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By Emil B. Milosavljevic

Problems associated with distillation and other classical methods for analyzing operationally defined cyanide (CATC, WAD, Total and Free Cyanide) will be discussed. These methods often achieve incomplete, species dependent cyanide recoveries and suffer from serious interferences. Depending on the relative concentrations of interferents and other matrix constituents, underestimation (ultimately Type II errors probability of not detecting a constituent when it is actually present) or overestimation (ultimately Type I errors -probability of deciding a constituent is present when it is actually absent) of the cyanide levels present in a ,given sample may occur, causing in the first case false security and in the second case, excessive cyanide treatment costs. Mahy, if not all, enumerated problems can be solved by using novel flow injection (FI) gas-diffusion amperometric methods. A modification of the recently approved FI ligand exchange (FIILE) method for determination of available cyanide (USEPA Method OIA-'l677) that obviates sulfide interference will be discussed. Eight laboratory round-robin data obtained for the FI UV -digestion (FIIUV) method that determines total cyanide (Proposed Method OIA-1678) will also be presented. In addition, some methods for cyanide speciation will be presented. Finally, research needed for developing reliable methods for determination of operationally defined cyanide in solid samples will be summarized.

Jan 1, 1998

By Rubén Alvarado

The markets and environmental protection rules are more and more exacting, both of which have determined that copper smelters should look for technological development and global management to ensure their viability and competitivity in the short and long term. The main facilities of the present and future Smelting-Converting Process at Codelco's Caletones Smelter, is based on Teniente Converter reactors with a high operational availability that have reached concentrate processing capacities near 2,000 tpd. These reactors are in operation in most of the smelters in Chile as well as in Zambia, Peru, Mexico and, in ?the near future, in Thailand. Since 1993, the Smelting-Converting process of the Caletones Smelter of Codelco-Chile has been based on one Reverberatory furnace, two Teniente Converters and four Peirce-Smith Converters. These facilities, together with the operation of two Fluidized Bed Dryers, three Slag Cleaning Furnaces, and two Oxygen Plants have allowed the smelter to reach concentrate smelting capacities and copper productions of 1,215 kt/year and 360 kt/year, respectively. This transitional operating scheme, combining together traditional and advanced technological equipment, needs further modernization to successfully face the modern world challenges, especially with relation to the environmental commitment, production costs and wide satisfaction of customers. For this reason, for the period 1997-2000, a Modernization Plan has been worked out. This plan considers an increase of the present throughput, which will permit a significant increase in productivity, as well as finding a definitive solution for meeting the environmental regulations. Among these projects, we can point out the definitive shut down of the Reverberatory Furnace, which is a contaminating piece of equipment of low energetic efficiency. Additionally, it considers the installation of two new Slag Cleaning Furnaces, one additional Oxygen Plant, and the incorporation of two new Sulphuric Acid Plants with a production capacity of 4,500 T/D, that will recover over 92% of the sulphur content, of process off-gases.

Jan 1, 1998

By Keith Heasley

As part of the initial investigation and validation of a new boundary-clement formulation for stress modeling in coal mines. the underground stresses and displacements at two multiple-seam coal mines with unique stress problems are modeled and predicted. The new program, LAMODEL, calculates stresses and displacements at the seam level and at requested locations in the overburden or at the surface. Both linear elastic and non-linear seam materials can he used: and surface effects, multiple seams, and multiple mining steps can be simulated. In order to most efficiently use LAMODEL for accurate stress prediction, the program is first calibrated to the site-specific geo-mechanics based on previously observed stress conditions at the mine. For this calibration process. a previously mined area is "stress mapped" by quantifying the observed pillar and strata behavior using a numerical rating system. Then, the site-specific mechanical properties in the model are adjusted to provide the best correlation between the predicted stresses and the observed underground stress rating. Once calibrated, the model is then used to predict future stress problems abead of mining. At the two case study mines, the calibrated models showed good correlation with the observed stresses, and also accurately predicted upcoming high stress areas for preventive action by the mines.

Jan 1, 1998

By C Woodall, G Jardine

The Henty Gold Mine, located in Western Tasmania uses innovative solutions to effectively manage a mining operation in an environmentally sensitive setting and has been presented with several environmental awards. Fill is required as part of the mining method to provide passive ground support, minimise rock exposure and ensure maximum recovery of the small but high-grade orebody. The use of the whole portion of leach residue in the backfill reduces the surface tailing disposal requirements. Therefore, High Density Paste Fill (HDPF) has been selected as the most appropriate fill method to meet these objectives. Additional benefits include the minimisation of excess water from fill and the subsequent need for the collection and treatment of water and slimes. There are minimal equipment requirements during placement, thereby optimising mine resources for production. This paper covers the development of a suitable paste fill system to meet the specific needs of the Henty Gold Mine and the successful commissioning of this system for the first time in Australia.

Jan 1, 1998

By R M. Smart, A T. Harrison

Backfill systems using unconventional cementitious binders have been successfully used in relatively deep and hard rock tabular mines for longwall, scattered stoping and shaft pillar removals. Two unconventional cementitious systems are discussed: A ground granulated blast furnace slag (GGBS) with an activator containing lime. This has been used with a total tailings æstableÆ slurry at a relatively low dosage of less than seven per cent, by mass, based on dry solids. The room and pillar stopes supported with this fill were up to 20 m high and the tailings were relatively high in pyrite. A GGBS binder plus a silicate based activator and gelling agent that virtually eliminated all water drainage (and hence post filling shrinkage). The system used a slurry, but the addition of the activator created a final placed product that had the behaviour of a paste. The system has been successfully used for almost ten years in the following applications: stoping widths (mining heights) above 1.6 m; and shaft pillar removals in seismically active areas at the end of the life of the shafts. This paper discusses the technical merits and costs of the systems and compares them to other fill systems (including true paste systems). the acceleration (normally g, 9.81m/sec2) is increased to a significantly larger (but generally unmeasured and unknown) value, as shown in Figure 1.

Jan 1, 1998

By L. E. Collins

"In western Canada, many new wells contain a significant fraction of H2S. As well, many older wells become increasingly sour over their operating lifetime. For these reasons, there has been increased demand for linepipe and casing for sour service applications in recent years. This paper will review the metallurgical factors which must be considered in designing steels for such applications. IPSCO’s development of linepipe and casing, and experience in fabricating products to meet test standards specified for sour service applications will be summarized. IntroductionWestern Canada produces the majority of Canada’s domestic crude oil and natural gas. A complex system of pipelines has been built to gather the oil and gas from the fields for transport to refining and/or cleaning operations. The gas carried in these pipelines can be either sweet or sour (i.e. containing no H2S or containing H2S) depending on the nature of the field from which it came. Many new fields contain a significant fraction of H2S and many older fields become more sour as their time in production increases. This uncertainty regarding product condition influences the user’s choice of materials for both casing and pipeline applications.It is well known (Merrick, 1989) that hydrogen induced cracking (HIC) will occur in steel when three conditions exist simultaneously: (1) the presence of H2S gas, (2) moisture, and (3) a susceptible material. Steelmakers can only address the latter of these factors. Development of steels to meet test requirements of sour service has been a major focus of IPSCO’s development work for several years."

Jan 1, 1998

A mining operation can be identified as demonstrating prudent management when a number of vital characteristics are evident.All risks and opportunities that are critical to the on-going success of the operation have been identified and are being effectively managed. All significant tasks and events are plan driven. All levels of management visibly support the policies of the operation through their attitude, behaviour and actions as well as words. Supporting evidence for required activity and the outcomes is readily available. Improvement mechanisms are working to advance the key business processes. Everyone is working towards satisfying the needs of the stakeholders of the operation. When these characteristics are integrated with the satisfaction of all legislative requirements, all industry codes and optionally all relevant international management system standards then an operation is fulfilling all the requirements of a Due Diligence Process. The majority of mining operations do not show all of these characteristics and therefore unnecessarily suffer from missed profit opportunity and constant cost pressure, less than acceptable safety and health and environmental performance and consequent poor relations with employees, unions and regulators. In these operations the characteristics to be observed are quite different.Serious incidents are occurring with no sign of a rate decrease. The operation lurches from one panic ituation to another. Management are absent in their leadership, but very active in developing rules and enforcement methodologies. The operation has no history. Re-inventing the wheel with employees who come and go at an alarming rate seems to be forever occurring. All efforts are directed at controlling the business outputs with a strong emphasis on blame. Everyone is trying to look busy to avoid the ever-present cost reduction threats. To change to more prudent management utilising a Due Diligence Process is not theoretically difficult. However it does take clear direction, focussed efforts, supporting actions with appropriate tools and perhaps most importantly an internal desire and drive to become such an operation. A Due Diligence Process is about doing the important things that have to be done, providing the understanding of why they are important, demonstrating proof of activity and effectiveness, and leading the way through effective management.

Jan 1, 1998

By Aïda Espinola

Decontamination of synthetic solutions containing cadmium ions using coconut fibers in natura was investigated in laboratory scale. Cadmium ions, a serious pollutant of water ways, where it is detrimental to the environment, may be absorbed by fish and mollusk used as food, which will, eventually, poison humans; these ions are usually present in minero-metallurgical and electroplating industrial effluents. Usually employed for the aqueous effluents treatment are chemical precipitation, adsorption and electrolytic processes. Precipitation is not effective for cadmium removal, because of the high KpS of the cadmium hydroxide, which requires high pH; only sulfide would be efficient in cases of very small amounts. Some vegetal refuses have shown to be practical for absorption processes of several metallic ions. We have applied coconut (Cocos nucifera) shells, which are extremely abundant over most of the extensive Brazilian coast, in the removal of cadmium: it has been verified, in our laboratory, that the surface of the fiber of this coconut is rich in chemical compounds which are active scavengers for Cd2+. For the optimization of the process, hydrosoluble components existing on the surface of the fiber, which may be deleterious, were previously washed out by water, and variables, such as the pH and the proportion of mass of fiber to volume of solution, were adjusted. As much as 99% of the initial contaminant metallic ion has been eliminated, resulting a solution to be discarded which contains ca. 0.1 ppm; this attends to the maximum impurity legally admitted by the environmental control agency of Rio de Janeiro, FEEMA, for cadmium ions in aqueous effluents to be disposed in rivers and in the Guanabara Bay area.

Jan 1, 1998

By Mark R. Stephenson

Everyone knows that mining is a noisy job, but did you know that you are nine times more likely to lose your hearing than someone who works in a quieter job? If unprotected from noise on the job, by age 50, you will probably need hearing aids. Obviously, the best solution is to engineer out the noise, but that isn?t always im­mediately possible. Until mines are quieter, one way you can help save your vital sense of hearing is to use hearing protectors whenever the noise around you is hazardous. Even if you already have some hearing loss, you can use hearing protectors to prevent your hearing from getting worse. When loud noise is present, proper use of hearing protectors will help miners pre-vent most or all noise-induced hearing loss.

Jan 1, 1998

By D. J. Adams

Cyanide heap leaching is the predominant technology used in processing low-grade gold ores. During closure ora heap leach operation, residual cyanide must be removed from the process and waste solutions, as well as the heap. Biological cyanide oxidation is a proven, economical technology for destroying cyanide in process and waste waters and spent heaps; The use of biological cyanide degradation eliminates the need for toxic or corrosive chemical oxidizers and has- been implemented at full scale at treatment costs usually <$0.50/1,000 gal. The Applied Biosciences biological cyanide destruction (BCND?) process has been demonstrated to effectively treat cyanide, concentrations up to 350 mg/L. Treated process solutions and wastewaters also contained other contaminants such as arsenic, copper, iron, silver. selenium, mercury, nitrate and zinc, much of which was removed in the cyanide degradation process. Under optimal conditions, microorganisms can rapidly oxidize free cyanide in some process solutions from over 250 mg/L down to 0.1 mg/L in 4 to 5 hr. Cyanide is degraded to ammonia and carbon dioxide, with 50%ofthe cyanide carbon liberated as C02. In general, carbon tank based bioreactors degrade cyanide at significantly higher rates than process or wastewater pond configured treatments, which usually degrade cyanide-more rapidly than in heap treatments. Investigation of cell-free enzyme preparations as an alternative to live microbial cyanide degradation shows promise. Advantages of enzymes over live microbes for cyanide degradation include: (I) the ability to tolerate and degrade higher cyanide concentrations (> I ;000 mg/L), (2) nutrients to support live microbial cells are not required, (3) the effects of other toxic contaminants, such as metals, found in mining waters-are eliminated and (4) the potential for greatly increased kinetics.

Jan 1, 1998

By R. S. Austin

One third of the world&apos;s and most US kaolin is produced from Late Cretaceous and Early Tertiary sedimentary strata in Georgia and South Carolina. The kaolin is part of a belt extending to Arkansas of aluminous lateritic deposits, including bauxite. Original sediments were profoundly altered by chemical weathering during Early Tertiary time. Mining exploits those uncommon deposits where extreme leaching and chemical recombination have produced a clay of nearly pure mineral kaolinite. . Its whiteness, brightness, fine particle size, platelet shape, surface chemistry, and chemical composition make kaolin an important pigment, filler, extender and chemical compound in the paper, paint, plastics, ceramics and catalyst industries.

Jan 1, 1998

A very wide range of technologies are utilised in the mining and processing of ores and a great deal of effort is expended in the development of ænew technologiesÆ to improve mining performance and economics. Traditionally, technology and people have been treated as separate aspects of an operation, when in fact they are inextricably linked. The successful implementation of new technologies is entirely dependent upon the actions, enthusiasm and skills of people, both as individuals and working in groups. This paper discusses the role of technology in mining and how new technologies are implemented by the industry. The paper argues that existing technologies have not been fully or adequately utilised and that effort should be re-focussed on the implementation of technologies that have been taken for granted for many years. The need for greater emphasis to be placed on the management of the human-technology interface is discussed.

Jan 1, 1998

By M. Cai

Transformation of the measured borehole deformations induced by stress relief relies on the traditional assumption that the rock is continuous and homogeneous. Systematic and quantitative tests were carried out to check the performance of devices commonly used for measuring borehole deformations within different types of discontinuous rock conditions. Test results provide a reliable basis for considering the influence of discontinuities on in situ stress measurement and for choosing the best measuring device for a given rock type and condition.

Jan 1, 1998

The total cost of horizontal development can be minimised by optimising the cost of each of the component operations (eg drilling, blasting, etc). Component costs should not be minimised. To optimise blasting results (ie the mean advance per round, muckpile characteristics and overbreak), operators need to optimise the blast design and drilling and blasting procedures. The costs of pulling extremely long (say >6 m) rounds, producing unnecessarily fine fragmentation, and minimising overbreak are excessively high. Operators should continually consider how they can shorten the cycle period by saving time at the face. To enable it to be matched to the pertinent rock properties, the blast design needs to be based on as much relevant experience as possible. To develop the most valid correlation between blasting results and blast design, the latter must be implemented carefully and accurately, but without sacrificing speed excessively. The total cost can often be reduced by using: 1. computer-controlled jumbos (to reduce the period and cost of drilling and to increase drilling accuracy); 2. larger diameter (51 mm to 64 mm) and longer (4.5 m to 6 m) blastholes; 3. at least three large diameter ( ¦89 mm) relief holes that are 0.2 m to 0.3 m longer than the blastholes; 4. explosive products that are selected on the basis of proven reliability and overall cost efficiency rather than price; and5. stemming (to increase the amount of effective work done by each kilogram of explosive and, hence, to reduce the powder factor and possibly the number of blastholes and the costs of drilling and initiation). Non-perimeter blastholes should be charged with ANFO or a bulk emulsion of established performance. Upper perimeter blastholes should be charged with a bulk explosive with a much lower effective density. But where geology varies considerably, greatest control over overbreak could possibly be achieved with the versatile pre-assembled charge shown in Figure 1. This paper presents numerous potential ways in which the total cost of development can be minimised. It concentrates on recommending blast design features and the safe, rapid, cost-effective implementation of designs.

Jan 1, 1998

By P. V. Golde, R. A. Poole, G. R. Baiden

"INCO is committed to proceed into the next century using automation and robotics to achieve safety and productivity goals necessary to enhance its competitive position. Stobie Mine, decades old, is the first of its mines to change from labour-intensive to automationassisted techniques. This paper is a synopsis of the progress made during the transition period including overviews of some of the projects as well as some of the difficulties in the assimilation of the technology. BackgroundThe ObjectiveThis paper is an update on remote control and LHD automation installation at Stobie mine. The communications system installed at the mine and the ability to remotely control underground equipment from surface is reviewed (Poole et al., 1996, 1997). It discusses some of the experiences and processes required to further the concept to consolidate the operation of multiple machines under a single operator. It considers the communications systems requirements and their focuses, particularly on the development of systems for the tele-operation of LHDs and drilling machines from surface."

Jan 1, 1998

By T. A. Toney

With new lightweight designs, spirals have become standard equipment in coal preparation plants worldwide. To their credit, spirals typically show very low coal losses to the refuse stream under most operating conditions. However, spirals do tend to separate at cut points in excess of 1.80 S.G. Attempts to obtain lower cut points have typically resulted in coal losses to middlings. Middlings retreatment with secondary spirals is therefore becoming common place. Other forms of retreatment with water-only cyclones, hydrosizers, and recirculation have been attempted with some success. This paper reports on a novel (Patent Applied For) approach to retreating spiral middlings m a heavy-media-cyclone circuit.

Jan 1, 1998

By K. R. Miller

In recent years, surface mine equipment operators in the Campbell County region of the Wyoming Powder River Basin have found new ways to solve old problems. This paper will examine overburden stripping equipment and techniques by focusing on evolving applications for draglines, shovels, and dozers.

Jan 1, 1998

By P Hatherly, H Gurgenci

With the depletion of the mineral reserves that can be mined by surface mining, demand for highly productive and safe underground mines will increase. Underground drill and blast techniques continue to be refined but true æmass productionÆ is difficult to achieve. As is evidenced by the longwall mining of coal, alternative mining methods based on mechanised mining can meet the expectations but the issues of how to effectively cut strong rocks, how to define the orebody and how the mechanised miners can be automated and maintained all need to be addressed. CMTE is working in all of these areas. We believe that the oscillating disc cutter may provide the long sought-after breakthrough in mechanised rock cutting. Disc cutters are one of the most robust designs of cutting tool and the cutters attack the rock in a manner which effects direct tensile breakage. The internal cutter drive and the inertial damping mean that the already low cutter forces are not all transmitted back to the machine, making it possible to design lightweight, flexible mining systems. For orebody delineation drill monitoring, drillhole logging and geophysical imaging are key procedures being developed at CMTE. To automate mining machines, work is progressing well in the development of systems for autonomous vehicle navigation and mining robotics. A strategic contribution to maintenance issues is being made through the development of procedures for automatic analysis of used oils, monitoring the strength of mechanical structures, and operating point optimisation.

Jan 1, 1998

By R. R. Tatiya

"The ultimate aim of a mine design is to determine the development work involved and resources required by adopting one or more specific alternatives. A part of the process is the production of mining plans/designs, an outline of the amount of work and costs involved as well as a prediction of the revenues expected. The paper aims to examine these aspects of mine design using the computer models developed. These models are capable of designing and performing economic analysis for one or more stopes for a continuous orebody. IntroductionTatiya and Allen (1987) have described ’defining stope boundaries using a computer.’ Using the stope boundaries defined or even hypothetical ones, algorithms have been prepared to design the layouts of the following stoping methods: 1. sublevel stoping (longitudinal as well as transverse);2. DTH (Down-the-hole) stoping; and3. flat back cut and fill stoping with posts and pillars.Tatiya (1989) presented this work at the 21st symposium on the application of computers and operations research in the mineral industry (APCOM). Economic analysis of a stope is the additional feature incorporated with these algorithms.The system has been tested by an economic analysis of the three stoping methods modeled for a small portion of a deposit of a copper mining complex. The deposits at this mining complex form lenses of varying shapes and sizes, having low copper content. These chalcopyrite lenses are steeply inclined with a thickness in the range of 5 m to 60 m. The strata are competent and suitable for underground mining.In different sections of the mines different sets of equipment are used to perform the basic unit operations. Some of the ore handling levels in the mines are trackless, the rest are tracked."

Jan 1, 1998

Two key elements in the design of a pastefill or high density backfill system are the preparation of the backfill material and its distribution underground. This paper examines these two areas. Owing to the essentially impervious nature of total mill tailings, preparation of pastefill and high density fill from current tailings involves a physical dewatering process. There are currently three methods available for this process: Vacuum or pressure filters. These represent the ætraditionalÆ approach to the preparation of pastefill. Paste production storage mechanism. This is a thickening/storage mechanism developed with the specific objective of producingpaste/high density backfills. Fluidization. This system utilises silos fitted with simple dewatering devices and nozzles. Recently developed by CANMET, it provides the simplest and most economical approach.This paper describes and compares the three preparation methods, from a practical and an economic point of view. Once the pastefill/high density fill has been prepared and binder added, the backfill must be distributed underground into the stopes. A fundamental factor in the design of a distribution system is the rheology of the material. No two materials will exhibit the same properties, and a sequence of rheological and related testing is required prior to the completion of the design of the underground distribution system. This paper covers the testwork normally required and discusses the fundamental design parameters of pastefill distribution systems. The final section of this paper summarises the use of pastefill at three mines in Canada.

Jan 1, 1998