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By Cleusa Cristina Bueno Martha de Souza

Hydrometallurgical techniques for processing metals are becoming an efficient method for recovering metals. Although batteries' manufacturers have got rid of mercury content, some efforts have been made for recovering other metals enclosed in the battery formula. This paper discusses the bench scale experiments in the purification process of leached solutions from alkaline spent batteries. After leaching process using sulfuric acid as leachant, the solutions containing Fe, Cd, Pb, MIl, Zn and K were neutralized to precipitate iron hydroxide. In a second step, the purification experiments were carried out with excess of zinc dust to try to remove Cd while Mn and Zn still remain in the solution to be recovered in an electrolysis stage. The purification experiments procedures were conducted at different temperatures and times to find out properly conditions from the viewpoint of metals removal After filtration the solutions were submitted to chemical analysis to certify the metals content extracted.

Jan 1, 2001

By Nathanael Hudson, Ruel A. Overfelt, Sushil H. Bhavnani

"In the aerospace and automotive industries, complex shapes exist which require casting. The problem with these cast parts is the empiricism required to develop the casting process and the accompanying time and expense to develop that process.There has been an interest in using fluidized beds to allow molding sand to better encapsulate the complicated surface geometries of lost foam patterns. Fluidization coupled with a mixing jet helps to homogenize the sand through stirring and may improve the integrity of the casting.At issue is the hydrodynamics of the sand and air around the foam pattern. The commercial package PHOENlCSTM is used to simulate the flow around the pre-casting foam geometry. Employing a two fluid approach, each component is considered a fluid that interpenetrates the other phase. To this end, the kinetic theory of granular 'flow for the sand phase was incorporated into the re-compilable PHOENlCSTM code.The results of this study consist of time-averaged void fraction patterns, with voidage being defined as the fraction of air in the mixture, around the foam pattern submerged in a two-dimensional fluidized bed. The model was benchmarked against past fluidized bed experiments. In order to better understand the dependence of the void fraction pattern around the lost foam pattern, certain physical parameters are varied and the resultant void fraction maps are predicted with the model. Physical parameters such as the aspect ratio of length to width, the placement of the mixing jet, and different mixing jet velocities are varied to illustrate the dependence of the time-averaged void fraction on those variables.Results consistently indicate the presence of channeling around the lost foam pattern, with the extent of the channeling and void formation reliant to a greater degree upon the placement of the mixing jet, and to a lesser degree on mixing jet velocity and aspect ratio.The increase in radial position of the mixing jet from the bed centerline had the desirable effect of granting the churning benefits of a penetrating jet, while at the same time minimizing the formation of excess void fraction at the top of the pattern."

Jan 1, 2001

By John J. Jonas, Sang-Hyun Cho, Ki-Bong Kang

"The recrystallization behavior of Nb micro alloyed steels containing Cr, Mo, Ni and Ti. was studied using hot torsion testing with the aim of modeling the recrystallization processes and the mean flow stress taking into account the microstructural behavior during hot rolling. The kinetics of static and metadynamic recrystallization were characterized and appropriate expressions were formulated for the recrystallization kinetics. These are shown that the recrystallization kinetics depend on steel composition and the processing conditions. The stress-strain curves were determined in order to derive new equations for the peak stress, peak strain, mean flow stress and softening kinetics. The peak strain is influenced by the presence of alloying elements; their addition, which has a solute drag effect, retards the rate of grain boundary motion, shifting the peak to the right. The addition of Nb to the steel results in a significant increment in the activation energy for hot deformation, and Mo has smaller effect than Nb, but Cr has the opposite effect. It was also found that the deformation activation energy in these steels was not altered by the addition of Ni. The rate of metadynamic recrystallization increases with strain rate and temperature and is observed to be independent of strain, in contrast to the observations for static recrystallization.The mean flow stress (MFS) calculations, based on the Sims analysis, are then compared with the predictions of a model based on an improved Misaka mean flow stress equation in which solute effects, strain accumulation, as well as the kinetics of static and metadynamic recrystallization are accounted for. Good agreement between the measured mean flow stresses, which is obtained from the mill logs of POSCO Kwangyang #3 HSM (hot strip mill), and 'predicted ones is obtained over the whole range of rolling temperatures. The results demonstrate that dynamic recrystallization followed by metadynamic recrystallization, supported by the unexpected load drops, sometimes occurs for the rolling schedules studied in the present analysis."

Jan 1, 2001

By Deming Wang, R. A. Overfelt

"This paper presents a computer-aided heat transfer simulation method to predict the thermal characteristics of an alloy sample in a special furnace for directional solidification. A two-dimensional transient heat transfer by conduction combined with radiation is developed to calculate the energy exchange between a directional solidification furnace and the sample. Finite difference equations with control volumes are used to calculate the transient heat transfer. A special boundary control volume is used to combine heat conduction and radiation in the transient heat transfer. Heat radiation effects on the surfaces of the special control volumes with a changeable view factor during directional solidification processing are also represented. The simulation results are verified by measurable experimental data. Using the computer simulation model, many thermal properties of the directional solidified castings can be obtained, such as temperature distribution, solidification velocity, the shapes and positions of the liquid/solid interface and thermal gradient at the interfaces. These are very important to analyze microstructure of casting alloys, avoid casting defects and control casting quality. 1 IntroductionIn directional solidification (DS) processing of castings, the temperature distribution, the interface between liquid and solid zone, thermal gradient in the mushy (pasty) zone and solidification rates are very important factors to analyze the microstructure and the casting quality. These variables affect the orientation and size of dendrites, shapes of grains, solute segregation and deleterious casting defects, such as microporosity, freckles and segregation channels. In order to avoid the casting defects, the temperature distribution and thermal gradients of castings during directional solidification must be strictly controlled. However, the structure of furnaces used for directional solidification is often complex. Heat transfer and temperature distribution within a casting not only depend on furnace temperature but also on the thermal properties of the casting alloy, crucibles, retorts etc. A more accurate heat transfer analysis."

Jan 1, 2001

By D Nourry

Optimising the blast is a major issue in the blasting business. It generally means acting on the blasting pattern (drilling, charging, detonating) in order to get a given æresultÆ. This result may either be related to economic reasons, such as the fragmentation influencing productivity, or technical reasons, for example vibrations and projections. Within the frame of the EEC funded Brite-Euram project entitled æBlast-ControlÆ, involving academic research and applied expertise, a general methodology was developed to approach such a problem and currently applied to the industrial partners of the project and final end-users of the generated results. These partners are the limestone ALZO quarry of the CALCINOR group in the north of Spain and the dolomite DMD (Dolomies-de-Marche-les-Dames) quarry of the LHOIST group in the east of Belgium. A first part of the project, over 18 months, was dedicated to establishing a clear relationship between productivity of operations from drilling to primary crushing and the fragmentation resulting from the blast. Extensive monitoring of blasting, production performance and fragmentation data was carried out and automatically collected into a database on both quarries. As expected, it appeared that excessive amounts of fines or boulders were substantially reducing productivity and thus profitability of the operation. Furthermore, an æoptimalÆ fragmentation was assessed for the quarries to run at the best (high throughput, low cost). The second and last part, for the remaining 18 months, was then dedicated to adapting the blasting practice in order to orientate the fragmentation towards a æbetterÆ one. A very common problem normally addressed by any consultant. Nevertheless, the target was not limited to solving the problem for these two quarries, but also to develop a generic method to address this blasting adaptation process and to implement it into a computerised tool. At this stage, it is then obvious that portability of the method and the system are major qualities to be looked for. This paper is aimed to present how this method was developed, how the system was implemented and how it was finally used.

Jan 1, 2001

By Edward M. Dowey

The concrete lining for a long 8.05 km (5 mi) section of New York City Water Tunnel No. 3 was cast in place. The contractor, Grow-Perini-Skanska, placed over76,841 m3 (100,505 cy) of concrete, pouring 24 hours per day, 5 days per week. The concrete was dropped 204 m (670 ft) to the tunnel level, transported by rail to a concrete remixer and pump, and placed in 146.3m (480 ft) of full circle forms. Some of the many challenges include the sheer magnitude of the job, navigating through drifts, a raise and curves, dealing with ground water inflows, and placing the concrete within time limits.

Jan 1, 2001

By Kéiko H. Hattori, Neil T. Pettigrew

"Abstract- The Legris Lake Complex is a northeast-trending, 7.3 km long by 3.5 km wide, maficultramafic intrusive complex located in the western Wabigoon Subprovince of the Archean Superior Province. It is one of a series of mafic-ultramafic igneous complexes, the most notable of which is the Lac des Iles Complex, host to Canada’s only producing Pd mine with reserves of 93.5 Mt grading 1.53 g/t Pd as of December 2001 (North American Palladium Ltd., Annual Report 2001). Cu-Ni- PGE mineralization was first discovered in the Legris Lake Complex by a local prospector late in 1999. Shortly thereafter, the property was jointly optioned by Avalon Ventures Ltd. and Starcore Resources Ltd., who continue to discover significant Cu-Ni-PGE mineralization.One of the most notable features of the Legris Lake Complex is the occurrence of extensive brecciation caused by multiple injections of volatile-rich magma. The Cu-Ni-PGE mineralization is hosted by leucogabbro within a 2 km long by 600 m wide, highly brecciated area in the northwestern area of the Complex. The mineralized rocks contain disseminated to blebby sulfides (1 to 5 vol.%), comprising chalcopyrite + pyrite ± pyrrhotite + millerite ± pentlandite, typically surrounded by epidote. The majority of the Cu-Ni-PGE mineralization displays low ratios of Pt/Pd (~0.20) and high ratios of Cu/Ni (~2.9), which are similar to those of the Lac des Iles and the River Valley mafic-ultramafic complexes. The lithologies in Legris Lake Complex bear similarities to the heterolithic gabbro of the Twilight and Roby Zone deposits at the nearby Lac des Iles mine. However, the mineralization at Legris Lake, which is restricted to leucogabbro overlying unmineralized clinopyroxenite, is similar to that of stratiform deposits such as the Stillwater and Munni Munni complexes. The mineralization at Legris Lake is best explained by the late-stage, immiscible separation of a sulfide melt from volatile-rich parental magmas and the subsequent minor redistribution of metals by deuteric fluids."

Jan 1, 2001

"The Cooperative Research Centre for Mining Technology and Equipment (CMTE) is funded by the Commonwealth Government, by its mining research members — the Universities of Queensland and Sydney and the CSIRO1, and by its industry members — BHP Coal, RioTinto R&TD, Hamersley Iron, Mining Technologies Australia, Pasminco, Shell Coal, WMC Resources, Advanced Mining Technologies, and Aberfoyle. The Centre conducts work aimed at improving the competitiveness of the Australian mining industry. The current work is focused in four areas: new mining and drilling systems, geological sensing, automation, and equipment maintenance and reliability. This paper describes much of the work in these program areas that relates to metalliferous mining. Mechanized Rock ExcavationThe disadvantages of the drill-and-blast excavation method are widely recognized and the last half of the 20th century has seen mining companies and mining research organizations aggressively pursue technology to excavate rock by other means. As discussed below, despite considerable effort and large amounts of funding, the quest for mining’s “Holy Grail” has been unsuccessful in all but the weakest rock types.COMRO (the Chamber of Mines Research Organisation) supported by the South African gold mining industry, spent three decades and (probably) tens of millions of dollars developing prototype drag bits and, later, impact breaking machines aimed at the mechanized stoping of narrow, tabular reefs. This work has not yet produced a commercially-attractive mining system. Work continues in South Africa to mechanize these stoping operations although now the emphasis is on the use of diamond-wire sawing techniques. This work remains in the experimental phase.Both British Coal and Germany’s Bergbau- Forschung spent many years developing techniques trying to extend the range of rock types which roadheaders could cut economically. Again, although new knowledge was produced, it is difficult to claim that any new commercial mining systems emerged from this work."

Jan 1, 2001

By Gunnar Eriksson

Computer simulation has become an everyday practice in thennodynamic and materials research. Advanced thennochemical algorithms take into account heat transfer effects and salient reaction kinetics when applied for process models. In particular, the combination of mass transfer or overall reaction rates with multi-component Gibbs energy minimisation provides an effective tool for simulation of industrial thennochemical processes and processing of materials. In this work the combination of rate factors with the Gibbs energy technique was studied by using the novel program ChemSheet, which operates through Microsoft's Excel® spreadsheets. Such processes as, for example, CVD of pure silicon production, titania pigment manufacturing, vapour pressure of Mercury in amalgams (in Hg-Iamp manufacturing) and melting behaviour of low-temperature alloys have been modelled. Provided that the thennochemical data is available simulations can be performed with any thennodynamic system. The calculation can be performed as an affinity study without a particular reactor model or with a specific reactor scheme.

Jan 1, 2001

By Paul C. Turner

In 1998, approximately 57,000 tons of titanium metal was consumed in the form of mill products (1). Only about 5% of the 4 million tons of titanium minerals consumed each year is used to produce titanium metal, with the remainder primarily used to produce titanium dioxide pigment. Titanium metal production is primarily based on the direct chlorination of rutile to produce titanium tetrachloride, which is then reduced to metal using the Kroll magnesium reduction process. The use of titanium is tied to its high strength-to-weight ratio and corrosion resistance. Aerospace is the largest application for titanium, and titanium cost has prevented its use in non-aerospace applications including the automotive and heavy vehicle industries.

Jan 1, 2001

By W. Barnett

The Limpopo Metamorphic Belt is a complex geological terrane with at least three major deformational events. Tectonically juxtaposed lithology, open to isoclinal folding, crosscutting and re-activated shear zones and metamorphic gneisses and schists make pit slope design and maintenance a risky business. Venetia diamond mine?s Cut 3 is planned to reach 360 m by 2011. The difficult rockmass created problems in the original pit and a new more comprehensive slope design was necessary. Nearly 9 km of geotechnical drilling were undertaken to produce a new geological model and provide geotechnical information near the final Cut 3 face. All existing data from the pit were brought together into a database. SRK Consulting were brought into the project to audit the process and provide most of the manpower for the data analysis. Existing failures were back-analysed and the geotechnical domains identified. Analyses of only the southern domains are discussed in this paper. Geotechnical engineers can design slopes at any angle, but it is up to the managers at the mine to decide what risk they are willing to accept in a slope design. Once the issue of risk was discussed and settled in respect of the consequences of failure, each of the main geotechnical domains were analysed to produce a slope design at5% probability of failure with 15% above the first ramp. A risk assessment of the design was then undertaken to determine what risk the design placed on the equipment, personnel and the profitability of the overall mining operation. The risk assessment indicated minimal risk to the operation. One of the main assumptions of the final design is that the pit slopes will be dewatered. A project was immediately put in place to determine a groundwater model for the mine and to thereby determine the best dewatering procedure. However, it should be obvious that it is practically impossible to prevent benches from getting briefly saturated with water during storm conditions. It was therefore necessary to look specifically at supporting the crests of the ramps in the problematic southern domains to guard against the possibility of crest failure during heavy rains. The data available were re-analysed toward this objective. Spiles were recommended as the most cost-effective support system, and a probabilistic approach was used in the design. The final design has a 5% probability of failure, and the analyses indicate a strong sensitivity of the required spile spacing to the strength of the reinforcement material that will eventually be used. The pit slope parameters derived as per the discussion in this paper have just begun to be implemented at Venetia Mine.

Jan 1, 2001

By I Grewal, B Klein

The Knelson Continuous Variable Discharge (CVD) is a continuous centrifugal gravity concentrator for high-mass yield recovery applications. It has four operating variables that enable control of mass yield, product grade and recovery namely: fluidisation water, bowl speed, pinch valve open time and pinch valve closed time. Plant testing of a pilot scale Knelson CVD6 was conducted to evaluate the effects of operating variables on mineral separation. The analysis of operating variable effects has provided a framework for the development of operating guidelines for the CVD.

Jan 1, 2001

By N Tyson

Throughout Australia and the world, there have been in recent years a number of incidents involving the reaction of ammonium nitrate based explosives with ground containing certain types of sulphides. This paper presents a comprehensive strategy designed to identify, assess and mitigate the risks involved with blasting in areas of reactive ground. Undertaking blasting in reactive or potentially reactive ground involves a degree of risk, the level of which is dependent upon the controls in place for specific sites; this in turn depends upon the degree of sound reasoning and judgement behind the implementation of these controls. Implementation of controls to minimise the risk of incidents also involves a measurable increase in production and blasting costs. To achieve a balanced solution to this matter, decision-makers need to understand how the risks eventuate, how they should be evaluated, and how control measures reduce the risk. Also required is an understanding of how the problem affects the economics of the operation, and the magnitude of this effect. It is the aim of this paper to provide a structured approach to gaining this knowledge, so that mine management, the workforce and explosive suppliers may jointly develop more effective economic and safe blasting systems for potentially reactive ground. Using a combination of fault/event tree risk assessment and semi-quantitative analysis, a structured approach to dealing with the issue will be illustrated.

Jan 1, 2001

By R. L. Lawson

I?ve been asked to appraise the global role of coal and mining, and the best place I can think of to begin is with the World watch Institute, which purports to monitor all things global. Last fall the institute?s magazine, entitled World Watch, in a cover story called for a worldwide campaign to outlaw the use of coal before this century?s end. To my mind the article began the campaign. However, the institute had to admit that no such ban will be possible unless there is special help and heavy intervention?that is, novel policies and punitive taxes. I?ll quote directly from the magazine to underscore the point: ?without them the market will continue to deceive us into thinking coal is cheap, abundant and irreplaceable?.

Jan 1, 2001

This paper summarizes the results from a project aimed at adapting scroll centrifuges for application to the dewatering of flotation concentrates. The main impetus for the project was to reduce the high cost and footprint size of the technology currently used to dewater fine coal. The technical challenge was to enhance solids capture by incorporating a laser-cut screen into the design of the basket. The project has shown that a pilot-scale scroll centrifuge can be used to dewater froth concentrate. A number of different basket designs were tested, the best results being achieved with a basket comprising a laser-cut screen of aperture 70 µm. The best result on a sample of untreated flotation concentrate, which was taken from the open trough flotation cells at a coal preparation plant (CPP) in NSW was a solids recovery of 82 wt% at a product moisture of 24.3wt%. By comparison the best product achieved with a conventional wedge wire basket was a similar moisture content but solids recovery was only 64 wt%. This could only be achieved after the feed had been artificially thickened. Conditioning of the centrifuge feed with polymer flocculants led to an increase in recovery up to 88 wt% with a moisture content of ca 25 wt%. It is thought that optimizing additive selection and conditioning parameters, as well as screen aperture and open area, could improve performance still further. The results were obtained using centrifuging conditions (centrifugal force, feed solids, feed rate) in the pilot-scale machine which should be possible to translate into conventional designs of commercial scale machines, without downgrading solids throughputs. However only with full-scale trials will it be possible to establish this assertion with certainty.

Jan 1, 2001

By T Ross, S Cameron

The requirement to use explosives in ground temperatures exceeding 50¦C is becoming more common as mines work to maximise the recovery of their resources. Orica Explosives was requested to assist in the development and implementation of æhot blastingÆ safe working procedures at Liddell Coal Open Cut in the Hunter Valley. The mine operator, Hunter Valley Earthmoving (HVE), had to contend not only with elevated temperatures in their overburden resulting from burning coal beneath, but also old underground workings which tended to exacerbate the problem. The paper discusses the following issues:the consultative process that was used to develop the procedures employed to ensure the process could be carried out safely; the technical issues surrounding blasting in hot ground, including temperature monitoring, product selection, application and design to ensure safety and performance were maintained; the need for confidence and trust in the team that was working together in a potentially hazardous environment, the emotive issues that were encountered and how they were addressed; the value of a regular review process combined with open and honest communication to ensure the procedures represented best practice and that all stakeholders understood the process; and the value delivered to Liddell Coal when sterilised areas of coal became accessible with little disruption to the mining process. The paper also discusses the challenges that were encountered in the Reservoir Block where proximity to major power lines and rail infrastructure meant that hot blasting procedures had to also consider vibration limits and the need for Energy Australia to disconnect the power.

Jan 1, 2001

By J. Peterson, D. D. Tannant, J. Todd

"A review of blast designs and improved blasting practices at the EkatiTM diamond mine is presented along with the results of three blast-monitoring experiments. Blast monitoring was undertaken to investigate blast damage mechanisms in the mine’s well jointed rock mass. Rock mass damage caused by production, pre-shear and wall control blasts was measured. EkatiTM uses 270 mm holes for production blasting, and 165 mm holes loaded with a decoupled charge for pre-shearing. The production blasts are loaded with bulk emulsion/ANFO blends. The mine plan involves using 30 m double benches. A 30 m high pre-shear is drilled and blasted prior to the production blasting that is done with sequential 15 m benches. This paper summarizes the monitoring equipment and data gathered to date. IntroductionThe EkatiTM diamond mine is located about 300 km northeast of Yellowknife, Northwest Territories, Canada. The mine is a joint venture of BHP Diamonds Inc. (80%) and geologists Charles Fipke and Stewart Blusson (10% each). The EkatiTM mine is Canada’s first diamond mine and BHP is the operator. The mine is accessed by air and by a winter ice road.The first kimberlite pipe mined at EkatiTM is known as the Panda pipe. The Panda open pit mine will have a total depth of 315 m (Fig. 1), a width of about 600 m, and a 50° overall slope. Initial ore production is 9000 tonnes per day.This paper summarizes the pre-strip blasting and the evolution of the production and wall control blast designs from 1997 to 2000. The initial blast designs and the rationale behind subsequent changes that took place are presented along with the techniques currently in use.The paper also briefly presents an experiment done to measure the rock mass response to blasting. Three blasts were instrumented with geophones, gas pressure sensors and time domain reflectometry cables. A brief summary of the instrumentation and data gathered is included."

Jan 1, 2001

By R. Vracar, D. Sinadinovic, Ž. Kamberovic

The paper presents a study on the oxidation of polymetallic gold ore by oxygen in an autoclave. It presents optimum parameters of autoclave leaching of sulphide refractory ore in self-generated sulphuric acid solutions aiming to get products with favourable technological characteristics from which precious and other useful metals can be recovered. A high partial oxygen pressure (1.5 MPa to 2 MPa), high leaching temperature (190°C to 200°C), pulp density 80 g/L to 240 g/L, ore fraction size 76 µm and leaching time up to 4 hours yield good results in rich ores. The full extent of copper and zinc conversion as well as a high extent of iron conversion has been achieved, while lead, gold and silver and a minor part of iron remain as a solid residue among gangue minerals.

Jan 1, 2001

By T. Shi, Q. Yuan, S. P. Vanka, B. G. Thomas

"The quality of continuous cast steel is greatly affected by fluid flow in the mold region, especially involving transient phenomena. Mathematical models are being applied to investigate many different aspects of these phenomena, but their accuracy must be validated before they can be applied with confidence. As part of a long-term effort to develop and apply comprehensive models of the continuous casting process, this work evaluates the relative accuracy of models of three different fluid flow phenomena in continuous casting through comparison with measurements.Firstly, transient flow simulations of velocities in the mold region are compared with digital particle image velocimetry (PIV) measurements in a single phase water model. Large-eddy simulations (LES) are found to reasonably match the flow measurements, including transient flow variations, except at long time scales, which could not be modeled owing to the excessive computation costs. The standard K-e model produced very good agreement with time-averaged velocities for relatively little computation time, although it is inaccurate at predicting the transient variations. Secondly, particle trajectory calculations are compared with water model measurements to study the distribution and flotation removal of inclusion particles. The LES model was able to match the measurements both qualitatively and quantitatively. Thirdly, steady, multi phase flow computations are compared with flow patterns observed in both a water model and an operating steel caster with argon gas injection. For the same conditions, the water model and steel caster produced very different flow behavior. The computational model was able to match the measured flow patterns in both cases.This work suggests that computational flow modeling has the potential to match real processes as well or better than water models, especially when complex related phenomena such as particle motion and multiphase flow are involved. Much work is still needed to further improve the models and to apply them in parametric studies."

Jan 1, 2001

By M M. Collisson

The Synthetic Rutile (SR) plant operations, North Capel, produce electrostatic precipitator (ESP) fume and kiln scrubber residue. Typically ESP contains about 18 per cent Ti, 13 per cent Fe, 0.5 per cent Mn, eight per cent Si, six per cent Al, 16 per cent C, 0.9 per cent Zn, 0.6 per cent Pb, 300 ppm As, 300 ppm Cr and 5 ppm Cd. These wastes are held in a storage dam together with neutralised acid effluent (AE) liquor. A project was initiated to treat the fume and produce a benign residue that could be delivered to landfill, reducing dam space storage. Plant AE, containing free acid (9 - 14 g/L), Fe (6 - 7 g/L) and Mn (1 g/L), was used to leach ESP. The degree of extraction achieved for various elements include about 20 per cent Zn, almost 50 per cent As, five per cent Al, 0.4 per cent Pb and 15 per cent Cd. Extraction was most effective at pH The residue from AE leaching still contained Pb. TCLP tests of the leach residue produced Pb extraction significantly higher than the 0.1 ppm stipulated by Class 2 landfill guidelines. Other elements (eg As, Cd, Cr) successfully met the limits. Further leaching of the residue with EDTA extracted up to 65 per cent of Pb content. TCLP tests on treated residue showed Pb leaching potential of Lead was removed from the leach circuit as the sulphate by acidification of EDTA leach liquor, allowing EDTA to be recycled. The study showed that one waste stream can be used to treat another and help reduce plant waste.

Jan 1, 2001