safety and reduce environmental issues."

Jan 1, 2017

By Olanrewaju A. Ojo, Xu Wang, Jian Xin Dong, Lina Zhang, Jerzy A. Szpunar

"The influence of crystallographic orientation on the pitting corrosion behavior of Ni-Fe-Cr alloy 028 was studied by a combination of X-ray diffraction (XRD), electron backscatter diffraction (EBSD), potentiodynamic polarization technique and atomic force microscopy (AFM). The results show that there is anisotropy of pitting corrosion that strongly depends on crystallographic orientation of surface planes. The distribution of pits frequency in standard stereographic triangle shows that the crystallographic planes close to {100} are more prone to pitting corrosion compared to planes of {110} and {111}. The calculation of surface energy (001) and (111) shows that the planes of high packing density of atoms have low surface energy with concomitant strong resistance to pitting corrosion. A correlation function between crystallographic orientation and pitting corrosion susceptibility suggests a method not only to predict the pitting resistance of a known textured materials, but also to improve corrosion resistance by controlling materials texture.INTRODUCTIONNickel-iron-chromium(Ni-Fe-Cr) alloys are widely used in various industries and engineering sectors due to their combination of good mechanical properties and high corrosion resistance(Hibner, 2001; Thomas, 2006; Ghosh, 2005).Ni-Fe-Cr alloy 028 (alloy 028)has such important characteristics worth mentioning. Alloy 028 contains high amounts of nickel, copper and molybdenum which improve its resistant to corrosion attack in reducing medium, and presence of high level of chromium makes it more resistant to oxidizing species. Moreover, alloy 028 is less expensive because of higher amount of iron compared to other similar alloys. Currently, alloy 028 is manufactured as evaporator tubes applied in the phosphoric acid production; production tubing and casing used in deep and sour gas wells; heat exchangers employed in nuclear power plants, and seawater-carrying piping and seawater-cooled heat exchangers (Bankiewicz, 2012; Kivisäkk, 2003; Gómez, 2003; Xian, 2012; Bellezze, 2004)"

Jan 1, 2017

By María Rocha, Benjamín Cebrián, Roberto Laredo

"Ring blasting designs have to achieve different goals in order to become efficient whether is done in up hole or downhole fashion. Ore recovery/dilution control, fragmentation and drift integrity all have to be taken into account when selecting parameters such as burden, spacing, linear explosive density and stemming. Blast energy simulation allows identifying contours of rock breakage and fragmentation, thuschoosing a combination of spacing at the end of holes and appropriate burden. Also, simulations are keyto concentrate energy levels on the mid part of the ring while making sure there is not too high of energy concentration around the drift, which integrity is needed for a safe ore mucking."

Jan 1, 2017

By T. W. Camm

"We hear all the time about the value of hard work and perseverance, and the part they play in the professional life of successful people. What we do not hear so much about are the many professionals who work hard and persevere, yet never seem to quite reach the level of success they aim for. Some current authors are beginning to give more attention to the part luck/black swans/outliers play in success. This is not a new phenomenon, Machiavelli had a lot to say about it back in the Renaissance. So how can knowledge of this dynamic help in a modern organization? INTRODUCTION Work hard and you will succeed. Go to the right school, major in the right degree, study hard, and get a good job. Look at the lives of successful people, and do what they do. Be all that you can be. You can be anything you want to be. Really? Those who are successful always get attention, people want to know what they did to reach such a high position. Invariably, at least part of their narrative will include hard work, wise insight, taking advantage of opportunities, etc. If they are of a more generous nature, they might also allow that building the right friendships and collaborations also played a role. All of this may be true; what we do not often hear are the stories of those who did all of these very same things, but did not find success. An example from pop culture: The Voice. I have watched this show occasionally the past couple of years. One of the things I like about the show is that the initial screening of contestants is based solely on their singing voice (hence the name of the show), and not on their appearance. At the time of this writing (early November), the judges have just finished elimination rounds for their final teams to go on to the live shows. Here is my point—in almost every case the judges agonized over choosing who would go forward and who would be eliminated. And the reason is because all of them are really talented singers. It is impressive how gifted they are. At the end of each season, only one is declared a winner, out of that gifted pool of singers. When you hear their stories, they are all talented, hard-working individuals sacrificing for their art. And as far as I know, none of them has ever become a star. Hard work, dedication, sacrifice, talent—sometimes it is enough, sometimes not. I will be looking at the part uncertainty/luck/black swans play in our lives, but I want to make it clear at the beginning that I am not saying everything that happens to us is out of our hands or beyond our control. Taleb makes this same point (2007, p. 52): “This problem is chronic: if you tell people that the key to success is not always skills, they think that you are telling them that it is never skills, always luck.”"

Jan 1, 2017

By X. Zhou

"Hydrogen induced failure and degradation in structural metals, namely hydrogen embrittlement, has been a long-standing industrial problem for more than one century and remains unsolved. Despite the proposal of numerous models, no consensus has been reached, and considerable discrepancies in experimental observations and theoretical calculations exist. One aspect that is central to the understanding of hydrogen embrittlement is the interaction between hydrogen and grain boundaries. In this study, we investigated the influence of several solute elements (i.e., Cr, Mo and Nb) on hydrogen segregation at the representative 9 grain boundary using first-principles calculations. Our results showed that the presence of Mo and Nb can reduce the tendency of hydrogen segregation at grain boundaries, while meanwhile enhance the grain boundary strength. This indicates that Mo and Nb are salutary elements that can be used to increase the material’s resistance to hydrogen embrittlement, providing new insights in designing hydrogen embrittlement resistant Ni alloys. INTRODUCTION Hydrogen embrittlement (HE), a phenomenon of hydrogen triggering premature failures in structural metals, has been a headache for industries ever since its first discovery one century ago (Johnson, 1874; Zhou, Marchand, McDowell, Zhu, & Song, 2016; Zhou, Ouyang, Curtin, & Song, 2016). It is well accepted that the segregation of hydrogen at microstructures such as grain boundaries (GBs) plays a key role in determining the occurrence and severity of HE. GBs are two-dimensional defects where significant local lattice distortion exist, which leads to large free volume and thus locations for hydrogen trapping and segregation. Numerous works have clarified GBs as the energetically preferable places for hydrogen segregation. For instance, Geng et al. demonstrated the preferential segregation of hydrogen at the S5(120) GB in several metals, and suggested a decohesion-type of HE in light of Rice-Wang thermodynamic theory (Geng, Freeman, & Olson, 2001). Birnbaum et al. illustrated that complete intergranular crack of Ni GBs can be induced by hydrogen segregation when the hydrogen concentration is sufficiently high, evidencing the significant role of hydrogen accumulation on GB weakening (Lassila & Birnbaum, 1987). Yamaguchi et al. demonstrated strong segregation hydrogen also occurs at S3 GBs in alpha-iron, showing that local hydrogen clustering (i.e., multiple hydrogen atoms, up to six, per unit cell) can be trapped at the S3 GB (Yamaguchi, Kameda, Ebihara, Itakura, & Kaburaki, 2012)."

Jan 1, 2017

By Gregory M. Landry

"There is an old joke at Moretrench that defines dewatering as “that element of an underground construction project, which, when disregarded, will generate the low bidder.” Sigmund Freud wrote that all jokes are true, and the kernel of truth behind this one is that dewatering is often misunderstood or neglected until the last possible moment in the life of a project. The purpose of this article is to describe commonly used dewatering methods and to clear up a pervasive but fundamental misunderstanding about how to determine the amount of dewatering effort required for a project. The Tools of DewateringDewatering may be divided into two broad categories: (1) methods that remove water from the excavation after it has already entered and (2) methods that seek to exclude or intercept the water before it reaches the excavation. The former is generally self-performed by general or earth moving contractors using sumps and ditches, while the latter is usually done by a specialty contractor. SumpsProperly installed sumps can be an effective and economical way to control water inflow into a site. In this technique, groundwater is allowed to enter the site before being pumped away. Advantages of this method include lost cost, easy availability of equipment and the fact that a general contractor can self-perform the dewatering. However, caution should be used when deciding whether to use this method, and consideration should be given to the following factors:1. How will the soil behave under seepage forces? Will it run, potentially causing ground loss?2. How much groundwater lowering is required? If the groundwater only needs to be lowered a few feet, using sumps will be much more practical than for a situation that requires significant drawdown.3. Will the excavation subgrade soften or otherwise be damaged by allowing water to run over it?4. Is my workforce skilled enough to implement and manage the sumping plan?In the photo, the sump is capturing groundwater that has already entered the excavation by traveling under the sheets. In this instance, the house in the background of the photo was eventually purchased by the project owner after sustaining damage due to ground loss."

Jan 1, 2017

By Jin-Wei Huang, Bradley J. Fleming, Sri Sritharan

"Although soil improvement and its application to deep foundations is gaining popularity in the engineering community, this technique is not widely used in high seismic regions due to lack of fundamental understanding of both the behavior of improved soils under high-strain cyclic loading and the interactions between the pile, improved soil, and unimproved soil. This paper describes part of an ongoing Network for Earthquake Engineering Simulation (NEES) project, where two identical full-scale steel pipe piles were driven at a soft clay site in Oklahoma. The soil surrounding one of these piles was improved using the cement deep soil mixing technique in order to enhance its lateral load behavior. Both piles were tested for seismic resistance using dynamic and quasi-static loading.The pile in unimproved soil provided larger displacements with limited lateral force resistance. This pile was subjected to lateral displacements of up to 400 mm, but experienced minimum inelastic actions. On the other hand, the pile in improved soil reached its lateral capacity at a displacement of 100 mm, at which point the critical region at the base of the pile just above the improved ground experienced buckling and fractured due to low cycle fatigue. Compared to the pile in unimproved soil, the improved ground increased the system strength by 42%. Although the soil was improved over 2900 mm, the effective improvement depth was approximately 1300 mm below the ground surface.In this paper, it is demonstrated that the effects of block type soil improvement of limited horizontal and vertical dimensions can be described using a simplified theoretical approach involving a modification to the well-known p-y representation of soil response. An example using this method is presented and shown to give adequate support to a standard 12-inch diameter steel pipe pile embedded in soft soil,IntroductionPilings are the preferred foundation support for many civil engineering structures including highway bridges, railroad bridges, and port wharves. These structures and their foundations are subjected to forces created by earthquakes, wind, waves, water current, vessel impact, ice, and gravity. All loads applied to the superstructure must be transmitted to the foundation where they are resisted by the surrounding soil. With significant lateral loads, use of pile foundations may be the only solution to transmit large structural loads to competent soils. Piles supported by competent soils are relatively easy to design and costs are often attainable. However, thick layers of weak soils such as soft clays are widespread in high seismic areas (e.g., San Francisco, southern Nevada, Washington, Eastern Missouri, and Arkansas), exacerbating design challenges. Soft clays reduce the lateral resistance of the pile-soil system, making the pile foundation less cost effective. In this case, the current design practice is to use an increased number of larger diameter piles, which is a costly alternative (see SDC, Caltrans 2010). An innovative and more cost-efficient solution to this problem is to improve the soil within a short depth surrounding the foundation, thereby increasing its lateral stiffness. Some well-known methods for improving soil include deep soil mixing, stone columns, and simple soft soil replacement with select granular material."

Jan 1, 2017